CN107099395A - A kind of alkaline cleaner and preparation method thereof - Google Patents
A kind of alkaline cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN107099395A CN107099395A CN201710201373.9A CN201710201373A CN107099395A CN 107099395 A CN107099395 A CN 107099395A CN 201710201373 A CN201710201373 A CN 201710201373A CN 107099395 A CN107099395 A CN 107099395A
- Authority
- CN
- China
- Prior art keywords
- sodium
- acid
- mixed liquor
- alkaline cleaner
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 51
- 239000007788 liquid Substances 0.000 claims abstract description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 24
- 239000011734 sodium Substances 0.000 claims abstract description 24
- -1 dimethyl sodium Chemical compound 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 18
- KMNWCNNLFBCDJR-UHFFFAOYSA-N [Si].[K] Chemical compound [Si].[K] KMNWCNNLFBCDJR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 18
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 18
- 239000003240 coconut oil Substances 0.000 claims abstract description 18
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229940043237 diethanolamine Drugs 0.000 claims abstract description 18
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 18
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims abstract description 18
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims abstract description 16
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 16
- 244000131522 Citrus pyriformis Species 0.000 claims abstract description 16
- 229940117013 triethanolamine oleate Drugs 0.000 claims abstract description 16
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 15
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims 1
- 229910001948 sodium oxide Inorganic materials 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 9
- 231100000614 poison Toxicity 0.000 abstract description 4
- 230000007096 poisonous effect Effects 0.000 abstract description 4
- 239000011521 glass Substances 0.000 description 24
- 238000003756 stirring Methods 0.000 description 14
- 239000012459 cleaning agent Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000004519 grease Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 239000013042 solid detergent Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011538 cleaning material Substances 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
- C11D3/075—Phosphates, including polyphosphates in admixture with ethers of polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of alkaline cleaner and preparation method thereof, it is made up of the 80g of AEO 50, the 100g of coconut oil alkanolamide 80, the 40g of triethanolamine oleate 20, the 100g of MEA 80, the 20g of BTA 10, the 20g of EDETATE SODIUM 10,20 30g of liquid Lemon acid, 16 18g of silicon potassium acid, the 15g of alkyl benzene sulphonate 14, the 27g of tetrapotassium pyrophosphate 25, the 14g of sodium metasilicate 13, the 34g of diethanol amine 30, the 9g of acid dimethyl sodium 7, the 12g of sodium hydroxide 11 and the 800g of water 700；This kind of alkaline cleaner has the characteristics of environment-protecting and non-poisonous, safety, financial cost are low, cleaning performance is good.
Description
Technical field
The present invention relates to a kind of alkaline cleaner and preparation method thereof.
Background technology
Cleaning agent, by surfactant (such as sodium alkyl benzene sulfonate, sodium alkyl sulfate) and various auxiliary agents (such as tripolyphosphate
Sodium), adjuvant be configured to, during dirt on body surface is washed, can reduce the surface tension of the aqueous solution, improve decontamination effect
The material of fruit.It is divided into solid detergent, liquid detergent by product appearance form.Solid detergent yield is maximum, traditionally claims
Washing powder, including fine-powdered, graininess and hollow bead shape etc..Detergent paste also therebetween, also referred to as does washing
Cream.All kinds of synthetic detergents have different production technologies, wherein the most complicated with solid detergent.Countries in the world generally produce sky
Heart granular solids detergent, using high tower spray drying method, its master operation has slurry to prepare, is spray-dried, wind send aging
And packaging.Liquid detergent manufacture is easy, need to only send surfactant, auxiliary agent and other additives, and the water through processing
Enter mixer to be mixed.
Existing cleaning agent typically all contains harmful material in the market, and cleaning performance is not good, easily to clear
Washing surface produces destruction, and price is costly.
The content of the invention
In view of this, have that environment-protecting and non-poisonous, safety, financial cost be low, cleaning performance is good it is an object of the present invention to provide one kind
Alkaline cleaner.
In order to solve the above-mentioned technical problem, the technical scheme is that：
A kind of alkaline cleaner, by AEO 50-80g, coconut oil alkanolamide 80-100g, oleic acid three
Monoethanolamine 20-40g, MEA 80-100g, BTA 10-20g, EDETATE SODIUM 10-20g, liquid Lemon acid 20-
30g, silicon potassium acid 16-18g, alkyl benzene sulphonate 14-15g, tetrapotassium pyrophosphate 25-27g, sodium metasilicate 13-14g, diethanol amine 30-
34g, acid dimethyl sodium 7-9g, sodium hydroxide 11-12g and water 700-800g are made.
