CN107130263A - The preparation method of magnesium metal - Google Patents
The preparation method of magnesium metal Download PDFInfo
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- CN107130263A CN107130263A CN201710203909.0A CN201710203909A CN107130263A CN 107130263 A CN107130263 A CN 107130263A CN 201710203909 A CN201710203909 A CN 201710203909A CN 107130263 A CN107130263 A CN 107130263A
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Abstract
The invention provides a kind of preparation method of magnesium metal.This method comprises the following steps：By the mass ratio configuration magnesium salts and the mixed material of lead salt of magnesium and lead in the magnesium metal to be prepared；Mixed material is subjected to fused salt electrolysis codeposition, during which controls the relative error of the electrolysis electricity of the magnesium ion in mixed material and faraday's electricity needed for lead ion electric discharge with being electrolysed mixed material within ± 15%, obtains magnesium metal.Utilize above-mentioned preparation method, pass through fused salt electrolysis codeposition method, faraday's electricity needed for the electric discharge of control magnesium ion and lead ion matches uniformity with electrolysis electricity during electrolysis, the two relative error is controlled within ± 15%, the content of two kinds of metal ingredients in magnesium metal product can be made substantially consistent with target content, so as to reach the purpose of effectively control alloying component.And by above-mentioned fused salt electrolysis codeposition method, the present invention has prepared magnesium metal.
Description
Technical field
The present invention relates to alloy material preparing technical field, in particular to a kind of preparation method of magnesium metal.
Background technology
Magnesium alloy has numerous excellent property such as density low, and mechanical performance and chemical property are excellent and can reclaim
The characteristic such as utilize, thus be known as " green alloy ".Magnesium alloy is widely used in various fields such as auto industry, electronics
Product, aviation, military affairs, and its consumption has the trend increased considerably.One kind that magnesium-based metal belongs in magnesium alloy series.
The method of this kind of alloy of traditional mode of production is smelting process, that is, is co-doped with method：Various alloying component elements pass through each independent
Metallurgical process be made after, by its melting obtain alloy.This method flow is long, and all metallic elements therein have to pass through respectively
From metallurgical process and its then refining obtain, this process is numerous and diverse, and cost is high；Because its bulk composition is active metal,
Melting production alloy process must have inert atmosphere or vacuum environment, and metal loss rate is high, and cause the pollution of environment.
For a long time, people continuously attempt to produce alloy using fused salt electrolysis process.Fused salt electrolysis process prepares alloy can divide again
For two methods of electrolysis diffusion method and electrolytic codeposition of nickel method.
It is electrolysed in diffusion method, most representative work is the magnesium alloy electrolysis diffusion method that Ram Sharma are proposed, in electricity
Solve and add liquid copper in liquid in advance as negative electrode, electrolytic oxidation magnesium or magnesium chloride, magnesium is deposited acquisition magnesium copper alloy on copper, its
Main thought is, using the alloying metal of relative inertness as negative electrode, other members to be deposited thereon and usually obtain alloy.
It is a kind of method that can effectively prevent alloying element scaling loss and can carry out exact composition control to be electrolysed diffusion method.
However, whole electrolytic process alloying element content is continuously increased, this causes alloying component not in the same time to have very very much not naturally
Together, especially master alloying composition gradually will increase to very high concentration from zero, when electrodeposited alloy element reached it is required
When measuring, electrolytic process must stop, and take out alloy, then change negative electrode and repeat said process.In electrolytic process not
The alloy of target component can be obtained at any time, and such process can not be referred to as a continuous process.
Electrolytic codeposition of nickel method is to discharge to obtain alloy simultaneously in negative electrode under same potential using many kinds of metal ions
Method.However, existing electrolytic codeposition of nickel method can not accomplish the composition in effectively control alloy, and it there is no magnesium metal at present
The report of co-deposition and Composition Control.
The content of the invention
It is a primary object of the present invention to provide a kind of preparation method of magnesium metal, to solve to be electrolysed in the prior art altogether
Sedimentation can not realize that magnesium metal is co-deposited, and the problem of can not effectively control magnesium metal composition.
To achieve these goals, according to an aspect of the invention, there is provided a kind of preparation method of magnesium metal, its
Comprise the following steps：By the mass ratio configuration magnesium salts and the mixed material of lead salt of magnesium and lead in the magnesium metal to be prepared；Will
Mixed material carries out fused salt electrolysis codeposition, during which controls the magnesium ion in mixed material and the faraday needed for lead ion electric discharge
The relative error of electrolysis electricity of the electricity with being electrolysed mixed material obtains magnesium metal within ± 15%.
