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CN106995639A - A kind of inexpensive anti-corrosion material under water - Google Patents

A kind of inexpensive anti-corrosion material under water Download PDF

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Publication number
CN106995639A
CN106995639A CN201710250880.1A CN201710250880A CN106995639A CN 106995639 A CN106995639 A CN 106995639A CN 201710250880 A CN201710250880 A CN 201710250880A CN 106995639 A CN106995639 A CN 106995639A
Authority
CN
China
Prior art keywords
component
under water
compositions
corrosion material
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710250880.1A
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Chinese (zh)
Inventor
张文宇
罗永康
刘鸿图
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kangyu Hydropower Machinery Complete Equipment Co Ltd
Original Assignee
Anhui Kangyu Hydropower Machinery Complete Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Kangyu Hydropower Machinery Complete Equipment Co Ltd filed Critical Anhui Kangyu Hydropower Machinery Complete Equipment Co Ltd
Priority to CN201710250880.1A priority Critical patent/CN106995639A/en
Publication of CN106995639A publication Critical patent/CN106995639A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0881Titanium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to technical field of anticorrosion under water, a kind of low cost anti-corrosion material under water is particularly belonged to, anti-corrosion material is made up of according to weight ratio 3~4 described low cost component A and component B under water:1 composition;Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol according to weight ratio 61~70:10~18:0.01~0.02:0.003~0.005:25~35:10~18 compositions;Described component B is by underwater epoxy curing agent, thixotropic agent, coupling agent according to weight than 50~60:25~35:3~8 compositions.Instant invention overcomes the deficiencies in the prior art, it is made up of component A and component B, does not trickle, do not disperse under water, conventional application means can be used, and with good coating performance, while material price is low in formula, batch mixing is convenient, and cost is low, and the scope of application is wide.

Description

A kind of inexpensive anti-corrosion material under water
Technical field
The present invention relates to technical field of anticorrosion under water, a kind of low cost anti-corrosion material under water is particularly belonged to.
Background technology
Water conservancy and hydropower steel construction underwater portion corrosion is a kind of phenomenon of generally existing, for the knot of water conservancy and hydropower building It is configured to very big harm;Have much for the preservative treatment material and method of hydraulic structure steel construction, but generally exist Used under dry environment.But the steel construction in power station has much under water, or even at the progress anti-corrosion that can not leave the water Reason, the particularly metallic structures such as gate slot;The conventional processing for problems is due to not good marine material and work Skill, reduces water level often through emptying reservoir or takes the method for building cofferdam to form construction at dry land condition, but thus bring Economic loss be sizable, and some hydraulic structures due to service condition limitation can not be vented.Therefore research and development are needed Go out it is a kind of can be with the curing materials and anticorrosive paint of underwater operation.
The content of the invention
It is an object of the invention to provide a kind of inexpensive anti-corrosion material under water, the deficiencies in the prior art are overcome, by group Divide A and component B compositions, do not trickle, do not disperse under water, conventional application means can be used, and with good application Performance, while material price is low in formula, batch mixing is convenient, and cost is low, and the scope of application is wide.
To solve the above problems, the technical solution used in the present invention is as follows:
A kind of inexpensive anti-corrosion material under water, anti-corrosion material is made up of according to weight described low cost component A and component B under water Than 3~4:1 composition;Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium and be combined Filler and phenol are according to weight ratio 61~70:10~18:0.01~0.02:0.003~0.005:25~35:10~18 compositions; Described component B is by underwater epoxy curing agent, thixotropic agent, coupling agent according to weight than 50~60:25~35:3~8 compositions;Institute The underwater epoxy curing agent stated is made up of nonyl phenol and paraformaldehyde.
Further, anti-corrosion material is made up of according to weight ratio 3.8 described low cost component A and component B under water:1 composition.
Further, anti-corrosion material is made up of according to weight ratio 3.2 described low cost component A and component B under water:1 composition.
Further, described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, to invade profit agent, nano-titanium multiple Filler and phenol are closed according to weight ratio 65:15:0.015:0.004:31:16 compositions.
Further, described component B compares 55 by underwater epoxy curing agent, thixotropic agent, coupling agent according to weight:29:6 groups Into.
Further, described nonyl phenol and paraformaldehyde weight ratio are 180:48 compositions.
Compared with prior art, implementation result of the invention is as follows by the present invention:
Anti-corrosion material is made up of low cost of the present invention component A and component B under water, is not trickled, is not disperseed under water, can make With conventional application means, and with good coating performance, while material price is low in formula, batch mixing is convenient, and cost is low, The scope of application is wide.
Embodiment
With reference to embodiment, the invention will be further described, but the present invention is not limited only to these examples, to be de- On the premise of from present inventive concept, carried out by it is any improvement be within the scope of the present invention.
Embodiment one
A kind of inexpensive anti-corrosion material under water of the present invention, is made up of according to weight ratio 3~4 component A and component B:1 group Into;Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol According to weight than 61~70:10~18:0.01~0.02:0.003~0.005:25~35:10~18 compositions;Described component B By underwater epoxy curing agent, thixotropic agent, coupling agent according to weight than 50~60:25~35:3~8 compositions;Described underwater epoxy Curing agent is by nonyl phenol and paraformaldehyde according to weight ratio 180:48 compositions.
Embodiment two
Anti-corrosion material is made up of according to weight ratio 3.8 a kind of low cost of the present invention component A and component B under water:1 composition; Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol according to Weight compares 65:15:0.015:0.004:31:16 compositions;Described component B is pressed by underwater epoxy curing agent, thixotropic agent, coupling agent Compare 55 according to weight:29:6 compositions;Described underwater epoxy curing agent is by nonyl phenol and paraformaldehyde according to weight ratio 180:48 groups Into;It is applicable as 10 DEG C -40 DEG C of temperature.
Embodiment three
A kind of inexpensive anti-corrosion material under water of the present invention, described inexpensive anti-corrosion material under water is by component A and component B Composition compares 3.2 according to weight:1 composition;Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, Nano-titanium compounded mix and phenol are according to weight ratio 65:15:0.015:0.004:31:16 compositions;Described component B is by ring under water Oxygen curing agent, thixotropic agent, coupling agent compare 55 according to weight:29:6 compositions;Described underwater epoxy curing agent is by nonyl phenol and many Polyformaldehyde compares 180 according to weight:48 compositions;It is applicable as 0 DEG C -10 DEG C of temperature.
Example IV
A kind of inexpensive anti-corrosion material under water of the present invention, is made up of according to weight ratio 3 component A and component B:1 composition;Institute The component A stated by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol according to weight Amount compares 61:10:0.01:0.003:25:10 compositions;Described component B by underwater epoxy curing agent, thixotropic agent, coupling agent according to Weight compares 50:25:3 compositions;Described underwater epoxy curing agent is by nonyl phenol and paraformaldehyde according to weight ratio 180:48 compositions.
Embodiment five
A kind of inexpensive anti-corrosion material under water of the present invention, is made up of according to weight ratio 4 component A and component B:1 composition;Institute The component A stated by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol according to weight Amount compares 70:18:0.02:0.005:35:18 compositions;Described component B by underwater epoxy curing agent, thixotropic agent, coupling agent according to Weight compares 60:35:8 compositions;Described underwater epoxy curing agent is by nonyl phenol and paraformaldehyde according to weight ratio 180:48 compositions.

