CN107022258A - A kind of high absorption affinity plastic paint and preparation method thereof - Google Patents
A kind of high absorption affinity plastic paint and preparation method thereof Download PDFInfo
- Publication number
- CN107022258A CN107022258A CN201710422805.9A CN201710422805A CN107022258A CN 107022258 A CN107022258 A CN 107022258A CN 201710422805 A CN201710422805 A CN 201710422805A CN 107022258 A CN107022258 A CN 107022258A
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- weight
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- plastic paint
- high absorption
- absorption affinity
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- 239000003973 paint Substances 0.000 title claims abstract description 31
- 229920003023 plastic Polymers 0.000 title claims abstract description 25
- 239000004033 plastic Substances 0.000 title claims abstract description 25
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000004743 Polypropylene Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- -1 polypropylene Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000013530 defoamer Substances 0.000 claims abstract description 12
- 229920001155 polypropylene Polymers 0.000 claims abstract description 12
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 12
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 11
- 239000011707 mineral Substances 0.000 claims abstract description 11
- 235000015096 spirit Nutrition 0.000 claims abstract description 11
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- KBDYPDHUODKDRK-UHFFFAOYSA-N n-acetyl-n-phenylacetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=CC=C1 KBDYPDHUODKDRK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 229920002635 polyurethane Polymers 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- AJEYQZVNHTXDRW-UHFFFAOYSA-N benzene;butane-2,3-dione Chemical compound CC(=O)C(C)=O.C1=CC=CC=C1 AJEYQZVNHTXDRW-UHFFFAOYSA-N 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 238000000034 method Methods 0.000 description 5
- 239000004568 cement Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/22—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D127/24—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment halogenated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of high absorption affinity plastic paint, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, the parts by weight of aqueous polyurethane emulsion 10~30, the parts by weight of Tissuemat E 5~15, the parts by weight of chlorinated polypropylene 5~15, the parts by weight of cellulose acetate 2~10, the parts by weight of diacetanilide 5~15, the parts by weight of defoamer 2~10, the parts by weight of non-toluene solvent 10~30, the parts by weight of aerosil powder 5~11, the parts by weight of Mineral spirits 6~8.
Description
Technical field
The present invention relates to one kind paint, and in particular to a kind of high absorption affinity plastic paint and preparation method thereof.
Background technology
Plastic paint is widely used in various fields, such as household electrical appliances, automobile, toy.However, due to plastic cement in the market
The paint plastic cement weak to surface-active（Such as polypropylene PP, nylon66 fiber and ethylene propylene diene rubber and polyethylene blend）Attachment
Power is poor, it is difficult to directly use.In order to improve this problem, prior art is mainly using first spray PP priming paint, then spray two-component color
Paint（That is colored paint+curing agent）Method.This process generally requires 2~3 procedures, and the colored paint of bi-component is being opened
2 hours after packaging must be finished, and no person understands oneself solidification, it is impossible to reuse.Therefore, the above method not only complex process,
High energy consumption, and due to being the colored paint of bi-component, so canned self-spraying paint can not be made, for wanting to repair the used time on plastic parts
Understand oneself solidification, block shower nozzle, it is impossible to make filling blowing mending paint.In addition, also there is alcohol resistance energy in existing plastic paint
The problem of poor, wear-resisting difference and bad ageing-resistant performance.
Hence it is highly desirable to which by the improvement of formula and production technology, a kind of wearability of exploitation is good, alcohol resistance energy
Good, ageing-resistant performance is high and has the one pack system plastic paint of high adhesion force.
The content of the invention
Goal of the invention：The invention aims to make up the deficiencies in the prior art, there is provided a kind of high absorption affinity plastic cement
Paint, matches science, glossiness can be effectively improved, easy application, while having very good adhesion, is widely used.
Technical scheme：A kind of high absorption affinity plastic paint, by following weight than raw material be formulated：Superchlorinated polyvinyl chloride resin
100 parts by weight, the parts by weight of aqueous polyurethane emulsion 10~30, the parts by weight of Tissuemat E 5~15, chlorinated polypropylene 5
~15 parts by weight, the parts by weight of cellulose acetate 2~10, the parts by weight of diacetanilide 5~15, the weight of defoamer 2~10
Part, the parts by weight of non-toluene solvent 10~30, the parts by weight of aerosil powder 5~11, the parts by weight of Mineral spirits 6~8.
