CN107151459A - A kind of processing method of waste and old fishing net - Google Patents
A kind of processing method of waste and old fishing net Download PDFInfo
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- CN107151459A CN107151459A CN201710426857.3A CN201710426857A CN107151459A CN 107151459 A CN107151459 A CN 107151459A CN 201710426857 A CN201710426857 A CN 201710426857A CN 107151459 A CN107151459 A CN 107151459A
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08K5/00—Use of organic ingredients
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- C08K5/57—Organo-tin compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
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- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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Abstract
Technical field is recycled the present invention relates to fishing net, a kind of processing method of waste and old fishing net is disclosed, comprises the following steps:(1)Discarded fishing net is classified according to the difference of material, obtained same category is concentrated and cleaned, using the soak of alkalescence, the spot of the mixing such as the salinity, protein, grease of fishing deposited thereon can be removed, the toughness of fishing net can be recovered after cleaning to certain level;(2)Fishing net after flushing is put into 80 90 DEG C of water-bath and submerged, hydrone is set to be deep into inside fishing net, add n-butanol, on the one hand the dirt hidden in scratch can further be removed, on the other hand solvent can be used as, carry out next step it is ultrasonically treated in, improve ultrasonotomography pollutant effect;(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.0 1.3% is added, is uniformly mixed, extruding pelletization is carried out in feeding double screw extruder.
Description
Technical field
The invention belongs to fishing net recycling technical field, and in particular to a kind of processing method of waste and old fishing net.
Background technology
According to archeological researches:The originator of Chinese fishing culture, before can tracing back in 15 thousand to 50,000 years away from the present
Paleolithic period, fish-bone is the earliest carrier of fishing culture.Hit when fishing and hunting is produced by manual capture, bastinade stone, make grid interception, cofferdam
Pool is exhausted, develops into that hook fishes arrow to penetrate, pitch gill net and drag for, boomerang is thrown when cage card and boat oar drive and take, fishery starts as the warp of the mankind earliest
One of form of helping;Understanding with the mankind to the subject of labour, identification its kind and habit, in time are evolved to from random intake
Catch and store up, fishing culture takes the lead in obtaining material achievement truly in production field, and thus derive other texts
Change form.
As people progressively go deep into the exploration of Yu Haiyang, the development of fishing industry becomes to advance by leaps and bounds, and greatly drives
The consumption of the development of fishing gear, wherein fishing net increases year by year, and various Novel fishing net features are good, is easy to use, and at the same time,
The waste and old product for causing fishing net are largely generated, and occupy great parking space, and intractability and cost are larger, easily cause pollution
Deng.
The content of the invention
The purpose of the present invention is there is provided a kind of processing method of waste and old fishing net, using a series of the problem of being directed to existing
Processing step, remove the deposit on fishing net surface, high polymer material recycled again, cost is reduced, prevented
Pollution.
The present invention is achieved by the following technical solutions:
A kind of processing method of waste and old fishing net, comprises the following steps:
(1)Discarded fishing net is classified according to the difference of material, the fishing net of identical material is classified as a class, is invested in cleaning cylinder
In, soak 1-2 hours, alkaline soak is loaded with cleaning cylinder, is made up in parts by weight of following component:Sodium carbonate 50-
55 parts, 25-35 parts of methylcellulose, 20-25 parts of polyvinyl alcohol, 15-20 parts of saponin, 10-15 parts of pinolenic acid potassium, sodium alginate 8-
10 parts, 5-8 parts of SODIUM PERCARBONATE, 4-6 parts of tribromosalicylanilide, 3-5 parts of mixing enzyme preparation, 2-3 parts of alumina powder, water 260-
300 parts, after immersion, stirring and washing 20-30 minutes reuses clear water and rinsed 2-3 times;
(2)Fishing net after flushing is put into 80-90 DEG C of water-bath and submerged, is heated 30-40 minutes, is 200-230 in rotating speed
Stirred 10-15 minutes under rev/min, the n-butanol for accounting for that water-bath reclaimed water mass fraction is 3-5% be uniformly added into whipping process,
After insulation 60-80 minutes, 30-40 DEG C is cooled to, multiple-frequency supersonic is carried out and disperses 5-10 minutes, pull fishing net out, cleaned using soap lye
1-2 times, clear water is rinsed 2-3 times;
(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.0-1.3%, stirring is added
It is well mixed, extruding pelletization is carried out in feeding double screw extruder, particle is recycled through supercooling, available for brand-new fishing net
Processing, addition accounts for the 10-15% best results of brand-new fishing net material.