Further, a kind of alkaline cleaner, by AEO 50g, coconut oil alkanolamide 100g,
Triethanolamine oleate 40g, MEA 100g, BTA 20g, EDETATE SODIUM 20g, liquid Lemon acid 30g, silicon potassium acid
18g, alkyl benzene sulphonate 15g, tetrapotassium pyrophosphate 27g, sodium metasilicate 14g, diethanol amine 34g, acid dimethyl sodium 9g, hydrogen-oxygen
Change sodium 12g and water 800g to be made.
Further, a kind of alkaline cleaner, by AEO 80g, coconut oil alkanolamide 80g,
Triethanolamine oleate 20g, MEA 80g, BTA 10g, EDETATE SODIUM 10g, liquid Lemon acid 20g, silicon potassium acid
16g, alkyl benzene sulphonate 14g, tetrapotassium pyrophosphate 25g, sodium metasilicate 13g, diethanol amine 30g, acid dimethyl sodium 7g, hydrogen-oxygen
Change sodium 11g and water 700g to be made.
Further, a kind of alkaline cleaner, by AEO 65g, coconut oil alkanolamide 90g,
Triethanolamine oleate 30g, MEA 90g, BTA 15g, EDETATE SODIUM 15g, liquid Lemon acid 25g, silicon potassium acid
17g, alkyl benzene sulphonate 14.5g, tetrapotassium pyrophosphate 26g, sodium metasilicate 13.5g, diethanol amine 32.5g, acid dimethyl sodium
8g, sodium hydroxide 11.5g and water 750g are made.
The invention solves the problems that another technical problem to provide a kind of preparation method of alkaline cleaner, including following step
Suddenly：
1) by AEO 50-80g, coconut oil alkanolamide 80-100g and triethanolamine oleate 20-40g
It is placed in mixer, 3~5min is stirred at a temperature of 20~30 DEG C, then pours into liquid in one glass container, is made first
Mixed liquor, it is standby；
2) MEA 80-100g, BTA 10-20g and EDETATE SODIUM 10-20g are placed in mixer, 20
7~10min is stirred at a temperature of~30 DEG C, then pours into liquid in one glass container, the second mixed liquor is made, it is standby；
3) by step 1) the first mixed liquor and step 2 is made) obtained second mixed liquor is poured into pot, and add water 700-
800g, heats 2-3min, and temperature reaches 70 DEG C, then pours into liquid in one glass container, and the 3rd mixed liquor is made, standby；
4) whne step 3) the 3rd mixed liquor is made when being cooled to 30 DEG C, add silicon potassium acid 16-18g, alkyl benzene sulphonate 14-
15g, tetrapotassium pyrophosphate 25-27g and sodium metasilicate 13-14g, are placed in 10~15min of stirring in mixer, then pour into liquid
In one glass container, the 4th mixed liquor is made, it is standby；
5) step 4 is treated) addition diethanol amine 30-34g, acid dimethyl sodium 7-9g and hydrogen-oxygen in the 4th mixed liquor is made
Change sodium 11-12g, be placed in mixer and stir 10min, then filtered, filtered fluid is put into a glass container, be made
5th mixed liquor, it is standby；
6) in step 5) addition liquid Lemon acid 20-30g in the 5th mixed liquor is made, it is placed in mixer and stirs 3min,
Then liquid is poured into a glass container, the 6th mixed liquor is made, it is standby；
7) whne step 6) the 6th mixed liquor is made when being cooled to 15 DEG C, it is bottled to seal up for safekeeping, produce.
The technology of the present invention effect major embodiment is in the following areas：By by AEO, coconut oil alkanol acyl
Amine and triethanolamine oleate are stirred obtained mixed liquor 1 and are made with MEA, BTA and EDETATE SODIUM stirring
Mixed liquor two mix after add water and carry out heating obtained mixed liquor three, silicon potassium acid, alkylbenzene are added after the cooling of mixed liquor three
Sulfonic acid, tetrapotassium pyrophosphate and sodium metasilicate are stirred obtained mixed liquor four, and diethanol amine, two are added in the 4th mixed liquor
Sodium Toluene Sulphonate and sodium hydroxide are stirred, and are then filtered, and the 5th mixed liquor is made, liquid is added in the 5th mixed liquor
Citric acid is stirred, and then cooling is sealed up for safekeeping, and a kind of environment-protecting and non-poisonous, safety, the alkalescence that financial cost is low, cleaning performance is good is made
Cleaning agent.
