CN107094790A - A kind of composition pesticide acted on Synergistic insecticidal - Google Patents
A kind of composition pesticide acted on Synergistic insecticidal Download PDFInfo
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- CN107094790A CN107094790A CN201710440706.3A CN201710440706A CN107094790A CN 107094790 A CN107094790 A CN 107094790A CN 201710440706 A CN201710440706 A CN 201710440706A CN 107094790 A CN107094790 A CN 107094790A
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- pesticidal combination
- component
- agent
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- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 description 1
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- HXEACLLIILLPRG-YFKPBYRVSA-N L-pipecolic acid Chemical class [O-]C(=O)[C@@H]1CCCC[NH2+]1 HXEACLLIILLPRG-YFKPBYRVSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000255893 Pyralidae Species 0.000 description 1
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- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
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- 239000000205 acacia gum Substances 0.000 description 1
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- 239000001361 adipic acid Substances 0.000 description 1
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical group 0.000 description 1
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- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
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- 150000001413 amino acids Chemical class 0.000 description 1
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- 239000000987 azo dye Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000007938 effervescent tablet Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000013401 experimental design Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
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- 230000012447 hatching Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
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- 230000010534 mechanism of action Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- LEIAZUKOBVWTEH-UHFFFAOYSA-N pyridine-2,5-dicarboxamide Chemical compound NC(=O)C1=CC=C(C(N)=O)N=C1 LEIAZUKOBVWTEH-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protection of plants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Pesticidal combination, its active component (a) comprising cooperative effective quantity and (b), wherein component (a) is compound (1), and component (b) is thiacloprid, the weight ratio most preferably 10 of the two：1.The Pesticidal combination can also include active component (c) triflumuron of cooperative effective quantity, the weight ratio most preferably 10: 1: 1 or 10: 1: 3 of component (a), (b) and (c).Compared with single-activity component, the compounding of two or three of active component generates synergistic function, can effectively prevent and treat lepidoptera pest, such as diamondback moth, cabbage caterpillar, beet armyworm, rice leaf roller or planthopper.The consumption of active component can be reduced simultaneously, extend the development of animal pest resistance.
Description
Technical field
The invention belongs to technical field of pesticide, in particular it relates to a kind of composition pesticide acted on Synergistic insecticidal, its
The purposes of insecticide as preventing and treating animal pest and the method for preventing and treating animal pest.
Background technology
Lepidoptera pest is to be only second to the second largest mesh of coleoptera in Insecta, while being also most one of agriculture and forestry injurious insect
Mesh, such as rice leaf roller, diamondback moth, cabbage caterpillar, beet armyworm are most commonly seen lepidoptera pests.Rice leaf roller belongs to squama
Wing mesh Pyralidae, is one of primary pest of paddy rice.The harmful characteristics of rice leaf roller are caused harm paddy rice with larva, sew leaf into vertical
Bud, hides and wherein takes food epicuticle and mesophyll, is only left white on color lower epidermis, worm bud and shows hickie, when endangering serious, field worm bud
Again and again, it is a piece of withered white.Seedling stage aggrieved influence paddy rice normal growth, in addition it is withered；Tillering stage to the jointing stage is aggrieved, and tiller is reduced,
Plant shortens, and breeding time postpones；Particularly heading is killed to full heading time sword-like leave after booting, and influence is blossomed and beared fruit, and Empty grain rate is improved,
Mass of 1000 kernel declines.Diamondback moth belongs to lepidoptera diamond-back moth section, is the important Leaf-feeding Insects of brassicaceous vegetable, it is considered to be distribution
Widest lepidoptera pest.Cyclostage of diamondback moth is short, breeding amount is big, reproduction speed is fast, generation overlap is serious, adaptability
Wide and can migrate over long distances, the production to brassicaceous vegetable constitutes very big threat.Due to long-term Irrational Use of Drugs, mesh
The resistance of preceding lepidoptera pest gradually increases, and the prevention effect of agricultural chemicals single dose is gradually reduced.The agricultural chemicals of the different mechanisms of action is entered
The resistance that row compounding is used to administer lepidoptera pest is a kind of simple and effective approach.
