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CN107142012A - A kind of TFT LCD displays nano protective film - Google Patents

A kind of TFT LCD displays nano protective film Download PDF

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Publication number
CN107142012A
CN107142012A CN201710470122.0A CN201710470122A CN107142012A CN 107142012 A CN107142012 A CN 107142012A CN 201710470122 A CN201710470122 A CN 201710470122A CN 107142012 A CN107142012 A CN 107142012A
Authority
CN
China
Prior art keywords
parts
nano
resin
protective film
tft
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710470122.0A
Other languages
Chinese (zh)
Inventor
白航空
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Huike Precision Mould Co Ltd
Original Assignee
Hefei Huike Precision Mould Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Huike Precision Mould Co Ltd filed Critical Hefei Huike Precision Mould Co Ltd
Priority to CN201710470122.0A priority Critical patent/CN107142012A/en
Publication of CN107142012A publication Critical patent/CN107142012A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2244Oxides; Hydroxides of metals of zirconium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of TFT LCD displays nano protective film, include the raw material of following parts by weight:30 42 parts of silicon-fluorine polymer thing, 8 11 parts of nano zircite, 6 12 parts of nano zine oxide, 9 14 parts of nano-titanium oxide, 22 34 parts of epoxy resin, 11 18 parts of urethane acrylate, 7 16 parts of UV diluting monomers, 8 14 parts of binding agent.The present invention makes the hardened layer of film surface reach 3~9H, wear-resisting to be subjected to 0000# steel wools, using 2kg pressure, rubs more than 50 times back and forth, does not have cut in anti-scratch layer surface, the scratch resistant abrasion resistant effect of the nano protective film is extremely excellent.

