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CN107129258A - A kind of magnesial gelatinized pressure plare and preparation method thereof - Google Patents

A kind of magnesial gelatinized pressure plare and preparation method thereof Download PDF

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Publication number
CN107129258A
CN107129258A CN201710446204.1A CN201710446204A CN107129258A CN 107129258 A CN107129258 A CN 107129258A CN 201710446204 A CN201710446204 A CN 201710446204A CN 107129258 A CN107129258 A CN 107129258A
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CN
China
Prior art keywords
parts
magnesium
pressure plare
weight
hydroxide
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Pending
Application number
CN201710446204.1A
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Chinese (zh)
Inventor
黄云清
蒙德友
石勇
郭万金
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Guizhou Sunshine Xingye Green Building Material Co Ltd
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Guizhou Sunshine Xingye Green Building Material Co Ltd
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Publication date
Application filed by Guizhou Sunshine Xingye Green Building Material Co Ltd filed Critical Guizhou Sunshine Xingye Green Building Material Co Ltd
Priority to CN201710446204.1A priority Critical patent/CN107129258A/en
Publication of CN107129258A publication Critical patent/CN107129258A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/52Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of magnesial gelatinized pressure plare, include the raw material of following parts by weight:42~56 parts of life waste material, 8~16 parts of light calcined magnesia, 5~12 parts of magnesium sulfate, 3~8 parts of magnesium chloride, 2~6 parts of magnesium hydroxide, 6~12 parts of aluminium hydroxide, 8~22 parts of nano silicon, 10~16 parts of sericite in powder, 8~18 parts of glass fibre, 10~18 parts of epoxy resin, 12~32 parts of Corvic, 1~3 part of crosslinking agent, 0.3~0.8 part of stabilizer;Its preparation method includes:The preparation of pressure plate, pressure plate feeding mould, then the pressurized, demoulding, drying and edging are got product.Pressure plare proposed by the present invention is environment-protecting and non-poisonous, and fire-protection rating reaches A grades, and wear-resisting, heat-resisting, waterproof, resistance to frost are good, and nail-holding ability is strong, and preparation method is simple, and production and use cost are low.

