CN107057617A - Effective adhering resin of steel plastic compount and preparation method thereof - Google Patents
Effective adhering resin of steel plastic compount and preparation method thereof Download PDFInfo
- Publication number
- CN107057617A CN107057617A CN201710289832.3A CN201710289832A CN107057617A CN 107057617 A CN107057617 A CN 107057617A CN 201710289832 A CN201710289832 A CN 201710289832A CN 107057617 A CN107057617 A CN 107057617A
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- Prior art keywords
- density polyethylene
- resin
- parts
- hdpe
- antioxidant
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- 239000011347 resin Substances 0.000 title claims abstract description 48
- 229920005989 resin Polymers 0.000 title claims abstract description 48
- 229920003023 plastic Polymers 0.000 title claims abstract description 37
- 239000004033 plastic Substances 0.000 title claims abstract description 37
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 27
- 239000010959 steel Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 32
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 28
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 26
- 238000002844 melting Methods 0.000 claims abstract description 18
- 230000008018 melting Effects 0.000 claims abstract description 18
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 claims abstract description 15
- 239000013078 crystal Substances 0.000 claims abstract description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000003505 terpenes Chemical class 0.000 claims abstract description 13
- 235000007586 terpenes Nutrition 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003999 initiator Substances 0.000 claims abstract description 8
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 7
- 239000003208 petroleum Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 229920004889 linear high-density polyethylene Polymers 0.000 claims abstract description 4
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- -1 polyethylene Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 230000002688 persistence Effects 0.000 abstract description 5
- 239000004840 adhesive resin Substances 0.000 abstract description 2
- 229920006223 adhesive resin Polymers 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 description 14
- 235000006708 antioxidants Nutrition 0.000 description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000008601 oleoresin Substances 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical group [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention proposes a kind of effective adhering resin of steel plastic compount, is made up of following raw material：The mass ratio of linear low density polyethylene (LLDPE), high density polyethylene (HDPE), maleic anhydride, initiator, antioxidant, hydrogenated petroleum resin, terpene resin, calcium sulfate crystal whiskers, acetic acid and viscosity-controlling agent, linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) is 8:1.Preparation method：Heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), then add maleic anhydride, initiator and antioxidant first at 175 DEG C~185 DEG C, after being well mixed, obtain graft copolymer；Hydrogenated petroleum resin, terpene resin, calcium sulfate crystal whiskers and acetic acid are continuously added, melting stirs, finally add viscosity-controlling agent, melting is uniform, and discharge to obtain adhering resin.The effective adhesive resin composition of the steel plastic compount may insure that obtained composited aluminum and plastic decking has good weatherability and persistence.
Description
Technical field
The invention belongs to field of adhesive technology, and in particular to a kind of effective adhering resin of steel plastic compount and its preparation side
Method.
Background technology
Steel-plastics composite pipe abbreviation steelplastic pipe, using steel pipe as base material, not only intensity and toughness with steel pipe, and with modeling
The environmentally-friendly sanitary of expects pipe material, not incrustation, the advantages of water resistance is small.Steel-plastics composite pipe is a kind of high-quality, efficient, high intensity, green ring
Guarantor, moderate novel composite pipe.Supported by national industrial policies within this several years and users accept, quickly grown, city
Field has a high potential.Easily degumming in steel-plastics composite pipe point hot water pipe, but the hot-water line application of most of steel-plastics composite pipe, is caused
Leak and then potential safety hazard is produced, its main cause is exactly to be bonded steel and the PUR properties of product of plastics are undesirable, resistance to cold
Performance is bad, after temperature change, easily produces offset phenomena.
It is made up of, is there is viscous metal and the completely different material of nonmetallic two kinds of property due to steel-plastics composite pipe
Knot problem is, it is necessary to from specific binder resin, just can ensure that obtained composited steel and plastic decking has good weatherability and lasting
Property.In real life application, steelplastic pipe often occurs after using 1 year, ground leak, this is mainly steel-plastics composite pipe
In the case of long term high temperature, what the adhering resin in the middle of tube layer was caused with tube layer degumming.
The content of the invention
The present invention proposes a kind of effective adhering resin of steel plastic compount, and the effective adhesive resin composition of the steel plastic compount can be true
Protecting obtained composited aluminum and plastic decking has good weatherability and persistence.