The compounding of different farm chemical ingredients, according to practical application effect, can produce synergy, plus with three kinds of different works of antagonism
With.Compound pesticide composition with synergistic function can both improve prevention effect, can also reduce Pesticide use amount, delay evil
The development of worm resistance.In the prior art it has been reported that some complex insecticidal compositions with synergistic function, however, by
In pest resistance continue to develop and environmental requirement it is increasingly strict, still have and hold for the efficient composition of this low toxicity
Continuous demand.
The application aims to provide a kind of new composition pesticide that there is Synergistic insecticidal to act on.The present inventor is by largely grinding
Study carefully discovery, compound (1) and thiacloprid compounding composition binary Pesticidal combination, or composition ternary is further compounded with desinsection urea
Pesticidal combination, synergistic function substantially, improves the quick-acting and lasting effect of agricultural chemicals, and to crop safety, to environment friend
It is good.Wherein, compound (1) is documented in WO2014/026984A1 first, and the document shows that the compound has in multiple experiments
There is good insecticidal activity.The chemical name of compound (1) is N5- cyclopropyl -1- ethyl -6- methyl-N2- { 2,2,2- tri-
Fluoro- 1- [3- (trifluoromethyl) phenyl] ethyl } -1H- pyrrolo-es [2,3-b] pyridine -2,5- diformamide.Structural formula is as follows：
The content of the invention
In a first aspect, the application provides a kind of Pesticidal combination, it includes the following active component of cooperative effective quantity：
(a) there is the compound (1) of following formula,
With
(b) thiacloprid；
Wherein the weight ratio of component (a) and (b) is 1: 1 to 20: 1.
Wherein component (a) and (b) weight ratio preferably 1: 1 to 18: 1, more preferably 1: 1 to 15: 1, particularly preferred 1: 1 to
12: 1, most preferably 10: 1.
The Pesticidal combination, it also includes active component (c) triflumuron of cooperative effective quantity, wherein component (a), (b)
Weight ratio is (1-20) (c): 1: (1-5), preferably (5-15): and 1: (1-5), more preferably 10: 1: (1-3), most preferably 10: 1:
1 or 10: 1: 3.
In the context of this application, the Pesticidal combination comprising component (a) and (b) be also referred to as binary Pesticidal combination or
Binary composition, the Pesticidal combination comprising component (a), (b) and (c) is also referred to as ternary Pesticidal combination or ternary composition.
Binary or the ternary Pesticidal combination also includes one or more auxiliary agents in following：Wetting agent, point
It is powder, emulsifying agent, cosurfactant, thickener, solvent, cosolvent, antifreezing agent, preservative, disintegrant, effervesce auxiliary agent, steady
Determine agent, film forming agent, into wafer, pH acid-base modifiers, defoamer, colouring agent, filler and water.
In the binary Pesticidal combination, the component (a) and (b) account for the 1-90% of Pesticidal combination gross weight, excellent
Select 5-60%.
In the ternary Pesticidal combination, the component (a), (b) account for the 1- of Pesticidal combination gross weight with (c)
90%, preferably 5-60%.
Second aspect, the application provides the purposes of the binary or ternary Pesticidal combination for preventing and treating animal pest.
Wherein described insect is lepidoptera pest, such as diamondback moth, cabbage caterpillar, beet armyworm, rice leaf roller or planthopper.
The Pesticidal combination be used for prevent and treat paddy rice, jujube tree, apple, pears, peach, citrus, cotton, wild cabbage, beet, grape or
Insect on potato.
The third aspect, the application provides a kind of method for preventing and treating animal pest, it is characterised in that by the binary or ternary
Pesticidal combination is applied to the plant attacked by animal pest.
Wherein described insect is lepidoptera pest, such as diamondback moth, cabbage caterpillar, beet armyworm, rice leaf roller or planthopper.
Wherein by the Pesticidal combination be applied to the paddy rice attacked by animal pest, jujube tree, apple, pears, peach, citrus,
Cotton, wild cabbage, beet, grape or potato.
In the Pesticidal combination of the present invention, described wetting agent is selected from EO/PO block polyethers, aliphatic alcohol polyethenoxy
Ether, fat alcohol ethoxyl compound, tallow ethyoxyl ammonium salt, alkylnaphthalene sulfonate, fatty alcohol polyoxyethylene ether sulfate and
One or more in acyl group glutamate.
