CN107032403B - The processing technology of improved nanometer wolframic acid caesium powder - Google Patents
The processing technology of improved nanometer wolframic acid caesium powder Download PDFInfo
- Publication number
- CN107032403B CN107032403B CN201710442266.5A CN201710442266A CN107032403B CN 107032403 B CN107032403 B CN 107032403B CN 201710442266 A CN201710442266 A CN 201710442266A CN 107032403 B CN107032403 B CN 107032403B
- Authority
- CN
- China
- Prior art keywords
- powder
- rack
- push
- fixed
- blending bin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 title claims abstract 21
- 229910052792 caesium Inorganic materials 0.000 title claims abstract 17
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 title claims abstract 17
- 239000002253 acid Substances 0.000 title claims abstract 13
- 238000005516 engineering process Methods 0.000 title claims abstract 10
- 239000011812 mixed powder Substances 0.000 claims abstract 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract 5
- 239000010937 tungsten Substances 0.000 claims abstract 5
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000008367 deionised water Substances 0.000 claims abstract 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 4
- 238000001035 drying Methods 0.000 claims abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract 2
- 239000007795 chemical reaction product Substances 0.000 claims abstract 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract 2
- 229940075582 sorbic acid Drugs 0.000 claims abstract 2
- 235000010199 sorbic acid Nutrition 0.000 claims abstract 2
- 239000004334 sorbic acid Substances 0.000 claims abstract 2
- 238000002156 mixing Methods 0.000 claims 16
- 239000000463 material Substances 0.000 claims 6
- 210000000078 claw Anatomy 0.000 claims 4
- 239000007788 liquid Substances 0.000 claims 4
- 239000007921 spray Substances 0.000 claims 4
- 239000002994 raw material Substances 0.000 claims 3
- 238000003756 stirring Methods 0.000 claims 3
- 238000012856 packing Methods 0.000 claims 2
- 244000144985 peep Species 0.000 claims 2
- 230000035939 shock Effects 0.000 claims 2
- 241000220324 Pyrus Species 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 230000003028 elevating effect Effects 0.000 claims 1
- 230000004807 localization Effects 0.000 claims 1
- 235000021017 pears Nutrition 0.000 claims 1
- 238000009527 percussion Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G41/00—Compounds of tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C19/00—Other disintegrating devices or methods
- B02C19/06—Jet mills
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Accessories For Mixers (AREA)
Abstract
The present invention provides a kind of processing technologys of improved nanometer wolframic acid caesium powder.It is excessively complicated that it solves the step of existing preparation method, and needs manual operation, the technical problems such as complicated for operation.The processing technology of this improved nanometer wolframic acid caesium powder, includes the following steps：A, the ammonium metatungstate of reacting dose and cesium nitrate are dissolved in deionized water, above-mentioned solution is dried to obtain powder, then obtained powder is further crushed, so as to obtain tungsten, caesium mixed-powder；B, tungsten, caesium mixed-powder are added in reaction kettle, and add in sorbic acid thereto；C, it will separate through the reaction product in step b, and washed using deionized water, dried by common baking oven, crushed after drying using airslide disintegrating mill later, obtain a nanometer wolframic acid caesium powder.The present invention has the advantages that easy to operate.
Description
Technical field
The present invention relates to a kind of processing technology, particularly a kind of processing technology of improved nanometer wolframic acid caesium powder.
Background technology
Wolframic acid caesium is a kind of chemical substance, and with acute toxicity, can be dissolved in water, the meeting under conditions of acid or alkali
It reacts, should avoid meeting place with moisture, acid, alkali when storing under room temperature, if touching skin, eyes of human body etc. accidentally,
Timely medical treatment is needed to handle.
Through retrieval, as Chinese patent literature discloses a kind of nanometer of wolframic acid caesium powder and preparation method and application【Application
Number：201510323309.9；Publication number：CN 104925867A】.This nanometer wolframic acid caesium raw powder's production technology, feature exist
In including step：A, according to n (Cs)/n (W)=0.33：1, cesium salt and tungsten salt are dissolved in citric acid solution and alcoholic solvent,
After stirring evenly, reacted 2-3 hours under the conditions of 180-200 DEG C, obtain tungsten, caesium mixed liquor；B, it is added in tungsten, caesium mixed liquor
Suitable urea adjusts the pH value of reaction solution to 3-5, stirs to urea and be completely dissolved；C, by the mixed liquor after being completely dissolved in step B
It is washed with argon gas, and chemical reaction 2-6h is carried out through Ultrasonic Radiation under 70-90 DEG C and argon gas protection, obtain gelatinous precipitate
Object；D, gelatinous precipitate is subjected to ageing 4-24h, be filtered, wash later, wash after be dried, finally calcined,
Obtain a nanometer wolframic acid caesium powder.
Although preparation method disclosed in the patent has preferable cost advantage, the step of the preparation method excessively
Complexity, and manual operation is needed, complicated for operation, therefore, designing a kind of processing technology of improved nanometer wolframic acid caesium powder is
Necessary.
Invention content
The purpose of the present invention is being directed to existing technology, there are the above problems, it is proposed that a kind of improved nanometer wolframic acid caesium powder
The processing technology at end, which has the characteristics that easy to operate.
The purpose of the present invention can be realized by following technical proposal：The processing technology of improved nanometer wolframic acid caesium powder,
It is characterised in that it includes following steps：
A, the ammonium metatungstate of reacting dose and cesium nitrate are dissolved in deionized water, above-mentioned solution are dried to obtain powder,
Obtained powder is further crushed again, so as to obtain tungsten, caesium mixed-powder；
B, tungsten, caesium mixed-powder are added in reaction kettle, and add in sorbic acid thereto, in 240-460 DEG C, stirring is anti-
Answer 4-6h, the quality of sorbic acid is tungsten, 2-4 times of caesium mixed-powder quality；
C, it will separate through the reaction product in step b, and washed using deionized water, later by common
Baking oven is dried, and drying time 20-30min is crushed after drying using airslide disintegrating mill, obtains a nanometer wolframic acid caesium powder
End.
Using process above, its procedure of processing can be greatly simplified, reduces the time of processing, it is easy to operate.