Claims (6)

1. a kind of inexpensive anti-corrosion material under water, it is characterised in that described inexpensive anti-corrosion material under water is by component A and component B compositions are according to weight than 3~4:1 composition;
Described component A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol According to weight than 61~70:10~18:0.01~0.02:0.003~0.005:25~35:10~18 compositions;
Described component B is by underwater epoxy curing agent, thixotropic agent, coupling agent according to weight than 50~60:25~35:3~8 groups Into;
Described underwater epoxy curing agent is made up of nonyl phenol and paraformaldehyde.
2. a kind of inexpensive anti-corrosion material under water according to claim 1, it is characterised in that:Described low cost is prevented under water Rotten material is made up of according to weight ratio 3.8 component A and component B:1 composition.
3. a kind of inexpensive anti-corrosion material under water according to claim 1, it is characterised in that:Described low cost is prevented under water Rotten material is made up of according to weight ratio 3.2 component A and component B:1 composition.
4. the inexpensive anti-corrosion material under water of one kind according to any one of claims 1 to 3, it is characterised in that:Described group Point A by modified epoxy, Nano-mter Ti-alloy powder, defoamer, invade profit agent, nano-titanium compounded mix and phenol according to weight ratio 65:15:0.015:0.004:31:16 compositions.
5. the inexpensive anti-corrosion material under water of one kind according to any one of claims 1 to 3, it is characterised in that:Described group B is divided to compare 55 according to weight by underwater epoxy curing agent, thixotropic agent, coupling agent:29:6 compositions.
6. a kind of inexpensive anti-corrosion material under water according to claim 1, it is characterised in that:Described nonyl phenol and poly Formaldehyde weight ratio is 180:48 compositions.
CN201710250880.1A 2017-04-18 2017-04-18 A kind of inexpensive anti-corrosion material under water Pending CN106995639A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710250880.1A CN106995639A (en) 2017-04-18 2017-04-18 A kind of inexpensive anti-corrosion material under water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710250880.1A CN106995639A (en) 2017-04-18 2017-04-18 A kind of inexpensive anti-corrosion material under water

Publications (1)

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CN106995639A true CN106995639A (en) 2017-08-01

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280144A (en) * 2007-12-28 2008-10-08 长沙科星纳米工程技术有限公司 High-elastic wave-absorbing heavy-duty anticorrosive nano-coating
CN101486871A (en) * 2008-01-18 2009-07-22 上海达旺化学科技有限公司 Preparations of underwater coating heavy anti-corrosive paint and coating resin
CN102533058A (en) * 2010-12-27 2012-07-04 海洋化工研究院 Solvent-free anticorrosive paint for damp interfaces and preparing method and application thereof
CN103980797A (en) * 2014-05-07 2014-08-13 西北矿冶研究院 Polyurethane modified epoxy resin anticorrosive nano-coating
US20150225446A1 (en) * 2012-10-04 2015-08-13 Immunogen, Inc. Use of a pvdf membrane to purify cell-binding agent cytotoxic agent conjugates

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101280144A (en) * 2007-12-28 2008-10-08 长沙科星纳米工程技术有限公司 High-elastic wave-absorbing heavy-duty anticorrosive nano-coating
CN101486871A (en) * 2008-01-18 2009-07-22 上海达旺化学科技有限公司 Preparations of underwater coating heavy anti-corrosive paint and coating resin
CN102533058A (en) * 2010-12-27 2012-07-04 海洋化工研究院 Solvent-free anticorrosive paint for damp interfaces and preparing method and application thereof
US20150225446A1 (en) * 2012-10-04 2015-08-13 Immunogen, Inc. Use of a pvdf membrane to purify cell-binding agent cytotoxic agent conjugates
CN103980797A (en) * 2014-05-07 2014-08-13 西北矿冶研究院 Polyurethane modified epoxy resin anticorrosive nano-coating

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Application publication date: 20170801

RJ01 Rejection of invention patent application after publication