CN107032737A - A kind of construction material of energy-conserving and environment-protective and preparation method thereof - Google Patents
A kind of construction material of energy-conserving and environment-protective and preparation method thereof Download PDFInfo
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- CN107032737A CN107032737A CN201710415136.2A CN201710415136A CN107032737A CN 107032737 A CN107032737 A CN 107032737A CN 201710415136 A CN201710415136 A CN 201710415136A CN 107032737 A CN107032737 A CN 107032737A
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- 239000004035 construction material Substances 0.000 title claims abstract description 77
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 68
- -1 polyethylene Polymers 0.000 claims abstract description 35
- 239000002699 waste material Substances 0.000 claims abstract description 32
- 239000011521 glass Substances 0.000 claims abstract description 30
- 239000004698 Polyethylene Substances 0.000 claims abstract description 29
- 229920000573 polyethylene Polymers 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920003023 plastic Polymers 0.000 claims abstract description 28
- 239000004033 plastic Substances 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 19
- 239000000835 fiber Substances 0.000 claims abstract description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 229960000892 attapulgite Drugs 0.000 claims abstract description 15
- 239000000919 ceramic Substances 0.000 claims abstract description 15
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- 239000011230 binding agent Substances 0.000 claims abstract description 14
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 13
- 239000004566 building material Substances 0.000 claims abstract description 12
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 10
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003500 flue dust Substances 0.000 claims abstract description 8
- 235000019976 tricalcium silicate Nutrition 0.000 claims abstract description 8
- 229910021534 tricalcium silicate Inorganic materials 0.000 claims abstract description 8
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 7
- 238000001125 extrusion Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 18
- 230000007613 environmental effect Effects 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 235000019353 potassium silicate Nutrition 0.000 claims description 11
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 11
- 238000004134 energy conservation Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000010426 asphalt Substances 0.000 claims description 6
- 238000001746 injection moulding Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 6
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 6
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003610 charcoal Substances 0.000 claims description 4
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 3
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 3
- 241001330002 Bambuseae Species 0.000 claims description 3
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 3
- 239000011425 bamboo Substances 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 2
- SDKTUKJXHDZWMB-UHFFFAOYSA-N phosphoric acid zirconium Chemical compound [Zr].P(O)(O)(O)=O SDKTUKJXHDZWMB-UHFFFAOYSA-N 0.000 claims 2
- 239000004952 Polyamide Substances 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical group CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 abstract description 16
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 abstract description 16
- 230000006835 compression Effects 0.000 abstract description 10
- 238000007906 compression Methods 0.000 abstract description 10
- 230000002742 anti-folding effect Effects 0.000 abstract description 5
- 230000007812 deficiency Effects 0.000 abstract description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 39
- 238000009413 insulation Methods 0.000 description 15
- 235000006708 antioxidants Nutrition 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 231100000252 nontoxic Toxicity 0.000 description 10
- 230000003000 nontoxic effect Effects 0.000 description 10
- 231100000614 poison Toxicity 0.000 description 10
- 230000007096 poisonous effect Effects 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 238000005452 bending Methods 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical group [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 5
- 229940063655 aluminum stearate Drugs 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 230000001351 cycling effect Effects 0.000 description 5
- 238000013016 damping Methods 0.000 description 5
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical group C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 description 5
- 230000029058 respiratory gaseous exchange Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 230000001934 delay Effects 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 229940037003 alum Drugs 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 3
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 2
- 235000011092 calcium acetate Nutrition 0.000 description 2
- 239000001639 calcium acetate Substances 0.000 description 2
- 229960005147 calcium acetate Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00025—Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of construction material of energy-conserving and environment-protective and preparation method thereof, is related to building material field, the construction material of energy-conserving and environment-protective includes the raw material of following parts by weight：59 parts of nano titanium oxide, 7 11 parts of pitch, 11 15 parts of bauxite, 8 10 parts of tricalcium silicate, 48 parts of acrylic resin, 13 21 parts of flue dust, basic zirconium phosphate carries 12 18 parts of silver powder, 13 17 parts of scrap glass, 59 parts of waste polyethylene foamed plastics, 9 13 parts of ceramic fibre, 7 11 parts of Fypro, 13 17 parts of activated carbon, 13 23 parts of attapulgite, 11 21 parts of diatomite, 24 parts of binding agent, 0.5 0.9 parts of retarder, 0.1 0.5 parts of antioxidant, 0.3 0.9 parts of heat stabilizer, 57 parts of 0.2 0.4 parts of water reducer and water；Preparation method comprises the following steps：（1）Weigh raw material, (2) heating,（3）Crush,（4）Stirring,（5）Extrusion forming,（6）Drying.The present invention solve existing building material applied to energy-conserving and environment-protective, resistance to compression, anti-folding, tensile property are required it is high it is architectural also there is deficiency the problem of.
