CN107011745A - A kind of ethene protective paint coating - Google Patents
A kind of ethene protective paint coating Download PDFInfo
- Publication number
- CN107011745A CN107011745A CN201710445171.9A CN201710445171A CN107011745A CN 107011745 A CN107011745 A CN 107011745A CN 201710445171 A CN201710445171 A CN 201710445171A CN 107011745 A CN107011745 A CN 107011745A
- Authority
- CN
- China
- Prior art keywords
- ethene
- micro mist
- protective paint
- paint coating
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000002519 antifouling agent Substances 0.000 title claims abstract description 19
- 239000011248 coating agent Substances 0.000 title claims abstract description 18
- 238000000576 coating method Methods 0.000 title claims abstract description 18
- 239000003973 paint Substances 0.000 claims abstract description 12
- 239000003595 mist Substances 0.000 claims abstract description 10
- 230000003075 superhydrophobic effect Effects 0.000 claims abstract description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 240000002853 Nelumbo nucifera Species 0.000 claims abstract description 5
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims abstract description 5
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims abstract description 5
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 5
- 239000012188 paraffin wax Substances 0.000 claims abstract description 5
- 230000001681 protective effect Effects 0.000 claims abstract description 5
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 4
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 239000004113 Sepiolite Substances 0.000 claims abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 3
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 3
- 239000011701 zinc Substances 0.000 claims abstract description 3
- 239000002245 particle Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 230000003628 erosive effect Effects 0.000 abstract description 5
- 239000005977 Ethylene Substances 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 3
- 238000003763 carbonization Methods 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000004321 preservation Methods 0.000 abstract description 3
- 239000010959 steel Substances 0.000 abstract description 3
- 239000002023 wood Substances 0.000 abstract description 3
- 230000009977 dual effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of ethene protective paint coating, the invention belongs to chemical technology field, its formula is characterized in：It is made up of polyvinyl butyral resin, n-butanol, micaceous iron oxide, Zinc phosphating solution, barium monoxide micro mist, ultra-fine paraffin micro mist, sepiolite powder, sorbester p17, phenmethylol.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, be the coating that its work is protected.The present invention has micron order and the dual coarse structure of nanoscale simultaneously, so just having the super-hydrophobic self-cleaning function of lotus leaf effect, after product using the present invention, the surface long term of object need not manually be cleaned and returned newly from overcoating brush, save substantial amounts of manpower and materials, also do not corroded simultaneously by wind and rain, the service life of 3 times of Natural ethylene protective paints, strictly a kind of service life is permanent and super-hydrophobic ethene protective paint coating of excellent performance.
Description
Technical field
The invention belongs to chemical field, the present invention relates to a kind of protective paint coating, and in particular to be a kind of protection of ethene
Paint coating.
Background technology
Ethene protective paint coating be one kind can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing, hull bottom prevent
The protective coating for the structure such as planktonic organism, deck be anti-wear.But the ethene of prior art protection lacquer coat do not have it is hydrophobic from
Clean function, will manually clean and be returned newly from overcoating brush in short term, service life is not long, wastes manpower and materials.
The content of invention
The purpose of the present invention is：There is provided it is a kind of there is self-cleaning function, need not manually clean for a long time and from overcoating brush return newly,
A large amount of manpower and materials can be saved, not by erosion by wind and rain, service life is permanent and super-hydrophobic ethene protective paint coating of excellent performance.
To achieve the above object, the technical solution adopted in the present invention is a kind of ethene protective paint coating, its spy being formulated
Levying is：By polyvinyl butyral resin, n-butanol, micaceous iron oxide, Zinc phosphating solution, barium monoxide micro mist (0.4um~
0.7um particle diameters), ultra-fine paraffin micro mist (16nm~85nm particle diameters), sepiolite powder, sorbester p17, phenmethylol composition.
The percentage by weight of its component is：
Beneficial effects of the present invention：The present invention is barium monoxide micro mist (0.4um~0.7um particle diameters), ultra-fine paraffin micro mist
The peptizaiton that (16nm~85nm particle diameters) is risen by dispersant sorbester p17, is highly dispersed in ethene protective paint, distributive law
More than 97%, after the finished product using the present invention, the super-hydrophobic self-cleaning surface of paint film formation tool lotus leaf effect is determined with half ball
The contact angle of the paint film samples of multiple ethene protective paints, its paint film sample and water is more than 150 °；Moreover, sample by using
The observation that electron microscope is carried out, finds its surface while having micron order and the dual coarse structure of nanoscale.The present invention into
Product can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, all kinds of outdoor indoor hardware vessels
The surface of material, makes the surface of object have the super-hydrophobic self-cleaning function of lotus leaf effect, need not can manually clean for a long time and from again
Brushing is returned newly, saves substantial amounts of manpower and materials, and is not corroded by wind and rain, the use longevity of 3 times of Natural ethylene protective paints
Life, is that a kind of service life is permanent and super-hydrophobic ethene protective paint coating of excellent performance.
