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CN106957070A - A kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation method and application - Google Patents

A kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation method and application Download PDF

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Publication number
CN106957070A
CN106957070A CN201710165507.6A CN201710165507A CN106957070A CN 106957070 A CN106957070 A CN 106957070A CN 201710165507 A CN201710165507 A CN 201710165507A CN 106957070 A CN106957070 A CN 106957070A
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ammonia nitrogen
removal agent
rapidly
nitrogen removal
acid
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Inventor
吴昊
张天瑞
姚伟英
张海平
白赞章
陈建军
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Clear Ingegneria Ambientale Srl In Zhejiang One
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Clear Ingegneria Ambientale Srl In Zhejiang One
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5254—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using magnesium compounds and phosphoric acid for removing ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/722—Oxidation by peroxides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • C02F1/766—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply
    • C02F2103/026—Treating water for medical or cosmetic purposes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32—Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/18—Removal of treatment agents after treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/20—Prevention of biofouling

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

The present invention relates to a kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation method and application, the ammonia nitrogen removal agent includes the component of following weight/mass percentage compositions：Oxidant 5~35%, inorganic coagulant 5~50%, sorbing material 2~40%, calcium salt 1~15%, gas-producing disintegrant 1~20%.The present invention can voluntarily dissolve in water, noresidue, without secondary pollution, it is simple to operate, it is short the time required to purifying water, can rapidly and efficiently remove ammonia nitrogen, and COD, total phosphorus, suspension etc. have certain removal effect simultaneously；The present invention collect oxidation, breakpoint chlorination, coagulating sedimentation, absorption, acid-base value control, quickly collapse body dissolve etc. act on one, can quickly, efficiently remove ammonia nitrogen.

