CN106967346A - A kind of water proof fire retardant paint for kitchen use and preparation method - Google Patents
A kind of water proof fire retardant paint for kitchen use and preparation method Download PDFInfo
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- CN106967346A CN106967346A CN201710199006.XA CN201710199006A CN106967346A CN 106967346 A CN106967346 A CN 106967346A CN 201710199006 A CN201710199006 A CN 201710199006A CN 106967346 A CN106967346 A CN 106967346A
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- fire retardant
- water proof
- proof fire
- retardant paint
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- 239000003973 paint Substances 0.000 title claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 229960000892 attapulgite Drugs 0.000 claims abstract description 41
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 41
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 37
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 28
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000012188 paraffin wax Substances 0.000 claims abstract description 28
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 24
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 24
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 21
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000006229 carbon black Substances 0.000 claims abstract description 18
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 18
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- 239000003822 epoxy resin Substances 0.000 claims abstract description 14
- 239000005011 phenolic resin Substances 0.000 claims abstract description 14
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 14
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 14
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 13
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000725 suspension Substances 0.000 claims description 11
- 239000004927 clay Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 238000003828 vacuum filtration Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 5
- -1 Boratex Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- CZCSLHYZEQSUNV-UHFFFAOYSA-N [Na].OB(O)O Chemical compound [Na].OB(O)O CZCSLHYZEQSUNV-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/24—Homopolymers or copolymers of amides or imides
- C09D133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water proof fire retardant paint for kitchen use and preparation method, the water proof fire retardant enamel-cover includes following component：Polyacrylamide emulsion, phenolic resin, epoxy resin, sodium metasilicate, ethyl acetate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex, carbon black, graphene, chrome green, attapulgite modified, micropore calcium carbonate, talcum powder, colorant.Preparation method includes：Weigh phenolic resin, epoxy resin, acetic acid ethyl reaction and obtain mixture a1；Polyacrylamide emulsion and graphene aqueous solution are added, sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex are added after mixing, is well mixed, reacts to obtain mixture a2；Add and the water proof fire retardant paint is produced after remaining ingredient, mixing.Water proof fire retardant paint for kitchen use of the present invention not only has preferable waterproof, fire protecting performance, also with preferable oil-stain-preventing performance, with preferable application value.
Description
Technical field
The present invention relates to kitchen's interior technical field, and in particular to a kind of water proof fire retardant paint for kitchen use and preparation method.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses is mixed
Compound coating.Chinese coating circle is more authoritative《Coating process》What one book was defined as：" coating is a kind of material, this
Material can be coated in object surface with different construction technologies, form adhesion firm, thin with some strength, continuous solid-state
Film.The film common name film so formed, also known as paint film or coating." belong to organic chemical industry's macromolecular material, the film category formed
In high-molecular compound type.The classification for the chemical products passed through according to the modern times, coating belongs to fine chemical product.Modern painting
Material progressively turns into the multi-functional engineering material of a class, is an important industry in chemical industry.
With the extensive use of paint in daily life, the requirement more and more higher to its fire resistance, and existing common paint
Security against fire in terms of main defective two：First, it is inflammable.Existing common paint belongs to combustibles, because they are present easily
Composition is fired, is extremely easily caught fire.Its burning velocity is fast, it is easy to occurs fire, and spreads rapidly, puts out a fire to save life and property and be easy to not in time
Produce massive losses.2nd, a large amount of electrostatic are produced.Due to the effect of the phase mutual friction between object, accumulation of static electricity is easily produced, is occurred
Electrostatic hazard.Such as interference calculation machine, the normal work of precision instrument, can discharge generation spark in severe cases, cause quick-fried
Fried and fire.The paint for being applied especially to kitchen is more rare, and conventional kitchen's interior adheres in order to avoid greasy dirt, generally pastes porcelain
Brick, not only increases use cost, also often occurs the phenomenon that ceramic tile is not firm, come off, with certain potential safety hazard.
Therefore, research and development one kind can be used in kitchen, and the paint with preferable fire prevention, water resistance has important meaning
Justice, also complies with the demand of existing market.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of water proof fire retardant paint for kitchen use and preparation side
Method, the water proof fire retardant paint for kitchen use not only has preferable waterproof, fire protecting performance, also with preferable oil-stain-preventing performance, tool
There is preferable application value.