The dispersant be selected from condensation naphthalene sulfonate, phenolsulfonic acid condensation product sodium salt, methyl naphthalene sulfonate formaldehyde condensate,
Sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate, acrylate homopolymer sodium salt, polymeric polycarboxylic acid salt, dioctyl sodium sulfosuccinates
One or more in acid sodium-salt, EO/PO block polyethers and maleic acid-acrylic acid copolymer sodium salt.
Described emulsifying agent be selected from APES, Ben-zylphenol Polyoxyethyl Ether, phenethyl phenol polyethenoxy ether,
AEO, phenethyl phenol polyethenoxy ether polyethenoxy ether, aliphatic amine polyoxyethylene ether, castor oil oxirane
Addition product and its derivative, polyol fatty acid ester and its ethylene oxide adduct, alkylbenzenesulfonate, alkylsulfonate, alkane
Base succinate sulfonate, alkyl biphenyl base ether sulfonate, naphthalene sulfonic acid-formaldehyde condensation product, aliphatic alcohol sulfate, alkyl phenol polyoxy
Ethene ether sulfate, aralkyl phenol polyethenoxy ether sulfate, APES phosphate, phenethyl phenol polyoxyethylene
Ether phosphate, polyoxyethylene carboxylate phosphate, ethoxylated fatty amines phosphate, alkylphosphonic, alkyl phenol polyoxy
Vinethene formaldehyde condensation products, aralkyl phenol polyethenoxy ether formaldehyde condensation products, biphenyl phenol polyethenoxy ether formaldehyde condensation products, polyoxy
Ethene polyoxypropylene block copolymers, alkyl naphthalene sulfonic acid formaldehyde condensation products, phenol formaldehyde condensate sulfonate, alkylphenol-polyethenoxy
Ether formaldehyde condensation products sulfate, contracting methylcellulose and its derivative, alkylammonium salt, amino alcohol fatty acid derivatives, polyamines fat
Pipecolic acid derivative, quaternary ammonium salt, tallow ethyoxyl ammonium salt, alkylnaphthalene sulfonate, amino acid, amine oxide, glycine betaine, poly alkyl alcohol
One or more in oxygen ethene ether sulfate and acyl group glutamate.
One or more of the cosurfactant in n-butanol, isobutanol, n-octyl alcohol, isopropanol.
The thickener is selected from xanthans, Magnesiumaluminumsilicate, sodium carboxymethylcellulose, starch phosphate sodium, octenyl succinic
One or more in acid-starch sodium and polyvinyl alcohol.
One or more of the solvent in dimethylbenzene, turpentine-based vegetable oil, methyl oleate and heavy aromatic solvent oil.
The cosolvent is selected from cyclohexanone, DMA, and/or DMF.
The one kind or many of the antifreezing agent in ethylene glycol, propane diols, glycerine, diethylene glycol, isopropanol and urea
Kind.
The film forming agent is selected from polyvinyl alcohol, polyvinyl acetate, polyethylene glycol, polymethylacrylic acid ethylene glycol
One or more in ester, carboxymethyl cellulose, gum arabic, xanthans and starch.
The cyst material into used in wafer is carbamide resin, is by isocyanate-monomer and polyalcohol or polyamine
It is made by interface polymerization reaction, including isocyanates includes toluene di-isocyanate(TDI), 4,4- diphenylmethane diisocyanates
The multiple methylene polyisocyanates of ester, many phenyl, polyphenyl polymethylene polyisocyanates etc..
The pH acid-base modifiers are selected from citric acid, glacial acetic acid, hydrochloric acid, ammoniacal liquor, triethylamine, triethanolamine and divinyl three
One or more in amine.
One or more of the disintegrant in sodium chloride, ammonium chloride, ammonium sulfate, sodium sulphate and soluble starch.
The effervesce auxiliary agent is selected from citric acid, tartaric acid, adipic acid, fumaric acid, malic acid, potassium citrate dihydrogen, winestone
Acid dihydride potassium, butanedioic acid, sodium carbonate, ammonium carbonate, sodium acid carbonate, calcium carbonate, potassium carbonate, saleratus.
The preservative is selected from Kathon CG, BIT, formaldehyde, phenyl salicylate, sodium benzoate, right
One or more in butoben and potassium sorbate.