Embodiment
The following examples are that the present invention is made further to prove, the invention is not restricted to this.
Embodiment one
A kind of ethene protective paint coating, its component and weight proportion are as follows：
Embodiment two
A kind of ethene protective paint coating, its component and weight proportion are as follows：
Embodiment three
A kind of ethene protective paint coating, its component and weight proportion are as follows：
Finished product obtained by the three above embodiment of the present invention is respectively coated on three pieces of slides, surveyed with half ball
The contact angle of fixed these three samples and water：
1st, the contact angle of the slide sample of embodiment one and water is 151.5 °
2nd, the contact angle of the slide sample of embodiment two and water is 151.3 °
3rd, the contact angle of the slide sample of embodiment three and water is 153.4 °
The sample of three above embodiment is determined with half ball, finished product its surface wettability of the present invention is all showed
For superhydrophobic characteristic.
A kind of ethene protective paint coating of the present invention, applies in western district of Guangdong, has supplied Duo Jia advertising companies, outdoor at it
Used on the surface of large-scale advertisement metal structure skeleton；Made comparisons with common ethene protective paint, product of the invention is had
The super-hydrophobic self-cleaning function of lotus leaf effect, makes the surface of metal structure not by erosion by wind and rain, and permanent light is such as new, saves a large amount of
Manpower and materials, product of the invention has the service life of 3 times of Natural ethylene protective paints, and strictly a kind of service life is permanent
And the super-hydrophobic ethene protective paint coating of excellent performance.
Claims (2)
1. a kind of ethene protective paint coating, it is characterised in that：The percentage by weight of the formula each component is：Polyvinyl butyral resin
Resin 46%--58%, n-butanol 17%--28%, micaceous iron oxide 4%--24%, Zinc phosphating solution 6%--23%, oxidation
Barium micro mist 4%--25%, ultra-fine paraffin micro mist 3%--26%, sepiolite powder 3%--22%, sorbester p17 3%--24%, benzene first
Alcohol 2%--23%.
2. a kind of ethene protective paint coating according to claim 1, it is characterized in that：Barium monoxide micro mist 0.4um~0.7um
Particle diameter, ultra-fine paraffin micro mist 16nm~85nm particle diameters, the peptizaiton risen by dispersant sorbester p17 are highly dispersed in ethene
In protective paint, distributive law is more than 97%, and using after this finished product, the super-hydrophobic self-cleaning surface of paint film formation tool lotus leaf effect is used
Half ball determines the paint film sample of multiple ethene protective paints, and the contact angle of its paint film sample and water is more than 150 °.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710445171.9A CN107011745A (en) | 2017-06-01 | 2017-06-01 | A kind of ethene protective paint coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710445171.9A CN107011745A (en) | 2017-06-01 | 2017-06-01 | A kind of ethene protective paint coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107011745A true CN107011745A (en) | 2017-08-04 |
Family
ID=59453119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710445171.9A Pending CN107011745A (en) | 2017-06-01 | 2017-06-01 | A kind of ethene protective paint coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107011745A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103894333A (en) * | 2006-06-23 | 2014-07-02 | 3M创新有限公司 | Articles having durable hydrophobic surfaces |
| CN105131817A (en) * | 2015-08-27 | 2015-12-09 | 岳西县永泰机械制造有限公司 | Impact resistant coating for metal and preparation method therefor |
| CN106047029A (en) * | 2016-06-12 | 2016-10-26 | 合肥和安机械制造有限公司 | Fluorinated modified metallic copper anticorrosive coating and preparation method thereof |
| CN106700936A (en) * | 2015-08-02 | 2017-05-24 | 王娟 | Material for super hydrophobic coating layer |
-
2017
- 2017-06-01 CN CN201710445171.9A patent/CN107011745A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103894333A (en) * | 2006-06-23 | 2014-07-02 | 3M创新有限公司 | Articles having durable hydrophobic surfaces |
| CN106700936A (en) * | 2015-08-02 | 2017-05-24 | 王娟 | Material for super hydrophobic coating layer |
| CN105131817A (en) * | 2015-08-27 | 2015-12-09 | 岳西县永泰机械制造有限公司 | Impact resistant coating for metal and preparation method therefor |
| CN106047029A (en) * | 2016-06-12 | 2016-10-26 | 合肥和安机械制造有限公司 | Fluorinated modified metallic copper anticorrosive coating and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170804 |
|
| WD01 | Invention patent application deemed withdrawn after publication |