The present invention solves technical problem and adopted the following technical scheme that：
The present invention relates to a kind of water proof fire retardant paint for kitchen use, include each raw material of following parts by weight：Polyacrylamide emulsion 20 ~ 46
Part, 12 ~ 19 parts of phenolic resin, 7 ~ 15 parts of epoxy resin, 5 ~ 12 parts of sodium metasilicate, 15 ~ 23 parts of ethyl acetate, nano titanium oxide 6 ~
17 parts, 6 ~ 16 parts of antimony oxide, 10 ~ 20 parts of chlorinated paraffin, 3 ~ 11 parts of Boratex, 5 ~ 12 parts of carbon black, 3 ~ 9 parts of graphene, three
Aoxidize 2 ~ 5 parts of two chromium, attapulgite modified 5 ~ 13 parts, 5 ~ 10 parts of micropore calcium carbonate, 6 ~ 15 parts of talcum powder, 1 ~ 5 part of colorant.
Preferably, 39 parts of the polyacrylamide emulsion, 15 parts of phenolic resin, 11 parts of epoxy resin, 8 parts of sodium metasilicate, second
18 parts of acetoacetic ester, 12 parts of nano titanium oxide, 14 parts of antimony oxide, 16 parts of chlorinated paraffin, 7 parts of Boratex, 9 parts of carbon black, stone
Black 8 parts of alkene, 3 parts of chrome green, attapulgite modified 10 parts, 6 parts of micropore calcium carbonate, 12 parts of talcum powder, 3 parts of colorant.
The invention further relates to a kind of method for preparing water proof fire retardant paint for kitchen use, comprise the following steps：
（1）Phenolic resin, epoxy resin, ethyl acetate are weighed according to proportioning to be added in reactor, are stirred and are warming up to 195
~ 205 DEG C, 0.5 ~ 2h of stirring reaction obtains reactant mixture a1；
（2）Temperature is adjusted to 110 ~ 130 DEG C, polyacrylamide emulsion and graphene aqueous solution, mixing are added into mixture a1
1 ~ 2h is stirred, sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex is then added, is well mixed, stirs
0.5 ~ 2h of reaction is mixed, mixture a2 is obtained；
（3）90 ~ 100 DEG C are adjusted the temperature to, carbon black, chrome green, attapulgite modified, microporous carbon are added into mixture a2
Sour calcium, talcum powder, colorant, are mixed evenly, then are placed in 10 ~ 20min of shearing in cutter, produce the water proof fire retardant paint.
Preferably, the step（2）The concentration of middle graphene aqueous solution is 0.15 ~ 0.25g/L.
Preferably, the step（2）Middle sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex
Addition sequence mixes 20 ~ 30min, then adds sodium metasilicate, nanometer two first to add antimony oxide and chlorinated paraffin
Titanium oxide and Boratex.
Preferably, the step（3）In it is attapulgite modified for natural attapulgite it is purified, it is acidified modified after it is recessed
Convex rod soil.
Preferably, the attapulgite modified preparation method includes：
Take natural attapulgite clay to carry out being crushed to 200 ~ 300 mesh, add water, stirring forms mud in suspension, takes upper suspension
5 ~ 10min of centrifugal treating in 4000 ~ 5000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in 800 DEG C ~
1000 DEG C of Muffle 2 ~ 4h of kiln roasting, is ground to particle diameter for 200 ~ 300 mesh after cooling, obtain modified attapulgite and glue
Soil.
Preferably, the step（3）Middle carbon black, chrome green, micropore calcium carbonate, talcum powder are first size-reduced before adding
Particle diameter is ground to for 200 ~ 300 mesh.
Compared with prior art, the present invention has following beneficial effect：
（1）Water proof fire retardant paint for kitchen use of the present invention, with preferable waterproof, fire protecting performance, also with preferably grease proofing
Dirty performance, applied to kitchen's interior, not only saves the high cost brought using ceramic tile, it is thus also avoided that ceramic tile comes off the people caused
Body property loss, substantially increases safety in utilization, and can easily remove surface and oil contaminant, greatly reduces what kitchen degreased
Difficulty, with preferable application value.