The stabilizer is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphite, glycidol ether and pentaerythrite
In one or more.
The defoamer is selected from organic silicon defoamer and/or polyether antifoam agent.
One or more of the colouring agent in iron oxide, titanium oxide and azo dyes.
One or more of the filler in kaolin, diatomite, talcum powder, precipitated calcium carbonate and white carbon.
The water is running water, deionized water or distilled water.
It is preferred that, the formulation of the Pesticidal combination is suspending agent, aqueous emulsion, wettable powder, pulvis, solvable pulvis,
Seed treatment dry powder doses, seed treatment dispersible pulvis, water dispersible granules, granule, microemulsion, missible oil, dry suspending agent, outstanding breast
Agent, microcapsule suspending agent, effervescent tablet, granulae effervescentes seed treatment suspending agent, seed treatment microcapsule suspending agent, suspension seed-coating agent,
Soluble concentrate or dispersible oil-suspending agent.
The Pesticidal combination of the present invention has the advantages that：
(1) component (a) and (b) in Pesticidal combination of the invention have obvious synergistic function, can effectively prevent
Lepidoptera animal pest is controlled, dosage is reduced, while mitigating pressure of the agricultural chemicals to environment；
(2) binary Pesticidal combination of the invention is made up of the active component of different mechanism of action, can effectively delay animal
The generation and development of pest resistance；And
(3) the binary Pesticidal combination comprising component (a) and (b) of the invention can also be with the further compounding group of component (c)
Into ternary Pesticidal combination, still with synergistic function, Lepidoptera animal pest can be effectively prevented and treated, dosage is reduced, prolongs
The development of slow pest resistance.
Embodiment
The present invention is described below in more detail to help to understand the present invention.It is pointed out that following prepare
Example and effect example are only for example, being not limiting as the protection model of the present invention to claimed technical scheme
Enclose.Protection scope of the present invention is defined by the content that claims are recorded.
In the case where being not specifically stated, used term or word have this in the specification and in the claims
The conventional sense in field." about " before numerical value or numeral represents to fluctuate 10% on the basis of the numerical value.As without especially
Indicate, the ratio in the application is weight ratio, and percentage composition is weight percentage.
It is prepared by method of the compound (1) as described in inventor according to patent document WO2014/026984A1.
Those skilled in the art can prepare the compound according to literature method, or according to ordinary skill in the art means system
The standby compound.
The effect example of the application is the method being combined using indoor biological determination of activity and field control effectiveness test.First
By indoor biological determination of activity, clear and definite two kinds of active components compound by a certain percentage after co-toxicity coefficient (CTC), it is basic herein
On, then carry out field control effectiveness test and verify its synergistic effect.Co-toxicity, which is judged, uses Sun Pei cloud methods：Calculate co-toxicity coefficient
(CTC) co-toxicity for, judging two kinds of medicaments with CTC values is acted on.
Actual measurement compounding toxicity index (ATI)=(standard agent LC50)/(reagent agent (compounding) LC50)；
Toxicity index × component (a) of theory compounding toxicity index (TTI) (binary)=component (a) is in complex composition
Content (%)+component (b) content (%) of the toxicity index × component (b) in complex composition；
Toxicity index × component (a) of theory compounding toxicity index (TTI) (ternary)=component (a) is in complex composition
The virulence of content (%)+component (c) of the toxicity index × component (b) in complex composition of content (%)+component (b) refer to
Content (%) of the number × component (c) in complex composition；
Co-toxicity coefficient (CTC)=actual measurement compounding toxicity index (ATI)/theoretical compounding toxicity index (TTI) × 100%；
If co-toxicity coefficient (CTC) ＞ 120, shows there is synergistic effect；If ＜ 80, is shown to be antagonism；Such as
Really >=80 and≤120, then it is shown to be summation action.