Airslide disintegrating mill in the step c includes rack, and feeding device, mixing dress are disposed in the rack
It puts, reducing mechanism and packing apparatus, the feeding device include feeding tube, storage tank and the positioning branch for positioning raw material bag
Frame, locating support and storage tank are arranged in rack, and storage tank lower end has the first delivery outlet, is provided in the first delivery outlet
First solenoid valve, storage tank upper end have first charging aperture, and first charging aperture is connected with feeding tube one end, the feeding tube other end
Above locating support, and the end has guide portion, and a moving machine that guide portion can be driven to move up and down is provided in rack
Structure is additionally provided with the first delivery pump in feeding tube；The mobile mechanism includes cylinder and mounting ring, and the cylinder body of cylinder is fixed on machine
On frame, straight down, the piston rod end of cylinder is connected the piston rod of cylinder by connecting rod with mounting ring, and guide portion is fixed on
The control mechanism that cylinder can be controlled to act is additionally provided in mounting ring, in rack；The mixing arrangement includes blending bin, fog-spray nozzle
And liquid reserve tank, blending bin and liquid reserve tank are each attached in rack, mixing upper box part has powder input port, and powder input port passes through
First connecting tube is connected with the first delivery outlet, and mixing lower box part has powder delivery outlet, and second is provided in powder delivery outlet
Solenoid valve, fog-spray nozzle are arranged in blending bin, and downward, the inlet of fog-spray nozzle passes through delivery pipe and liquid storage to the liquid outlet of fog-spray nozzle
Case is connected, and the second delivery pump is provided in delivery pipe, and mixing upper box part is additionally provided with agitating shaft, agitating shaft upper end and stirring electricity
Machine is connected, and agitating shaft lower end is penetrated in blending bin to be connected with stirring blade, and material in blending bin can be drawn by being provided in rack
Draw frame machine, draw frame machine include suction pipe, the second push-rod electric machine, asepwirator pump, mounting blocks and case, and the second push-rod electric machine leads to
Crossing one can drive its moving structure moved horizontally to be arranged in blending bin, the push rod of the second push-rod electric machine straight down, second
The push rod end of push-rod electric machine is mutually fixed with mounting blocks, and the feed end of suction pipe is fixed on mounting blocks, and the feed end is downward,
The discharge end of suction pipe is pierced by blending bin and is located in case, and asepwirator pump is arranged in suction pipe；The packing apparatus includes depositing
Batch can, material stock tank are fixed in rack, and material stock tank top has the second input port, and the second input port passes through the second connecting tube and powder
Body delivery outlet is connected, and material stock tank lower part has the second delivery outlet, is provided with third solenoid valve in the second delivery outlet, is set in rack
The detent mechanism that finished bag edge can be positioned is equipped with, shock structure is additionally provided in rack, shock structure includes the second shake
Movable plate, the second vibration motor and the second installing plate, the second installing plate can drive the first elevating mechanism that it moves up and down by one
It being arranged in rack, the second jolting plate is arranged on the second installing plate, and the second jolting plate is in immediately below the second delivery outlet, the
There is third spring, third spring one end and the second jolting plate lower surface are connected, third between two jolting plates and the second installing plate
The spring other end and the second installing plate upper surface are connected, and the second vibration motor is fixed on the second jolting plate lower surface.
The operation principle of airslide disintegrating mill is as follows：Locating support will be located in for storing the raw material bag of raw material, opened
First delivery pump, the first delivery pump by feeding tube by the feedstock transportation to storage tank in raw material bag, in raw material bag
Raw material gradually decreases, and controls the piston rod of cylinder that mounting ring is driven to move down, mounting ring drives guide portion to move down, and makes to lead
Material portion contacts always with the raw material in raw material bag；Raw material in storage tank is transported to by the first communicating pipe in blending bin, control
The output shaft of stirring motor drives agitating shaft rotation, and agitating shaft drives stirring blade rotation, meanwhile, the second delivery pump is opened, the
Modifying agent in liquid reserve tank is transported in fog-spray nozzle by two delivery pumps by delivery pipe, and modifying agent and raw material is made uniformly to mix；It is mixed
Raw material in mould assembling is transported to by the second communicating pipe in material stock tank after crushing, by detent mechanism by the edge of finished bag
It is fixed on the second delivery outlet, control third solenoid valve makes the second equipped at outlet port in opening state；Pass through the first elevating mechanism band
Dynamic second installing plate moves up and down, and the second installing plate drives the second jolting plate to move up and down, and makes the second jolting plate and finished bag
Bottom contacts, and the second jolting plate is driven to shake by the second vibration motor, and the second jolting plate, which drives finished bag to generate vibrations, to be made into
Product are packed full, process operation so as to complete it, production efficiency is high.
The control mechanism includes displacement sensor, mounting rod and controller, and mounting rod one end is connected with mounting ring, pacifies
The dress bar other end is connected, and the induction part of displacement sensor, towards locating support, controller is fixed on machine with displacement sensor
On frame, cylinder and displacement sensor are connected with the controller.
Using more than structure, the distance of raw material in guide portion and material bag is detected by displacement sensor, signal is transmitted
To controller, the piston rod of controller control cylinder moves down, and control is accurate.
The locating support upper end has and can position the positioning column of raw material bag, locating support lower end have can to raw material bag into
The percussion mechanism of row vibrations, the percussion mechanism include the first jolting plate and the first vibration motor, and the first jolting plate is arranged on fixed
On the bottom plate of position stent, there is the first spring, one end of the first spring and the between the first jolting plate and the bottom plate of locating support
One jolting plate is mutually fixed, and the other end of the first spring is mutually fixed with the bottom plate of locating support, and the first vibration motor is fixed on first
Jolting plate lower surface.
When needing to shake raw material bag, the edge of raw material bag is penetrated in positioning column, passes through the first vibration motor
The first jolting plate is made to generate vibrations, the first jolting plate drives raw material bag vibrations, moves down the material in raw material bag, vibrations side
Just.
Be additionally provided with anti-slipping mechanism on the locating support, anti-slipping mechanism includes claw and second spring, claw lower end and
Locating support is hinged, and is connected in the middle part of one end of second spring and claw, the other end of second spring is connected with locating support
It connects, claw upper end can be resisted against on locating support.
Using more than structure, claw and locating support is made to lean by second spring, so as to avoid raw material bag from calmly
It is slid out in the column of position, good antiskid effect.
The positioning column upper end has introduction part.
Using more than structure, it can be facilitated by introduction part and penetrate at raw material bag edge in positioning column, guiding role is good.
The positioning column lower end is arranged with rubber ring.
Using more than structure, its frictional force can be increased by rubber ring, it is rational in infrastructure.
Several idler wheels are additionally provided on the locating support, idler wheel and one can drive the second elevating mechanism of its oscilaltion
It is connected.
Using more than structure, idler wheel can be packed up or be put down by the second elevating mechanism, it is highly practical.
Second elevating mechanism includes the first installing plate, the first push-rod electric machine, guide rail and sliding block, guide rail and is fixed on vertically
On locating support, sliding block is arranged in guide rail, and the first push-rod electric machine is fixed on the bottom plate of locating support, the first push-rod electric machine
Straight down, the push rod end of the first push-rod electric machine is connected push rod with sliding block, and the first installing plate upper surface is connected with sliding block,
First installing plate lower surface is connected with idler wheel.