（2）Modified attapulgite clay is added with water proof fire retardant paint for kitchen use of the present invention, with preferable viscosity
And plasticity, emulsification rate is higher, saves emulsification production process, reduces production cost, be conducive to emulsification between raw material and
Bond, adhesive property, antistrip performance and the waterproof effect of paint and building surface can be greatly increased by being applied in paint.
Because attapulgite also has preferable suspension, levelability and thickening property, and hence it is also possible to instead of original suspending agent, increasing
Thick dose and stabilizer, greatly reduce consumption of raw materials and cost of material.Further, since Concave-convex clay rod is pure natural substance,
Chemical inertness, it is pollution-free, suppress growth of microorganism, absorb poisonous volatile ingredient, applied to can effectively adsorb kitchen in kitchen
In pernicious gas and bad smell, play a part of purify air.
（3）Grapheme material is added with water proof fire retardant paint for kitchen use of the present invention, because graphene has uniqueness
It is laminar structured, it is layering to form the physical isolation layer of densification so that the modified flame retardant paint prepared of graphene has
Preferable physical isolation waterproof action, along with graphene has excellent mechanical property so that painting layer has preferable
Mechanical strength and wearability, guarantee is provided for the service life of paint.
（4）The antimony oxide added in water proof fire retardant paint for kitchen use of the present invention and chlorinated paraffin synergy, show
Fire prevention, the fire resistance for improving paint are write, safety guarantee is provided applied to kitchen for paint.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.The experimental method of unreceipted actual conditions in the following example, generally according to normal condition, for example
Sambrook equimoleculars are cloned：Laboratory manual（New York:Cold Spring Harbor Laboratory Press,
1989）Described in condition, or according to the condition proposed by manufacturer
Embodiment 1：
A kind of water proof fire retardant paint for kitchen use and preparation method of the preferred embodiment of the present invention；
The water proof fire retardant paint for kitchen use, is prepared from by each raw material of following parts by weight：
39 parts of polyacrylamide emulsion, 15 parts of phenolic resin, 11 parts of epoxy resin, 8 parts of sodium metasilicate, ethyl acetate 18 part, nanometer
12 parts of titanium dioxide, 14 parts of antimony oxide, 16 parts of chlorinated paraffin, 7 parts of Boratex, 9 parts of carbon black, 8 parts of graphene, three oxidations two
3 parts of chromium, attapulgite modified 10 parts, 6 parts of micropore calcium carbonate, 12 parts of talcum powder, 3 parts of colorant.
The preparation method of water proof fire retardant paint for kitchen use of the present invention, comprises the following steps：
（1）Phenolic resin, epoxy resin, ethyl acetate are weighed according to proportioning to be added in reactor, are stirred and are warming up to 200
DEG C, stirring reaction 1.5h obtains reactant mixture a1；
（2）Temperature is adjusted to 120 DEG C, polyacrylamide emulsion and graphene aqueous solution are added into mixture a1, is mixed
1.5h, then adds sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex, is well mixed, and stirring is anti-
1h is answered, mixture a2 is obtained；
（3）90 DEG C are adjusted the temperature to, carbon black, chrome green, attapulgite modified, micropore carbonic acid are added into mixture a2
Calcium, talcum powder, colorant, are mixed evenly, then are placed in cutter and shear 15min, produce the water proof fire retardant paint.
Step（2）The concentration of middle graphene aqueous solution is 0.2 g/L.
Step（2）Middle sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, the addition sequence of Boratex is first
Antimony oxide and chlorinated paraffin are added, 20 min is mixed, then adds sodium metasilicate, nano titanium oxide and boric acid
Sodium.The purpose so operated is first antimony oxide, chlorinated paraffin to be cooperated, and then adds other components, can be with
Effectively improve the fire retardant performance of paint.
Step（3）In it is attapulgite modified for natural attapulgite it is purified, it is acidified modified after attapulgite.
The attapulgite modified preparation method includes：
Take natural attapulgite clay to carry out being crushed to 200 ~ 300 mesh, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 10min in 4000 ~ 5000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in 800 DEG C ~
1000 DEG C of Muffle kiln roasting 3h, is ground to particle diameter for 200 ~ 300 mesh, obtains modified Concave-convex clay rod after cooling.