Description
Technical field
The invention belongs to building material field, and in particular to a kind of construction material of energy-conserving and environment-protective and preparation method thereof.
Background technology
With social progress and the raising of living standards of the people, requirement more and more higher of the people to construction material, especially
Construction material with superior energy-conserving and environment-protective performance, still, generally existing effects of energy conservation and environmental protection in existing construction material
General the problem of, it is impossible to the building applied to high standards.
Further, since construction material is widely used, in addition to above-mentioned energy-conserving and environment-protective performance, for its resistance to compression, anti-folding,
Tensile property is also required to further reinforcement so that the functional diversities of construction material, can adapt to the high building of combination property.
Therefore, existing building material is formulated to it in the building in face of high standards and stills need further improvement,
Make it in addition to good energy-conserving and environment-protective performance, also with good resistance to compression, anti-folding, tensile property, can adapt to existing
High standards of the generation building to the combination property of construction material.
The content of the invention
In order to solve existing building material high building is being required applied to energy-conserving and environment-protective, resistance to compression, anti-folding, tensile property
On the problem of also there is deficiency, it is an object of the invention to provide a kind of construction material of energy-conserving and environment-protective and preparation method thereof, system
Energy-conserving and environment-protective construction material have that effects of energy conservation and environmental protection is good, compression strength is high, that High anti bending strength, tensile strength are high is excellent
Point.
The invention provides following technical scheme：
A kind of construction material of energy-conserving and environment-protective, includes the raw material of following parts by weight：5-9 parts of nano titanium oxide, 7-11 parts of pitch,
11-15 parts of bauxite, 8-10 parts of tricalcium silicate, 4-8 parts of acrylic resin, 13-21 parts of flue dust, basic zirconium phosphate carry silver powder 12-18
Part, 13-17 parts of scrap glass, 5-9 parts of waste polyethylene foamed plastics, 9-13 parts of ceramic fibre, 7-11 parts of Fypro, work
It is 13-17 parts of charcoal of property, 13-23 parts of attapulgite, 11-21 parts of diatomite, 2-4 parts of binding agent, 0.5-0.9 parts of retarder, anti-oxidant
5-7 parts of 0.1-0.5 parts of agent, 0.3-0.9 parts of heat stabilizer, 0.2-0.4 parts of water reducer and water.
Scrap glass and waste polyethylene foamed plastics, scrap glass and waste polyethylene are with the addition of in the raw material of the present invention
Foamed plastics is shelved on city for a long time as construction waste, does not only take up urban land, and the local environment of pollution, now will
Scrap glass and waste polyethylene foamed plastics cycling and reutilization, have reached the purpose of energy-conserving and environment-protective；Scrap glass has heat-insulated
Property good and intensity it is high the characteristics of；Waste polyethylene foamed plastics has that resiliency is good, heat-resist, heat insulation property is good and chemical
The characteristics of stability is good.
With the addition of in raw material basic zirconium phosphate carry silver powder, basic zirconium phosphate carry silver powder have antibacterial, the growth that harmful bacteria can be suppressed and
The characteristics of safety non-toxic.
It with the addition of ceramic fibre in raw material, ceramic fibre has that light weight, high temperature resistant, heat endurance be good, heat insulation property is good
The characteristics of with tension High anti bending strength.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Activated carbon is with the addition of in raw material, activated carbon is loose structure, can adsorb the poisonous of formaldehyde etc. in air has
Evil material.
Attapulgite is with the addition of in raw material, attapulgite has good thixotropy, good leveling property, good weatherability, thermal insulation good
The good advantage with disinfection.