The technical proposal of the invention is realized in this way：
A kind of effective adhering resin of steel plastic compount, is prepared from the following raw materials in parts by weight：Linear low density polyethylene (LLDPE) 64
~96 parts, 8~12 parts of high density polyethylene (HDPE), 0.5~2.2 part of maleic anhydride, 0.04~0.15 part of initiator, antioxidant 0.1
~0.3 part, 6~12 parts of hydrogenated petroleum resin, 2~6 parts of terpene resin, 2~6 parts of calcium sulfate crystal whiskers, 4~8 parts of acetic acid and glutinous
The mass ratio of 1~4 part of conditioning agent of degree, linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) is 8:1.
Preferably, initiator is cumyl peroxide or benzoyl peroxide.
Preferably, antioxidant is antioxidant 1010, antioxidant 1076 or antioxidant 225.
Preferably, viscosity-controlling agent is Tissuemat E or atoleine.
It is a further object to provide a kind of preparation method of the effective adhering resin of steel plastic compount, first 175
DEG C~185 DEG C at heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), then add maleic anhydride, initiator with it is anti-
Oxidant, after being well mixed, obtains graft copolymer；Continuously add hydrogenated petroleum resin, terpene resin, calcium sulfate crystal whiskers and second
Acid, melting stirs, and finally adds viscosity-controlling agent, and melting is uniform, and discharge to obtain adhering resin.
Beneficial effects of the present invention：
1st, the mass ratio of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) is 8:Under conditions of 1, it is grafted with maleic anhydride
The adhering resin of acquisition has the processing characteristics and condition as polyolefin, while showing splendid adhesive property.175
DEG C~185 DEG C under the conditions of be grafted, improve grafting efficiency.
Connecing before the 2nd, being coordinated using hydrogenated petroleum resin, terpene resin, calcium sulfate crystal whiskers, acetic acid and viscosity-controlling agent
Graft copolymer, improves the cohesive force energy of adhering resin so that it ensures that obtained steel-plastics composite pipe has good weatherability
With persistent purpose.
Embodiment
Embodiment 1
A kind of effective adhering resin of steel plastic compount, is prepared from the following raw materials in parts by weight：Linear low density polyethylene (LLDPE) 80
Part, 10 parts of high density polyethylene (HDPE), 0.8 part of maleic anhydride, 0.08 part of cumyl peroxide, 0.18 part of antioxidant 1010, hydrogen
3 parts of 10 parts of fossil oleoresin, 4 parts of terpene resin, 4 parts of calcium sulfate crystal whiskers, 6 parts of acetic acid and atoleine.
Preparation method, heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), are then added first at 180 DEG C
Maleic anhydride, cumyl peroxide and antioxidant 1010, after being well mixed, obtain graft copolymer；Continuously add hydrogenation
Petropols, terpene resin, calcium sulfate crystal whiskers and acetic acid, melting stir, last adding liquid paraffin, and melting is uniform, goes out
Expect to obtain adhering resin.
The effective binder resin of the present embodiment steel plastic compount reaches 395N/m to the adhesive strength of metallic steel, when it is used to prepare
During steel-plastics composite pipe, it can be ensured that obtained steel-plastics composite pipe has good weatherability and persistence.
Embodiment 2
A kind of effective adhering resin of steel plastic compount, is prepared from the following raw materials in parts by weight：Linear low density polyethylene (LLDPE) 64
Part, 8 parts of high density polyethylene (HDPE), 0.5 part of maleic anhydride, 0.04 part of benzoyl peroxide, 10760.1 parts of antioxidant, hydrogenation stone
1 part of 12 parts of oleoresin, 2 parts of terpene resin, 2 parts of calcium sulfate crystal whiskers, 8 parts of acetic acid and Tissuemat E.
Preparation method, heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), are then added first at 175 DEG C
Maleic anhydride, benzoyl peroxide and antioxidant 1076, after being well mixed, obtain graft copolymer；Continuously add hydrogenation stone
Oleoresin, terpene resin, calcium sulfate crystal whiskers and acetic acid, melting stir, and finally add Tissuemat E, and melting is uniform, discharging
Obtain adhering resin.
The effective binder resin of the present embodiment steel plastic compount reaches 391N/m to the adhesive strength of metallic steel, when it is used to prepare
During steel-plastics composite pipe, it can be ensured that obtained steel-plastics composite pipe has good weatherability and persistence.
Embodiment 3
A kind of effective adhering resin of steel plastic compount, is prepared from the following raw materials in parts by weight：Linear low density polyethylene (LLDPE) 96
Part, 12 parts of high density polyethylene (HDPE), 2.2 parts of maleic anhydride, 0.15 part of cumyl peroxide, 2250.3 parts of antioxidant, hydrogenation
4 parts of 6 parts of Petropols, 6 parts of terpene resin, 6 parts of calcium sulfate crystal whiskers, 4 parts of acetic acid and atoleine.