Embodiment
Embodiment 1
A kind of alkaline cleaner, by AEO 50g, coconut oil alkanolamide 100g, triethanolamine oleate
40g, MEA 100g, BTA 20g, EDETATE SODIUM 20g, liquid Lemon acid 30g, silicon potassium acid 18g, alkyl benzene sulphonate
15g, tetrapotassium pyrophosphate 27g, sodium metasilicate 14g, diethanol amine 34g, acid dimethyl sodium 9g, sodium hydroxide 12g and water
800g is made.
A kind of preparation method of alkaline cleaner, comprises the following steps：
1) AEO 50g, coconut oil alkanolamide 100g and triethanolamine oleate 40g are placed in mixer
In, 5min is stirred at a temperature of 20 DEG C, then pours into liquid in one glass container, the first mixed liquor is made, it is standby；
2) MEA 100g, BTA 20g and EDETATE SODIUM 20g are placed in mixer, at a temperature of 30 DEG C
10min is stirred, then pours into liquid in one glass container, the second mixed liquor is made, it is standby；
3) by step 1) the first mixed liquor and step 2 is made) the second mixed liquor is made pours into pot, and add water 800g,
3min is heated, temperature reaches 70 DEG C, then pours into liquid in one glass container, the 3rd mixed liquor is made, it is standby；
4) whne step 3) the 3rd mixed liquor is made when being cooled to 30 DEG C, add silicon potassium acid 18g, alkyl benzene sulphonate 15g, Jiao's phosphorus
Acid four potassium 27g and sodium metasilicate 14g, are placed in mixer and stir 10min, then pour into liquid in one glass container, are made
4th mixed liquor, it is standby；
5) step 4 is treated) addition diethanol amine 34g, acid dimethyl sodium 9g and sodium hydroxide in the 4th mixed liquor is made
12g, is placed in mixer and stirs 10min, is then filtered, and filtered fluid is put into a glass container, is made the 5th and is mixed
Liquid is closed, it is standby；
6) in step 5) addition liquid Lemon acid 30g in the 5th mixed liquor is made, it is placed in mixer and stirs 3min, then
Liquid is poured into a glass container, the 6th mixed liquor is made, it is standby；
7) whne step 6) the 6th mixed liquor is made when being cooled to 15 DEG C, it is bottled to seal up for safekeeping, produce.
Embodiment 2
A kind of alkaline cleaner, by AEO 80g, coconut oil alkanolamide 80g, triethanolamine oleate
20g, MEA 80g, BTA 10g, EDETATE SODIUM 10g, liquid Lemon acid 20g, silicon potassium acid 16g, alkyl benzene sulphonate
14g, tetrapotassium pyrophosphate 25g, sodium metasilicate 13g, diethanol amine 30g, acid dimethyl sodium 7g, sodium hydroxide 11g and water
700g is made.
A kind of preparation method of alkaline cleaner, comprises the following steps：
1) AEO 80g, coconut oil alkanolamide 80g and triethanolamine oleate 20g are placed in mixer
In, 5min is stirred at a temperature of 20 DEG C, then pours into liquid in one glass container, the first mixed liquor is made, it is standby；
2) MEA 80g, BTA 10g and EDETATE SODIUM 10g are placed in mixer, stirred at a temperature of 30 DEG C
10min is mixed, then pours into liquid in one glass container, the second mixed liquor is made, it is standby；
3) by step 1) the first mixed liquor and step 2 is made) the second mixed liquor is made pours into pot, and add water 700g,
3min is heated, temperature reaches 70 DEG C, then pours into liquid in one glass container, the 3rd mixed liquor is made, it is standby；
4) whne step 3) the 3rd mixed liquor is made when being cooled to 30 DEG C, add silicon potassium acid 16g, alkyl benzene sulphonate 14g, Jiao's phosphorus
Acid four potassium 25g and sodium metasilicate 13g, are placed in mixer and stir 10min, then pour into liquid in one glass container, are made
4th mixed liquor, it is standby；
5) step 4 is treated) addition diethanol amine 30g, acid dimethyl sodium 7g and sodium hydroxide in the 4th mixed liquor is made
11g, is placed in mixer and stirs 10min, is then filtered, and filtered fluid is put into a glass container, is made the 5th and is mixed
Liquid is closed, it is standby；
6) in step 5) addition liquid Lemon acid 20g in the 5th mixed liquor is made, it is placed in mixer and stirs 3min, then
Liquid is poured into a glass container, the 6th mixed liquor is made, it is standby；
7) whne step 6) the 6th mixed liquor is made when being cooled to 15 DEG C, it is bottled to seal up for safekeeping, produce.