Description

A kind of magnesial gelatinized pressure plare and preparation method thereof
Technical field
The present invention relates to building material technical field, more particularly to a kind of magnesial gelatinized pressure plare and preparation method thereof.
Background technology
Conventional pressure plare is mainly cement pressure plate on the market, its using natural fiber and cement as raw material, through slurrying, into Type, cutting, pressurization, a kind of building panel of maintenance, are widely used in civilian and industrial building.But cement pressure Plate can produce the three wastes in process of production, have harm to the environment around manufactory, and would generally make when manufacturing pressure plare Organic solvent, such as formaldehyde are used, hidden danger is come to the safety belt of user.The pressure plare of conventional cement material is due to natural fiber For raw material, therefore larger to the demand of natural fiber, and to be nature exist and grow natural fiber, so yield is few, Scarcity of resources, so the production to cement pressure plate also has certain binding character, and the pressure plare unit weight of cement production systD is big, It is prepared into larger compared with the difficulty of small pressure plate.
Binder materials is that one kind can become firm Shi Zhuanti in the case where physically or chemically acting on from slurry, and can it is cementing its His material, is formed with the material of the complex solid of certain mechanical strength.The appearance of gel rubber material can effectively alleviate cement pressure The shortcoming of the scarcity of resources of plate, can carry out extensive, industrialized production, therefore its application in life is wide.But Pressure plare prepared by existing gel rubber material still suffers from some places having much room for improvement, such as water resistance is poor, in moist feelings Easy efflorescence under condition, go mouldy;Fire resistance rating is not high, typically up to less than A grades;Nail-holding ability is poor, is not fixed easily when using, and often needs to use Support frame is fixed.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of magnesial gelatinized pressure plare proposed And preparation method thereof.
A kind of magnesial gelatinized pressure plare, includes the raw material of following parts by weight:42~56 parts of life waste material, light calcined magnesia 8 ~16 parts, 5~12 parts of magnesium sulfate, 3~8 parts of magnesium chloride, 2~6 parts of magnesium hydroxide, 6~12 parts of aluminium hydroxide, nano silicon 8~22 parts, 10~16 parts of sericite in powder, 8~18 parts of glass fibre, 10~18 parts of epoxy resin, Corvic 12~32 Part, 1~3 part of crosslinking agent, 0.3~0.8 part of stabilizer.
It is preferred that, a kind of described magnesial gelatinized pressure plare includes the raw material of following parts by weight:Life waste material 46~52 Part, 10~16 parts of light calcined magnesia, 8~12 parts of magnesium sulfate, 4~8 parts of magnesium chloride, 2~6 parts of magnesium hydroxide, aluminium hydroxide 8~12 Part, 10~18 parts of nano silicon, 12~16 parts of sericite in powder, 10~16 parts of glass fibre, 12~18 parts of epoxy resin gathers 14~28 parts of vinyl chloride resin, 1~3 part of crosslinking agent, 0.4~0.8 part of stabilizer.
It is preferred that, a kind of described magnesial gelatinized pressure plare includes the raw material of following parts by weight:49 parts of life waste material, gently 13 parts of burned magnesium oxide, 10 parts of magnesium sulfate, 6 parts of magnesium chloride, 4 parts of magnesium hydroxide, 10 parts of aluminium hydroxide, 14 parts of nano silicon, 14 parts of sericite in powder, 13 parts of glass fibre, 15 parts of epoxy resin, 22 parts of Corvic, 2 parts of crosslinking agent, stabilizer 0.6 Part.
It is preferred that, the life waste material is any one in waste straw, tobacco rod, structure skin tree and wooden building rubbish or several The combination planted.
It is preferred that, the weight part ratio of the light calcined magnesia, magnesium sulfate and magnesium chloride is 1~5:0.8~4:1.
It is preferred that, the weight part ratio of the magnesium hydroxide and aluminium hydroxide is 1:1~6.
The invention also provides a kind of preparation method of magnesial gelatinized pressure plare, comprise the following steps:
S1:Life waste material is put into pulverizer to be crushed, block life waste material of the granularity in below 1mm is ground into, The magnesium sulfate and magnesium chloride of corresponding parts by weight are dissolved in suitable quantity of water again, the aqueous solution is obtained, it is standby;
S2:Epoxy resin and Corvic are added in melting machine, heating fusing, and add corresponding parts by weight Crosslinking agent and stabilizer, continue to stir 10~20min, obtain compound A;
S3:Block life waste material after crushing is put into the compound A prepared in S2 steps, 5~10min is stirred, The aqueous solution prepared in S1 steps is added, continues to stir 5~10min, sequentially adds magnesium hydroxide, the hydrogen of corresponding parts by weight Aluminum oxide, nano silicon, sericite in powder and glass fibre are disperseed, and produce pressure plate;
S4:The pressure plate prepared in S3 steps is delivered in mould, then the pressurized, demoulding, drying and edging operation, i.e., Obtain magnesial gelatinized pressure plare.