When needing that idler wheel is packed up or put down, the push rod band movable slider of the first push-rod electric machine is controlled to move up and down, sliding block
The first installing plate is driven to move up and down, the first installing plate drives idler wheel to move up and down, so as to pack up or put down idler wheel.
The delivery device that the material of blending bin side-walls can be pushed at agitating shaft is additionally provided in the rack, is pushed
Mechanism includes several push pipes and air compressor machine, and several push pipes are located on blending bin side wall vertically, and push pipe lower end is blind end,
It is inlet end to push pipe upper end, and push pipe is connected by communicating pipe with air compressor machine, and push tube side part offers several ventholes,
Venthole is towards agitating shaft.
Using more than structure, delivered air in push pipe by air compressor machine, air is exported from venthole, in air-flow
Under the action of, the material of blending bin side-walls is pushed at agitating shaft, can significantly less stirring time, push effect it is good.
The moving structure includes driving cylinder, movable plate, sliding block and guide rail, guide rail and is horizontally fixed in blending bin, sliding
Block is arranged in guide rail, and the cylinder body of cylinder is driven to be fixed in blending bin, and the piston rod end of cylinder is driven to be connected with sliding block, is moved
Movable plate is fixed on sliding block, and the second push-rod electric machine is fixed on movable plate.
When needing to move back and forth the second push-rod electric machine, the piston rod band movable slider of control driving cylinder comes along guide rail
Return is dynamic, and sliding block drives movable plate to move back and forth, and movable plate drives the second push-rod electric machine to move back and forth, so as to make the second push rod
Motor moves back and forth.
Flow control valve is additionally provided in the delivery pipe.
Using more than structure, the uninterrupted of liquid in delivery pipe is adjusted by flow control valve, it is easy to adjust.
Peep hole is provided in the blending bin, transparent access panel is provided at peep hole.
Using more than structure, working condition that can be in rapid examination to blending bin by access panel, observation is intuitive, conveniently.
Passage is additionally provided on the suction pipe, passage upper end is connected with the feed end of suction pipe, under passage
End can be resisted against blending bin bottom.
It using more than structure, can conveniently be transported material in suction pipe by passage, guiding role is good.
First elevating mechanism includes third push-rod electric machine, sliding block and guide rail, and guide rail is fixed in rack vertically, sliding block
Be arranged in guide rail, third push-rod electric machine is fixed in rack, the push rod of third push-rod electric machine straight up, third push-rod electric machine
Push rod end be connected with sliding block, the second installing plate is fixed on sliding block.
When needing to move up and down the second installing plate, the push rod band movable slider of third push-rod electric machine is controlled along on guide rail
Lower movement, sliding block drives the second installing plate to move up and down, so as to move up and down the second installing plate.
The detent mechanism includes locating ring, locating piece and positioning cylinder, and locating ring is arranged and is fixed on the second delivery outlet
On, positioning cylinder is fixed by the bracket in rack, piston rod the second delivery outlet of direction of positioning cylinder, the piston of positioning cylinder
Boom end is mutually fixed with locating piece, and the locating slot to match with locating ring is offered on locating piece.
When the edge by finished bag is needed to be fixed on the second delivery outlet, the edge of finished bag is sleeved on locating ring,
The piston rod of positioning cylinder is controlled to drive locating piece movement, locating piece and locating ring lean, so as to by the edge of finished bag
It is fixed on the second delivery outlet, positioning is quick.
Rubber strip is provided in the locating slot, there is the protrusion of several protrusions on rubber strip.
Using more than structure, the phenomenon that can increasing its frictional force by rubber strip, avoid the occurrence of slip, job stability
It is good.
Prompting mechanism is additionally provided in the rack, prompting mechanism, which includes travel switch, detection bar, alarm bell and PLC, to be compiled
Range controller, alarm bell are fixed in rack, and travel switch is fixed on the second installing plate lower surface, and detection bar is fixed in rack,
Detection bar can be in contact with travel switch, and travel switch and alarm bell are connected with the PLC programmable controller.
After material is filled in finished bag, the push rod of third push-rod electric machine drives the second installing plate to move down, the second peace
Loading board drives travel switch to move down, and signal is passed to PLC programmable controls by travel switch and detection bar contact, travel switch
Device processed, PLC programmable controller make alarm bell send out alarm sound, prompt intuitively, conveniently.
The third solenoid valve is connected with above-mentioned PLC programmable controller.
Using more than structure, third solenoid valve can control to obtain electric or dead electricity by PLC programmable controller.
Several limited posts are fixed on second jolting plate, a high position for limited post is 30-50mm.
Using more than structure, the bottom of finished bag can be limited by limited post, avoid finished bag from the second vibrations
It is detached from plate, position-limiting action is good.
Compared with prior art, the processing technology of this improved nanometer wolframic acid caesium powder has the following advantages：
1st, its procedure of processing can be greatly simplified in the present invention, reduces the time of processing, it is easy to operate.
2nd, the first jolting plate is made to generate vibrations by the first vibration motor, the first jolting plate drives raw material bag vibrations, makes original
Material in material bag moves down, and vibrations are convenient.
3rd, claw and locating support is made to lean by second spring, raw material bag can be avoided to be slid out from positioning column,
Good antiskid effect.
4th, by above and below suction pipe and will move horizontally, asepwirator pump is defeated by the mixture in blending bin everywhere by suction pipe
Go out into case, it can be achieved that comprehensive to being sampled in blending bin, check precisely.
5th, it is delivered air in push pipe by air compressor machine, air is exported from venthole, by blending bin side-walls
Material is pushed at agitating shaft, can significantly less stirring time, push effect it is good.
Description of the drawings
Fig. 1 is the planar structure schematic diagram of feeding device.
Fig. 2 is the close-up schematic view at A in Fig. 1.
Fig. 3 is the close-up schematic view at B in Fig. 1.
Fig. 4 is the sectional view of mixing arrangement.
Fig. 5 is the close-up schematic view at C in Fig. 4.
Fig. 6 is the sectional view of delivery device in mixing arrangement.
Fig. 7 is the planar structure schematic diagram of packing apparatus.
Fig. 8 is the close-up schematic view at D in Fig. 7.
Fig. 9 is the dimensional structure diagram that packing apparatus removes part.