First, the indoor biological determination of activity of complex composition
Effect example 1：Toxicity Determination of the binary Pesticidal combination of the present invention to rice leaf roller
For examination insect：Rice leaf roller (Cnaphalocrocis medialis (Guenee))
Test method：Reference《People's Republic of China (PRC) agricultural industry criteria NY/T1154.7-2006》.Rice is gathered from field
The female moth egg of leaf-roller.Female adult is released into cylinder and shrouds interior, interior wall liner coating of wax paper, outer cover black cloth is fed with 10% honeybee
Mulse.Pieces of an egg are cut to put in culture dish and are incubated by next day with paraffin paper, are raised after hatching with the fresh rice leaf of culture.Insectary temperature
(28 ± 1) DEG C, photoperiod 16 (L)：8(D).Choose 2 instar larvaes of growth uniformity, the diameter 12 of fresh rice leaf is put in access
Centimetre culture dish.10 rice leaf roller are put into per ware, 5 wares are often processed as.With Potter spray towers under 50PSI pressure
Spraying, one culture dish of spray, every 3 milliliters of ware spraying liquid, have sprayed and 25 DEG C, 12H/12H light are put into after rear rapid airing rice leaf every time
Cultivated according in incubator, check within 48 hours dead borer population, calculate corrected mortality.Equivalent clear water is sprayed in blank control.
LC is calculated with DPS softwares50And virulence regression equation, asked with reference to NY/T1154.7-2006 using Sun Yunpei method
Go out the co-toxicity coefficient (CTC) of each compound proportion, and evaluate the synergistic effect of the two compounding.Experiment matches and the results are shown in Table 1.
Table 1：Toxicity test result of the binary Pesticidal combination of the present invention to rice leaf roller
Result in table 1 shows that active component (a) and (b) are compounded in the range of weight ratio is 1: 1 to 20: 1 and rice indulged
The co-toxicity coefficient (CTC) of leaf roll snout moth's larva is more than 120, with synergistic function, when the weight ratio of the two is 10: 1, co-toxicity coefficient
For 186.97, synergistic effect is the most notable.And in other weight proportions, co-toxicity coefficient is less than 120, synergy work is not shown
With.
In addition, inventor tests active component (a) with Diacloden or clothianidin (with component respectively in the same manner
(b) it is all novel nicotinamide insecticide) co-toxicity coefficient under above-mentioned each weight proportion, as a result show that co-toxicity coefficient is respectively less than
120, do not show synergistic effect.
Effect example 2：Indoor biological determination of activity of the binary Pesticidal combination of the present invention to wild cabbage diamondback moth
It is wild cabbage diamondback moth (Plutella xylostella (Linneaus)) for examination insect, test method uses virulence
Simultaneous determination method, experiment matches and the results are shown in Table 2.
Table 2：Toxicity test result of the binary Pesticidal combination of the present invention to wild cabbage diamondback moth
Result in table 2 shows that active component (a) and (b) are compounded in the range of weight ratio is 1: 1 to 20: 1 and rice indulged
The co-toxicity coefficient (CTC) of leaf roll snout moth's larva is more than 120, with synergistic function, when the weight ratio of the two is 10: 1, co-toxicity coefficient
For 179.51, synergistic effect is the most notable.And in other weight proportions, co-toxicity coefficient is less than 120, synergy work is not shown
With.
In addition, inventor tests active component (a) with Diacloden or clothianidin (with component respectively in the same manner
(b) it is all novel nicotinamide insecticide) co-toxicity coefficient under above-mentioned each weight proportion, as a result show that co-toxicity coefficient is respectively less than
120, do not show synergistic effect.
Effect example 3：Toxicity Determination of the ternary Pesticidal combination of the present invention to rice leaf roller
Test method matches and the results are shown in Table 3 with effect example 1, experiment.
Table 3：Toxicity test result of the ternary Pesticidal combination of the present invention to rice leaf roller
Result in table 4 shows, on the basis of active component (a) and (b) weight ratio is 10: 1, then adds certain ratio
Active component (c) triflumuron of example (particularly the weight ratio of component (a), (b) and (c) is 10: 1: when (1-3)), can be further
The co-toxicity coefficient (CTC) to wild cabbage diamondback moth is improved, with more obvious synergistic function.
In addition, inventor tests active component (a) and (b) in the base that weight ratio is 10: 1 respectively in the same manner
Flufenoxuron or HEXAFLUMURON (being all benzoylurea derivertives with component (c)) are added on plinth under above-mentioned each weight proportion
Co-toxicity coefficient, as a result shows that adding flufenoxuron or HEXAFLUMURON is not improved the co-toxicity coefficient of the binary composition, without table
Reveal further synergistic effect.
