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CN107162382A - A kind of mud dewatering method - Google Patents

A kind of mud dewatering method Download PDF

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Publication number
CN107162382A
CN107162382A CN201610128211.2A CN201610128211A CN107162382A CN 107162382 A CN107162382 A CN 107162382A CN 201610128211 A CN201610128211 A CN 201610128211A CN 107162382 A CN107162382 A CN 107162382A
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CN
China
Prior art keywords
sludge
drained
delivered
completion
uniform velocity
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Pending
Application number
CN201610128211.2A
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Chinese (zh)
Inventor
胡轶
屈林
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SHENZHEN HUIYUAN ENVIRONMENT TECHNOLOGY Co Ltd
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SHENZHEN HUIYUAN ENVIRONMENT TECHNOLOGY Co Ltd
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Priority to CN201610128211.2A priority Critical patent/CN107162382A/en
Publication of CN107162382A publication Critical patent/CN107162382A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/127Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The present invention discloses a kind of mud dewatering method, and the mud dewatering method comprises the following steps:Dewatered sludge is treated with the concentrated sulfuric acid and carries out acidification, the pH value of sludge to be drained off is adjusted between 3-5;Ferrous sulfate is delivered toward the sludge to be drained off after acidifying, is at the uniform velocity stirred 30 minutes;After the completion of stirring, hydrogen peroxide is delivered toward sludge to be drained off, is at the uniform velocity stirred 35 minutes;After the completion of stirring, magnesium chloride, calcium chloride, calcium oxide are delivered simultaneously toward sludge to be drained off, two hours are at the uniform velocity stirred;Sludge to be drained off after the completion of conditioning is delivered to centrifugal dehydrator and carries out dewater treatment, the dehydration of sludge is completed.The mud dewatering method dehydration rate is high, floor space is small, operating cost is relatively low, cost of investment is relatively low and is easy to operation, and automaticity is high.