Preparation method, heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), are then added first at 185 DEG C
Maleic anhydride, cumyl peroxide and antioxidant 225, after being well mixed, obtain graft copolymer；Continuously add hydrogenation stone
Oleoresin, terpene resin, calcium sulfate crystal whiskers and acetic acid, melting stir, last adding liquid paraffin, and melting is uniform, discharging
Obtain adhering resin.
The effective binder resin of the present embodiment steel plastic compount reaches 490N/m to the adhesive strength of metallic steel, when it is used to prepare
During steel-plastics composite pipe, it can be ensured that obtained steel-plastics composite pipe has good weatherability and persistence.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (5)
1. a kind of effective adhering resin of steel plastic compount, it is characterised in that be prepared from the following raw materials in parts by weight：Linear, low density
64~96 parts of polyethylene, 8~12 parts of high density polyethylene (HDPE), 0.5~2.2 part of maleic anhydride, 0.04~0.15 part of initiator, antioxygen
0.1~0.3 part of agent, 6~12 parts of hydrogenated petroleum resin, 2~6 parts of terpene resin, 2~6 parts of calcium sulfate crystal whiskers, 4~8 parts of acetic acid
And 1~4 part of viscosity-controlling agent, the mass ratio of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE) is 8:1.
2. the effective adhering resin of steel plastic compount according to claim 1, it is characterised in that initiator is peroxidating diisopropyl
Benzene or benzoyl peroxide.
3. the effective adhering resin of steel plastic compount according to claim 1, it is characterised in that antioxidant is antioxidant
1010th, antioxidant 1076 or antioxidant 225.
4. the effective adhering resin of steel plastic compount according to claim 1, it is characterised in that viscosity-controlling agent is Tissuemat E
Or atoleine.
5. the preparation method of the effective adhering resin of steel plastic compount as claimed in claim 1, it is characterised in that first at 175 DEG C
Heating melting high density polyethylene (HDPE) and linear low density polyethylene (LLDPE), then add maleic anhydride, initiator and antioxygen at~185 DEG C
Agent, after being well mixed, obtains graft copolymer；Continuously add hydrogenated petroleum resin, terpene resin, calcium sulfate crystal whiskers and second
Acid, melting stirs, and finally adds viscosity-controlling agent, and melting is uniform, and discharge to obtain adhering resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289832.3A CN107057617A (en) | 2017-04-27 | 2017-04-27 | Effective adhering resin of steel plastic compount and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289832.3A CN107057617A (en) | 2017-04-27 | 2017-04-27 | Effective adhering resin of steel plastic compount and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057617A true CN107057617A (en) | 2017-08-18 |
Family
ID=59605330
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710289832.3A Pending CN107057617A (en) | 2017-04-27 | 2017-04-27 | Effective adhering resin of steel plastic compount and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057617A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161730A (en) * | 2010-12-30 | 2011-08-24 | 曲阜市东宏实业有限公司 | Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof |
| CN104388013A (en) * | 2014-12-16 | 2015-03-04 | 广州市合诚化学有限公司 | Adhesive resin with high resistance to water soaking, and preparation method and application thereof |
| CN105694763A (en) * | 2016-02-03 | 2016-06-22 | 长春中科应化材料科技有限公司 | Composite adhesive resin and preparation method and application thereof |
| CN106349976A (en) * | 2016-09-12 | 2017-01-25 | 广州鹿山新材料股份有限公司 | Adhesive resin for steel-mesh reinforcing polyethylene hot water pipe and preparation method of adhesive resin |
-
2017
- 2017-04-27 CN CN201710289832.3A patent/CN107057617A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102161730A (en) * | 2010-12-30 | 2011-08-24 | 曲阜市东宏实业有限公司 | Special adhesive resin for wire-frame-reinforced polyethylene tube and production method thereof |
| CN104388013A (en) * | 2014-12-16 | 2015-03-04 | 广州市合诚化学有限公司 | Adhesive resin with high resistance to water soaking, and preparation method and application thereof |
| CN105694763A (en) * | 2016-02-03 | 2016-06-22 | 长春中科应化材料科技有限公司 | Composite adhesive resin and preparation method and application thereof |
| CN106349976A (en) * | 2016-09-12 | 2017-01-25 | 广州鹿山新材料股份有限公司 | Adhesive resin for steel-mesh reinforcing polyethylene hot water pipe and preparation method of adhesive resin |
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Application publication date: 20170818 |
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