Diatomite is with the addition of in raw material, diatomite has natural micropore structure, can realize breathing damping, while it may be used also
To adsorb the poisonous and harmful substance of formaldehyde etc. in air.
Preferably, the raw material of following parts by weight is included：7 parts of nano titanium oxide, 9 parts of pitch, 13 parts of bauxite, silicic acid three
9 parts of calcium, 6 parts of acrylic resin, 17 parts of flue dust, basic zirconium phosphate carry 15 parts of silver powder, 11 parts of glass fibre, 9 parts of polyester fiber, bamboo charcoal
15 parts, 18 parts of bentonite, 16 parts of diatomite, 3 parts of binding agent, 0.7 part of retarder, 0.3 part of antioxidant, 0.6 part of heat stabilizer,
6 parts of 0.3 part of water reducer and water.
Preferably, the binding agent is waterglass, and waterglass has the characteristics of caking property is strong, intensity is high and heat-resist,
Improve the intensity of the construction material of energy-conserving and environment-protective.
Preferably, the retarder is sodium pyrophosphate, delays the time of the raw material hardening of the construction material of energy-conserving and environment-protective, makes
Must by extend mixing time by raw material stir it is more uniform, so as to improve the intensity of the construction material of energy-conserving and environment-protective.
Preferably, the antioxidant is thio-2 acid 2 stearyl ester, can prevent or delay building for energy-conserving and environment-protective
Build material oxidation.
Preferably, the heat stabilizer is aluminum stearate, it is possible to increase the thermostability of the construction material of energy-conserving and environment-protective.
Preferably, the water reducer is poly carboxylic acid series water reducer, with volume is low, water-reducing rate is up to 45%, shrink small, production
Product stability is good, environmental protection, cost is low, convenient and safety advantage when using.
A kind of preparation method of the construction material of energy-conserving and environment-protective, comprises the following steps：
（1）Parts by weight according to the raw material of building materials of energy-conserving and environment-protective weigh raw material；
（2）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（3）Scrap glass and waste polyethylene foamed plastics are added into pulverizer to crush, crushed material is produced；
（4）By step（2）In heated asphalt, step（3）In crushed material and other surplus stocks be added in mixer and stir
Mix, mixing time is 30-40min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 4-5h, produces energy-conservation
The construction material of environmental protection.
The beneficial effects of the invention are as follows：
1st, the present invention solves existing building material and is requiring high build applied to energy-conserving and environment-protective, resistance to compression, anti-folding, tensile property
Build the problem of also there is deficiency.
2nd, scrap glass and waste polyethylene foamed plastics, scrap glass and discarded poly- second are with the addition of in raw material of the invention
Alkene foamed plastics is shelved on city for a long time as construction waste, does not only take up urban land, and the local environment of pollution, existing
By scrap glass and waste polyethylene foamed plastics cycling and reutilization, the purpose of energy-conserving and environment-protective has been reached；Scrap glass have every
The characteristics of hot good and intensity is high；Waste polyethylene foamed plastics has that resiliency is good, heat-resist, heat insulation property is good and changes
Learn the characteristics of stability is good.
3rd, basic zirconium phosphate is with the addition of in raw material of the invention and carries silver powder, basic zirconium phosphate, which carries silver powder, to be had antibacterial, can suppress harmful thin
The characteristics of growth of bacterium and safety non-toxic.
4th, it with the addition of ceramic fibre in raw material of the invention, ceramic fibre has that light weight, high temperature resistant, heat endurance are good, protect
Warm thermal insulation is good and the characteristics of tension High anti bending strength.
5th, with the addition of Fypro in raw material of the invention, Fypro have nontoxic, light weight, high mechanical strength,
The characteristics of wearability is good and elastic good.
6th, activated carbon is with the addition of in raw material of the invention, activated carbon is loose structure, can adsorb such as formaldehyde in air
Deng poisonous and harmful substance.
7th, attapulgite is with the addition of in raw material of the invention, attapulgite has good thixotropy, good leveling property, weatherability
Good, thermal insulation is good and the good advantage of disinfection.