Effect example 4：Indoor biological determination of activity of the ternary Pesticidal combination of the present invention to wild cabbage diamondback moth
Test method matches and the results are shown in Table 4 with effect example 2, experiment.
Table 4：Toxicity test result of the ternary Pesticidal combination of the present invention to wild cabbage diamondback moth
Result in table 4 shows, on the basis of active component (a) and (b) weight ratio is 10: 1, then adds certain ratio
Active component (c) triflumuron of example (particularly the weight ratio of component (a), (b) and (c) is 10: 1: when (1-3)), can be further
The co-toxicity coefficient (CTC) to wild cabbage diamondback moth is improved, with more obvious synergistic function.
In addition, inventor tests active component (a) and (b) in the base that weight ratio is 10: 1 respectively in the same manner
Flufenoxuron or HEXAFLUMURON (being all benzoylurea derivertives with component (c)) are added on plinth under above-mentioned each weight proportion
Co-toxicity coefficient, as a result shows that adding flufenoxuron or HEXAFLUMURON is not improved the co-toxicity coefficient of the binary composition, without table
Reveal further synergistic effect.
2nd, the preparation embodiment of built agent
Preparation example 1：44% binary (10: 1) suspending agent
By 44% active component (40.0% compound (1) and 4.0% thiacloprid), alkylnaphthalene sulfonate 2.0%, macromolecule
Carboxylate 4.0%, phenolsulfonic acid condensation product sodium salt 2.0%, sodium carboxymethylcellulose 0.5%, glycerine 2.0%, potassium sorbate
0.4%th, organic silicon defoamer 0.2%, distilled water are added to 100%, put into high shear homogeneous emulsifying machine high speed shearing 30
Minute, then transport in sand mill, circulation be sanded produce for 2-3 times 44% binary (10: 1) suspending agent.
Preparation example 2：42% binary (20: 1) aqueous emulsion
By 42% active component (40.0% compound (1) and 2.0% thiacloprid), phenethyl phenol polyethenoxy ether phosphate
4.0%th, alkylammonium salt 6.0%, methyl oleate 10.0%, cyclohexanone 5.0%, propane diols 5.0%, distilled water are mended to 100%, are filled
Point mixing again it is clipped produce 42% binary (20: 1) aqueous emulsion.
Preparation example 3：50% binary (1: 1) suspending agent
By 50% active component (25.0% compound (1) and 25.0% thiacloprid), alkylnaphthalene sulfonate 2.0%, fat
Alcohol polyoxyethylene ether sulfate 1.0%, polymeric carboxylic salt 4.0%, xanthans 0.05%, ethylene glycol 4.0%, phenyl salicylate
0.4%th, organic silicon defoamer 0.2%, running water are added to 100%, put into high shear homogeneous emulsifying machine high speed shearing 30
Minute, then transport in sand mill, circulation be sanded produce for 2-3 times 50% binary (1: 1) suspending agent.
Preparation example 4：36% ternary (10: 1: 1) suspending agent
By 36% active component (30.0% compound (1), 3.0% thiacloprid and 3.0% triflumuron), alkylnaphthalene sulfonate
2.0%th, fatty alcohol polyoxyethylene ether sulfate 1.0%, sodium lignin sulfonate 4.0%, xanthans 0.05%, propane diols 4.0%,
Kathon CG 0.4%, organic silicon defoamer 0.2%, deionized water are added to 100%, put into high shear homogeneous emulsifying machine high speed
Shearing 30 minutes, then is transported in sand mill, circulation be sanded produce for 2-3 times 36% ternary (10: 1: 1) suspending agent.
Preparation example 5：40% ternary (10: 1: 3) suspending agent
By 35% active component (25.0% compound (1), 2.5% thiacloprid and 7.5% triflumuron), fatty alcohol polyoxy second
It is alkene ether sulphate 4.0%, phenolsulfonic acid condensation product sodium salt 5.0%, xanthans 0.05%, propane diols 5.0%, Kathon CG 0.4%, poly-
Ether defoaming agent 0.2%, deionized water are added to 100%, are put into high shear homogeneous emulsifying machine high speed and are sheared 30 minutes, then defeated
Into sand mill, circulation be sanded produce for 2-3 times 40% ternary (10: 1: 5) suspending agent.