Description

A kind of mud dewatering method
Technical field
The present invention relates to a kind of mud dewatering method.
Background technology
In recent years, with the fast development and the effect of energy-saving and emission-reduction policy of national economy, China's town sewage Treatment industry is developed rapidly, and water environment treatment obtains remarkable effect.Bioanalysis is that sewage disposal is the most frequently used Method, and excess sludge is the inevitable outcome during it.Excess sludge is perishable, foul smelling, and contains There are the harmful substances such as a large amount of pathogenic microorganisms, parasitic ovum or heavy metal, if can not effectively be handled Disposal, it is easy to which secondary pollution threatening environment safety and public health are caused to underground water, soil etc..
Because excess sludge moisture content is high, disposal is difficult, therefore excess sludge need to be dehydrated, Zhi Houzai Further disposed.Disposal is further handled for ease of sludge, at present, relevant department of China requires will The moisture control for the sludge that municipal sewage plant is produced is within 60%.However, still lacking energy at present The relatively low, additive amount of consumption is few, production capacity is big and the deep dehydration equipment of processing can be carried out continuously to sludge.
Existing dehydration technique mainly has following several in current industry:
1st, the technology being dehydrated using conventional mechanical pressure
Current dewatering technology of mud mainly has based on mechanical dehydration:Vacuum suction filter method, centrifugal process and press filtration Method.Main plant equipment has:Drum type vacuum filter, Revolving-drum centrifuge, plate compression, belt Filter-press dehydration, screw press dehydration etc..What this type dewatering machine was sloughed is only free clearance water in sludge, Though through dehydration, sludge moisture content still has 75%~85% or so.
2nd, steam, flue gas or other thermals source are typically used using the technology Thermal dehydration of Thermal dehydration, it is not It is the drying of general significance.Common equipment is paddle machine, sleeve machine or fluid bed etc., also has to granulate or spray Mist form improves the thermal efficiency.Heated or UTILIZATION OF VESIDUAL HEAT IN because Thermal dehydration has to rely on thermal source, but due to existing It is uneconomical using steam, it is stable using boiler flue influence system, build independent thermal source cost greatly, utilize Waste heat must change the factors such as original process facility, furthermore, recycling is wanted after desiccation, and can not be because of dehydration And destroy the calorific value that sludge original possesses.Therefore, in a sense, heating power desiccation be with heat energy displacement, " with heat heat exchange " serious thermal balance negative effect occur, but the result is that " with put greatly it is small, not repay Lose ".
3rd, carry out sludge using addition solid powder modification+plate and frame filter press pressure filtering technique addition solid powder and change Property, make modified sludge through plate and frame filter press press filtration by sludge dewatering to moisture content below 60%, but addition Solid powder amount is larger, only increases solids content in sludge, adds ash content in sludge, reduces dirt Content of organics and calorific value in mud etc..Only it is using one kind its essence is without the moisture in reduction sludge Water adds face, a kind of illusion added water more in the face.
4th, the technology being dehydrated using heating power and mechanical pressure Integral sludge it be to use a kind of low-temperature heat source handle Sludge is heated to 150 degree -180 degree, is then dehydrated with screw press, " FKC " that such as Japan releases Machine.This equipment still needs one thermal source of dependence, and this special pressafiner construction is complicated, valency Lattice are expensive, and the cost for changing part is very big;Meanwhile, its production efficiency is relatively low.Therefore, in the industry using not It is many, it is difficult to as a kind of type selecting " focus ".
5th, using current so-called " new " plate and frame filter press of technology of frame filter press filter-press dehydration, Only add be only possible in one layer of diaphragm of rubber, barrier film moment be passed through 0.6~0.8Mpa compressed airs or Water, presses to sludge moment and is dehydrated, moisture percentage in sewage sludge is likely to decrease to 70%-75% or so.
The content of the invention
The present invention is in order to overcome the deficiencies in the prior art, and purpose aims to provide a kind of mud dewatering method, the dirt Mud dewatering solves existing mud dewatering method complexity and the not high technical problem of dewatering rate.
In order to solve above-mentioned technical problem, basic technical scheme proposed by the present invention is:
A kind of mud dewatering method, it comprises the following steps:
Dewatered sludge is treated with the concentrated sulfuric acid and carries out acidification, the pH value of sludge to be drained off is adjusted in 3-5 Between;
Ferrous sulfate is delivered toward the sludge to be drained off after acidifying, is at the uniform velocity stirred 30 minutes;
After the completion of stirring, hydrogen peroxide is delivered toward sludge to be drained off, is at the uniform velocity stirred 35 minutes;
After the completion of stirring, magnesium chloride, calcium chloride, calcium oxide are delivered simultaneously toward sludge to be drained off, is at the uniform velocity stirred Two hours;
Sludge to be drained off after the completion of conditioning is delivered to centrifugal dehydrator and carries out dewater treatment, sludge is completed Dehydration.
Further, the injected volume of the ferrous sulfate is the 0.1%-4% of sludge weight to be drained off.
Further, the injected volume of the hydrogen peroxide is the 1%-7% of sludge weight to be drained off.
Further, the injected volume of the magnesium chloride is the 3%-10% of sludge weight to be drained off.
Further, the calcium chloride is the 2%-9% of sludge weight to be drained off.
Further, the calcium oxide is the 0.1%-5% of sludge weight to be drained off.
The beneficial effects of the invention are as follows:Sludge to be drained off is acidified with the concentrated sulfuric acid and by the pH value of sludge to be drained off Adjust between 3-5, and toward the sludge to be drained off dispensing ferrous sulfate and hydrogen peroxide after acidifying and at the uniform velocity Stirring, what above step can greatly improve sludge can degree of dehydration.Then again toward sludge to be drained off simultaneously Deliver magnesium chloride, calcium chloride, calcium oxide and at the uniform velocity stir, the acidity of sludge conditioning system can be neutralized, made Sludge and filtrate are attained by defined acid-base property requirement.Centrifugal dehydrator is to the dirt to be drained off after the completion of conditioning Mud carries out dewater treatment, completes the dehydration of sludge.Learnt from above-mentioned dehydration, sludge dewatering of the invention Technological process is succinct, is easy to operation, and the medicament price needed for sludge conditioning is low, so as to save sludge Dewater treatment cost.
Brief description of the drawings
Fig. 1 provides a kind of flow chart of mud dewatering method for the embodiment of the present invention.