8th, diatomite is with the addition of in raw material of the invention, diatomite has natural micropore structure, can realize breathing damping,
It can also adsorb the poisonous and harmful substance of formaldehyde etc. in air simultaneously.
9th, heretofore described binding agent is waterglass, and waterglass has the spy that caking property is strong, intensity is high and heat-resist
Point, improves the intensity of the construction material of energy-conserving and environment-protective.
10th, heretofore described retarder be sodium pyrophosphate, delay energy-conserving and environment-protective construction material raw material hardening when
Between so that by extend mixing time by raw material stir it is more uniform, so as to improve the intensity of the construction material of energy-conserving and environment-protective.
11st, heretofore described antioxidant is thio-2 acid 2 stearyl ester, can prevent or delay energy-conserving and environment-protective
Construction material oxidation.
12nd, heretofore described heat stabilizer is aluminum stearate, it is possible to increase the thermostability of the construction material of energy-conserving and environment-protective.
13rd, heretofore described water reducer is poly carboxylic acid series water reducer, with volume is low, water-reducing rate is up to 45%, shrink
Small, product stability is good, environmental protection, cost is low, convenient and safety advantage when using.
Embodiment
Embodiment 1
A kind of construction material of energy-conserving and environment-protective, includes the raw material of following parts by weight：7 parts of nano titanium oxide, 9 parts of pitch, aluminium alum
13 parts of soil, 9 parts of tricalcium silicate, 6 parts of acrylic resin, 17 parts of flue dust, basic zirconium phosphate carry 15 parts of silver powder, 11 parts of glass fibre, gathered
9 parts of ester fiber, 15 parts of bamboo charcoal, 18 parts of bentonite, 16 parts of diatomite, 3 parts of binding agent, 0.7 part of retarder, 0.3 part of antioxidant,
6 parts of 0.6 part of heat stabilizer, 0.3 part of water reducer and water.
Scrap glass and waste polyethylene foamed plastics, scrap glass and waste polyethylene are with the addition of in the raw material of the present invention
Foamed plastics is shelved on city for a long time as construction waste, does not only take up urban land, and the local environment of pollution, now will
Scrap glass and waste polyethylene foamed plastics cycling and reutilization, have reached the purpose of energy-conserving and environment-protective；Scrap glass has heat-insulated
Property good and intensity it is high the characteristics of；Waste polyethylene foamed plastics has that resiliency is good, heat-resist, heat insulation property is good and chemical
The characteristics of stability is good.
With the addition of in raw material basic zirconium phosphate carry silver powder, basic zirconium phosphate carry silver powder have antibacterial, the growth that harmful bacteria can be suppressed and
The characteristics of safety non-toxic.
It with the addition of ceramic fibre in raw material, ceramic fibre has that light weight, high temperature resistant, heat endurance be good, heat insulation property is good
The characteristics of with tension High anti bending strength.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Activated carbon is with the addition of in raw material, activated carbon is loose structure, can adsorb the poisonous of formaldehyde etc. in air has
Evil material.
Attapulgite is with the addition of in raw material, attapulgite has good thixotropy, good leveling property, good weatherability, thermal insulation good
The good advantage with disinfection.
Diatomite is with the addition of in raw material, diatomite has natural micropore structure, can realize breathing damping, while it may be used also
To adsorb the poisonous and harmful substance of formaldehyde etc. in air.
Binding agent is waterglass, and waterglass has the characteristics of caking property is strong, intensity is high and heat-resist, improves energy-saving ring
The intensity of the construction material of guarantor.
Retarder is sodium pyrophosphate, delays the time of the raw material hardening of the construction material of energy-conserving and environment-protective so that pass through extension
Mixing time by raw material stir it is more uniform, so as to improve the intensity of the construction material of energy-conserving and environment-protective.
Antioxidant is thio-2 acid 2 stearyl ester, can prevent or delay the construction material of energy-conserving and environment-protective to aoxidize.
Heat stabilizer is aluminum stearate, it is possible to increase the thermostability of the construction material of energy-conserving and environment-protective.
Water reducer is poly carboxylic acid series water reducer, with volume is low, water-reducing rate is up to 45%, to shrink small, product stability good,
Environmental protection, cost is low, convenient and safety advantage when using.
