CN107026287B - Manufacturing method of lead-acid horizontal battery - Google Patents
Manufacturing method of lead-acid horizontal battery Download PDFInfo
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- CN107026287B CN107026287B CN201610497559.9A CN201610497559A CN107026287B CN 107026287 B CN107026287 B CN 107026287B CN 201610497559 A CN201610497559 A CN 201610497559A CN 107026287 B CN107026287 B CN 107026287B
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- 238000011049 filling Methods 0.000 claims abstract description 17
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/73—Grids for lead-acid accumulators, e.g. frame plates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
The invention provides a manufacturing method of a lead-acid horizontal battery, and belongs to the technical field of storage batteries. The horizontal battery solves the problems of high self-discharge and difficult popularization of the existing horizontal battery. The manufacturing method of the lead-acid horizontal battery comprises the following steps: firstly, producing and purchasing accessories; manufacturing a grid; uniformly coating the prepared positive and negative lead pastes on a grid to prepare a positive plate and a negative plate; welding the lugs of one part of the positive plate and the negative plate together to form a continuous horizontal polar plate, and using the other part of the positive plate and the negative plate as a unipolar plate; fifthly, stacking the horizontal polar plate and the unipolar plate in a staggered manner; filling filler in the gaps among the sealing element, the partition wall, the positive electrode lugs and the negative electrode lugs; seventhly, welding a terminal; and eighthly, finishing assembly after covering the battery cover. The present invention uses the present grid structure to replace the light composite material (i.e. lead cloth) in the traditional horizontal battery to manufacture the bipolar plate, and the bipolar plate is in butt joint with the present production process, equipment, etc., so that the resistance of popularization is reduced.
Description
Technical Field
The invention belongs to the technical field of storage batteries, and relates to a manufacturing method of a lead-acid horizontal battery.
Background
Currently, chemical power sources used as power storage batteries for electric vehicles are: nickel metal hydride batteries, zinc air batteries, lithium ion/lithium polymer batteries, fuel cells and lead acid batteries, but to date none of the power cell technologies have matured to a point where the presence of other batteries is negligible. The lead-acid storage battery has the advantages of low price, mature technology, safety, reliability, abundant resources, recyclability and the like, but the traditional lead-acid storage battery as a power battery has a larger difference with other types of storage batteries on the key index of specific energy, so the lead-acid storage battery has to be technically innovated to possibly meet the requirements of electric vehicles, and the horizontal lead-cloth battery greatly improves the specific energy, specific power and cycle life of the battery due to the revolutionary change of the structure and the application of novel composite materials, thereby greatly improving the competitiveness of the lead-acid battery as the electric vehicle battery.
The horizontal battery has four technical characteristics:
1.1 light composite material technology: the lead net grid is a lead net woven by lead wires formed by coating pure lead (or lead alloy) on high-strength glass fibers through solid-state extrusion. The structure reduces the weight of the battery and improves the gravimetric energy.
1.2 horizontal bipolar structure; the positive and negative plates and the partition plates are horizontally staggered and stacked, except that the two ends are provided with unipolar plates, the rest are bipolar plates. This configuration also determines the busbars that must be used in conventional batteries, reducing the amount of lead used and, on the other hand, increasing the gravimetric energy of the battery.
1.3 unique battery case design and pressure frame construction; each monomer all has independent pressure frame during battery equipment, and the battery case is inside to be a whole body, and each face of battery case all has the constant head tank, and during the equipment, pressure frame's rib inserts the constant head tank of battery case, prevents that the battery from taking place the drunkenness in the impact vibrations environment inside, has improved the shock resistance of battery, has prolonged battery life.
1.4 full automation of the production process: the automatic plate coating line, the automatic mechanical arm assembly line, the automatic welding and detection line, the temperature compensation battery testing equipment and the like are all unique.
Secondly, the current situation: to date, there are no reliable horizontal battery products in bulk at home and abroad for the following reasons:
2.1 coating paste: because the lead cloth is thin, compared with the common grid coating plate, the lead cloth is easy to stretch and deform, and the coating is difficult. In addition, the positive and negative electrode lead pastes are coated on the bipolar plate grid at the same time, as shown in fig. 1, the positive and negative electrode lead pastes are respectively coated and filled at two ends of a piece of lead cloth, and a separation band of about 10mm is reserved in the middle without coating the lead paste. Because the lead-acid battery is very sensitive to the mixing of positive and negative lead pastes, only a 10mm isolation strip is enough to ensure that the positive and negative lead pastes are completely separated in the processes of coating, curing, drying, cleaning and the like of the polar plate.