Gel pressure plate proposed by the present invention, environment-protecting and non-poisonous, using life waste material as main material, resource utilization is high, Produced in manufacturing process without waste gas, waste water and waste residue, and waste material is recyclable in manufacturing process;Fire-protection rating is high, Fire proofing is collectively formed with magnesium hydroxide and aluminium hydroxide in raw material, fire-protection rating can be made to reach A grades, nanometer in pressure plare Silica, the addition of sericite in powder and glass fibre can strengthen the anti-wear performance and heat resistance of pressure plare, and epoxy The addition of resin and Corvic can effectively improve the waterproof, antifreeze of pressure plare, make pressure plare long period of soaking in water Also do not deform and go mouldy, and still ensure that below -6 DEG C good performance;And the invention also provides one kind makes The method of magnesial gelatinized pressure plare, fixed and install convenient strong according to the pressure plare nail-holding ability that formula and preparation method are produced, The use of decoration support frame is prevented effectively from, use cost is reduced.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment one
A kind of magnesial gelatinized pressure plare proposed by the present invention, includes the raw material of following parts by weight:48 parts of waste straw, light-burned oxygen Change 12 parts of magnesium, 12 parts of magnesium sulfate, 8 parts of magnesium chloride, 4 parts of magnesium hydroxide, 10 parts of aluminium hydroxide, 10 parts of nano silicon, thin,tough silk cloud 12 parts of female powder, 15 parts of glass fibre, 10 parts of epoxy resin, 32 parts of Corvic, 2 parts of crosslinking agent, 0.5 part of stabilizer.
Its preparation method, comprises the following steps:
S1:Waste straw is put into pulverizer to be crushed, block waste straw of the granularity in below 1mm is ground into, then will The magnesium sulfate and magnesium chloride of corresponding parts by weight are dissolved in suitable quantity of water, obtain the aqueous solution, standby;
S2:Epoxy resin and Corvic are added in melting machine, heating fusing, and add corresponding parts by weight Crosslinking agent and stabilizer, continue to stir 20min, obtain compound A;
S3:Block waste straw after crushing is put into the compound A prepared in S2 steps, 10min is stirred, adds The aqueous solution prepared in S1 steps, continues to stir 5min, sequentially adds the magnesium hydroxides of corresponding parts by weight, aluminium hydroxide, receives Rice silica, sericite in powder and glass fibre are disperseed, and produce pressure plate;
S4:The pressure plate prepared in S3 steps is delivered in mould, then the pressurized, demoulding, drying and edging operation, i.e., Obtain magnesial gelatinized pressure plare.
Embodiment two
A kind of magnesial gelatinized pressure plare proposed by the present invention, includes the raw material of following parts by weight:Useless 21 parts of tobacco rod, give up structure skin 21 parts of tree, 16 parts of light calcined magnesia, 8 parts of magnesium sulfate, 8 parts of magnesium chloride, 6 parts of magnesium hydroxide, 8 parts of aluminium hydroxide, nanometer titanium dioxide 12 parts of silicon, 16 parts of sericite in powder, 8 parts of glass fibre, 15 parts of epoxy resin, 22 parts of Corvic, 3 parts of crosslinking agent is stable 0.3 part of agent.
Its preparation method, comprises the following steps:
S1:Useless tobacco rod and useless structure skin tree are put into pulverizer and crushed, the bulk for being ground into granularity in below 1mm is mixed Waste material is closed, then the magnesium sulfate and magnesium chloride of corresponding parts by weight are dissolved in suitable quantity of water, the aqueous solution is obtained, it is standby;
S2:Epoxy resin and Corvic are added in melting machine, heating fusing, and add corresponding parts by weight Crosslinking agent and stabilizer, continue to stir 10~20min, obtain compound A;
S3:Block mixing waste after crushing is put into the compound A prepared in S2 steps, 5min is stirred, then add Enter the aqueous solution prepared in S1 steps, continue to stir 10min, sequentially add the magnesium hydroxides of corresponding parts by weight, aluminium hydroxide, Nano silicon, sericite in powder and glass fibre are disperseed, and produce pressure plate;
S4:The pressure plate prepared in S3 steps is delivered in mould, then the pressurized, demoulding, drying and edging operation, i.e., Obtain magnesial gelatinized pressure plare.
Embodiment three
A kind of magnesial gelatinized pressure plare proposed by the present invention, includes the raw material of following parts by weight:56 parts of wooden building rubbish, 9 parts of light calcined magnesia, 8 parts of magnesium sulfate, 8 parts of magnesium chloride, 2 parts of magnesium hydroxide, 8 parts of aluminium hydroxide, 9 parts of nano silicon, thin,tough silk 10 parts of mica powder, 8 parts of glass fibre, 14 parts of epoxy resin, 12 parts of Corvic, 3 parts of crosslinking agent, 0.8 part of stabilizer.
Its preparation method, comprises the following steps:
S1:Wooden building rubbish is put into pulverizer to be crushed, granularity is ground into and wooden is built in the block of below 1mm Building refuse, then the magnesium sulfate and magnesium chloride of corresponding parts by weight are dissolved in suitable quantity of water, the aqueous solution is obtained, it is standby;
S2:Epoxy resin and Corvic are added in melting machine, heating fusing, and add corresponding parts by weight Crosslinking agent and stabilizer, continue to stir 10min, obtain compound A;
S3:Block wooden building rubbish after crushing is put into the compound A prepared in S2 steps, 5min is stirred, The aqueous solution prepared in S1 steps is added, continues to stir 10min, sequentially adds magnesium hydroxide, the hydrogen-oxygen of corresponding parts by weight Change aluminium, nano silicon, sericite in powder and glass fibre to be disperseed, produce pressure plate;