A kind of preparation method of the construction material of energy-conserving and environment-protective, comprises the following steps：
（1）Parts by weight according to the raw material of building materials of energy-conserving and environment-protective weigh raw material；
（2）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（3）Scrap glass and waste polyethylene foamed plastics are added into pulverizer to crush, crushed material is produced；
（4）By step（2）In heated asphalt, step（3）In crushed material and other surplus stocks be added in mixer and stir
Mix, mixing time is 30-40min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 4-5h, produces energy-conservation
The construction material of environmental protection.
Embodiment 2
A kind of construction material of energy-conserving and environment-protective, includes the raw material of following parts by weight：5 parts of nano titanium oxide, 7 parts of pitch, aluminium alum
11 parts of soil, 8 parts of tricalcium silicate, 4 parts of acrylic resin, 13 parts of flue dust, basic zirconium phosphate carry 12 parts of silver powder, 13 parts of scrap glass, given up
Abandon 5 parts of polyethylene foams, 9 parts of ceramic fibre, 7 parts of Fypro, 13 parts of activated carbon, 13 parts of attapulgite, diatomite
5 parts of 11 parts, 2 parts of binding agent, 0.5 part of retarder, 0.1 part of antioxidant, 0.3 part of heat stabilizer, 0.2 part of water reducer and water.
Scrap glass and waste polyethylene foamed plastics, scrap glass and waste polyethylene are with the addition of in the raw material of the present invention
Foamed plastics is shelved on city for a long time as construction waste, does not only take up urban land, and the local environment of pollution, now will
Scrap glass and waste polyethylene foamed plastics cycling and reutilization, have reached the purpose of energy-conserving and environment-protective；Scrap glass has heat-insulated
Property good and intensity it is high the characteristics of；Waste polyethylene foamed plastics has that resiliency is good, heat-resist, heat insulation property is good and chemical
The characteristics of stability is good.
With the addition of in raw material basic zirconium phosphate carry silver powder, basic zirconium phosphate carry silver powder have antibacterial, the growth that harmful bacteria can be suppressed and
The characteristics of safety non-toxic.
It with the addition of ceramic fibre in raw material, ceramic fibre has that light weight, high temperature resistant, heat endurance be good, heat insulation property is good
The characteristics of with tension High anti bending strength.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Activated carbon is with the addition of in raw material, activated carbon is loose structure, can adsorb the poisonous of formaldehyde etc. in air has
Evil material.
Attapulgite is with the addition of in raw material, attapulgite has good thixotropy, good leveling property, good weatherability, thermal insulation good
The good advantage with disinfection.
Diatomite is with the addition of in raw material, diatomite has natural micropore structure, can realize breathing damping, while it may be used also
To adsorb the poisonous and harmful substance of formaldehyde etc. in air.
Binding agent is waterglass, and waterglass has the characteristics of caking property is strong, intensity is high and heat-resist, improves energy-saving ring
The intensity of the construction material of guarantor.
Retarder is sodium pyrophosphate, delays the time of the raw material hardening of the construction material of energy-conserving and environment-protective so that pass through extension
Mixing time by raw material stir it is more uniform, so as to improve the intensity of the construction material of energy-conserving and environment-protective.
Antioxidant is thio-2 acid 2 stearyl ester, can prevent or delay the construction material of energy-conserving and environment-protective to aoxidize.
Heat stabilizer is aluminum stearate, it is possible to increase the thermostability of the construction material of energy-conserving and environment-protective.
Water reducer is poly carboxylic acid series water reducer, with volume is low, water-reducing rate is up to 45%, to shrink small, product stability good,
Environmental protection, cost is low, convenient and safety advantage when using.
A kind of preparation method of the construction material of energy-conserving and environment-protective, comprises the following steps：
（1）Parts by weight according to the raw material of building materials of energy-conserving and environment-protective weigh raw material；
（2）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（3）Scrap glass and waste polyethylene foamed plastics are added into pulverizer to crush, crushed material is produced；
（4）By step（2）In heated asphalt, step（3）In crushed material and other surplus stocks be added in mixer and stir
Mix, mixing time is 30-40min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 4-5h, produces energy-conservation
The construction material of environmental protection.