Step（3）Middle carbon black, chrome green, micropore calcium carbonate, talcum powder are first size-reduced before adding to be ground to particle diameter
For 200 ~ 300 mesh, enabling have more preferable compatibility between various ingredients.
Embodiment 2：
A kind of water proof fire retardant paint for kitchen use and preparation method of the preferred embodiment of the present invention；
The water proof fire retardant paint for kitchen use, is prepared from by each raw material of following parts by weight：
20 parts of polyacrylamide emulsion, 12 parts of phenolic resin, 7 parts of epoxy resin, 5 parts of sodium metasilicate, part, nanometer two of ethyl acetate 15
6 parts of titanium oxide, 6 parts of antimony oxide, 10 parts of chlorinated paraffin, 3 parts of Boratex, 5 parts of carbon black, 3 parts of graphene, chrome green 2
Part, attapulgite modified 5 parts, 5 parts of micropore calcium carbonate, 6 parts of talcum powder, 1 part of colorant.
The preparation method of water proof fire retardant paint for kitchen use of the present invention, comprises the following steps：
（1）Phenolic resin, epoxy resin, ethyl acetate are weighed according to proportioning to be added in reactor, are stirred and are warming up to 195
DEG C, stirring reaction 2h obtains reactant mixture a1；
（2）Temperature is adjusted to 110 DEG C, polyacrylamide emulsion and graphene aqueous solution are added into mixture a1, is mixed
1h, then adds sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex, is well mixed, stirring reaction
0.5h, obtains mixture a2；
（3）90 DEG C are adjusted the temperature to, carbon black, chrome green, attapulgite modified, micropore carbonic acid are added into mixture a2
Calcium, talcum powder, colorant, are mixed evenly, then are placed in cutter and shear 20min, produce the water proof fire retardant paint.
Step（2）The concentration of middle graphene aqueous solution is 0.15g/L.
Step（2）Middle sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, the addition sequence of Boratex is first
Antimony oxide and chlorinated paraffin are added, 20min is mixed, then adds sodium metasilicate, nano titanium oxide and Boratex.
The purpose so operated is first antimony oxide, chlorinated paraffin to be cooperated, and then adds other components, can be effective
Improve the fire retardant performance of paint.
Step（3）In it is attapulgite modified for natural attapulgite it is purified, it is acidified modified after attapulgite.
The attapulgite modified preparation method includes：
Take natural attapulgite clay to carry out being crushed to 200 ~ 300 mesh, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 5min in 4000 ~ 5000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in 800 DEG C ~
1000 DEG C of Muffle kiln roasting 2h, is ground to particle diameter for 200 ~ 300 mesh, obtains modified Concave-convex clay rod after cooling.
Step（3）Middle carbon black, chrome green, micropore calcium carbonate, talcum powder are first size-reduced before adding to be ground to particle diameter
For 200 ~ 300 mesh, enabling have more preferable compatibility between various ingredients.
Embodiment 3：
A kind of water proof fire retardant paint for kitchen use and preparation method of the preferred embodiment of the present invention；
The water proof fire retardant paint for kitchen use, is prepared from by each raw material of following parts by weight：
46 parts of polyacrylamide emulsion, 19 parts of phenolic resin, 15 parts of epoxy resin, 12 parts of sodium metasilicate, ethyl acetate 23 part, nanometer
17 parts of titanium dioxide, 16 parts of antimony oxide, 20 parts of chlorinated paraffin, 11 parts of Boratex, 12 parts of carbon black, 9 parts of graphene, three oxidations
Two 5 parts of chromium, attapulgite modified 13 parts, 10 parts of micropore calcium carbonate, 15 parts of talcum powder, 5 parts of colorant.
The preparation method of water proof fire retardant paint for kitchen use of the present invention, comprises the following steps：
（1）Phenolic resin, epoxy resin, ethyl acetate are weighed according to proportioning to be added in reactor, are stirred and are warming up to 205
DEG C, stirring reaction 0.5h obtains reactant mixture a1；
（2）Temperature is adjusted to 130 DEG C, polyacrylamide emulsion and graphene aqueous solution are added into mixture a1, is mixed
2h, then adds sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex, is well mixed, stirring reaction
2h, obtains mixture a2；
（3）100 DEG C are adjusted the temperature to, carbon black, chrome green, attapulgite modified, micropore carbonic acid are added into mixture a2
Calcium, talcum powder, colorant, are mixed evenly, then are placed in cutter and shear 10min, produce the water proof fire retardant paint.