Comparative example 1：50% compound (1) suspending agent
By 50% compound (1), alkylnaphthalene sulfonate 2.0%, polymeric carboxylic salt 4.0%, phenolsulfonic acid condensation product sodium
Salt 2.0%, sodium carboxymethylcellulose 0.5%, glycerine 2.0%, potassium sorbate 0.4%, organic silicon defoamer 0.2%, distillation
Water is added to 100%, is put into high shear homogeneous emulsifying machine high speed and is sheared 30 minutes, then is transported in sand mill, and circulation is sanded
Compound (1) suspending agent for producing 50% 2-3 times.
Comparative example 2：50% thiacloprid suspending agent
By 50% thiacloprid, alkylnaphthalene sulfonate 2.0%, polymeric carboxylic salt 4.0%, phenolsulfonic acid condensation product sodium salt
2.0%th, sodium carboxymethylcellulose 0.5%, glycerine 2.0%, potassium sorbate 0.4%, organic silicon defoamer 0.2%, distilled water
Add to 100%, put into high shear homogeneous emulsifying machine high speed and shear 30 minutes, then transport in sand mill, 2-3 is sanded in circulation
It is secondary produce 50% thiacloprid suspending agent.
Comparative example 3：50% triflumuron suspending agent
By 50% triflumuron, alkylnaphthalene sulfonate 2.0%, polymeric carboxylic salt 4.0%, phenolsulfonic acid condensation product sodium salt
2.0%th, sodium carboxymethylcellulose 0.5%, glycerine 2.0%, potassium sorbate 0.4%, organic silicon defoamer 0.2%, distilled water
Add to 100%, put into high shear homogeneous emulsifying machine high speed and shear 30 minutes, then transport in sand mill, 2-3 is sanded in circulation
It is secondary produce 50% triflumuron suspending agent.
3rd, the field efficacy experiment of built agent
Effect example 3：The binary and ternary composition of the present invention is used for the field test for preventing and treating early rice rice leaf roller
Experimental design：Live for studying thing for paddy rice, kind is Huaihe River rice No. 8, and controlling object is paddy rice rice leaf roller.
Totally 9 processing of preparation example 1-5, comparative example 1-3 and 1 blank control (aqua sterilisa), each 3 repetitions of processing, totally 27 are set
Cell, each plot area 30m2.Worm radix is looked into before dispenser, the 3rd day after dispenser, the residual worm of cell is investigated within 7 days, 14 days, during investigation
Take at random by cell at 5 points, every investigation 20 is from 1 cell investigates 100 clumps of strippings and looks into all volume bags altogether, and record borer population living is converted into
Hundred clumps of worm amounts.Calculate Revision insect recluced rate and Rectifying efficacies.
Table 5：Field test results of the binary and ternary Pesticidal combination of the present invention to paddy rice rice leaf roller
Above-mentioned result of the test shows that synergistic effect is obvious after binary of the invention and ternary Pesticidal combination compounding, to rice
Leaf-roller has preferable prevention effect, after dispenser 3 days prevention effects more than 85% and after dispenser 7 days and 10 days preventing and treating effect
Fruit is more than 90%, and quick-acting and lasting effect are significantly better than single single dose (i.e. comparative example 1-3).
Effect example 4：The binary and ternary composition of the present invention is used for the field test for preventing and treating wild cabbage diamondback moth
For studying thing for wild cabbage, controlling object is wild cabbage diamondback moth.Preparation example 1-5, comparative example 1-3 and 1 blank are set
(aqua sterilisa) totally 9 processing are compareed, 3 repetitions are each handled, totally 27 cells, each plot area 30m2.Each cell mark
10 plants of note has worm strain, and worm radix is looked into before dispenser, the 3rd day after dispenser, investigates within 7 days, 10 days the residual worm of cell, record borer population living.Calculate
Revision insect recluced rate and Rectifying efficacies.
Table 6：Field test results of the binary and ternary Pesticidal combination of the present invention to wild cabbage diamondback moth
Above-mentioned result of the test shows that synergistic effect is obvious after binary of the invention and ternary Pesticidal combination compounding, to rice
Leaf-roller has preferable prevention effect, after dispenser 3 days prevention effects more than 85% and after dispenser 7 days and 10 days preventing and treating effect
Fruit is more than 90%, and quick-acting and lasting effect are significantly better than single single dose (i.e. comparative example 1-3).