Embodiment 3
A kind of construction material of energy-conserving and environment-protective, includes the raw material of following parts by weight：9 parts of nano titanium oxide, 11 parts of pitch, aluminium alum
15 parts of soil, 10 parts of tricalcium silicate, 8 parts of acrylic resin, 21 parts of flue dust, basic zirconium phosphate carry 18 parts of silver powder, 17 parts of scrap glass, given up
Abandon 9 parts of polyethylene foams, 13 parts of ceramic fibre, 11 parts of Fypro, 17 parts of activated carbon, 23 parts of attapulgite, diatom
7 parts of 21 parts of soil, 4 parts of binding agent, 0.9 part of retarder, 0.5 part of antioxidant, 0.9 part of heat stabilizer, 0.4 part of water reducer and water.
Scrap glass and waste polyethylene foamed plastics, scrap glass and waste polyethylene are with the addition of in the raw material of the present invention
Foamed plastics is shelved on city for a long time as construction waste, does not only take up urban land, and the local environment of pollution, now will
Scrap glass and waste polyethylene foamed plastics cycling and reutilization, have reached the purpose of energy-conserving and environment-protective；Scrap glass has heat-insulated
Property good and intensity it is high the characteristics of；Waste polyethylene foamed plastics has that resiliency is good, heat-resist, heat insulation property is good and chemical
The characteristics of stability is good.
With the addition of in raw material basic zirconium phosphate carry silver powder, basic zirconium phosphate carry silver powder have antibacterial, the growth that harmful bacteria can be suppressed and
The characteristics of safety non-toxic.
It with the addition of ceramic fibre in raw material, ceramic fibre has that light weight, high temperature resistant, heat endurance be good, heat insulation property is good
The characteristics of with tension High anti bending strength.
With the addition of Fypro in raw material, Fypro have nontoxic, light weight, high mechanical strength, wearability good and
The characteristics of elasticity is good.
Activated carbon is with the addition of in raw material, activated carbon is loose structure, can adsorb the poisonous of formaldehyde etc. in air has
Evil material.
Attapulgite is with the addition of in raw material, attapulgite has good thixotropy, good leveling property, good weatherability, thermal insulation good
The good advantage with disinfection.
Diatomite is with the addition of in raw material, diatomite has natural micropore structure, can realize breathing damping, while it may be used also
To adsorb the poisonous and harmful substance of formaldehyde etc. in air.
Binding agent is waterglass, and waterglass has the characteristics of caking property is strong, intensity is high and heat-resist, improves energy-saving ring
The intensity of the construction material of guarantor.
Retarder is sodium pyrophosphate, delays the time of the raw material hardening of the construction material of energy-conserving and environment-protective so that pass through extension
Mixing time by raw material stir it is more uniform, so as to improve the intensity of the construction material of energy-conserving and environment-protective.
Antioxidant is thio-2 acid 2 stearyl ester, can prevent or delay the construction material of energy-conserving and environment-protective to aoxidize.
Heat stabilizer is aluminum stearate, it is possible to increase the thermostability of the construction material of energy-conserving and environment-protective.
Water reducer is poly carboxylic acid series water reducer, with volume is low, water-reducing rate is up to 45%, to shrink small, product stability good,
Environmental protection, cost is low, convenient and safety advantage when using.
A kind of preparation method of the construction material of energy-conserving and environment-protective, comprises the following steps：
（1）Parts by weight according to the raw material of building materials of energy-conserving and environment-protective weigh raw material；
（2）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（3）Scrap glass and waste polyethylene foamed plastics are added into pulverizer to crush, crushed material is produced；
（4）By step（2）In heated asphalt, step（3）In crushed material and other surplus stocks be added in mixer and stir
Mix, mixing time is 30-40min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 4-5h, produces energy-conservation
The construction material of environmental protection.
Comparative example 1
A kind of construction material of nano energy-saving environment-friendly, includes the raw material of following parts by weight：6.5 parts of nano titanium oxide, pitch 11
Part, 15 parts of bauxite, 10.5 parts of tricalcium silicate, 6.5 parts of acrylic resin, 8 parts of quartz, 7 parts of calcium acetate and 20 parts of water.