In figure, 1, rack；2nd, the first solenoid valve；3rd, storage tank；3a, the first delivery outlet；3b, first charging aperture；4th, first
Delivery pump；5th, feeding tube；5a, guide portion；6th, link；7th, locating support；7a, bottom plate；8th, connecting rod；9th, mounting ring；10th, displacement
Sensor；10a, induction part；11st, mounting rod；12nd, cylinder；13rd, positioning column；13a, introduction part；14th, claw；15th, second spring；
16th, the first installing plate；17th, the first vibration motor；18th, the first jolting plate；19th, the first spring；20th, the first push-rod electric machine；21st, it leads
Rail；22nd, sliding block；23rd, idler wheel；24th, controller；25th, blending bin；25a, powder delivery outlet；25b, peep hole；25c, powder input
Mouthful；26th, stirring blade；27th, second solenoid valve；28th, case；29th, suction pipe；30th, asepwirator pump；31st, access panel；32nd, it stirs
Axis；33rd, stirring motor；34th, guide rail；35th, fog-spray nozzle；36th, delivery pipe；37th, flow control valve；38th, the second delivery pump；39th, it stores up
Liquid case；40th, cylinder is driven；41st, sliding block；42nd, movable plate；43rd, the second push-rod electric machine；44th, mounting blocks；45th, passage；46th, even
Siphunculus；47th, air compressor machine；48th, push pipe；48a, venthole；49th, PLC programmable controller；50th, alarm bell；51st, stent；52nd, it is fixed
Position cylinder；53rd, locating piece；53a, locating slot；54th, locating ring；55th, third solenoid valve；56th, material stock tank；56a, the second delivery outlet；
56b, the second input port；57th, detection bar；58th, third push-rod electric machine；59th, guide rail；60th, sliding block；61st, limited post；62nd, the second shake
Movable plate；63rd, the second vibration motor；64th, the second installing plate；65th, third spring；66th, travel switch；67th, rubber strip.
Specific embodiment
The following is specific embodiments of the present invention and with reference to attached drawing, technical scheme of the present invention is further described,
But the present invention is not limited to these embodiments.
The processing technology of this improved nanometer wolframic acid caesium powder, includes the following steps：
A, the ammonium metatungstate of reacting dose and cesium nitrate are dissolved in deionized water, above-mentioned solution are dried to obtain powder,
Obtained powder is further crushed again, so as to obtain tungsten, caesium mixed-powder；
B, tungsten, caesium mixed-powder are added in reaction kettle, and add in sorbic acid thereto, in 240-460 DEG C, stirring is anti-
Answer 4-6h, the quality of sorbic acid is tungsten, 2-4 times of caesium mixed-powder quality, in the present embodiment, in 300 DEG C, is stirred to react
5h, the quality of sorbic acid is tungsten, 3 times of caesium mixed-powder quality；
C, it will separate through the reaction product in step b, and washed using deionized water, later by common
Baking oven is dried, and drying time 20-30min is crushed after drying using airslide disintegrating mill, obtains a nanometer wolframic acid caesium powder
End；In the present embodiment, drying time 25min.
Using the technique, its procedure of processing can be greatly simplified, reduces the time of processing, it is easy to operate.
As shown in Figure 1, Figure 2, shown in Fig. 4, Fig. 5, Fig. 7, Fig. 8, airslide disintegrating mill in step c includes rack 1, in rack 1 according to
Secondary to be provided with feeding device, mixing arrangement, reducing mechanism and packing apparatus, reducing mechanism is using air-flow of the prior art
Grinding mode；Feeding device includes feeding tube 5, storage tank 3 and the locating support 7 for positioning raw material bag, locating support 7 and storage
Batch can 3 is arranged at 1 in rack, and 3 lower end of storage tank, which has in the first delivery outlet 3a, the first delivery outlet 3a, is provided with the first electromagnetism
There is first charging aperture 3b, first charging aperture 3b to be connected with 5 one end of feeding tube for valve 2,3 upper end of storage tank, 5 other end of feeding tube
Above locating support 7, and the end has guide portion 5a, and being provided with one in rack 1 can drive what guide portion 5a was moved up and down
Mobile mechanism is additionally provided with the first delivery pump 4 in feeding tube 5；Mobile mechanism includes cylinder 12 and mounting ring 9, the cylinder of cylinder 12
Body is fixed in rack 1, and the cylinder body of cylinder 12 is fixed on by link 6 in rack 1；The piston rod of cylinder 12 straight down,
The piston rod end of cylinder 12 is connected by connecting rod 8 with mounting ring 9, and guide portion 5a is fixed in mounting ring 9, and guide portion 5a leads to
Bolted mode is crossed to be fixed in mounting ring 9；The control mechanism that cylinder 12 can be controlled to act is additionally provided in rack 1；It is mixed
It attaches together and puts including blending bin 25, fog-spray nozzle 35 and liquid reserve tank 39, blending bin 25 and liquid reserve tank 39 are each attached in rack 1, mixing
Case 25 and liquid reserve tank 39 are fixed in rack 1 by welding；25 top of blending bin has powder input port 25c, powder
Body input port 25c is connected by the first connecting tube with the first delivery outlet 3a, and 25 lower part of blending bin has powder delivery outlet 25a,
Second solenoid valve 27 is provided in powder delivery outlet 25a, fog-spray nozzle 35 is arranged in blending bin 25, the liquid outlet court of fog-spray nozzle 35
Under, the inlet of fog-spray nozzle 35 is connected by delivery pipe 36 with liquid reserve tank 39, and the second delivery pump 38 is provided in delivery pipe 36,
25 top of blending bin is additionally provided with agitating shaft 32, and 32 upper end of agitating shaft is connected with stirring motor 33, and the upper end of agitating shaft 32 passes through
The mode of key connection is connected with the output shaft of stirring motor 33, and stirring motor 33 is fixed in blending bin 25；32 lower end of agitating shaft
It penetrates in blending bin 25 and is connected with stirring blade 26, the lower end of agitating shaft 32 is by way of key connection and 26 phase of stirring blade
Even；The draw frame machine of material in blending bin 25 can be drawn by being provided in rack 1, and draw frame machine includes suction pipe 29, the second push rod
Motor 43, asepwirator pump 30, mounting blocks 44 and case 28, the second push-rod electric machine 43 can drive the movement that it moves horizontally by one
Structure setting in blending bin 25, the push rod of the second push-rod electric machine 43 straight down, the push rod end of the second push-rod electric machine 43 and
44 phase of mounting blocks is fixed, and the push rod end of the second push-rod electric machine 43 is mutually fixed by bolted connection with mounting blocks 44；It inhales
The feed end of pipe 29 is taken to be fixed on mounting blocks 44, and the feed end is downward, the discharge end of suction pipe 29 is pierced by blending bin 25
In in case 28, asepwirator pump 30 is arranged in suction pipe 29；Packing apparatus includes material stock tank 56, and material stock tank 56 is fixed on rack
On 1, material stock tank 56 is fixed on by welding in rack 1；56 top of material stock tank has the second input port 56b, and second is defeated
Entrance 56b is connected by the second connecting tube with powder delivery outlet 25a, and 56 lower part of material stock tank has the second delivery outlet 56a, and second
Third solenoid valve 55 is provided in delivery outlet 56a, the detent mechanism that finished bag edge can be positioned, machine are provided in rack 1
Shock structure is additionally provided on frame 1, shock structure includes the second jolting plate 62, the second vibration motor 63 and the second installing plate 64,
Second installing plate 64 can drive its first elevating mechanism moved up and down to be arranged in rack 1 by one, and the second jolting plate 62 is set
It puts on the second installing plate 64, and the second jolting plate 62 is in immediately below the second delivery outlet 56a, the second jolting plate 62 and the second peace
There is third spring 65, in the present embodiment, the quantity of third spring 65 is four between loading board 64；65 one end of third spring and
Second jolting plate, 62 lower surface is connected, and 65 other end of third spring and 64 upper surface of the second installing plate are connected, the second vibration motor
63 are fixed on 62 lower surface of the second jolting plate, and the second vibration motor 63 is fixed on the second jolting plate 62 by bolted connection
Lower surface.