Further, the magnesium ion in control mixed material and faraday's electricity needed for lead ion electric discharge are mixed with electrolysis
During the relative error of the electrolysis electricity of raw material is the step of within ± 15%, determine that electrolysis mixing is former according to formula I or formula II
The Faradaic current and electrolysis time of material, and then magnesium metal is obtained, wherein,
Formula I is：
Formula II is：
In formula I and II, m(Mg ) sa ltFor the quality of magnesium salts in mixed material, m(Pb)saltFor the matter of lead salt in mixed material
Amount, MMgFor the relative atomic mass of magnesium, MPbFor the relative atomic mass of lead, M(Mg)saltFor the relative molecular mass of magnesium salts,
M(Pb)saltFor the relative molecular mass of lead salt, I is Faradaic current, and t is electrolysis time, and a is the quality of lead in 100g magnesium metals,
F is Faraday constant.
Further, using electrolysis time t as interval time, mixed material is periodically added into electrolytic furnace, with continuous
Property prepares magnesium metal.
Further, magnesium salts is magnesium chloride, and lead salt is lead chloride.
Further, during fused salt electrolysis codeposition, the electrolyte of use includes alkali molten salt.
Further, the composition of alkali molten salt includes lithium chloride and/or sodium chloride.
Further, the magnesium chloride that mass fraction is 8~15% is also included in electrolyte.
Further, by weight percentage, electrolyte include 8~15% magnesium chloride, 50~70% lithium chloride and
20~40% sodium chloride.
Further, during fused salt electrolysis codeposition, electrolysis temperature is 700~900 DEG C.
Further, during fused salt electrolysis codeposition, cathode-current density is 0.5~1.5A/cm2。
Apply the technical scheme of the present invention there is provided a kind of preparation method of magnesium metal, it comprises the following steps：By institute
The mass ratio configuration magnesium salts and the mixed material of lead salt of magnesium and lead in the magnesium metal to be prepared；Mixed material is subjected to fused salt electricity
Solution is co-deposited, and during which controls the magnesium ion in mixed material and faraday's electricity needed for lead ion electric discharge and electrolysis mixed material
Electrolysis electricity relative error within ± 15%, obtain magnesium metal.
Using above-mentioned preparation method, by fused salt electrolysis codeposition method, magnesium ion and lead ion are controlled during electrolysis
Faraday's electricity needed for electric discharge matches uniformity with electrolysis electricity, and the two relative error is controlled within ± 15%, can
Make the content of two kinds of metal ingredients in magnesium metal product substantially consistent with target content, so as to reach effectively control alloying component
Purpose.And by above-mentioned fused salt electrolysis codeposition method, the present invention has prepared magnesium metal.
Embodiment
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the application can phase
Mutually combination.The present invention is described in detail below in conjunction with embodiment.
The application is described in further detail below in conjunction with specific embodiment, these embodiments are it is not intended that limit this
Apply for scope claimed.
As described by background section, electrolytic codeposition of nickel method of the prior art can not realize that magnesium metal is coprecipitated
Product, and can not effectively control magnesium metal composition.
In order to solve this problem, the invention provides a kind of preparation method of magnesium metal, it comprises the following steps：Press
The mass ratio configuration magnesium salts and the mixed material of lead salt of magnesium and lead in the magnesium metal to be prepared；Mixed material is subjected to fused salt
Electrolytic codeposition of nickel, faraday's electricity needed for during which controlling the electric discharge of magnesium ion and lead ion in mixed material is mixed with being electrolysed this
The relative error of electrolysis electricity of raw material is closed within ± 15%, magnesium metal is obtained.
Using above-mentioned preparation method, by fused salt electrolysis codeposition method, magnesium ion and lead ion are controlled during electrolysis
Faraday's electricity needed for electric discharge match uniformity with the electrolysis electricity of electrolysis mixed material, will both relative error control ±
Within 15%, the content of two kinds of metal ingredients in magnesium metal product can be made substantially consistent with target content, so that reaching has
The purpose of effect control alloying component.And magnesium metal has been prepared by above-mentioned fused salt electrolysis codeposition method.
Specifically, compared to traditional fused salt electrolysis codeposition process, the step of adding control composition in the present invention.