Embodiment 3
A kind of alkaline cleaner, by AEO 65g, coconut oil alkanolamide 90g, triethanolamine oleate
30g, MEA 90g, BTA 15g, EDETATE SODIUM 15g, liquid Lemon acid 25g, silicon potassium acid 17g, alkyl benzene sulphonate
14.5g, tetrapotassium pyrophosphate 26g, sodium metasilicate 13.5g, diethanol amine 32.5g, acid dimethyl sodium 8g, sodium hydroxide
11.5g and water 750g are made.
A kind of preparation method of alkaline cleaner, comprises the following steps：
1) AEO 65g, coconut oil alkanolamide 90g and triethanolamine oleate 30g are placed in mixer
In, 5min is stirred at a temperature of 20 DEG C, then pours into liquid in one glass container, the first mixed liquor is made, it is standby；
2) MEA 90g, BTA 15g and EDETATE SODIUM 15g are placed in mixer, stirred at a temperature of 30 DEG C
10min is mixed, then pours into liquid in one glass container, the second mixed liquor is made, it is standby；
3) by step 1) the first mixed liquor and step 2 is made) the second mixed liquor is made pours into pot, and add water 750g,
3min is heated, temperature reaches 70 DEG C, then pours into liquid in one glass container, the 3rd mixed liquor is made, it is standby；
4) whne step 3) the 3rd mixed liquor is made when being cooled to 30 DEG C, add silicon potassium acid 17g, alkyl benzene sulphonate 14.5g, Jiao
The potassium 26g of phosphoric acid four and sodium metasilicate 13.5g, is placed in mixer and stirs 10min, then pours into liquid in one glass container,
The 4th mixed liquor is made, it is standby；
5) step 4 is treated) addition diethanol amine 32.5g, acid dimethyl sodium 8g and hydroxide in the 4th mixed liquor is made
Sodium 11.5g, is placed in mixer and stirs 10min, is then filtered, and filtered fluid is put into a glass container, is made the
Five mixed liquors, it is standby；
6) in step 5) addition liquid Lemon acid 25g in the 5th mixed liquor is made, it is placed in mixer and stirs 3min, then
Liquid is poured into a glass container, the 6th mixed liquor is made, it is standby；
7) whne step 6) the 6th mixed liquor is made when being cooled to 15 DEG C, it is bottled to seal up for safekeeping, produce.
A kind of alkaline cleaner of the present invention is made up of the material such as alkali and surfactant, and alkaline cleaner is utilized
Saponification and emulsification, it is impregnated with wetting action mechanism to remove the metal surface such as sponifiable grease and non-saponified grease grease, soap
Change effect refers to that the vegetable and animals oils main component in the grease of metal surface is the alkali generation tristearin in stearic acid, with alkaline cleaner
Sour sodium is that soap and glycerine dissolving enter alkaline solution, is commonly called as saponification, to remove metal surface grease, emulsification refers to
Emulsifying agent is surface reactive material, is adsorbed on interface, hydrophobic group is towards metallic matrix, and hydrophilic radical solution direction makes gold
Interfacial tension is reduced between category and solution, so that in the presence of the factors such as fluid dynamic, rupture of oil film becomes tiny pearl, is taken off
From metal surface, emulsion is formed into solution, saponification is complementary with emulsification, and mutual cooperation could be removed thoroughly
Metal surface greasy dirt, is impregnated with wetting action and refers to that saponification is progressively to be carried out from greasy surfaces with emulsification, and makes containing alkalescence
The alkaline solution of agent is impregnated with inside grease, is reached and wetted workpieces surface, is enhanced the effect of degreasing degreasing,
Experimental example
Experimental subjects：Using the alkaline cleaner of the present invention as experimental group, ordinary solid cleaning agent as a control group one is special
Liquid ceanser processed as a control group two.
Experimental method：It is dirty to 3 with the alkaline cleaner, ordinary solid cleaning agent and special liquid ceanser of equivalent respectively
Soiled surface is accumulated consistent smoke exhaust ventilator and cleaned, and the cleaning performance and performance of three groups of cleaning agents are contrasted after 10 minutes.
Criterion：
Clean level：After being cleaned using cleaning agent, scavenger surface also has a large amount of dirts for clean level is poor, cleaning materials
Surface also has a small amount of dirt to be that clean level is general, scavenger surface does not have residual soil to be that clean level is good；
Destruction is whether there is to cleaning materials：There is cut, have burn into without destruction；
There is odorlessness：Unpleasant, a little peculiar smell, smell delicate fragrance；
Human body is had no side effect：Hand significant discomfort, hand be a little uncomfortable, without discomfort；
Price：Cheaply, moderate, costliness.