S4:The pressure plate prepared in S3 steps is delivered in mould, then the pressurized, demoulding, drying and edging operation, i.e., Obtain magnesial gelatinized pressure plare.
Performance detection is carried out to magnesial gelatinized pressure plare prepared by embodiment one~tri-, testing result is as follows:
Wherein, the condition of waterproof test is boiling water boiling 12 hours;
"-" represents not detect.
The above results show, the magnesial gelatinized pressure plare prepared using embodiment one~tri- can fire-protection rating it is high, can be with Reach A grades;Water resistance is good, and it 12 hours is not in situation that is loose, coming off to be boiled in boiling water;And environment-protecting and non-poisonous, no first Aldehyde.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of magnesial gelatinized pressure plare, it is characterised in that include the raw material of following parts by weight:42~56 parts of life waste material, gently 8~16 parts of burned magnesium oxide, 5~12 parts of magnesium sulfate, 3~8 parts of magnesium chloride, 2~6 parts of magnesium hydroxide, 6~12 parts of aluminium hydroxide is received 8~22 parts of silica of rice, 10~16 parts of sericite in powder, 8~18 parts of glass fibre, 10~18 parts of epoxy resin, polyvinyl chloride 12~32 parts of resin, 1~3 part of crosslinking agent, 0.3~0.8 part of stabilizer.
2. a kind of magnesial gelatinized pressure plare according to claim 1, it is characterised in that include the raw material of following parts by weight: 46~52 parts of life waste material, 10~16 parts of light calcined magnesia, 8~12 parts of magnesium sulfate, 4~8 parts of magnesium chloride, magnesium hydroxide 2~6 Part, 8~12 parts of aluminium hydroxide, 10~18 parts of nano silicon, 12~16 parts of sericite in powder, 10~16 parts of glass fibre, ring 12~18 parts of oxygen tree fat, 14~28 parts of Corvic, 1~3 part of crosslinking agent, 0.4~0.8 part of stabilizer.
3. a kind of magnesial gelatinized pressure plare according to claim 1, it is characterised in that include the raw material of following parts by weight: 49 parts of life waste material, 13 parts of light calcined magnesia, 10 parts of magnesium sulfate, 6 parts of magnesium chloride, 4 parts of magnesium hydroxide, 10 parts of aluminium hydroxide is received 4 parts of silica 1 of rice, 14 parts of sericite in powder, 13 parts of glass fibre, 15 parts of epoxy resin, 22 parts of Corvic, crosslinking agent 2 parts, 0.6 part of stabilizer.
4. a kind of magnesial gelatinized pressure plare according to claim 1, it is characterised in that the life waste material be waste straw, Any one or a few combination in tobacco rod, structure skin tree and wooden building rubbish.
5. a kind of magnesial gelatinized pressure plare according to claim 1, it is characterised in that the light calcined magnesia, magnesium sulfate Weight part ratio with magnesium chloride is 1~5:0.8~4:1.
6. a kind of magnesial gelatinized pressure plare according to claim 1, it is characterised in that the magnesium hydroxide and aluminium hydroxide Weight part ratio be 1:1~6.
7. a kind of preparation method of magnesial gelatinized pressure plare, it is characterised in that comprise the following steps:
S1:Life waste material is put into pulverizer to be crushed, block life waste material of the granularity in below 1mm is ground into, then will The magnesium sulfate and magnesium chloride of corresponding parts by weight are dissolved in suitable quantity of water, obtain the aqueous solution, standby;
S2:Epoxy resin and Corvic are added in melting machine, heating fusing, and add the crosslinking of corresponding parts by weight Agent and stabilizer, continue to stir 10~20min, obtain compound A;
S3:Block life waste material after crushing is put into the compound A prepared in S2 steps, 5~10min is stirred, then add Enter the aqueous solution prepared in S1 steps, continue to stir 5~10min, sequentially add magnesium hydroxide, the hydroxide of corresponding parts by weight Aluminium, nano silicon, sericite in powder and glass fibre are disperseed, and produce pressure plate;
S4:The pressure plate prepared in S3 steps is delivered in mould, then the pressurized, demoulding, drying and edging operation, produce magnesium Matter gelling pressure plare.
CN201710446204.1A 2017-06-14 2017-06-14 A kind of magnesial gelatinized pressure plare and preparation method thereof Pending CN107129258A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109592955A (en) * 2019-01-09 2019-04-09 慧百安康新材料(深圳)有限公司 A kind of Fireproof plant fiber pressure plare and its manufacturing method
CN111718179A (en) * 2020-06-22 2020-09-29 张家港市盛港绿色防火建材有限公司 Heat-resistant anti-corrosion material and preparation method of wall body plate
CN116143490A (en) * 2022-12-27 2023-05-23 江苏佳饰家新材料集团股份有限公司 Inorganic biomass material non-combustible plate and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1792987A (en) * 2005-11-09 2006-06-28 张维善 Silicon magnesium fibre energy saving high strengthening composite building board of decoration and preparation process thereof
CN101096299A (en) * 2006-06-30 2008-01-02 贺建军 Technique for reinforcing inorganic glass steel by fiberglass anti-erosion reinforcement wet process
CN102531528A (en) * 2010-12-27 2012-07-04 牛赫铖 Magnesite fireproofing heat-insulation board
CN103803885A (en) * 2014-01-27 2014-05-21 常州高能新型建材有限公司 Inorganic modified heat insulation plate and preparation process thereof
CN104449411A (en) * 2014-12-10 2015-03-25 中南林业科技大学 Adhesive and preparation method thereof as well as application of adhesive in vegetable fiberboard or artificial board