For preparing the alloy of magnesium lead binary system, by the magnesium metal to be prepared magnesium and lead mass ratio configure magnesium salts and
The mixed material of lead salt, then mixed material is put into electrolytic furnace carry out fused salt electrolysis codeposition.If not controlling faraday
Electricity matches uniformity with electrolysis electricity, and metal ion is equally existed in the electrolyte used due to electrolytic process, these gold
Belonging to ion, electrolysis is separated out in the lump easily in electrolytic process, so as to destroy the binary system of magnesium metal as impurity component.This
Invention is based on this point, it is proposed that the magnesium ion of mixed material and putting for lead ion are controlled during fused salt electrolysis codeposition
The relative error of the required faraday's electricity of electricity and the electrolysis electricity of electrolysis mixed material within ± 15%, so equivalent to for
The electrolysis of magnesium ion and lead ion separates out the supply sum for being provided with electrolysis electricity, miscellaneous in electrolyte so as to effectively prevent
Matter metal ion is separated out, and has been efficiently controlled the magnesium lead content of alloy product, has been made it substantially consistent with target content.
In the above-mentioned preparation method that the present invention is provided, electrolysis electricity can be controlled by electrolysis time and Faradaic current.
In a preferred embodiment, magnesium ion and the required faraday's electricity of lead ion electric discharge and electrolysis in control mixed material
During the relative error of the electrolysis electricity of above-mentioned mixed material is the step of within ± 15%, electricity is determined according to formula I or formula II
The Faradaic current and electrolysis time of mixed material are solved, and then obtains magnesium metal,
Formula I is
Formula II is
In formula I and II, m(Mg)saltFor the quality of magnesium salts in mixed material, m(Pb)saltFor the matter of lead salt in mixed material
Amount, MMgFor the relative atomic mass of magnesium, MCuFor the relative atomic mass of lead, M(Mg)saltFor the relative molecular mass of magnesium salts,
M(Pb)saltFor the relative molecular mass of lead salt, I is Faradaic current, and t is electrolysis time (s), and a is the matter of lead in 100g magnesium metals
Amount, F is Faraday constant (96485C/mol).
What deserves to be explained is, above-mentioned 1 ± 0.15 refers to a value range, and it is more than or equal to 0.85, less than or equal to 1.15.
Above-mentioned a values can pass through the mass ratio of the lead in the subject alloy to be prepared to obtain.m(Mg)saltIt can lead to
The quality and proportioning for crossing be electrolysed mixed material are obtained.So, Faradaic current can be known by above-mentioned Formulas I or Formula II
With the relation of electrolysis time.In actual mechanical process, the value of Faradaic current can be preset, it is possible to obtain according to above formula
Electrolysis time, so as to apply during actual electrolytic codeposition of nickel.On the contrary, electrolysis time can also be preset, such as
It is required that how long it is interior complete electrolysis, it is possible to the size of Faradaic current is determined according to above formula.In addition it is also possible to default electrolysis
Time and Faradaic current, so as to determine the quality of magnesium salts and lead salt in mixed material according to above formula.
Generally, the preferably relative error of faraday's electricity and electrolysis electricity is within+15%, i.e., 0≤(electrolysis electricity
Amount-faraday's electricity)/electrolysis electricity ＜ 15%.
Electrolysis electricity is controlled using electrolysis time and Faradaic current, so as to control alloying component so that in the present invention
Preparation method can use continuous production technology.In a preferred embodiment, using electrolysis time t as interval time,
Mixed material is periodically added into electrolytic furnace, magnesium metal is prepared with continuity.
As it was noted above, the present invention controls electrolysis electricity by electrolysis time and Faradaic current, so as to reach mixing
In raw material one is matched needed for magnesium ion and lead ion electric discharge between faraday's electricity and the electrolysis electricity for being electrolysed the mixed material
Cause property.Therefore, can be just by the mixed material electrolytic codeposition of nickel in the electrolysis time t shown in above-mentioned Formulas I or Formula II.
On the basis of this, using electrolysis time t as interval time, above-mentioned mixed material is periodically added into electrolytic furnace, company can be reached
Continuous property prepares the purpose of magnesium metal.And the alloy taken out after each time interval, its composition is basically identical with preset value.
In a preferred embodiment, above-mentioned magnesium salts is magnesium chloride, and lead salt is lead chloride.Compared to other magnesium salts and
Lead salt, magnesium chloride and lead chloride have higher electrolysis performance.
The electrolyte used during above-mentioned fused salt electrolysis codeposition can be electrolyte commonly used in the art, the purpose is to
Support the electron motion in electrolytic process.In a preferred embodiment, during fused salt electrolysis codeposition, the electricity of use
Solving matter includes alkali molten salt.The activity of alkali metal is better than magnesium and lead, correspondingly, be later than in electrolytic process magnesium ion and lead from
Son.Using alkali molten salt as electrolyte, with reference to above-mentioned electrolysis electricity rate-determining steps, further it can prevent metal impurities from entering
Enter in alloy, so as to be more beneficial for the Composition Control of binary system alloy.It is highly preferred that the composition of alkali molten salt includes chlorination
Lithium and/or sodium chloride.