Preferably, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, aqueous polyurethane
The parts by weight of emulsion 25, the parts by weight of Tissuemat E 13, the parts by weight of chlorinated polypropylene 8, the parts by weight of cellulose acetate 6, biacetyl
The parts by weight of aniline 9, the parts by weight of defoamer 8, the parts by weight of non-toluene solvent 20, the parts by weight of aerosil powder 8, the weight of Mineral spirits 7
Part.
A kind of preparation method of high absorption affinity plastic paint, comprises the following steps：By superchlorinated polyvinyl chloride resin, aqueous polyurethane breast
Liquid and deionized water are added in reactor, and 15 ~ 20min is stirred with 700 ~ 800r/min rotating speed, are kept stirring for rotating speed, then add
Enter Tissuemat E, chlorinated polypropylene, cellulose acetate, diacetanilide continues to stir 15 ~ 20min, rotating speed is promoted to
900 ~ 1000r/min, adds defoamer, and non-toluene solvent, aerosil powder, Mineral spirits stir 15 ~ 20min, adds remaining
Deionized water adjusts viscosity to 50 ~ 70KU, obtains the plastic paint.
Beneficial effect：A kind of disclosed high absorption affinity plastic paint, matches science, gloss can be effectively improved
Degree, easy application, while having very good adhesion, is widely used.
Embodiment
With reference to specific embodiment, the invention will be further described：
A kind of high absorption affinity plastic paint, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, it is aqueous
The parts by weight of polyaminoester emulsion 10~30, the parts by weight of Tissuemat E 5~15, the parts by weight of chlorinated polypropylene 5~15, vinegar
The parts by weight of acid cellulose 2~10, the parts by weight of diacetanilide 5~15, the parts by weight of defoamer 2~10, non-toluene solvent 10~
30 parts by weight, the parts by weight of aerosil powder 5~11, the parts by weight of Mineral spirits 6~8.
A kind of preparation method of high absorption affinity plastic paint, comprises the following steps：
By superchlorinated polyvinyl chloride resin, aqueous polyurethane emulsion and deionized water are added in reactor, with 700 ~ 800r/min rotating speed
15 ~ 20min is stirred, rotating speed is kept stirring for, adds Tissuemat E, chlorinated polypropylene, cellulose acetate, biacetyl benzene
Amine, continues to stir 15 ~ 20min, rotating speed is promoted into 900 ~ 1000r/min, add defoamer, non-toluene solvent, gas phase titanium dioxide
Silica flour, Mineral spirits stir 15 ~ 20min, add remaining deionized water and adjust viscosity to 50 ~ 70KU, obtain the plastic paint.
Embodiment 1：
A kind of high absorption affinity plastic paint, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, it is aqueous
The parts by weight of polyaminoester emulsion 10, the parts by weight of Tissuemat E 5, the parts by weight of chlorinated polypropylene 5, the parts by weight of cellulose acetate 2,
The parts by weight of diacetanilide 5, the parts by weight of defoamer 2, the parts by weight of non-toluene solvent 10~30, the parts by weight of aerosil powder 5,
The parts by weight of Mineral spirits 6.
Embodiment 2：
A kind of high absorption affinity plastic paint, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, it is aqueous
The parts by weight of polyaminoester emulsion 25, the parts by weight of Tissuemat E 13, the parts by weight of chlorinated polypropylene 8, the parts by weight of cellulose acetate 6,
The parts by weight of diacetanilide 9, the parts by weight of defoamer 8, the parts by weight of non-toluene solvent 20, the parts by weight of aerosil powder 8, Dormant oils
Smart 7 parts by weight.
Embodiment 3
A kind of high absorption affinity plastic paint, by following weight than raw material be formulated：The parts by weight of superchlorinated polyvinyl chloride resin 100, it is aqueous
The parts by weight of polyaminoester emulsion 30, the parts by weight of Tissuemat E 15, the parts by weight of chlorinated polypropylene 15, the weight of cellulose acetate 10
Measure part, the parts by weight of diacetanilide 15, the parts by weight of defoamer 10, the parts by weight of non-toluene solvent 30, the weight of aerosil powder 11
Measure part, the parts by weight of Mineral spirits 8.
Claims (3)
1. a kind of high absorption affinity plastic paint, it is characterised in that：By following weight than raw material be formulated：Superchlorinated polyvinyl chloride resin
100 parts by weight, the parts by weight of aqueous polyurethane emulsion 10~30, the parts by weight of Tissuemat E 5~15, chlorinated polypropylene 5
~15 parts by weight, the parts by weight of cellulose acetate 2~10, the parts by weight of diacetanilide 5~15, the weight of defoamer 2~10
Part, the parts by weight of non-toluene solvent 10~30, the parts by weight of aerosil powder 5~11, the parts by weight of Mineral spirits 6~8.