A kind of preparation method of the construction material of nano energy-saving environment-friendly, comprises the following steps：
（1）Parts by weight according to the raw material of building materials of nano energy-saving environment-friendly weigh raw material；
（2）By quartz grinds, the mesh number of powder is 300 mesh；
（3）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（4）By step（2）In 300 mesh silica flours, step（3）In heated asphalt, nano titanium oxide, bauxite, silicic acid
DFP, acrylic resin, calcium acetate and water are added in mixer and stirred, and mixing time is 30-45min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 5-6h, produces nanometer
The construction material of energy-conserving and environment-protective.
By nano-energy-saving made from the construction material and comparative example 1 of energy-conserving and environment-protective made from embodiment 1, embodiment 2 and embodiment 3
The construction material of environmental protection carries out performance test, and test result is as shown in table 1：
| Index | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Rupture strength（MPa） | 44.2 | 38.2 | 35.5 | 30.5 |
| Compression strength（MPa） | 88.2 | 73.2 | 66.2 | 53.6 |
| Tensile strength（MPa） | 89.1 | 74.2 | 67.1 | 52.3 |
| Purifying formaldehyde performance (%) | 85 | 79 | 74 | 56 |
| Anti-microbial property (%) | 81 | 73 | 65 | 57 |
| Material loss slip（%） | 29 | 24 | 20 | 0 |
From the data of table 1 compare as can be seen that it is an advantage of the invention that：
1st, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, from the rupture strength value measured as can be seen that embodiment 1-3
Rupture strength value be above comparative example 1, illustrate the High anti bending strength of the construction material of energy-conserving and environment-protective of the present invention.
2nd, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, implementation is can be seen that from the compression strength value measured
Example 1-3 compression strength value is above comparative example 1, illustrates that the compression strength of the construction material of energy-conserving and environment-protective of the present invention is high.
3rd, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, implementation is can be seen that from the tensile strength values measured
Example 1-3 tensile strength values are above comparative example 1, illustrate that the tensile strength of the construction material of energy-conserving and environment-protective of the present invention is high.
4th, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, reality is can be seen that from the purifying formaldehyde performance measured
The purifying formaldehyde performance for applying a 1-3 is above comparative example 1, illustrates that the feature of environmental protection of the construction material of the energy-conserving and environment-protective of the present invention is good.
5th, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, from the anti-microbial property measured as can be seen that embodiment
1-3 anti-microbial property is above comparative example 1, illustrates that the feature of environmental protection of the construction material of the energy-conserving and environment-protective of the present invention is good.
6th, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, can be seen that from the material loss slip measured
Embodiment 1-3 material loss slip is above comparative example 1, illustrates the energy saving of the construction material of the energy-conserving and environment-protective of the present invention
It is good.
7th, a kind of construction material of energy-conserving and environment-protective and preparation method thereof, can be seen that from the data of each index measured
Embodiment 1 is superior to embodiment 2, embodiment 3 and comparative example 1, illustrates the composition of raw materials of the construction material of energy-conserving and environment-protective of the present invention
With the reasonability of preparation method.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or equivalent substitution, all essences in the present invention are carried out to which part technical characteristic
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of construction material of energy-conserving and environment-protective, it is characterised in that include the raw material of following parts by weight：Nano titanium oxide 5-9
Part, 7-11 parts of pitch, 11-15 parts of bauxite, 8-10 parts of tricalcium silicate, 4-8 parts of acrylic resin, 13-21 parts of flue dust, phosphoric acid
Zirconium carries 12-18 parts of silver powder, 13-17 parts of scrap glass, 5-9 parts of waste polyethylene foamed plastics, 9-13 parts of ceramic fibre, polyamide
7-11 parts of fiber, 13-17 parts of activated carbon, 13-23 parts of attapulgite, 11-21 parts of diatomite, 2-4 parts of binding agent, retarder 0.5-
5-7 parts of 0.9 part, 0.1-0.5 parts of antioxidant, 0.3-0.9 parts of heat stabilizer, 0.2-0.4 parts of water reducer and water.
2. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that include the raw material of following parts by weight：
7 parts of nano titanium oxide, 9 parts of pitch, 13 parts of bauxite, 9 parts of tricalcium silicate, 6 parts of acrylic resin, 17 parts of flue dust, phosphoric acid
Zirconium carries 15 parts of silver powder, 11 parts of glass fibre, 9 parts of polyester fiber, 15 parts of bamboo charcoal, 18 parts of bentonite, 16 parts of diatomite, binding agent 3
Part, 0.7 part of retarder, 0.3 part of antioxidant, 0.6 part of heat stabilizer, 0.3 part of water reducer and 6 parts of water.
3. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that：The binding agent is waterglass.
4. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that：The retarder is sodium pyrophosphate.
5. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that：The antioxidant is thio dipropyl
Sour distearyl alcohol ester.
6. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that：The heat stabilizer is stearic acid
Aluminium.
7. the construction material of energy-conserving and environment-protective according to claim 1, it is characterised in that：The water reducer subtracts for polycarboxylic-acid
Aqua.
8. a kind of preparation method of the construction material of energy-conserving and environment-protective as described in claim 1-7 any one, its feature exists
In comprising the following steps：
（1）Parts by weight according to the raw material of building materials of energy-conserving and environment-protective weigh raw material；
（2）Pitch is heated to 90 DEG C, pitch is in heating process along with stirring；
（3）Scrap glass and waste polyethylene foamed plastics are added into pulverizer to crush, crushed material is produced；
（4）By step（2）In heated asphalt, step（3）In crushed material and other surplus stocks be added in mixer and stir
Mix, mixing time is 30-40min, produces compound；
（5）By step（4）In compound injection moulding mould in, extrusion forming, produce molding mass；
（6）By step（5）In molding mass dried, drying temperature be 85-90 DEG C, drying time is 4-5h, produces energy-conservation
The construction material of environmental protection.
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| CN201710415136.2A CN107032737A (en) | 2017-06-05 | 2017-06-05 | A kind of construction material of energy-conserving and environment-protective and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986680A (en) * | 2017-12-06 | 2018-05-04 | 付主枝 | The preparation method and applications of energy conservation and environmental protection construction material |
| CN108314368A (en) * | 2018-04-16 | 2018-07-24 | 合肥月煌新型装饰材料有限公司 | A kind of environment-friendly light decorative insulation board and preparation method thereof |
| WO2023113631A1 (en) * | 2021-12-17 | 2023-06-22 | The Climate Change Srl | Asphalt concrete with aggregates and waste derived from recycled glass and plastics and manufacturing process |
| CN119101368A (en) * | 2024-09-30 | 2024-12-10 | 北京工业大学 | A kind of aging-resistant asphalt-based material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104310935A (en) * | 2014-10-15 | 2015-01-28 | 深圳市宜丽家生态建材有限公司 | Ceiling material with functions of breathing, adjusting moisture and purifying air |
| CN105314999A (en) * | 2014-07-29 | 2016-02-10 | 金承黎 | Nano porous high-temperature-insulating material taking thixotropic colloid as template agent and preparation method for high-temperature-insulating material |
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- 2017-06-05 CN CN201710415136.2A patent/CN107032737A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105314999A (en) * | 2014-07-29 | 2016-02-10 | 金承黎 | Nano porous high-temperature-insulating material taking thixotropic colloid as template agent and preparation method for high-temperature-insulating material |
| CN104310935A (en) * | 2014-10-15 | 2015-01-28 | 深圳市宜丽家生态建材有限公司 | Ceiling material with functions of breathing, adjusting moisture and purifying air |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107986680A (en) * | 2017-12-06 | 2018-05-04 | 付主枝 | The preparation method and applications of energy conservation and environmental protection construction material |
| CN108314368A (en) * | 2018-04-16 | 2018-07-24 | 合肥月煌新型装饰材料有限公司 | A kind of environment-friendly light decorative insulation board and preparation method thereof |
| WO2023113631A1 (en) * | 2021-12-17 | 2023-06-22 | The Climate Change Srl | Asphalt concrete with aggregates and waste derived from recycled glass and plastics and manufacturing process |
| CN119101368A (en) * | 2024-09-30 | 2024-12-10 | 北京工业大学 | A kind of aging-resistant asphalt-based material and preparation method thereof |
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