Description

A kind of TFT-LCD display screens nano protective film
Technical field
The present invention relates to TFT-LCD display screen technologies field, and in particular to a kind of TFT-LCD display screens nano protective film.
Background technology
As science and technology is maked rapid progress, modern does not almost take off relation with action electronic device, action in the market Electronic installation has many types, for example:Mobile phone, PDA, GPS, e-book etc., have design screen or even are also designed to touch Screen, can cause the abrasion gradually of screen due to these action electronic devices are used for a long time, thus it is promising this and design screen guarantor Cuticula is produced.But the screen protecting film existed currently on the market is plastic film mostly, its impact resistance is poor, definition It is poor, easily the marking is left, and service life is shorter after human hand touch, people need ceaselessly to change electronic product protection Film, therefore virtually add the purchase cost of screen protecting film.
The content of the invention
The present invention is intended to provide a kind of TFT-LCD display screens nano protective film.
The present invention provides following technical scheme:
A kind of TFT-LCD display screens nano protective film, includes the raw material of following parts by weight:30-42 parts of silicon-fluorine polymer thing, 8-11 parts of nano zircite, 6-12 parts of nano zine oxide, 9-14 parts of nano-titanium oxide, 22-34 parts of epoxy resin, polyurethane propylene 11-18 parts of acid esters, 7-16 parts of UV diluting monomers, 8-14 parts of binding agent.
The nano zircite, nano zine oxide, nano-titanium oxide particle diameter are between 30~200nm.
The silicon-fluorine polymer thing is poly- trifluoro propyl methyl cyclotrisiloxane, poly- trifluoropropylmethyldichlorosilane, poly- two One or more in the poly- seven fluorine butyl methyl acrylate of methylsiloxane-b-.
The photoresist is polyvinyl alcohol laurate, light-sensitive polyimide, the ultraviolet negative photoresist of epoxy radicals or cyclisation Polyisoprene-two-fold nitrogen type ultraviolet photoresist.
The epoxy resin is bisphenol A-type or glycidyl ester type epoxy resin and fatty amine, aliphatic cyclic amine, aromatic amine, poly- The blend of acid amides or acid anhydrides.
The binding agent is epoxy resin, acrylate, acrylic resin, polyester resin, polyamide, poly- ammonia One or more in ester resin, polyimide resin, polyvinyl alcohol resin, polyketone resin, phenolic resin, titanate coupling agent Mixing.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention makes the hardened layer of film surface reach 3~9H, It is wear-resisting to be subjected to 0000# steel wools, using 2kg pressure, rub more than 50 times back and forth, there is no cut in anti-scratch layer surface, The scratch resistant abrasion resistant effect of the nano protective film is extremely excellent.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
A kind of TFT-LCD display screens nano protective film of embodiment 1, includes the raw material of following parts by weight:Silicon-fluorine polymer thing 30 parts, 8 parts of nano zircite, 6 parts of nano zine oxide, 9 parts of nano-titanium oxide, 22 parts of epoxy resin, urethane acrylate 11 Part, 7 parts of UV diluting monomers, 8 parts of binding agent.
The nano zircite, nano zine oxide, nano-titanium oxide particle diameter are between 30~200nm.
The silicon-fluorine polymer thing is poly- trifluoro propyl methyl cyclotrisiloxane, poly- trifluoropropylmethyldichlorosilane, poly- two One or more in the poly- seven fluorine butyl methyl acrylate of methylsiloxane-b-.
The photoresist is polyvinyl alcohol laurate, light-sensitive polyimide, the ultraviolet negative photoresist of epoxy radicals or cyclisation Polyisoprene-two-fold nitrogen type ultraviolet photoresist.
The epoxy resin is bisphenol A-type or glycidyl ester type epoxy resin and fatty amine, aliphatic cyclic amine, aromatic amine, poly- The blend of acid amides or acid anhydrides.
The binding agent is epoxy resin, acrylate, acrylic resin, polyester resin, polyamide, poly- ammonia One or more in ester resin, polyimide resin, polyvinyl alcohol resin, polyketone resin, phenolic resin, titanate coupling agent Mixing.
A kind of TFT-LCD display screens nano protective film of embodiment 2, includes the raw material of following parts by weight:Silicon-fluorine polymer thing 42 parts, 11 parts of nano zircite, 12 parts of nano zine oxide, 14 parts of nano-titanium oxide, 34 parts of epoxy resin, urethane acrylate 18 parts, 16 parts of UV diluting monomers, 14 parts of binding agent.
The nano zircite, nano zine oxide, nano-titanium oxide particle diameter are between 30~200nm.
The silicon-fluorine polymer thing is poly- trifluoro propyl methyl cyclotrisiloxane, poly- trifluoropropylmethyldichlorosilane, poly- two One or more in the poly- seven fluorine butyl methyl acrylate of methylsiloxane-b-.
The photoresist is polyvinyl alcohol laurate, light-sensitive polyimide, the ultraviolet negative photoresist of epoxy radicals or cyclisation Polyisoprene-two-fold nitrogen type ultraviolet photoresist.
The epoxy resin is bisphenol A-type or glycidyl ester type epoxy resin and fatty amine, aliphatic cyclic amine, aromatic amine, poly- The blend of acid amides or acid anhydrides.
The binding agent is epoxy resin, acrylate, acrylic resin, polyester resin, polyamide, poly- ammonia One or more in ester resin, polyimide resin, polyvinyl alcohol resin, polyketone resin, phenolic resin, titanate coupling agent Mixing.
A kind of TFT-LCD display screens nano protective film of embodiment 3, includes the raw material of following parts by weight:Silicon-fluorine polymer thing 36 parts, 10 parts of nano zircite, 9 parts of nano zine oxide, 12 parts of nano-titanium oxide, 26 parts of epoxy resin, urethane acrylate 14 parts, 13 parts of UV diluting monomers, 11 parts of binding agent.
The nano zircite, nano zine oxide, nano-titanium oxide particle diameter are between 30~200nm.
The silicon-fluorine polymer thing is poly- trifluoro propyl methyl cyclotrisiloxane, poly- trifluoropropylmethyldichlorosilane, poly- two One or more in the poly- seven fluorine butyl methyl acrylate of methylsiloxane-b-.
The photoresist is polyvinyl alcohol laurate, light-sensitive polyimide, the ultraviolet negative photoresist of epoxy radicals or cyclisation Polyisoprene-two-fold nitrogen type ultraviolet photoresist.
The epoxy resin is bisphenol A-type or glycidyl ester type epoxy resin and fatty amine, aliphatic cyclic amine, aromatic amine, poly- The blend of acid amides or acid anhydrides.
The binding agent is epoxy resin, acrylate, acrylic resin, polyester resin, polyamide, poly- ammonia One or more in ester resin, polyimide resin, polyvinyl alcohol resin, polyketone resin, phenolic resin, titanate coupling agent Mixing.
It is obvious to a person skilled in the art that the invention is not restricted to the details of the one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than the explanation is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Although not each moreover, it will be appreciated that the present specification is described in terms of embodiments Embodiment is only comprising an independent technical scheme, and this narrating mode of specification is only this area for clarity Technical staff should be using specification as an entirety, and the technical solutions in the various embodiments may also be suitably combined, forms this Art personnel may be appreciated other embodiment.