2. a kind of high absorption affinity plastic paint according to claim 1, it is characterised in that：By following weight than raw material match somebody with somebody
System is formed：The parts by weight of superchlorinated polyvinyl chloride resin 100, the parts by weight of aqueous polyurethane emulsion 25, the parts by weight of Tissuemat E 13, chlorination gathers
The parts by weight of allyl resin 8, the parts by weight of cellulose acetate 6, the parts by weight of diacetanilide 9, the parts by weight of defoamer 8, non-toluene solvent 20
Parts by weight, the parts by weight of aerosil powder 8, the parts by weight of Mineral spirits 7.
3. a kind of preparation method for preparing high absorption affinity plastic paint in claim 1, it is characterised in that comprise the following steps：
By superchlorinated polyvinyl chloride resin, aqueous polyurethane emulsion and deionized water are added in reactor, with 700 ~ 800r/min rotating speed
15 ~ 20min is stirred, rotating speed is kept stirring for, adds Tissuemat E, chlorinated polypropylene, cellulose acetate, biacetyl benzene
Amine, continues to stir 15 ~ 20min, rotating speed is promoted into 900 ~ 1000r/min, add defoamer, non-toluene solvent, gas phase titanium dioxide
Silica flour, Mineral spirits stir 15 ~ 20min, add remaining deionized water and adjust viscosity to 50 ~ 70KU, obtain the plastic paint.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710422805.9A CN107022258A (en) | 2017-06-07 | 2017-06-07 | A kind of high absorption affinity plastic paint and preparation method thereof |
| PCT/CN2017/088325 WO2018223410A1 (en) | 2017-06-07 | 2017-06-14 | Plastic paint with high adsorption capacity and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710422805.9A CN107022258A (en) | 2017-06-07 | 2017-06-07 | A kind of high absorption affinity plastic paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107022258A true CN107022258A (en) | 2017-08-08 |
Family
ID=59531410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710422805.9A Withdrawn CN107022258A (en) | 2017-06-07 | 2017-06-07 | A kind of high absorption affinity plastic paint and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN107022258A (en) |
| WO (1) | WO2018223410A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114874683A (en) * | 2022-06-16 | 2022-08-09 | 上海正欧实业有限公司 | Paint for plastic court track |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327609A (en) * | 2014-10-17 | 2015-02-04 | 青岛智谷创新技术有限公司 | Wear-resistant plastic paint |
| CN105505034A (en) * | 2016-02-25 | 2016-04-20 | 上海祥水汽车零配件有限公司 | Single-component air-dried plastic paint |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5258444A (en) * | 1993-01-22 | 1993-11-02 | Ppg Industries, Inc. | Aqueous coating composition for plastic substrates |
| RU2067106C1 (en) * | 1993-03-04 | 1996-09-27 | Московский институт прикладной биотехнологии | Polymeric composition for coating |
| CN101638536B (en) * | 2009-08-28 | 2011-08-10 | 临海市龙岭化工厂 | High chlorinated polyethylene fluorescent paint containing fluorine |
| CN102888157A (en) * | 2012-09-19 | 2013-01-23 | 启东市天盟机电科技有限公司 | Vinylidene chloride coating for plastic |
| CN106046974A (en) * | 2016-08-05 | 2016-10-26 | 吴静 | Preparation method for special waterborne vinylidene chloride anticorrosive paint used for agitator tank |
-
2017
- 2017-06-07 CN CN201710422805.9A patent/CN107022258A/en not_active Withdrawn
- 2017-06-14 WO PCT/CN2017/088325 patent/WO2018223410A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327609A (en) * | 2014-10-17 | 2015-02-04 | 青岛智谷创新技术有限公司 | Wear-resistant plastic paint |
| CN105505034A (en) * | 2016-02-25 | 2016-04-20 | 上海祥水汽车零配件有限公司 | Single-component air-dried plastic paint |
Non-Patent Citations (1)
| Title |
|---|
| 傅绍燕: "《涂装工艺及车间设计手册》", 31 January 2013, 机械工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114874683A (en) * | 2022-06-16 | 2022-08-09 | 上海正欧实业有限公司 | Paint for plastic court track |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018223410A1 (en) | 2018-12-13 |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170808 |
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