2.2 terminal welding: the lead wire wall is too thin, lead and glass fiber are not infiltrated, and if the lead wire is improperly welded, the inner core is easily melted to cause insufficient welding, so that the qualified rate of the battery is low.
2.3 self-discharge: since no partition wall is provided between the cells, the self-discharge is large, reaching 10%/month. There may also be some reason that self-discharge may occur between some of the liquid film and the grid despite the use of a poor liquid design.
2.4 cycle life: the U.S. power company declared a horizontal battery cycle life of 800-900 weeks, but the actual test life was only 200-300 weeks.
Disclosure of Invention
The invention aims to solve the problems of the existing horizontal battery, and provides a manufacturing method of a lead-acid horizontal battery which can reduce self-discharge and can be butted with the production process and equipment of the existing common storage battery.
The purpose of the invention can be realized by the following technical scheme:
a manufacturing method of a lead-acid horizontal battery is characterized by comprising the following steps:
firstly, producing and purchasing accessories;
manufacturing a grid;
uniformly coating the prepared positive and negative lead pastes on a grid, and respectively curing to prepare a positive plate and a negative plate;
welding the lugs of one part of the positive plate and the negative plate together to form a continuous horizontal polar plate, and using the other part of the positive plate and the negative plate as a unipolar plate;
the horizontal polar plate and the unipolar plate are stacked in a staggered mode, a partition plate is inserted between the upper polar plate and the lower polar plate for separation, the lug welding positions in the horizontal polar plates are clamped in the gaps of the partition walls, and a sealing piece is pressed at the lug welding positions of the gaps each time one horizontal polar plate is stacked until the stacking is finished;
filling filler in the gaps among the sealing element, the partition wall, the positive electrode lugs and the negative electrode lugs;
seventhly, welding a terminal;
and eighthly, finishing assembly after covering the battery cover.
In the above method for manufacturing a lead-acid horizontal battery, the grid structure is the same as the conventional structure.
In the above method for manufacturing a lead-acid horizontal battery, the lead-acid horizontal battery comprises a battery shell, a separator, an electrolyte, a positive plate and a negative plate, the battery shell is divided into a plurality of cells by partitions, each cell is provided with a corresponding electrode group, the novel horizontal polar plate is characterized in that each polar group is formed by stacking a plurality of horizontal plates and negative plates up and down alternately, a partition plate is arranged between the positive plate and the negative plate which are adjacent up and down in the same polar group, gaps between monomers on two sides of the communication are formed in the stacking direction of the positive plate and the negative plate on the partition wall, positive lugs and negative lugs are arranged on the side edges of the positive plate and the negative plate respectively, the positive lugs and the negative plates which are correspondingly arranged in one-to-one opposite mode between the two adjacent polar groups are connected together through the lugs to form a horizontal polar plate, the lug connection position is clamped at the gap, and a sealing mechanism is further arranged at the.
In the above method for manufacturing a lead-acid horizontal battery, the sealing mechanism includes a plurality of sealing members and a filler filled between the sealing members, the partition wall, and the positive and negative electrode tabs, and the sealing members are correspondingly clamped between two adjacent horizontal electrode plates one by one.
In the above method for manufacturing a lead-acid horizontal battery, the sealing element is disposed at the notch, a through filling hole is formed along the stacking direction of the horizontal type polar plates, the filling holes of the sealing elements are sequentially communicated from top to bottom to form a filling channel, and a positioning mechanism for limiting the position of the sealing element is disposed between the sealing element and the partition wall.
In the above method for manufacturing a lead-acid horizontal battery, the positioning mechanism includes two limiting sliding grooves respectively formed at two ends of the sealing member, partition wall portions at two sides of the notch are clamped in the limiting sliding grooves at opposite ends of the sealing member in a one-to-one correspondence manner, and when the partition walls are clamped in the limiting sliding grooves, the sealing member can move up and down along the notch.
In the above method for manufacturing a lead-acid horizontal battery, a bayonet for connecting the positive and negative electrode tabs, which are corresponding to both sides, extending into the filling hole is formed between the upper and lower stacked sealing members.
In the manufacturing method of the lead-acid horizontal battery, the width of the bayonet is matched with the width of the corresponding side tab.