It is used as further improvement of these options, step(1)Described in mixing enzyme preparation according to mass percent meter
Contain following components:Protease accounts for 50-60%, lipase and accounts for 20-30%, remaining as cellulase.
It is used as further improvement of these options, step(2)It is in 25-30KHz, 55-60W/ that middle multiple-frequency supersonic is scattered
cm2With 0.85-0.88MHz, 5-10W/cm2Compound lower progress.
It is used as further improvement of these options, step(3)Described in mixed aid contain according to mass percent meter
There is following component:Neck phthalic acid dihexyl accounts for 10-15%, BHT and accounts for 10-15%, maleic acid dibutyl
Tin, which accounts for 5-10%, benzophenone and accounts for 5-10%, TBHP and account for 3-5%, the oxygen vinethene organic phosphate disodium salt of laurate four, to be accounted for
5-7%, zinc oxide account for 0.3-0.5%, remaining as diethylene glycol.
The present invention has advantages below compared with prior art:In order to which the waste and old product for solving fishing net are largely generated, pole is occupied
Big parking space, intractability and cost are larger, the problems such as easily causing pollution, and the invention provides a kind of place of waste and old fishing net
Reason method, comprises the following steps:(1)Discarded fishing net is classified according to the difference of material, obtained same category is concentrated
Cleaned, using the soak of alkalescence, the spot of the mixing such as the salinity, protein, grease of fishing deposited thereon can be removed, added
Plus rubbing agent under agitation dirt-removing power strengthen, the toughness of fishing net can be recovered after cleaning to certain level;(2)It will rinse
Fishing net afterwards is put into 80-90 DEG C of water-bath and submerged, and hydrone is deep into inside fishing net, adds n-butanol, one side energy
It is enough further to remove the dirt hidden in scratch, on the other hand can as solvent, carry out next step it is ultrasonically treated in, carry
The effect of high ultrasound degradation of contaminant;(3)Fishing net after rinsing is dried, molten state is heated to, addition mass fraction is 1.0-
1.3% mixed aid, the mixed aid can improve plasticity, inoxidizability, heat endurance, the photostability of high polymer material
And amalgamation, it is uniformly mixed, carrying out extruding pelletization in feeding double screw extruder can be reused.
Embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
A kind of processing method of waste and old fishing net, comprises the following steps:
(1)Discarded fishing net is classified according to the difference of material, the fishing net of identical material is classified as a class, is invested in cleaning cylinder
In, soak 1 hour, alkaline soak is loaded with cleaning cylinder, is made up in parts by weight of following component:50 parts of sodium carbonate,
25 parts of methylcellulose, 20 parts of polyvinyl alcohol, 15 parts of saponin, 10 parts of pinolenic acid potassium, 8 parts of sodium alginate, 5 parts of SODIUM PERCARBONATE, three
4 parts of bromine salicylanilide, 3 parts of mixing enzyme preparation, 2 parts of alumina powder, 260 parts of water, after immersion, stirring and washing 20 minutes, then make
Rinsed 2 times with clear water;
(2)Fishing net after flushing is put into 80 DEG C of water-bath and submerged, is heated 30 minutes, is stirred in the case where rotating speed is 200 rev/min
Mix 10 minutes, the n-butanol for accounting for that water-bath reclaimed water mass fraction is 3%, after being incubated 60 minutes, cooling are uniformly added into whipping process
To 30 DEG C, carry out multiple-frequency supersonic and disperse 5 minutes, pull fishing net out, use soap lye to clean 1 time, clear water is rinsed 2 times;
(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.0%, stirring mixing is added
Uniformly, extruding pelletization is carried out in feeding double screw extruder, particle is recycled through supercooling, available for adding for brand-new fishing net
Work, addition accounts for 10% best results of brand-new fishing net material.
It is used as further improvement of these options, step(1)Described in mixing enzyme preparation according to mass percent meter
Contain following components:Protease accounts for 50%, lipase and accounts for 20%, remaining as cellulase.
It is used as further improvement of these options, step(2)It is in 25KHz, 55W/cm that middle multiple-frequency supersonic is scattered2With
0.85MHz、5W/cm2Compound lower progress.
It is used as further improvement of these options, step(3)Described in mixed aid contain according to mass percent meter
There is following component:Neck phthalic acid dihexyl account for 10%, BHT account for 10%, dibutyitin maleate account for 5%,
Benzophenone, which accounts for 5%, TBHP and accounts for the oxygen vinethene organic phosphate disodium salt of 3%, laurate four and account for 5%, zinc oxide, to be accounted for
0.3%th, remaining as diethylene glycol.