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1792987A (en) * 2005-11-09 2006-06-28 张维善 Silicon magnesium fibre energy saving high strengthening composite building board of decoration and preparation process thereof
CN101096299A (en) * 2006-06-30 2008-01-02 贺建军 Technique for reinforcing inorganic glass steel by fiberglass anti-erosion reinforcement wet process
CN102531528A (en) * 2010-12-27 2012-07-04 牛赫铖 Magnesite fireproofing heat-insulation board
CN103803885A (en) * 2014-01-27 2014-05-21 常州高能新型建材有限公司 Inorganic modified heat insulation plate and preparation process thereof
CN104449411A (en) * 2014-12-10 2015-03-25 中南林业科技大学 Adhesive and preparation method thereof as well as application of adhesive in vegetable fiberboard or artificial board

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109592955A (en) * 2019-01-09 2019-04-09 慧百安康新材料(深圳)有限公司 A kind of Fireproof plant fiber pressure plare and its manufacturing method
CN111718179A (en) * 2020-06-22 2020-09-29 张家港市盛港绿色防火建材有限公司 Heat-resistant anti-corrosion material and preparation method of wall body plate
CN116143490A (en) * 2022-12-27 2023-05-23 江苏佳饰家新材料集团股份有限公司 Inorganic biomass material non-combustible plate and preparation method thereof
CN116143490B (en) * 2022-12-27 2024-01-26 江苏佳饰家新材料集团股份有限公司 Inorganic biomass material non-combustible plate and preparation method thereof

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Inventor after: Liu Shihong

Inventor after: Lei Juxiang

Inventor after: He Aiai

Inventor before: Huang Yunqing

Inventor before: Meng Deyou

Inventor before: Shi Yong

Inventor before: Guo Wanjin

RJ01 Rejection of invention patent application after publication
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Application publication date: 20170905