Embodiment
Below with reference to accompanying drawing 1, the present invention is described further, but should not limit the present invention's with this Protection domain.For convenience of explanation and understand technical scheme, illustrate below used in orientation The orientation that word is shown by accompanying drawing is defined.
In step sl, it is acidified sludge to be drained off.Herein, the present embodiment uses the concentrated sulfuric acid to dirt to be drained off Mud carries out acidification, and the pH value of sludge to be drained off is adjusted between 3-5.With under acid environment, dense sulphur The lysis effect of acid is better than hydrochloric acid, and the concentrated sulfuric acid has strong oxidizing property, therefore selection is adjusted using the concentrated sulfuric acid Save sludge acid-base property.
In step s 2, deliver ferrous sulfate and at the uniform velocity stir.Herein, toward the sludge to be drained off after acidifying Ferrous sulfate is delivered, is at the uniform velocity stirred 30 minutes, the injected volume of ferrous sulfate herein is sludge weight to be drained off The 0.1%-4% of amount.
In step s3, deliver hydrogen peroxide and at the uniform velocity stir.Herein, it is past after the completion of step S2 stirrings Sludge to be drained off delivers hydrogen peroxide, at the uniform velocity stirs 35 minutes, and the injected volume of hydrogen peroxide herein is to treat The 1%-7% of dewatered sludge weight.
In step s 4, while delivering magnesium chloride, calcium chloride, calcium oxide and at the uniform velocity stirring.Herein, walk After the completion of rapid S3 stirrings, magnesium chloride, calcium chloride, calcium oxide are delivered simultaneously toward sludge to be drained off, is at the uniform velocity stirred Mix two hours, the injected volume of magnesium chloride is the 3%-10% of sludge weight to be drained off, calcium chloride is to be drained off The 2%-9% of sludge weight, calcium oxide is the 0.1%-5% of sludge weight to be drained off.
In step s 5, centrifugal dehydrator dewater treatment.Herein, by the sludge to be drained off after the completion of conditioning It is delivered to centrifugal dehydrator and carries out dewater treatment, completes the dehydration of sludge.Herein, the sludge after processing, contains Water rate can be controlled in less than 60%.
Sludge to be drained off is acidified with the concentrated sulfuric acid and adjusts the pH value of sludge to be drained off between 3-5, and Ferrous sulfate and hydrogen peroxide are delivered toward the sludge to be drained off after acidifying and is at the uniform velocity stirred, and above step can be big The earth improve sludge can degree of dehydration.Then again toward sludge to be drained off simultaneously deliver magnesium chloride, calcium chloride, Calcium oxide is simultaneously at the uniform velocity stirred, and can be neutralized the acidity of sludge conditioning system, sludge and filtrate is attained by rule Fixed acid-base property requirement.
Learnt from above-mentioned dehydration, mud dewatering method provided in an embodiment of the present invention has advantages below:
1st, floor space is small.In sludge dehydration process, sludge reaction time control in very short scope, Therefore the reaction vessel volume required for is smaller, simultaneously because technological process is more succinct, required equipment, Number of containers is also seldom;
2nd, operating cost is relatively low.Medicament in this programme required for sludge conditioning is inexpensive, and dosage Less, therefore, the processing cost shared equally is not also relatively high;
3rd, cost of investment is relatively low.Because program flow is succinct, required equipment, number of containers are few, Therefore the one-time investment in terms of civil engineering, equipment is relatively low;
4th, it is easy to operation, automaticity is high.Because technological process is succinct, therefore it is easier to realize automatically Change control, streamline operation.
Embodiment one
Certain percolate treatment plant, takes 1 ton of the sludge to be drained off of moisture content 90%, is added into sludge to be drained off The concentrated sulfuric acid, and the pH value of sludge to be drained off is adjusted to 3.5, complete after acidifying, delivered toward sludge to be drained off 20 kilograms of ferrous sulfate, is at the uniform velocity stirred 30 minutes.After the completion of stirring, 60 were delivered toward sludge to be drained off Kilogram hydrogen peroxide, at the uniform velocity stir 35 minutes.After the completion of stirring, 50 are delivered simultaneously toward sludge to be drained off Kilogram magnesium chloride, 40 kilograms of calcium chloride, 30 kilograms of calcium oxide and at the uniform velocity stir two hours.With After the completion of upper process, the sludge for nursing one's health completion is delivered to centrifugal dehydrator and carries out dewater treatment, after processing Sludge, it is 51.04% to measure moisture content.
Embodiment two
Certain municipal sewage plant, takes 1 ton of the sludge of moisture content 95%, dense sulphur is added into sludge to be drained off Acid, and the pH value of sludge to be drained off is adjusted to 4, complete after acidifying, 40,000 are delivered toward sludge to be drained off Gram ferrous sulfate, at the uniform velocity stir 30 minutes.After the completion of stirring, 70 kilograms were delivered toward sludge to be drained off Hydrogen peroxide, at the uniform velocity stir 35 minutes.After the completion of stirring, 100,000 are delivered simultaneously toward sludge to be drained off Gram magnesium chloride, 90 kilograms of calcium chloride, 50 kilograms of calcium oxide and at the uniform velocity stir two hours.More than After the completion of process, the sludge for nursing one's health completion is delivered to centrifugal dehydrator and carries out dewater treatment, the dirt after processing Mud, it is 48.03% to measure moisture content.
Embodiment three
Certain municipal sewage plant, takes 1 ton of the sludge of moisture content 95%, dense sulphur is added into sludge to be drained off Acid, and the pH value of sludge to be drained off is adjusted to 3, complete after acidifying, 5,000 are delivered toward sludge to be drained off Gram ferrous sulfate, at the uniform velocity stir 30 minutes.After the completion of stirring, 15 kilograms were delivered toward sludge to be drained off Hydrogen peroxide, at the uniform velocity stir 35 minutes.After the completion of stirring, 35 kilograms are delivered simultaneously toward sludge to be drained off Magnesium chloride, 20 kilograms of calcium chloride, 5 kilograms of calcium oxide and at the uniform velocity stir two hours.Above process After the completion of, by nurse one's health complete sludge be delivered to centrifugal dehydrator carry out dewater treatment, the sludge after processing, It is 58.8% to measure moisture content.
The announcement and teaching of book according to the above description, those skilled in the art in the invention can also be to above-mentioned Embodiment is changed and changed.Therefore, the invention is not limited in specific reality disclosed and described above Mode is applied, some modifications and changes to the present invention should also be as falling into the scope of the claims of the present invention It is interior.Although in addition, having used some specific terms in this specification, these terms are intended merely to conveniently Illustrate, any limitation is not constituted to the present invention.