Embodiment 2
A kind of processing method of waste and old fishing net, comprises the following steps:
(1)Discarded fishing net is classified according to the difference of material, the fishing net of identical material is classified as a class, is invested in cleaning cylinder
In, soak 1.5 hours, alkaline soak is loaded with cleaning cylinder, is made up in parts by weight of following component:Sodium carbonate 52
Part, 30 parts of methylcellulose, 22 parts of polyvinyl alcohol, 17 parts of saponin, 12 parts of pinolenic acid potassium, 9 parts of sodium alginate, 6 parts of SODIUM PERCARBONATE,
5 parts of tribromosalicylanilide, 4 parts of mixing enzyme preparation, 2.5 parts of alumina powder, 280 parts of water, after immersion, stirring and washing 25 minutes,
Clear water is reused to rinse 2 times;
(2)Fishing net after flushing is put into 85 DEG C of water-bath and submerged, is heated 35 minutes, is stirred in the case where rotating speed is 210 rev/min
Mix 12 minutes, the n-butanol for accounting for that water-bath reclaimed water mass fraction is 4%, after being incubated 70 minutes, cooling are uniformly added into whipping process
To 35 DEG C, carry out multiple-frequency supersonic and disperse 7 minutes, pull fishing net out, use soap lye to clean 1 time, clear water is rinsed 2 times;
(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.2%, stirring mixing is added
Uniformly, extruding pelletization is carried out in feeding double screw extruder, particle is recycled through supercooling, available for adding for brand-new fishing net
Work, addition accounts for 13% best results of brand-new fishing net material.
It is used as further improvement of these options, step(1)Described in mixing enzyme preparation according to mass percent meter
Contain following components:Protease accounts for 55%, lipase and accounts for 25%, remaining as cellulase.
It is used as further improvement of these options, step(2)It is in 28KHz, 57W/cm that middle multiple-frequency supersonic is scattered2With
0.86MHz、7W/cm2Compound lower progress.
It is used as further improvement of these options, step(3)Described in mixed aid contain according to mass percent meter
There is following component:Neck phthalic acid dihexyl account for 12%, BHT account for 13%, dibutyitin maleate account for 7%,
Benzophenone, which accounts for 7%, TBHP and accounts for the oxygen vinethene organic phosphate disodium salt of 4%, laurate four and account for 6%, zinc oxide, to be accounted for
0.4%th, remaining as diethylene glycol.
Embodiment 3
A kind of processing method of waste and old fishing net, comprises the following steps:
(1)Discarded fishing net is classified according to the difference of material, the fishing net of identical material is classified as a class, is invested in cleaning cylinder
In, soak 2 hours, alkaline soak is loaded with cleaning cylinder, is made up in parts by weight of following component:55 parts of sodium carbonate,
35 parts of methylcellulose, 25 parts of polyvinyl alcohol, 20 parts of saponin, 15 parts of pinolenic acid potassium, 10 parts of sodium alginate, 8 parts of SODIUM PERCARBONATE, three
6 parts of bromine salicylanilide, 5 parts of mixing enzyme preparation, 3 parts of alumina powder, 300 parts of water, after immersion, stirring and washing 30 minutes, then make
Rinsed 3 times with clear water;
(2)Fishing net after flushing is put into 90 DEG C of water-bath and submerged, is heated 40 minutes, is stirred in the case where rotating speed is 230 rev/min
Mix 15 minutes, the n-butanol for accounting for that water-bath reclaimed water mass fraction is 5%, after being incubated 80 minutes, cooling are uniformly added into whipping process
To 40 DEG C, carry out multiple-frequency supersonic and disperse 10 minutes, pull fishing net out, use soap lye to clean 2 times, clear water is rinsed 3 times;
(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.3%, stirring mixing is added
Uniformly, extruding pelletization is carried out in feeding double screw extruder, particle is recycled through supercooling, available for adding for brand-new fishing net
Work, addition accounts for 15% best results of brand-new fishing net material.
It is used as further improvement of these options, step(1)Described in mixing enzyme preparation according to mass percent meter
Contain following components:Protease accounts for 60%, lipase and accounts for 30%, remaining as cellulase.
It is used as further improvement of these options, step(2)It is in 30KHz, 60W/cm that middle multiple-frequency supersonic is scattered2With
0.88MHz、10W/cm2Compound lower progress.
It is used as further improvement of these options, step(3)Described in mixed aid contain according to mass percent meter
There is following component:Neck phthalic acid dihexyl, which accounts for 15%, BHT and accounts for 15%, dibutyitin maleate, to be accounted for
10%th, benzophenone, which accounts for 10%, TBHP and accounts for the oxygen vinethene organic phosphate disodium salt of 5%, laurate four, accounts for 7%, zinc oxide
Account for 0.5%, remaining as diethylene glycol.