As shown in Figure 1 and Figure 2, control mechanism includes displacement sensor 10, mounting rod 11 and controller 24, mounting rod 11 1
End is connected with mounting ring 9, and one end of mounting rod 11 is connected by bolted connection with mounting ring 9；Mounting rod 11 is another
One end is connected with displacement sensor 10, and the other end of mounting rod 11 is connected by bolted connection with displacement sensor 10
It connects；And the induction part 10a of displacement sensor 10, towards locating support 7, controller 24 is fixed in rack 1, and controller 24 passes through
The mode of bolted mode is fixed in rack 1, and controller 24 is using the microcontroller that can be bought in the market, microcontroller control
The program of cylinder and sensor processed is existing, and program does not need to update；Cylinder 12 and displacement sensor 10 and the control
Device 24 processed is connected.
As shown in Figure 1, Figure 2, Figure 3 shows, 7 upper end of locating support has the positioning column 13 that can position raw material bag, in the present embodiment
In, the quantity of positioning column 13 is four；13 upper end of positioning column has introduction part 13a, can by introduction part 13a using the structure
Facilitate and penetrate at raw material bag edge in positioning column 13, guiding role is good；13 lower end of positioning column is arranged with rubber ring, using the knot
Structure can increase its frictional force by rubber ring；7 lower end of locating support, which has, to shake the percussion mechanism that raw material bag is shaken
Motivation structure includes the first jolting plate 18 and the first vibration motor 17, and the first jolting plate 18 is arranged on the bottom plate 7a of locating support 7,
There are the first spring 19, one end of the first spring 19 and the first vibrations between first jolting plate 18 and the bottom plate 7a of locating support 7
18 phase of plate is fixed, and the other end of the first spring 19 is fixed with the bottom plate 7a phases of locating support 7, and the first vibration motor 17 is fixed on
One jolting plate, 18 lower surface, the first vibration motor 17 are fixed on the lower surface of the first jolting plate 18 by bolted connection.
As shown in Figure 1 and Figure 2, anti-slipping mechanism is additionally provided on locating support 7, anti-slipping mechanism includes 14 and second bullet of claw
Spring 15,14 lower end of claw and locating support 7 are hinged, and one end of second spring 15 is connected with 14 middle part of claw, second spring
15 other end is connected with locating support 7, and 14 upper end of claw can be resisted against on locating support 7.
As shown in Figure 1, Figure 3, several idler wheels 23, in the present embodiment, the quantity of idler wheel 23 are additionally provided on locating support 7
It is four；Idler wheel 23 can drive the second elevating mechanism of its oscilaltion to be connected with one, using the structure, pass through the second elevator
Idler wheel 23 can be packed up or put down by structure.
As shown in Figure 1, Figure 3, the second elevating mechanism includes the first installing plate 16, the first push-rod electric machine 20, guide rail 21 and slides
Block 22, guide rail 21 are fixed on vertically on locating support 7, and guide rail 21 is fixed on by bolted connection on locating support 7；It is sliding
Block 22 is arranged in guide rail 21, and sliding block 22 can be moved up and down along guide rail 21；First push-rod electric machine 20 is fixed on locating support 7
On bottom plate 7a, straight down, the push rod end of the first push-rod electric machine 20 is connected the push rod of the first push-rod electric machine 20 with sliding block 22,
First installing plate, 16 upper surface is connected with sliding block 22, and 16 lower surface of the first installing plate is connected with idler wheel 23.
As shown in fig. 6, pushing away at agitating shaft 32 can be pushed to by the material of 25 side-walls of blending bin by being additionally provided in rack 1
Mechanism is sent, delivery device includes several push pipes 48 and air compressor machine 47, and in the present embodiment, the quantity of push pipe 48 is 12
Root；Several push pipes 48 are located at vertically on 25 side wall of blending bin, and 48 lower end of push pipe is blind end, and 48 upper end of push pipe is air inlet
End, push pipe 48 are connected by communicating pipe 46 with air compressor machine 47, and air compressor machine 47 is fixed in rack 1；It opens 48 side of push pipe
Equipped with several venthole 48a, in the present embodiment, the quantity of venthole 48a is six；Venthole 48a is towards agitating shaft 32.
As shown in Figure 4, Figure 5, moving structure includes driving cylinder 40, movable plate 42, sliding block 41 and guide rail 34,34 water of guide rail
Flat to be fixed in blending bin 25, guide rail 34 is fixed on by bolted connection in blending bin 25；Sliding block 41 is arranged on guide rail
In 34, sliding block 41 can move back and forth along guide rail 34；The cylinder body of driving cylinder 40 is fixed in blending bin 25, driving cylinder 40
Cylinder body is fixed on by bolted connection in blending bin 25；The piston rod end of driving cylinder 40 is connected with sliding block 41, drives
The take offence piston rod end of cylinder 40 is connected by bolted connection with sliding block 41；Movable plate 42 is fixed on sliding block 41, is moved
Movable plate 42 is fixed on by bolted connection on sliding block 41；Second push-rod electric machine 43 is fixed on movable plate 42, and second pushes away
Bar motor 43 is fixed on by bolted connection on movable plate 42.
As shown in figure 4, flow control valve 37 is additionally provided in delivery pipe 36；Peep hole 25b is provided in blending bin 25, is seen
It examines and transparent access panel 31 is provided at the 25b of hole, access panel 31 is organic plates.
As shown in Figure 4, Figure 5, passage 45, the charging of 45 upper end of passage and suction pipe 29 are additionally provided on suction pipe 29
End is connected, and 45 lower end of passage can be resisted against 25 bottom of blending bin, using the structure, can be facilitated material by passage 45
It is transported in suction pipe 29, guiding role is good.