In the above method for manufacturing a lead-acid horizontal battery, the filler is epoxy resin or paraffin.
In the above method for manufacturing a lead-acid horizontal battery, the positive and negative plates are formed by respectively coating positive and negative lead pastes on respective corresponding grids.
In the above method for manufacturing a lead-acid horizontal battery, the grid is made of a lead-based alloy.
In the manufacturing method of the lead-acid horizontal battery, the grid is made of lead calcium or lead antimony alloy.
In the above method for manufacturing a lead-acid horizontal battery, the grid is a foam grid or a composite grid manufactured by an electrodeposition method. Because the grid structure is the same as that of a normal grid, the terminal welding is consistent with the current process, and no problem exists.
In the manufacturing method of the lead-acid horizontal battery, the single cells and the corresponding pole groups are all discharged in a U shape, an S shape or a straight line shape. The series connection lines of the pole groups are respectively in a corresponding U shape, S shape or straight line shape, the U shape and the S shape are arranged, the length of the battery can be greatly shortened, and the practicability of the battery is enhanced.
In the above method for manufacturing a horizontal lead-acid battery, the positive plate and the negative plate in the horizontal plate are horizontally arranged at an interval, and the positive tab of the positive plate and the negative tab of the negative plate are located at the interval and are connected in a one-to-one correspondence manner.
In the above method for manufacturing a lead-acid horizontal battery, the positive plate and the negative plate in the horizontal plate are on the same plane.
In the above method for manufacturing a lead-acid horizontal battery, the positive electrode tab and the negative electrode tab in the horizontal electrode plate are stacked and then welded together.
In the above method for manufacturing a lead-acid horizontal battery, the positive tab and the negative tab of the horizontal plate are welded together after being butted.
The positive plate and the negative plate are conventional plates which are coated, cured and dried, the plates are horizontally arranged at intervals, the lugs are opposite, the lugs are stacked or butted together, and then the corresponding positive lugs and the corresponding negative lugs are connected together through hot welding or cold welding.
The horizontal polar plate produced according to the invention avoids the problem that the positive and negative lead pastes are coated on the bipolar plate grid at the same time to cause the positive and negative lead pastes to be mixed, and adopts the mode of coating the positive and negative lead pastes separately, solidifying and drying and then butting, namely, the positive and negative plate grids, the coating plate, solidifying and drying processes are carried out according to the production process of the normal battery at present, so that the utilization of the existing equipment can be ensured, the product quality is ensured, and the mass production is realized. After the solidification is finished, a procedure is added, namely the lugs of the positive and negative plates are melted into a whole by a cold welding or hot welding method.
Compared with the prior art, the invention uses the grid structure used at present to replace the light composite material (namely lead cloth) in the traditional horizontal battery to manufacture the bipolar plate, appropriately changes the structure of the battery shell, is convenient to seal, inherits all the electrical properties of the horizontal battery, improves the stability of the product, forms butt joint with the current production process, equipment and the like, reduces the resistance of popularization, and has wide development prospect.
Drawings
Fig. 1 is a schematic view of a quasi-bipolar plate structure of a horizontal cell in the prior art.
Fig. 2 is a schematic structural diagram of the lead-acid horizontal battery.
Fig. 3 is a schematic structural view of fig. 2 with the battery cover removed.
Fig. 4 is an anatomical schematic of the present lead-acid horizontal battery.
Fig. 5 is a partial enlarged view of fig. 4 at a.
Fig. 6 is a schematic view of the structure of the sealing member.
Fig. 7 is a schematic view of the installation of the seal.
FIG. 8 is a schematic view of a U-shaped arrangement of pole groups.
Fig. 9 is a schematic structural diagram of a horizontal plate.
In the figure, 1, a battery case; 2. a partition plate; 3. between monomers; 4. a pole group; 5. a terminal; 6. a positive plate; 7. a negative plate; 8. a partition wall; 9. a positive tab; 10. a negative tab; 11. a positive electrode lug group; 12. a negative electrode ear group; 13. a seal member; 14. filling the hole; 15. a limiting chute; 16. a bayonet; 17. a notch; 18. a bus bar; 19. a filler; 20. a unipolar plate.
Detailed Description
The following are specific embodiments of the present invention and are further described with reference to the drawings, but the present invention is not limited to these embodiments.