Step（2）The concentration of middle graphene aqueous solution is 0.25g/L.
Step（2）Middle sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, the addition sequence of Boratex is first
Antimony oxide and chlorinated paraffin are added, 30min is mixed, then adds sodium metasilicate, nano titanium oxide and Boratex.
The purpose so operated is first antimony oxide, chlorinated paraffin to be cooperated, and then adds other components, can be effective
Improve the fire retardant performance of paint.
Step（3）In it is attapulgite modified for natural attapulgite it is purified, it is acidified modified after attapulgite.
The attapulgite modified preparation method includes：
Take natural attapulgite clay to carry out being crushed to 200 ~ 300 mesh, add water, stirring forms mud in suspension, takes upper suspension
The centrifugal treating 10min in 4000 ~ 5000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in 800 DEG C ~
1000 DEG C of Muffle kiln roasting 4h, is ground to particle diameter for 200 ~ 300 mesh, obtains modified Concave-convex clay rod after cooling.
Step（3）Middle carbon black, chrome green, micropore calcium carbonate, talcum powder are first size-reduced before adding to be ground to particle diameter
For 200 ~ 300 mesh, enabling have more preferable compatibility between various ingredients.
In summary, water proof fire retardant paint for kitchen use of the present invention, with preferable waterproof, fire protecting performance, also has
Preferable oil-stain-preventing performance, applied to kitchen's interior, not only saves the high cost brought using ceramic tile, it is thus also avoided that ceramic tile takes off
Fall the loss of personal property caused, substantially increase safety in utilization, and can easily remove surface and oil contaminant, greatly reduce kitchen
The difficulty that room degreases, with preferable application value.And preparation method of the present invention is simple, easy to implement, reaction condition is gentle,
It is adapted to industrialized production.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of water proof fire retardant paint for kitchen use, it is characterised in that：Each raw material including following parts by weight：Polyacrylamide emulsion 20
~ 46 parts, 12 ~ 19 parts of phenolic resin, 7 ~ 15 parts of epoxy resin, 5 ~ 12 parts of sodium metasilicate, 15 ~ 23 parts of ethyl acetate, nanometer titanium dioxide
6 ~ 17 parts of titanium, 6 ~ 16 parts of antimony oxide, 10 ~ 20 parts of chlorinated paraffin, 3 ~ 11 parts of Boratex, 5 ~ 12 parts of carbon black, graphene 3 ~ 9
Part, 2 ~ 5 parts of chrome green, attapulgite modified 5 ~ 13 parts, 5 ~ 10 parts of micropore calcium carbonate, 6 ~ 15 parts of talcum powder, colorant 1 ~ 5
Part.
2. water proof fire retardant paint for kitchen use according to claim 1, it is characterised in that：39 parts of the polyacrylamide emulsion,
15 parts of phenolic resin, 11 parts of epoxy resin, 8 parts of sodium metasilicate, 18 parts of ethyl acetate, 12 parts of nano titanium oxide, antimony oxide
14 parts, 16 parts of chlorinated paraffin, 7 parts of Boratex, 9 parts of carbon black, 8 parts of graphene, 3 parts of chrome green, attapulgite modified 10 parts,
6 parts of micropore calcium carbonate, 12 parts of talcum powder, 3 parts of colorant.
3. a kind of method for preparing water proof fire retardant paint for kitchen use as claimed in claim 1 or 2, it is characterised in that：Including as follows
Step：
（1）Phenolic resin, epoxy resin, ethyl acetate are weighed according to proportioning to be added in reactor, are stirred and are warming up to 195
~ 205 DEG C, 0.5 ~ 2h of stirring reaction obtains reactant mixture a1；
（2）Temperature is adjusted to 110 ~ 130 DEG C, polyacrylamide emulsion and graphene aqueous solution, mixing are added into mixture a1
1 ~ 2h is stirred, sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex is then added, is well mixed, stirs
0.5 ~ 2h of reaction is mixed, mixture a2 is obtained；
（3）90 ~ 100 DEG C are adjusted the temperature to, carbon black, chrome green, attapulgite modified, microporous carbon are added into mixture a2
Sour calcium, talcum powder, colorant, are mixed evenly, then are placed in 10 ~ 20min of shearing in cutter, produce the water proof fire retardant paint.