Contrast test
Waste and old fishing net is reclaimed using embodiment 1-3 method processing respectively, while with existing processing method as a control group, will
Processing cost and the benefit brought carry out Integrated comparative, and comparative result is recorded into as shown in the table:
It can be seen that by comparing:The present invention is handling the waste and old more reasonable science of fishing line method, using a series of technique
Step, removes the deposit on fishing net surface, high polymer material is recycled again, cost is reduced, it is therefore prevented that pollution.
Claims (4)
1. a kind of processing method of waste and old fishing net, it is characterised in that comprise the following steps:
(1)Discarded fishing net is classified according to the difference of material, the fishing net of identical material is classified as a class, is invested in cleaning cylinder
In, soak 1-2 hours, alkaline soak is loaded with cleaning cylinder, is made up in parts by weight of following component:Sodium carbonate 50-
55 parts, 25-35 parts of methylcellulose, 20-25 parts of polyvinyl alcohol, 15-20 parts of saponin, 10-15 parts of pinolenic acid potassium, sodium alginate 8-
10 parts, 5-8 parts of SODIUM PERCARBONATE, 4-6 parts of tribromosalicylanilide, 3-5 parts of mixing enzyme preparation, 2-3 parts of alumina powder, water 260-
300 parts, after immersion, stirring and washing 20-30 minutes reuses clear water and rinsed 2-3 times;
(2)Fishing net after flushing is put into 80-90 DEG C of water-bath and submerged, is heated 30-40 minutes, is 200-230 in rotating speed
Stirred 10-15 minutes under rev/min, the n-butanol for accounting for that water-bath reclaimed water mass fraction is 3-5% be uniformly added into whipping process,
After insulation 60-80 minutes, 30-40 DEG C is cooled to, multiple-frequency supersonic is carried out and disperses 5-10 minutes, pull fishing net out, cleaned using soap lye
1-2 times, clear water is rinsed 2-3 times;
(3)Fishing net after rinsing is dried, molten state is heated to, the mixed aid that mass fraction is 1.0-1.3%, stirring is added
It is well mixed, extruding pelletization is carried out in feeding double screw extruder, particle is recycled through supercooling, available for brand-new fishing net
Processing, addition accounts for the 10-15% best results of brand-new fishing net material.
2. a kind of processing method of waste and old fishing net as claimed in claim 1, it is characterised in that step(1)Described in mixed enzyme
Preparation contains following components according to mass percent meter:Protease accounts for 50-60%, lipase and accounts for 20-30%, remaining as cellulose
Enzyme.
3. a kind of processing method of waste and old fishing net as claimed in claim 1, it is characterised in that step(2)Middle multiple-frequency supersonic disperses
It is in 25-30KHz, 55-60W/cm2With 0.85-0.88MHz, 5-10W/cm2Compound lower progress.
4. a kind of processing method of waste and old fishing net as claimed in claim 1, it is characterised in that step(3)Described in mixing help
Agent contains following component according to mass percent meter:Neck phthalic acid dihexyl accounts for 10-15%, BHT and accounted for
10-15%, dibutyitin maleate, which account for 5-10%, benzophenone and account for 5-10%, TBHP, accounts for 3-5%, the oxygen of laurate four
Vinethene organic phosphate disodium salt accounts for 5-7%, zinc oxide and accounts for 0.3-0.5%, remaining as diethylene glycol.
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Cited By (1)
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CN110904667A (en) * | 2019-11-20 | 2020-03-24 | 利辛县雨果家居有限公司 | Method for cleaning stains on surface of woven handicraft |
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CN104630916A (en) * | 2013-11-11 | 2015-05-20 | 柯汉哲 | Waste fishing net recycling method |
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2017
- 2017-06-08 CN CN201710426857.3A patent/CN107151459A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104364364A (en) * | 2012-06-11 | 2015-02-18 | 宝洁公司 | Detergent composition |
CN104630916A (en) * | 2013-11-11 | 2015-05-20 | 柯汉哲 | Waste fishing net recycling method |
CN104387731A (en) * | 2014-08-28 | 2015-03-04 | 天津市利顺塑料制品有限公司 | Waste plastic modification recovery method |
Non-Patent Citations (1)
Title |
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夏星辉等: "应用化学清洗剂去除包气带石油污染物的实验研究", 《环境化学》 * |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110904667A (en) * | 2019-11-20 | 2020-03-24 | 利辛县雨果家居有限公司 | Method for cleaning stains on surface of woven handicraft |
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