As shown in figures 2 and 3, the lead-acid horizontal battery comprises a battery shell, a partition plate, electrolyte, positive plates and negative plates, wherein the inside of the battery shell is divided into a plurality of cells by partition walls, a polar group is correspondingly arranged in each cell, two ends of the polar group are connected with two terminals on the battery shell in a one-to-one correspondence mode after being connected in series in sequence, and gaps communicated with the cells on two sides are formed in the stacking direction of the positive plates and the negative plates on the partition walls. In this embodiment, the single cells and the corresponding electrode groups are arranged in a line.
As shown in fig. 4 and 5, each polar group is formed by stacking a plurality of horizontal positive and negative plates alternately from top to bottom, the upper and lower adjacent positive and negative plates in the same polar group are provided with a partition plate, the side edges of the positive and negative plates are respectively provided with a positive lug and a negative lug, the positive lug corresponding to each positive plate in the same polar group is positioned at the same side to form a positive lug group, the negative lug corresponding to each negative plate is positioned at the other side to form a negative lug group, the two adjacent polar groups are connected in series through the positive lug group and the negative pole, the positive lug in the positive lug group and the negative lug in the corresponding negative lug group are connected in one-to-one correspondence at a gap to form a horizontal polar plate to connect the two corresponding polar groups in series, and the gap is further provided with a sealing mechanism for sealing. The sealing mechanism includes a plurality of sealing members and a filler filled between the sealing members, the partition walls, and the positive and negative electrode tabs.
As shown in fig. 6 and 7, the sealing members are correspondingly clamped between two adjacent horizontal pole plates one by one, the sealing members are provided with through filling holes along the stacking direction of the horizontal pole plates, the filling holes of the sealing members are sequentially communicated from top to bottom to form a filling channel, and a positioning mechanism for limiting the position of the sealing member is arranged between the sealing member and the partition wall. The positioning mechanism comprises two limiting sliding grooves which are respectively arranged at two ends of the sealing element, partition wall parts on two sides of the notch are clamped in the limiting sliding grooves of opposite ends of the sealing element in a one-to-one correspondence mode, and when the partition walls are clamped in the limiting sliding grooves, the sealing element can move up and down along the notch. A bayonet for connecting the positive electrode lug and the negative electrode lug which correspond to two sides and extend into the filling hole is formed between the upper sealing element and the lower sealing element which are stacked, and the width of the bayonet is matched with that of the corresponding side electrode lug.
The series connection of the pole groups may also be U-shaped as shown in fig. 8.
The manufacturing method of the invention comprises the following steps:
firstly, producing and purchasing accessories;
secondly, manufacturing a grid by adopting a lead-calcium or lead-antimony alloy material;
uniformly coating the prepared positive and negative lead pastes on a grid, and respectively curing to prepare a positive plate and a negative plate;
welding the lugs of one part of the positive plate and the negative plate together to form a continuous horizontal polar plate, and using the other part of the positive plate and the negative plate as a unipolar plate;
fifthly, stacking the positive and negative electrodes of the horizontal type pole plates in a staggered manner, wherein the adjacent horizontal type pole plates are separated by a partition plate, the welding positions of the pole lugs in the horizontal type pole plates are clamped in the gaps of the partition plates, each horizontal type pole plate is stacked, a sealing piece is pressed at the welding position of the pole lug of each gap, the single pole plates at two ends of the cluster after series connection are stacked in a staggered manner with the corresponding horizontal type pole plates, and the positive pole lugs and the negative pole lugs of the cluster are respectively connected through a bus bar; after the stacking is finished, after the stacked pole groups are compressed by applying force, the pole groups are fixed by a prepressing plate, and the partition plate keeps a certain compression ratio;
filling filler in the gaps between the sealing element, the partition wall and the positive and negative electrode lugs, wherein the filler can be epoxy resin or paraffin;
seventhly, correspondingly welding the bus bars at the two ends with the terminals of the battery shell respectively;
and eighthly, finishing assembly after covering the battery cover.
The prepared horizontal battery can achieve better effects on the performances of deep cycle life, quick charge and discharge, stability, batch degree and the like, and the following table shows that:
item | Conventional battery | Horizontal battery | This patent horizontal battery |
Specific energy | Is low in | Height of | In |
Specific power | Is low in | Height of | In |
Deep cycle life | Is low in | Height of | Height of |
Fast charge and discharge | Difference (D) | Good taste | Good taste |
Stability of | Good taste | Difference (D) | Good taste |
Degree of mass production | Is easy to use | Difficulty in | Is easy to use |
It is to be understood that in the claims, the specification of the present invention, all "including … …" are to be interpreted in an open-ended sense, i.e., in a sense equivalent to "including at least … …", and not in a closed sense, i.e., in a sense not to be interpreted as "including only … …".