4. the preparation method of water proof fire retardant paint for kitchen use according to claim 3, it is characterised in that：The step（2）In
The concentration of graphene aqueous solution is 0.15 ~ 0.25g/L.
5. the preparation method of water proof fire retardant paint for kitchen use according to claim 3, it is characterised in that：The step（2）In
Sodium metasilicate, nano titanium oxide, antimony oxide, chlorinated paraffin, Boratex addition sequence for first add antimony oxide and
Chlorinated paraffin, mixes 20 ~ 30min, then adds sodium metasilicate, nano titanium oxide and Boratex.
6. the preparation method of water proof fire retardant paint for kitchen use according to claim 3, it is characterised in that：The step（3）In
It is attapulgite modified for natural attapulgite it is purified, it is acidified modified after attapulgite.
7. the preparation method of water proof fire retardant paint for kitchen use according to claim 6, it is characterised in that：The modified attapulgite
The preparation method of soil includes：
Take natural attapulgite clay to carry out being crushed to 200 ~ 300 mesh, add water, stirring forms mud in suspension, takes upper suspension
5 ~ 10min of centrifugal treating in 4000 ~ 5000 turns/min centrifuge, vacuum filtration；Filter cake is dried, be subsequently placed in 800 DEG C ~
1000 DEG C of Muffle 2 ~ 4h of kiln roasting, is ground to particle diameter for 200 ~ 300 mesh after cooling, obtain modified attapulgite and glue
Soil.
8. the preparation method of water proof fire retardant paint for kitchen use according to claim 3, it is characterised in that：The step（3）In
The first size-reduced particle diameter that is ground to is 200 ~ 300 mesh before carbon black, chrome green, micropore calcium carbonate, talcum powder addition.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227057A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of building roof waterproofing slurry and preparation method |
| CN107267020A (en) * | 2017-07-26 | 2017-10-20 | 合肥尚强电气科技有限公司 | Coating for capacitor shell and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013028344A1 (en) * | 2011-08-25 | 2013-02-28 | Chemtura Corporation | Brominated flame retardant, antimony oxide free polymer formulations |
| CN103342951A (en) * | 2013-06-27 | 2013-10-09 | 天长市巨龙车船涂料有限公司 | Chlorinated polyether resin fireproof coating and preparation method thereof |
| CN103773165A (en) * | 2014-01-20 | 2014-05-07 | 南通钰成光电科技有限公司 | Waterproof flame-retardant coating for wood lampshade and preparation method thereof |
| CN103911029A (en) * | 2014-03-21 | 2014-07-09 | 苏州宇希新材料科技有限公司 | Powder material used for exterior coating |
| CN105176346A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Heat-resistant flame-retardant anticorrosion water-based coating |
-
2017
- 2017-03-29 CN CN201710199006.XA patent/CN106967346A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013028344A1 (en) * | 2011-08-25 | 2013-02-28 | Chemtura Corporation | Brominated flame retardant, antimony oxide free polymer formulations |
| CN103342951A (en) * | 2013-06-27 | 2013-10-09 | 天长市巨龙车船涂料有限公司 | Chlorinated polyether resin fireproof coating and preparation method thereof |
| CN103773165A (en) * | 2014-01-20 | 2014-05-07 | 南通钰成光电科技有限公司 | Waterproof flame-retardant coating for wood lampshade and preparation method thereof |
| CN103911029A (en) * | 2014-03-21 | 2014-07-09 | 苏州宇希新材料科技有限公司 | Powder material used for exterior coating |
| CN105176346A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Heat-resistant flame-retardant anticorrosion water-based coating |
Non-Patent Citations (1)
| Title |
|---|
| 沈海斌等: "石墨烯在涂料领域中的应用", 《涂料技术与文摘》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227057A (en) * | 2017-07-25 | 2017-10-03 | 合肥欧仕嘉机电设备有限公司 | A kind of building roof waterproofing slurry and preparation method |
| CN107267020A (en) * | 2017-07-26 | 2017-10-20 | 合肥尚强电气科技有限公司 | Coating for capacitor shell and preparation method |
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