In a preferred embodiment, the magnesium chloride that mass fraction is 8~15% is also included in electrolyte.In electrolysis
The magnesium chloride of addition 8~15%, can further improve the stability during fused salt electrolysis codeposition in matter.It is worth explanation
It is that, based on foregoing Composition Control step, the magnesium chloride in electrolyte system has no effect on the component content in alloy product.More
Preferably, by weight percentage, electrolyte includes 8~15% magnesium chloride, 50~70% lithium chloride and 20~40%
Sodium chloride.
Other electrolysis process can be adjusted.In a preferred embodiment, during fused salt electrolysis codeposition,
Electrolysis temperature is 700~900 DEG C.Cathode-current density is 0.5~1.5A/cm2.Under the process conditions, electrolytic codeposition of nickel process
More stablize, so as to be conducive to further improving the quality stability of magnesium metal product.
Beneficial effects of the present invention are further illustrated by the following examples.
Embodiment 1
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate mixed material
The quality of middle magnesium chloride, it is mixed material accordingly to weigh the part in said mixture, and presses this mixed material to electrolytic furnace
In periodically feed, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is stainless steel, and anode is graphite；Dc source：2A；700 DEG C of electrolyte temperature；Cathode-current density
1A/cm2；Electrolyte is constituted：Magnesium chloride 15wt%- lithium chloride 60wt%- sodium chloride 25wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
| Alloy is designed | Mg-5wt%Pb |
| Gained alloying component | Mg-4.60wt%Pb |
Embodiment 2
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate mixed
Close the quality of magnesium chloride in raw material, it is mixed material accordingly to weigh a part in said mixture, and by this mixed material to
Periodically fed in electrolytic furnace, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is molybdenum, and anode is graphite；Dc source：2A；900 DEG C of electrolyte temperature；Cathode-current density 0.5A/
cm2；Electrolyte is constituted：Magnesium chloride 8wt%- lithium chloride 70wt%- sodium chloride 22wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
Embodiment 3
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate mixed
Close the quality of magnesium chloride in raw material, it is mixed material accordingly to weigh a part in said mixture, and by this mixed material to
Periodically fed in electrolytic furnace, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is tungsten, and anode is graphite；Dc source：2A；950 DEG C of electrolyte temperature；Cathode-current density 1.5A/
cm2；Electrolyte is constituted：Magnesium chloride 10wt%- lithium chloride 50wt%- sodium chloride 40wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
| Alloy is designed | Mg-5wt%Pb |
| Gained alloying component | Mg-4.45wt%Pb |
Embodiment 4
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate
The quality of magnesium chloride in mixed material, it is mixed material accordingly to weigh the part in said mixture, and by this mixed material
Periodically fed into electrolytic furnace, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is tungsten, and anode is graphite；Dc source：2A；950 DEG C of electrolyte temperature；Cathode-current density 1.6A/
cm2；Electrolyte is constituted：Magnesium chloride 5wt%- lithium chloride 75wt%- sodium chloride 20wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
| Alloy is designed | Mg-5wt%Pb |
| Gained alloying component | Mg-4.40wt%Pb |
Comparative example 1
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate
The quality of magnesium chloride in mixed material, it is mixed material accordingly to weigh the part in said mixture, and by this mixed material
Periodically fed into electrolytic furnace, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is tungsten, and anode is graphite；Dc source：2A；950 DEG C of electrolyte temperature；Cathode-current density 1.6A/
cm2；Electrolyte is constituted：Magnesium chloride 5wt%- lithium chloride 75wt%- sodium chloride 20wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
| Alloy is designed | Mg-5wt%Pb |
| Gained alloying component | Mg-4.20wt%Pb-0.06wt%Li-0.03wt%Na |
Comparative example 2
Alloy is designed as Mg-5wt%Pb (wherein Pb content is 5wt%), by this proportional arrangement magnesium chloride and lead chloride
Mixture.
Electrolysis time (interval time) is preset for 30min, Faradaic current is dc source 2A；
By formulaCalculate
The quality of magnesium chloride in mixed material, it is mixed material accordingly to weigh the part in said mixture, and by this mixed material
Periodically fed into electrolytic furnace, carry out continuous fused salt electrolysis codeposition.