Claims (6)

1. a kind of mud dewatering method, it is characterised in that comprise the following steps:
Dewatered sludge is treated with the concentrated sulfuric acid and carries out acidification, the pH value of sludge to be drained off is adjusted in 3-5 Between;
Ferrous sulfate is delivered toward the sludge to be drained off after acidifying, is at the uniform velocity stirred 30 minutes;
After the completion of stirring, hydrogen peroxide is delivered toward sludge to be drained off, is at the uniform velocity stirred 35 minutes;
After the completion of stirring, magnesium chloride, calcium chloride, calcium oxide are delivered simultaneously toward sludge to be drained off, is at the uniform velocity stirred Two hours;
Sludge to be drained off after the completion of conditioning is delivered to centrifugal dehydrator and carries out dewater treatment, sludge is completed Dehydration.
2. mud dewatering method according to claim 1, it is characterised in that the ferrous sulfate Injected volume is the 0.1%-4% of sludge weight to be drained off.
3. mud dewatering method according to claim 1, it is characterised in that the hydrogen peroxide Injected volume is the 1%-7% of sludge weight to be drained off.
4. mud dewatering method according to claim 1, it is characterised in that the throwing of the magnesium chloride It is high-volume the 3%-10% of sludge weight to be drained off.
5. mud dewatering method according to claim 1, it is characterised in that the calcium chloride is to treat The 2%-9% of dewatered sludge weight.
6. mud dewatering method according to claim 1, it is characterised in that the calcium oxide is to treat The 0.1%-5% of dewatered sludge weight.
CN201610128211.2A 2016-03-07 2016-03-07 A kind of mud dewatering method Pending CN107162382A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610128211.2A CN107162382A (en) 2016-03-07 2016-03-07 A kind of mud dewatering method