As shown in Figure 7, Figure 8, the first elevating mechanism includes third push-rod electric machine 58, sliding block 60 and guide rail 59, and guide rail 59 is perpendicular
It is directly fixed in rack 1, guide rail 59 is fixed on by bolted connection in rack 1；Sliding block 60 is arranged in guide rail 59, sliding
Block 60 can be moved up and down along guide rail 59；Third push-rod electric machine 58 is fixed in rack 1, and third push-rod electric machine 58 is connected by bolt
The mode connect is fixed in rack 1；The push rod of third push-rod electric machine 58 straight up, the push rod end of third push-rod electric machine 58 and
Sliding block 60 is connected, and the push rod end of third push-rod electric machine 58 is connected by bolted connection with sliding block 60；Second installing plate
64 are fixed on sliding block 60, and the second installing plate 64 is fixed on by bolted connection on sliding block 60.
As shown in Fig. 7, Fig. 9, detent mechanism includes locating ring 54, locating piece 53 and positioning cylinder 52, and locating ring 54 is arranged
And be fixed on the second delivery outlet 56a, positioning cylinder 52 is fixed on by stent 51 in rack 1, the piston rod of positioning cylinder 52
Towards the second delivery outlet 56a, the piston rod end of positioning cylinder 52 is mutually fixed with locating piece 53, the tailpiece of the piston rod of positioning cylinder 52
Portion is mutually fixed by bolted connection with locating piece 53；The locating slot to match with locating ring 54 is offered on locating piece 53
53a；In the present embodiment, the quantity of locating piece 53 and positioning cylinder 52 is two.
As shown in figure 9, being provided with rubber strip 67 in locating slot 53a, using the structure, it can be increased by rubber strip 67 and rubbed
The phenomenon that wiping power, avoiding the occurrence of slip；There is the protrusion of several protrusions, in the present embodiment, protrusion on rubber strip 67
Quantity is 30.
As shown in Figure 7, Figure 8, prompting mechanism is additionally provided in rack 1, prompting mechanism includes travel switch 66, detection bar
57th, alarm bell 50 and PLC programmable controller 49, alarm bell 50 are fixed in rack 1, and alarm bell 50 is fixed by bolted connection
In rack 1；Travel switch 66 is fixed on 64 lower surface of the second installing plate, and travel switch 66 is fixed by bolted connection
In the lower surface of the second installing plate 64；Detection bar 57 is fixed in rack 1, and detection bar 57 is fixed on by bolted connection
In rack 1；Detection bar 57 can and travel switch 66 be in contact, travel switch 66 and alarm bell 50 with the PLC programmable controller
49 are connected, and in the present embodiment, PLC programmable controller 49 is using the controller that can be bought in the market, controller control row
The program of Cheng Kaiguan, alarm bell and third solenoid valve are existing, and program does not need to update；Third solenoid valve 55 and PLC can
Programmable controller 49 is connected, and using the structure, third solenoid valve 55 can control to obtain electric or lose by PLC programmable controller 49
Electricity.
As shown in Figure 7, Figure 8, be fixed with several limited posts 61 on the second jolting plate 62, the high position of limited post 61 for 30-
50mm, in the present embodiment, the height of limited post 61 is 40mm, can be to the bottom of finished bag by limited post 61 using the structure
Portion is limited, and finished bag is avoided to be detached from from the second jolting plate 62, position-limiting action is good.
The operation principle of airslide disintegrating mill is as follows：It will penetrate in positioning column 13, lead to for storing the raw material bag edge of raw material
Crossing second spring 15 makes claw 14 and locating support 7 lean, and opens the first delivery pump 4, and the first delivery pump 4 passes through feeding tube 5
By in the feedstock transportation in raw material bag to storage tank 3, as the raw material in raw material bag gradually decreases, examined by displacement sensor 10
The distance of raw material in guide portion 5a and material bag is surveyed, signal is passed into controller 24, controller 24 controls the piston of cylinder 12
Bar drive mounting ring 9 move down, mounting ring 9 drive guide portion 5a move down, make guide portion 5a always in raw material bag
Raw material contacts；Raw material in storage tank 3 is transported to by the first communicating pipe in blending bin 25, controls the output shaft of stirring motor 33
Agitating shaft 32 is driven to rotate, agitating shaft 32 drives stirring blade 26 to rotate, and push pipe 48 is delivered air to by air compressor machine 47
In, air is exported from venthole 48a, and under the action of air-flow, the material of 25 side-walls of blending bin is pushed to agitating shaft 32
Place；Meanwhile the second delivery pump 38 is opened, the modifying agent in liquid reserve tank 39 is transported to spray by the second delivery pump 38 by delivery pipe 36
In mist head 35, modifying agent and raw material is made uniformly to mix, when needing to be sampled it, the piston rod band of control driving cylinder 40
Movable slider 41 moves back and forth, and sliding block 41 drives movable plate 42 to move back and forth, and movable plate 42 drives the second push-rod electric machine 43 to move back
It is dynamic；Control the push rod of the second push-rod electric machine 43 that mounting blocks 44 is driven to move down, mounting blocks 44 drive suction pipe 29 to move down,
Mixture in blending bin 25 everywhere can be output in case 28, it can be achieved that comprehensive right by asepwirator pump 30 by suction pipe 29
It is sampled in blending bin 25；Raw material in blending bin 25 is transported to by the second communicating pipe in material stock tank 56 after crushing, will be into
The edge of product bag is sleeved on locating ring 54, and the piston rod of control positioning cylinder 52 drives locating piece 53 to move, locating piece 53 and fixed
Position ring 54 leans, and the edge of finished bag is fixed on the second delivery outlet 56a, passes through the control of PLC programmable controller 49 the
Three solenoid valves 55 make the second delivery outlet 56a be in opening state；The push rod band movable slider 60 for controlling third push-rod electric machine 58 is upward
Mobile, sliding block 60 drives the second installing plate 64 to move up, and the second installing plate 64 drives the second jolting plate 62 to move up, and makes the
The bottom of two jolting plates 62 and finished bag contacts, and the second jolting plate 62 is driven to shake by the second vibration motor 63, the second vibrations
Plate 62 drives finished bag to generate vibrations, and as material gradually increases in finished bag, the push rod of control third push-rod electric machine 58 drives
Sliding block 60 moves gradually downward, and sliding block 60 drives the second installing plate 64 to move gradually downward, after material is filled in finished bag, row
Cheng Kaiguan 66 and detection bar 57 contact, and signal is passed to PLC programmable controller 49, PLC PLC technologies by travel switch 66
Device 49 makes alarm bell 50 send out alarm sound；The mixing of raw material and other auxiliary agents can select the function according to actual needs.