The specific embodiments described herein are merely illustrative of the spirit of the invention. Various modifications or additions may be made to the described embodiments or alternatives may be employed by those skilled in the art without departing from the spirit or ambit of the invention as defined in the appended claims.
Claims (9)
1. A manufacturing method of a lead-acid horizontal battery is characterized by comprising the following steps:
firstly, producing and purchasing accessories; production of a battery case, the inside of which is partitioned into a plurality of cell compartments by partition walls;
manufacturing a grid;
uniformly coating the prepared positive and negative lead pastes on a grid, and respectively curing to prepare a positive plate and a negative plate;
welding the lugs of one part of the positive plate and the negative plate together to form a continuous horizontal polar plate, and using the other part of the positive plate and the negative plate as a unipolar plate;
the horizontal polar plate and the unipolar plate are stacked in a staggered mode, a partition plate is inserted between the upper polar plate and the lower polar plate for separation, the lug welding positions in the horizontal polar plates are clamped in the gaps of the partition walls, and a sealing piece is pressed at the lug welding positions of the gaps each time one horizontal polar plate is stacked until the stacking is finished;
filling filler in the gaps among the sealing element, the partition wall, the positive electrode lugs and the negative electrode lugs;
seventhly, welding a terminal;
and eighthly, finishing assembly after covering the battery cover.
2. The method of claim 1, wherein the lead-acid horizontal battery comprises a battery case, a separator, an electrolyte, a positive plate and a negative plate, wherein the battery case is divided into a plurality of cells by a partition wall, each cell is correspondingly provided with a plate group, each plate group is formed by stacking a plurality of the positive plates and the negative plates horizontally arranged in an up-down alternating manner, the separator is arranged between the positive plates and the negative plates which are adjacent to each other in the same plate group, a gap communicated with the cells at two sides is formed in the stacking direction of the positive plates and the negative plates on the partition wall, the side edges of the positive plates and the negative plates are respectively provided with the positive lugs and the negative lugs, the positive plates and the negative plates which are correspondingly arranged between the two adjacent plate groups in one-to-one direction are connected together to form a horizontal type, and the connection positions of the lugs are clamped at the gap, and a sealing mechanism is further arranged at the notch for sealing.
3. The method according to claim 2, wherein the sealing mechanism comprises a plurality of sealing elements and a filler filled between the sealing elements, the partition walls, and the positive and negative electrode tabs, and the sealing elements are correspondingly clamped between two adjacent horizontal electrode plates one by one.
4. The method according to claim 3, wherein the sealing member is disposed at the gap and has a filling hole extending therethrough along the stacking direction of the horizontal plates, the filling holes of the plurality of sealing members are sequentially communicated with each other to form a filling channel, and a positioning mechanism for positioning the sealing member is disposed between the sealing member and the partition wall.
5. The method according to claim 4, wherein the positioning mechanism comprises two limiting sliding grooves respectively formed at two ends of the sealing member, partition wall portions at two sides of the notch are correspondingly clamped in the limiting sliding grooves at the opposite ends of the sealing member one by one, and when the partition walls are clamped in the limiting sliding grooves, the sealing member can move up and down along the notch.
6. The method according to claim 3, wherein a bayonet for inserting the corresponding positive and negative electrode tabs at both sides into the filling hole is formed between the upper and lower stacked sealing members.
7. The method of claim 1, wherein the positive and negative plates are formed by applying positive and negative lead pastes to respective grids.
8. The method according to claim 2, wherein the cells and the corresponding electrode groups are arranged in a U-shape, S-shape or in-line shape.
9. The method for manufacturing a lead-acid horizontal battery according to claim 2, wherein the positive electrode plates and the negative electrode plates in the horizontal electrode plates are horizontally arranged at intervals, and the positive electrode lugs of the positive electrode plates and the negative electrode lugs of the negative electrode plates are positioned at the intervals and are connected in a one-to-one correspondence manner.
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CN201610497559.9A CN107026287B (en) | 2016-06-24 | 2016-06-24 | Manufacturing method of lead-acid horizontal battery |
Applications Claiming Priority (1)
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