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675614A (en) * 2018-06-14 2018-10-19 广州市浩逸环保科技有限公司 A kind of sludge environment-friendly furnace drying method
CN110092569A (en) * 2019-04-15 2019-08-06 华南理工大学 A kind of mud dewatering method
CN110590121A (en) * 2019-08-30 2019-12-20 中山大学 A kind of sludge dewatering agent and sludge dehydration method
CN111635113A (en) * 2020-04-27 2020-09-08 同济大学 A method for sludge dewatering and conditioning using calcium peroxide
CN111807676A (en) * 2020-05-31 2020-10-23 浙江工业大学 A method of ferrous iron-induced calcium peroxide coupled with polymer flocculants to promote sludge dewatering
CN119281790A (en) * 2024-11-05 2025-01-10 东北林业大学 Resource treatment method for printing and dyeing sludge building materials based on non-burning low-temperature process

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464440A (en) * 2010-11-05 2012-05-23 广东溢达纺织有限公司 Method for reducing physicochemical and biochemical mixed sludge
WO2012146324A1 (en) * 2011-04-29 2012-11-01 Feralco Ab Method for treatment of sludge from water and wastewater treatment plants with chemical treatment
KR101235889B1 (en) * 2011-02-25 2013-02-21 현대제철 주식회사 Method for Water Treatment
CN103723906A (en) * 2013-12-20 2014-04-16 湖南大学 Deep dehydration recycling method for livestock and poultry feces
CN104176900A (en) * 2014-08-21 2014-12-03 北京同创碧源水务科技发展有限公司 Deep dehydration method of sludge after domestic sewage treatment
CN104891779A (en) * 2015-06-29 2015-09-09 北京工业大学 Combination type efficient sludge dewatering conditioning method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464440A (en) * 2010-11-05 2012-05-23 广东溢达纺织有限公司 Method for reducing physicochemical and biochemical mixed sludge
KR101235889B1 (en) * 2011-02-25 2013-02-21 현대제철 주식회사 Method for Water Treatment
WO2012146324A1 (en) * 2011-04-29 2012-11-01 Feralco Ab Method for treatment of sludge from water and wastewater treatment plants with chemical treatment
CN103723906A (en) * 2013-12-20 2014-04-16 湖南大学 Deep dehydration recycling method for livestock and poultry feces
CN104176900A (en) * 2014-08-21 2014-12-03 北京同创碧源水务科技发展有限公司 Deep dehydration method of sludge after domestic sewage treatment
CN104891779A (en) * 2015-06-29 2015-09-09 北京工业大学 Combination type efficient sludge dewatering conditioning method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675614A (en) * 2018-06-14 2018-10-19 广州市浩逸环保科技有限公司 A kind of sludge environment-friendly furnace drying method
CN110092569A (en) * 2019-04-15 2019-08-06 华南理工大学 A kind of mud dewatering method
CN110590121A (en) * 2019-08-30 2019-12-20 中山大学 A kind of sludge dewatering agent and sludge dehydration method
CN111635113A (en) * 2020-04-27 2020-09-08 同济大学 A method for sludge dewatering and conditioning using calcium peroxide
CN111807676A (en) * 2020-05-31 2020-10-23 浙江工业大学 A method of ferrous iron-induced calcium peroxide coupled with polymer flocculants to promote sludge dewatering
CN119281790A (en) * 2024-11-05 2025-01-10 东北林业大学 Resource treatment method for printing and dyeing sludge building materials based on non-burning low-temperature process

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