Specific embodiment described herein is only explanation for example to spirit.Technical field that the present invention belongs to
Technical staff can do various modifications or additions to described specific embodiment or substitute in a similar way, but
Spirit without departing from invention or beyond the scope of the appended claims.
Claims (7)
1. the processing technology of improved nanometer of wolframic acid caesium powder, which is characterized in that include the following steps：
A, the ammonium metatungstate of reacting dose and cesium nitrate are dissolved in deionized water, above-mentioned solution is dried to obtain powder, then will
Obtained powder is further crushed, so as to obtain tungsten, caesium mixed-powder；
B, tungsten, caesium mixed-powder are added in reaction kettle, and add in sorbic acid thereto, in 300 DEG C, be stirred to react 5h, mountain
The quality of pears acid is tungsten, 3 times of caesium mixed-powder quality；
C, it will separate through the reaction product in step b, and washed using deionized water, pass through common baking later
Case is dried, and drying time 25min is crushed after drying using airslide disintegrating mill, obtains a nanometer wolframic acid caesium powder；Institute
It states the airslide disintegrating mill in step c and includes rack, feeding device, mixing arrangement, reducing mechanism are disposed in the rack
And packing apparatus, the feeding device include feeding tube, storage tank and the locating support for positioning raw material bag, locating support and
Storage tank is arranged in rack, and storage tank lower end has the first delivery outlet, and the first solenoid valve is provided in the first delivery outlet, stores up
Batch can upper end has first charging aperture, and first charging aperture is connected with feeding tube one end, and the feeding tube other end is located at locating support
Top, and the end has guide portion, and a mobile mechanism that guide portion can be driven to move up and down is provided in rack, is gone back in feeding tube
It is provided with the first delivery pump；The mobile mechanism includes cylinder and mounting ring, and the cylinder body of cylinder is fixed in rack, the work of cylinder
Straight down, the piston rod end of cylinder is connected stopper rod by connecting rod with mounting ring, and guide portion is fixed in mounting ring, rack
On be additionally provided with can control cylinder act control mechanism；The mixing arrangement includes blending bin, fog-spray nozzle and liquid reserve tank, mixing
Case and liquid reserve tank are each attached in rack, and mixing upper box part has a powder input port, powder input port by the first connecting tube and
First delivery outlet is connected, and mixing lower box part has powder delivery outlet, and second solenoid valve, fog-spray nozzle are provided in powder delivery outlet
It is arranged in blending bin, downward, the inlet of fog-spray nozzle is connected the liquid outlet of fog-spray nozzle by delivery pipe with liquid reserve tank, conveying
The second delivery pump is provided in pipe, mixing upper box part is additionally provided with agitating shaft, and agitating shaft upper end is connected with stirring motor, agitating shaft
Lower end is penetrated in blending bin to be connected with stirring blade, and the draw frame machine that can draw material in blending bin is provided in rack, is drawn
Mechanism includes suction pipe, the second push-rod electric machine, asepwirator pump, mounting blocks and case, and the second push-rod electric machine can drive it by one
The moving structure moved horizontally is arranged in blending bin, and straight down, the second push-rod electric machine pushes away the push rod of the second push-rod electric machine
Boom end is mutually fixed with mounting blocks, and the feed end of suction pipe is fixed on mounting blocks, and the feed end is downward, the discharging of suction pipe
End is pierced by blending bin and is located in case, and asepwirator pump is arranged in suction pipe；The packing apparatus includes material stock tank, and material stock tank is consolidated
It is scheduled in rack, material stock tank top has the second input port, and the second input port is connected by the second connecting tube with powder delivery outlet
Logical, material stock tank lower part has the second delivery outlet, is provided with third solenoid valve in the second delivery outlet, being provided in rack can be by finished product
The detent mechanism that positions of bag edge is additionally provided with shock structure in rack, and shock structure includes the second jolting plate, the second vibrations
Motor and the second installing plate, the second installing plate can drive its first elevating mechanism moved up and down to be arranged in rack by one,
Second jolting plate is arranged on the second installing plate, and the second jolting plate is in immediately below the second delivery outlet, the second jolting plate and the
There is third spring between two installing plates, third spring one end and the second jolting plate lower surface be connected, the third spring other end and
Second installing plate upper surface is connected, and the second vibration motor is fixed on the second jolting plate lower surface；The locating support upper end has
The positioning column of raw material bag can be positioned, locating support lower end has can be to the percussion mechanism that raw material bag is shaken, the jarring machine
Structure includes the first jolting plate and the first vibration motor, and the first jolting plate is arranged on the bottom plate of locating support, the first jolting plate and
There is the first spring between the bottom plate of locating support, one end of the first spring mutually fixes with the first jolting plate, the first spring it is another
One end is mutually fixed with the bottom plate of locating support, and the first vibration motor is fixed on the first jolting plate lower surface；The positioning column upper end
With introduction part；The positioning column lower end is arranged with rubber ring；Peep hole is provided in the blending bin, is provided at peep hole
Transparent access panel；Several limited posts are fixed on second jolting plate, a high position for limited post is 30-50mm.
2. the processing technology of improved nanometer wolframic acid caesium powder according to claim 1, which is characterized in that the positioning branch
Anti-slipping mechanism is additionally provided on frame, anti-slipping mechanism includes claw and second spring, and claw lower end and locating support are hinged, and second
It is connected in the middle part of one end of spring and claw, the other end of second spring is connected with locating support, and claw upper end can be resisted against
On locating support.
3. the processing technology of improved nanometer wolframic acid caesium powder according to claim 1, which is characterized in that in the rack
The delivery device that the material of blending bin side-walls can be pushed at agitating shaft is additionally provided with, delivery device includes several push and manages
And air compressor machine, several push pipes are located on blending bin side wall vertically, push pipe lower end is blind end, and push pipe upper end is air inlet
End, push pipe are connected by communicating pipe with air compressor machine, and push tube side part offers several ventholes, venthole direction stirring
Axis.
4. the processing technology of improved nanometer wolframic acid caesium powder according to claim 1, which is characterized in that the delivery pipe
In be additionally provided with flow control valve.
5. the processing technology of improved nanometer wolframic acid caesium powder according to claim 1, which is characterized in that the suction pipe
On be additionally provided with passage, passage upper end is connected with the feed end of suction pipe, and passage lower end can be resisted against blending bin bottom
Portion.
6. the processing technology of improved nanometer wolframic acid caesium powder according to claim 1, which is characterized in that the localization machine
Structure includes locating ring, locating piece and positioning cylinder, and locating ring is arranged and is fixed on the second delivery outlet, and positioning cylinder passes through stent
It is fixed in rack, piston rod the second delivery outlet of direction of positioning cylinder, the piston rod end of positioning cylinder is mutually solid with locating piece
It is fixed, the locating slot to match with locating ring is offered on locating piece.