In summary, binary of the invention or ternary Pesticidal combination use the active component with the different mechanisms of action to answer
Match somebody with somebody, under constant weight proportioning, its insecticidal effect is not the simple superposition of each component activity, but generate significant collaboration and increase
Effect is acted on, and quick-acting is improved, lasting effect extension, can effectively prevent and treat lepidoptera pest (such as rice leaf roller and diamondback moth), and can
Delay the generation and development of pest resistance, reduce dosage, environmentally safe, close friend is a kind of with broad mass market prospect
Complex insecticidal composition.
Claims (10)
1. a kind of Pesticidal combination, it includes the following active component of cooperative effective quantity：
(a) there is the compound (1) of following formula,
With
(b) thiacloprid；
Wherein the weight ratio of component (a) and (b) is 1: 1 to 20: 1.
2. the weight ratio preferably 1: 1 to 18: 1 of the Pesticidal combination of claim 1, wherein component (a) and (b), more preferably 1: 1
To 15: 1, particularly preferred 1: 1 to 12: 1, most preferably 10: 1.
3. the Pesticidal combination of claim 1, also comprising one or more auxiliary agents in following：Wetting agent, dispersant,
Emulsifying agent, cosurfactant, thickener, solvent, cosolvent, antifreezing agent, preservative, disintegrant, effervesce auxiliary agent, stabilizer,
Film forming agent, into wafer, pH acid-base modifiers, defoamer, colouring agent, filler and water；Wherein described component (a) and (b) account for desinsection
The 1-90% of composition total weight, preferably 5-60%.
4. any one of claim 1-3 Pesticidal combination, it also includes active component (c) triflumuron of cooperative effective quantity,
Wherein the weight ratio of component (a), (b) and (c) is (1-20): 1: (1-5), preferably (5-15): and 1: (1-5), more preferably 10: 1:
(1-3), most preferably 10: 1: 1 or 10: 1: 3.
5. the Pesticidal combination of claim 4, wherein the component (a), (b) account for the 1- of Pesticidal combination gross weight with (c)
90%, preferably 5-60%.
6. the Pesticidal combination of any one of claim 1 to 5 is used for the purposes for preventing and treating animal pest, wherein the insect is squama
Wing mesh insect, such as diamondback moth, cabbage caterpillar, beet armyworm, rice leaf roller or planthopper.
7. the purposes of claim 6, wherein the Pesticidal combination is used to prevent and treat paddy rice, jujube tree, apple, pears, peach, citrus, cotton
Insect on flower, wild cabbage, beet, grape or potato.
8. a kind of method for preventing and treating animal pest, it is characterised in that apply the Pesticidal combination of any one of claim 1 to 5
For the plant attacked by animal pest.
9. the method for claim 8, wherein the insect is lepidoptera pest, such as diamondback moth, cabbage caterpillar, beet armyworm, rice are indulged
Leaf roll snout moth's larva or planthopper.
10. the method for claim 8 or 9, wherein the Pesticidal combination is applied into the paddy rice attacked by animal pest, jujube
Tree, apple, pears, peach, citrus, cotton, wild cabbage, beet, grape or potato.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102264232A (en) * | 2008-12-31 | 2011-11-30 | 马克特辛姆化学工厂有限公司 | Method for controlling insects in plants |
| WO2014026984A1 (en) * | 2012-08-17 | 2014-02-20 | Bayer Cropscience Ag | Azaindole carboxylic acid amides and azaindole thiocarboxylic acid amides for use as insecticides and acaricides |
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2017
- 2017-06-12 CN CN201710440706.3A patent/CN107094790A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102264232A (en) * | 2008-12-31 | 2011-11-30 | 马克特辛姆化学工厂有限公司 | Method for controlling insects in plants |
| WO2014026984A1 (en) * | 2012-08-17 | 2014-02-20 | Bayer Cropscience Ag | Azaindole carboxylic acid amides and azaindole thiocarboxylic acid amides for use as insecticides and acaricides |
| CN104718206A (en) * | 2012-08-17 | 2015-06-17 | 拜尔农作物科学股份公司 | Azaindole carboxylic acid amides and azaindole thiocarboxylic acid amides for use as insecticides and acaricides |
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