Specific electrolytic parameter is as follows：
Electrolysis cathode is tungsten, and anode is graphite；Dc source：2A；950 DEG C of electrolyte temperature；Cathode-current density 1.6A/
cm2；Electrolyte is constituted：Magnesium chloride 5wt%- lithium chloride 75wt%- sodium chloride 20wt%.Mixed material feeding study on period is
30min.Under the conditions of above-mentioned technological parameter, continuous electrolysis takes out alloy, uses icp analysis lead content after 10 hours.
Specific data are as shown in the table：
| Alloy is designed | Mg-5wt%Pb |
| Gained alloying component | Mg-4.01wt%Pb |
As can be seen from the above description, the above embodiments of the present invention realize following technique effect：
Using above-mentioned preparation method, by fused salt electrolysis codeposition method, magnesium metal can be prepared.More importantly, originally
Invention is matched unanimously by faraday's electricity needed for the electric discharge of control magnesium ion and lead ion during electrolysis with electrolysis electricity
Property, the two relative error is controlled within ± 15%, the content of two kinds of metal ingredients in magnesium metal product can be made basic
It is consistent with target content, so as to reach the purpose of effectively control alloying component.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (10)
1. a kind of preparation method of magnesium metal, it is characterised in that comprise the following steps：
By the mass ratio configuration magnesium salts and the mixed material of lead salt of magnesium and lead in the magnesium metal to be prepared；
The mixed material is subjected to fused salt electrolysis codeposition, during which controls magnesium ion and lead ion in the mixed material to put
The relative error of electrolysis electricity of the required faraday's electricity of electricity with being electrolysed the mixed material obtains described within ± 15%
Magnesium metal.
2. preparation method according to claim 1, it is characterised in that magnesium ion in the control mixed material and
The relative error of electrolysis electricity of faraday's electricity with being electrolysed the mixed material needed for lead ion electric discharge is within ± 15%
The step of in, determined to be electrolysed the Faradaic current and electrolysis time of the mixed material according to formula I or formula II, and then obtain institute
Magnesium metal is stated, wherein,
The formula I is：
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In the formula I and II, m(Mg)saltThe quality of magnesium salts, m described in the mixed material(Pb)saltFor the mixed material
Described in lead salt quality, MMgFor the relative atomic mass of magnesium, MPbFor the relative atomic mass of lead, M(Mg)saltFor the magnesium salts
Relative molecular mass, M(Pb)saltFor the relative molecular mass of the lead salt, I is the Faradaic current, when t is the electrolysis
Between, a is the quality of lead in magnesium metal described in 100g, and F is Faraday constant.
3. preparation method according to claim 2, it is characterised in that using the electrolysis time t as interval time, to electrolysis
The mixed material is periodically added into stove, the magnesium metal is prepared with continuity.
4. preparation method according to any one of claim 1 to 3, it is characterised in that the magnesium salts is magnesium chloride, described
Lead salt is lead chloride.
5. preparation method according to claim 4, it is characterised in that during the fused salt electrolysis codeposition, use
Electrolyte includes alkali molten salt.
6. preparation method according to claim 5, it is characterised in that the composition of the alkali molten salt includes lithium chloride
And/or sodium chloride.
7. preparation method according to claim 6, it is characterised in that also include in the electrolyte mass fraction be 8~
15% magnesium chloride.
8. preparation method according to claim 7, it is characterised in that by weight percentage, the electrolyte includes 8~
15% magnesium chloride, 50~70% lithium chloride and 20~40% sodium chloride.
9. the preparation method according to any one of claim 6 to 8, it is characterised in that the fused salt electrolysis codeposition mistake
Cheng Zhong, electrolysis temperature is 700~900 DEG C.
10. preparation method according to claim 9, it is characterised in that during the fused salt electrolysis codeposition, negative electrode electricity
Current density is 0.5~1.5A/cm2。
Priority Applications (1)
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1035532A (en) * | 1988-02-06 | 1989-09-13 | 东北工学院 | The method of electrolysis production aluminum silicon alloy |
| JP2008195969A (en) * | 2007-02-08 | 2008-08-28 | Toyohashi Univ Of Technology | Method for producing alloy ingot by molten salt electrolysis using ESR heating |
| CN101440508A (en) * | 2008-12-12 | 2009-05-27 | 北京科技大学 | Preparation of reactive metal based alloy |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1035532A (en) * | 1988-02-06 | 1989-09-13 | 东北工学院 | The method of electrolysis production aluminum silicon alloy |
| JP2008195969A (en) * | 2007-02-08 | 2008-08-28 | Toyohashi Univ Of Technology | Method for producing alloy ingot by molten salt electrolysis using ESR heating |
| CN101440508A (en) * | 2008-12-12 | 2009-05-27 | 北京科技大学 | Preparation of reactive metal based alloy |
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