7. the processing technology of improved nanometer wolframic acid caesium powder according to claim 6, which is characterized in that the locating slot
In be provided with rubber strip, the protrusion on rubber strip with several protrusions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710442266.5A CN107032403B (en) | 2016-08-16 | 2016-08-16 | The processing technology of improved nanometer wolframic acid caesium powder |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710442266.5A CN107032403B (en) | 2016-08-16 | 2016-08-16 | The processing technology of improved nanometer wolframic acid caesium powder |
| CN201610675935.9A CN106277058B (en) | 2016-08-16 | 2016-08-16 | A kind of processing technology of nanometer of wolframic acid caesium powder |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610675935.9A Division CN106277058B (en) | 2016-08-16 | 2016-08-16 | A kind of processing technology of nanometer of wolframic acid caesium powder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107032403A CN107032403A (en) | 2017-08-11 |
| CN107032403B true CN107032403B (en) | 2018-06-29 |
Family
ID=57678626
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610675935.9A Active CN106277058B (en) | 2016-08-16 | 2016-08-16 | A kind of processing technology of nanometer of wolframic acid caesium powder |
| CN201710442266.5A Active CN107032403B (en) | 2016-08-16 | 2016-08-16 | The processing technology of improved nanometer wolframic acid caesium powder |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610675935.9A Active CN106277058B (en) | 2016-08-16 | 2016-08-16 | A kind of processing technology of nanometer of wolframic acid caesium powder |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN106277058B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104925867A (en) * | 2015-06-12 | 2015-09-23 | 深圳大学 | Nano cesium tungstate powder and preparing method and application of nano cesium tungstate powder |
| CN105664920A (en) * | 2016-01-30 | 2016-06-15 | 苏州大学 | Cs2W3O10 (cesium tungstate) powder, preparation method and application thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19720297A1 (en) * | 1997-05-15 | 1998-11-19 | Bayer Ag | Method and device for metering granular coarse material into an air jet mill |
| CN101607223B (en) * | 2009-07-06 | 2011-03-02 | 华南理工大学 | Ultra-fine powder processing device |
| CN202410790U (en) * | 2011-12-30 | 2012-09-05 | 潍坊埃尔派粉体技术设备有限公司 | Jet mill with modifying function |
| CN103818962B (en) * | 2013-12-30 | 2016-05-11 | 烟台佳隆纳米产业有限公司 | A kind of preparation method of caesium tungsten oxide superfine powder |
| CN205269833U (en) * | 2015-12-28 | 2016-06-01 | 山东禾宜生物科技有限公司 | But wettable powder production facility |
| CN105668633B (en) * | 2016-01-11 | 2017-06-23 | 大连工业大学 | Sea urchin shape tungsten bronze particle prepared by a kind of utilization template and preparation method thereof |
-
2016
- 2016-08-16 CN CN201610675935.9A patent/CN106277058B/en active Active
- 2016-08-16 CN CN201710442266.5A patent/CN107032403B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104925867A (en) * | 2015-06-12 | 2015-09-23 | 深圳大学 | Nano cesium tungstate powder and preparing method and application of nano cesium tungstate powder |
| CN105664920A (en) * | 2016-01-30 | 2016-06-15 | 苏州大学 | Cs2W3O10 (cesium tungstate) powder, preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106277058B (en) | 2018-02-16 |
| CN107032403A (en) | 2017-08-11 |
| CN106277058A (en) | 2017-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106986382B (en) | The preparation method of improved nano antimony tin oxide powder | |
| CN107224905B (en) | A kind of pulping device for Rare Earth Mine | |
| CN107032403B (en) | The processing technology of improved nanometer wolframic acid caesium powder | |
| CN108047339A (en) | The production method of the nano-class rice starch of improvement | |
| CN221192022U (en) | Lime slaking device for dry slaking | |
| CN210448886U (en) | Organic compound preparation facilities | |
| CN107188211B (en) | The production method of improved powdered whiting | |
| CN217431545U (en) | Mixing arrangement is used in pesticide production | |
| CN203400649U (en) | Gantry type drying, stirring and solvent recovering integrated device | |
| CN108063250A (en) | The production technology of the nanometer lithium iron phosphate cathode material of improvement | |
| CN206661608U (en) | A kind of surface processing device of fastener | |
| CN206868207U (en) | A kind of methyl hydrazine synthesizer | |
| CN208302700U (en) | A kind of culture materials of edible fungi agitating device | |
| CN206267505U (en) | A kind of dry powder accelerator automatic filling device | |
| CN106276930B (en) | A kind of manufacture craft of nano-scale white carbon black | |
| CN107714730A (en) | A kind of processing method of nano-pearl powder | |
| CN203484156U (en) | Stirring reaction tank | |
| CN208427029U (en) | A kind of lifting stirring-type pesticide producing processing unit (plant) | |
| CN219502739U (en) | Hyaluronic acid fermentation liquor treatment facility | |
| CN209451694U (en) | A kind of proportioner for diluent automatic mixing | |
| CN218028134U (en) | Pipeline scale removal is input device for biological agent | |
| CN218278423U (en) | Walnut planting spouts medicine machine | |
| CN217615183U (en) | Medicine processing is with smashing integrative equipment of stirring measurement | |
| CN203302306U (en) | Conditioner with adjustable axial inclination angle | |
| CN214545621U (en) | Movable multipurpose agricultural spraying device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180330 Address after: 318000 Taizhou City, Taizhou City, Zhejiang, Haimen street, Jing Hui District, No. 1, No. 1 Applicant after: Guan Yongbin Address before: Jiaxing City, Zhejiang province 314400 Haining City Economic Development Zone construction way 16-1 No. 1 building 4 floor Applicant before: HAINING YONGXIN TECHNOLOGY CONSULTING Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180925 Address after: 244002 three floor of No. 2 factory building No. 1688, North Taishan Road, Tongling, Anhui (Tai Xiang Industrial Park) Patentee after: ANHUI HERO ELECTRONIC SCIENCE AND TECHNOLOGY CO.,LTD. Address before: 318000 No. 109 building, King Hui District, Haimen street, Jiaojiang District, Taizhou, Zhejiang, 1 Patentee before: Guan Yongbin |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221108 Address after: No. 99, Gangcheng Road, Administrative Committee of Dongying Port Economic Development Zone, Dongying City, Shandong Province 257237 Patentee after: Dongying Ruigang Investment Promotion Service Co.,Ltd. Address before: 244002 three floor of No. 2 factory building No. 1688, North Taishan Road, Tongling, Anhui (Tai Xiang Industrial Park) Patentee before: ANHUI HERO ELECTRONIC SCIENCE AND TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right |