The specific cleaning performance of three groups of smoke exhaust ventilators is as shown in the table：
Table one
The specific performance contrast of three groups of smoke exhaust ventilators is as shown in the table：
Table two
With reference to table one and table two, contrasted by cleaning performance and performance to three groups of cleaning agents, it can be seen that this hair
Bright alkaline cleaner cleaning performance compared with existing ordinary solid cleaning agent and existing special liquid ceanser is good, safety
Environmental protection, moderate cost.
The technology of the present invention effect major embodiment is in the following areas：By by AEO, coconut oil alkanol acyl
Amine and triethanolamine oleate are stirred obtained mixed liquor 1 and are made with MEA, BTA and EDETATE SODIUM stirring
Mixed liquor two mix after add water and carry out heating obtained mixed liquor three, silicon potassium acid, alkylbenzene are added after the cooling of mixed liquor three
Sulfonic acid, tetrapotassium pyrophosphate and sodium metasilicate are stirred obtained mixed liquor four, and diethanol amine, two are added in the 4th mixed liquor
Sodium Toluene Sulphonate and sodium hydroxide are stirred, and are then filtered, and the 5th mixed liquor is made, liquid is added in the 5th mixed liquor
Citric acid is stirred, and then cooling is sealed up for safekeeping, and a kind of environment-protecting and non-poisonous, safety, the alkalescence that financial cost is low, cleaning performance is good is made
Cleaning agent.
Certainly, it is the representative instance of the present invention above, in addition, the present invention can also have other a variety of specific implementations
The technical scheme of mode, all use equivalent substitutions or equivalent transformation formation, all falls within the scope of protection of present invention.
Claims (4)
1. a kind of alkaline cleaner, by AEO 50-80g, coconut oil alkanolamide 80-100g, oily triethylenetetraminehexaacetic acid
Hydramine 20-40g, MEA 80-100g, BTA 10-20g, EDETATE SODIUM 10-20g, liquid Lemon acid 20-30g,
Silicon potassium acid 16-18g, alkyl benzene sulphonate 14-15g, tetrapotassium pyrophosphate 25-27g, sodium metasilicate 13-14g, diethanol amine 30-34g,
Acid dimethyl sodium 7-9g, sodium hydroxide 11-12g and water 700-800g are made.
2. a kind of alkaline cleaner as claimed in claim 1, by AEO 50g, coconut oil alkanolamide
100g, triethanolamine oleate 40g, MEA 100g, BTA 20g, EDETATE SODIUM 20g, liquid Lemon acid 30g, silicon
Potassium acid 18g, alkyl benzene sulphonate 15g, tetrapotassium pyrophosphate 27g, sodium metasilicate 14g, diethanol amine 34g, acid dimethyl sodium 9g,
Sodium hydroxide 12g and water 800g are made.
3. a kind of alkaline cleaner as claimed in claim 1, by AEO 80g, coconut oil alkanolamide
80g, triethanolamine oleate 20g, MEA 80g, BTA 10g, EDETATE SODIUM 10g, liquid Lemon acid 20g, silicon potassium
Sour 16g, alkyl benzene sulphonate 14g, tetrapotassium pyrophosphate 25g, sodium metasilicate 13g, diethanol amine 30g, acid dimethyl sodium 7g, hydrogen
Sodium oxide molybdena 11g and water 700g are made.
4. a kind of alkaline cleaner as claimed in claim 1, by AEO 65g, coconut oil alkanolamide
90g, triethanolamine oleate 30g, MEA 90g, BTA 15g, EDETATE SODIUM 15g, liquid Lemon acid 25g, silicon potassium
Sour 17g, alkyl benzene sulphonate 14.5g, tetrapotassium pyrophosphate 26g, sodium metasilicate 13.5g, diethanol amine 32.5g, acid dimethyl
Sodium 8g, sodium hydroxide 11.5g and water 750g are made.
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| CN109402649A (en) * | 2018-12-27 | 2019-03-01 | 江苏丰东热技术有限公司 | A kind of processing method of workpiece cleaning method and workpiece |
| CN109535568A (en) * | 2018-12-19 | 2019-03-29 | 上海睿聚环保科技有限公司 | A kind of low VOC regenerating polypropylene material and its preparation process |
| CN113201416A (en) * | 2021-05-20 | 2021-08-03 | 中山市迈微环保科技有限公司 | Alkaline multifunctional cleaning agent, preparation method and application thereof |
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Application publication date: 20170829 |