Claims (6)

1. a kind of TFT-LCD display screens nano protective film, it is characterised in that include the raw material of following parts by weight:Silicon-fluorine polymer 30-42 parts of thing, 8-11 parts of nano zircite, 6-12 parts of nano zine oxide, 9-14 parts of nano-titanium oxide, 22-34 parts of epoxy resin, 11-18 parts of urethane acrylate, 7-16 parts of UV diluting monomers, 8-14 parts of binding agent.
2. a kind of TFT-LCD display screens nano protective film according to claim 1, it is characterised in that:It is described nano oxidized Zirconium, nano zine oxide, nano-titanium oxide particle diameter are between 30~200nm.
3. a kind of TFT-LCD display screens nano protective film according to claim 1, it is characterised in that:The silicon-fluorine polymer Thing is poly- trifluoro propyl methyl cyclotrisiloxane, poly- trifluoropropylmethyldichlorosilane, the poly- seven fluorine fourths of dimethyl silicone polymer-b- One or more in methyl acrylate.
4. a kind of TFT-LCD display screens nano protective film according to claim 1, it is characterised in that:The photoresist is The ultraviolet negative photoresist of polyvinyl alcohol laurate, light-sensitive polyimide, epoxy radicals or Cyclized Polyisoprene-two-fold nitrogen type Ultraviolet photoresist.
5. a kind of TFT-LCD display screens nano protective film according to claim 1, it is characterised in that:The epoxy resin For bisphenol A-type or the blend of glycidyl ester type epoxy resin and fatty amine, aliphatic cyclic amine, aromatic amine, polyamide or acid anhydrides.
6. a kind of TFT-LCD display screens nano protective film according to claim 1, it is characterised in that:The binding agent is Epoxy resin, acrylate, acrylic resin, polyester resin, polyamide, polyurethane resin, polyimide resin, One or more of mixing in polyvinyl alcohol resin, polyketone resin, phenolic resin, titanate coupling agent.
CN201710470122.0A 2017-06-20 2017-06-20 A kind of TFT LCD displays nano protective film Pending CN107142012A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710470122.0A CN107142012A (en) 2017-06-20 2017-06-20 A kind of TFT LCD displays nano protective film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710470122.0A CN107142012A (en) 2017-06-20 2017-06-20 A kind of TFT LCD displays nano protective film

Publications (1)

Publication Number Publication Date
CN107142012A true CN107142012A (en) 2017-09-08

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112859523A (en) * 2019-11-12 2021-05-28 台湾永光化学工业股份有限公司 Polyimide positive photoresist composition

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002225442A (en) * 2001-01-30 2002-08-14 Ricoh Co Ltd Reversible heat-sensitive recording material, and its manufacturing method
CN1821813A (en) * 2005-02-16 2006-08-23 柯尼卡美能达精密光学株式会社 Antireflection film, production method of the same, polarizing plate and display
CN1841094A (en) * 2005-03-29 2006-10-04 株式会社巴川制纸所 Anti-glare film
JP2010222524A (en) * 2009-03-25 2010-10-07 Dic Corp Active energy ray-curable resin composition for film protective layer
CN102717549A (en) * 2012-06-05 2012-10-10 上海本朴科技发展有限公司 Nano-sized anti-glare peep-proof fingerprint-resistant screen protecting film
CN103911067A (en) * 2014-03-19 2014-07-09 苏州袭麟光电科技产业有限公司 Protection film with high hardness, super wearing resistance and no newton ring, and its preparation method
CN104788699A (en) * 2015-03-31 2015-07-22 苏州市鼎立包装有限公司 Self-cleaning protective film and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002225442A (en) * 2001-01-30 2002-08-14 Ricoh Co Ltd Reversible heat-sensitive recording material, and its manufacturing method
CN1821813A (en) * 2005-02-16 2006-08-23 柯尼卡美能达精密光学株式会社 Antireflection film, production method of the same, polarizing plate and display
CN1841094A (en) * 2005-03-29 2006-10-04 株式会社巴川制纸所 Anti-glare film
JP2010222524A (en) * 2009-03-25 2010-10-07 Dic Corp Active energy ray-curable resin composition for film protective layer
CN102717549A (en) * 2012-06-05 2012-10-10 上海本朴科技发展有限公司 Nano-sized anti-glare peep-proof fingerprint-resistant screen protecting film
CN103911067A (en) * 2014-03-19 2014-07-09 苏州袭麟光电科技产业有限公司 Protection film with high hardness, super wearing resistance and no newton ring, and its preparation method
CN104788699A (en) * 2015-03-31 2015-07-22 苏州市鼎立包装有限公司 Self-cleaning protective film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112859523A (en) * 2019-11-12 2021-05-28 台湾永光化学工业股份有限公司 Polyimide positive photoresist composition
CN112859523B (en) * 2019-11-12 2024-04-26 台湾永光化学工业股份有限公司 Polyimide positive photoresist composition

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Application publication date: 20170908

RJ01 Rejection of invention patent application after publication