Description

A kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation method and application
Technical field
The invention belongs to water-treatment technology field, a kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation are concretely related to Methods and applications.
Background technology
High-concentration ammonia nitrogenous wastewater source very wide and discharge capacity is big, such as chemical fertilizer, coking, petrochemical industry, pharmacy, food, garbage loading embeading Field etc. produces a large amount of high-concentration ammonia nitrogenous wastewaters.A large amount of ammonia nitrogen waste waters, which are discharged into water body, not only to be caused body eutrophication, causes water Body is black smelly, and will increase the difficulty and cost of Water purification, or even to crowd and biological generation toxic action.Pollution administration, Energy-saving and emission-reduction have turned into the important topic of China's the Implement of sustainable development strategy, and ammonia nitrogen waste water is used as the important of body eutrophication Pollutant becomes the emphasis of improvement.Ammonia nitrogen waste water is discharged into after the water bodys such as lake, reservoir, river mouth, bay, will cause the richness of water body Amount reproduction is destroyed the ecological balance of water body by nutrient laden, aquatile particularly algae, causes water quality deterioration, fish dead. Therefore, removing ammonia nitrogen technology just turns into the focus of research and development and application in field of waste water treatment.So must be in waste water Ammonia nitrogen is handled.
Over nearly 20 years, both at home and abroad to having carried out more research in terms of ammonia nitrogen waste water processing, its research range is related to biology Method, the various handling process of physico-chemical process, such as biological method have nitrification and algal culture, but this method can only handle low concentration ammonia Nitrogen waste water, and treatment time is longer, is difficult to control in actual applications, can suppress the growth of microorganism for ammonia nitrogen in high density, And nitric efficiency is not high；Physical method has counter-infiltration, distillation etc., there is processing cost height, can not be used in big production；Chemistry Method has ion-exchange, ammonia aeration, chemical precipitation method, breakpoint chlorination, electrochemical treatments, catalytic pyrolysis etc., and these methods are passed through Ammonia nitrogen is unable to qualified discharge in waste water after single treatment, also needs subsequent treatment.Blow-off method nitric efficiency is high, but ammonia nitrogen not from Fundamentally remove.
The content of the invention
In order to overcome the shortcomings of that prior art is present, the invention provides a kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation Methods and applications.Ammonia nitrogen removal agent of the present invention can voluntarily dissolve in water, noresidue, without secondary pollution, it is simple to operate, only It is short the time required to changing water quality, ammonia nitrogen can be rapidly and efficiently removed, and there is certain removal to imitate COD, total phosphorus, suspension etc. simultaneously Really.
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent includes the component of following weight/mass percentage compositions：Oxidation Agent 5~35%, inorganic coagulant 5~50%, sorbing material 2~40%, calcium salt 1~15%, gas-producing disintegrant 1~20%.
The present invention operation principle be：
Oxidant is that ammonia nitrogen is direct oxidation into a kind of method that nitrogen is removed, wherein chloride oxidant also has Break point chlorination removal is acted on, and is that, using the ammonia in water and chlorine reaction generation ammonia deamination, can also play sterilizing effect；
Inorganic coagulant mainly removes ammonia nitrogen by coprecipitation mode, has and removes ammonia by generating ammonium sulfate magnesium i.e. guanite method Nitrogen, cardinal principle is NH4+、Mg2+、PO4 3+MgNH is generated in alkaline aqueous solution4PO4·6H2O, it is synchronous to remove N, P, also mix The flocculation sediment effect of solidifying agent is removed；
Sorbing material main function is to adsorb, the ammonia nitrogen in adsorbable waste water；
The dosage of calcium salt is relevant with the basicity of water, available for the pH value for maintaining water sample；
When gas-producing disintegrant meets water, two kinds of substance reactions of soda acid produce CO2And up to effervesce effect, make medicament a few minutes it Interior rapid disintegration；So that medicament also can quickly dissolve under the conditions of unpowered agitation, carrying out reaction with water sample tells on.
Preferably, the oxidant is sodium hypochlorite, calcium hypochlorite, chlorine dioxide, hydrogen peroxide, trichlorine isocyanide urine Any group of one or two or more kinds in acid, sodium dichloro cyanurate, bleaching powder, potassium hyperchlorate, potassium ferrate, sodium peroxydisulfate Close.
Preferably, the inorganic coagulant is aluminum sulfate, polyaluminium sulfate, iron chloride, poly-ferric chloride, hydroxide Magnesium, magnesium chloride, magnesium sulfate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, dipotassium hydrogen phosphate, disodium hydrogen phosphate, polyacrylamide, carboxylic first Two kinds of any of the above combination in base sodium cellulosate.
Preferably, the sorbing material is activated carbon, bentonite, diatomite, chitosan, zeolite, aluminum sulfate, active oxygen Change one or two or more kinds of any combination in aluminium, Emathlite, flyash, ferromanganese filtrate.
Preferably, the calcium salt is calcium hydroxide, calcium oxide, calcium chloride, calcium chlorate, Calcium perchlorate, calcium dihydrogen phosphate In one or two or more kinds of any combination.
Preferably, the gas-producing disintegrant includes acid source and alkali source, the acid source is citric acid, malic acid, boric acid, wine One or two or more kinds of any combination in stone acid, fumaric acid, citric acid, inorganic ore deposit acid；The alkali source is sodium acid carbonate, carbonic acid Sodium and its mixture of the two；Acid source, the weight ratio of alkali source are 1~2：1.
A kind of preparation method of rapidly and efficiently ammonia nitrogen removal agent, is produced each component mixing and stirring by proportioning.Prepare Technique is simple.
A kind of application of rapidly and efficiently ammonia nitrogen removal agent, the processing for nitrogen-containing wastewater.
Preferably, the nitrogen-containing wastewater is one of the following：Coking nitrogen-containing wastewater, food nitrogen-containing wastewater, chemical fertilizer Nitrogen-containing wastewater, river course nitrogen-containing wastewater, life in the countryside nitrogen-containing wastewater, pharmacy nitrogen-containing wastewater.
Preferably, the concentration of the nitrogen-containing wastewater is 15~1500mg/l.
The present invention has advantages below：
(1) each component mixing and stirring can be obtained into finished product by proportioning, preparation technology is simple；
(2) meet bubble and rise disintegration, can also be reacted in unpowered agitation condition, reaction is quick；
(3) integrate oxidation, breakpoint chlorination, absorption, coagulating sedimentation, acid-base value control, quickly collapse body dissolution, soon It is fast efficiently to remove ammonia nitrogen, and influenceed smaller by external conditions such as temperature, treatment effect is stable, not by Water Temperature, is swift in response Completely, and there is a disinfective action.
Embodiment
With reference to specific embodiment, the invention will be further described, but invention which is intended to be protected is not limited to This.
Embodiment 1
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：It is secondary Sodium chlorate 21%, magnesium sulfate 15%, sodium dihydrogen phosphate 14%, aluminum sulfate 15%, bentonite 10%, zeolite 6%, calcium hydroxide 8%th, citric acid 6%, sodium acid carbonate 5%；Each component mixing and stirring is produced into ammonia nitrogen removal agent by said ratio.
In the coking nitrogen-containing wastewater of the 550mg/l containing ammonia nitrogen, 1500mg/l ammonia nitrogen removal agent is added, 10min is reacted It is 4.5mg/l that ammonia-nitrogen content is remained in water outlet waste water afterwards, reaches going for ammonia nitrogen in national integrated wastewater discharge primary standard, waste water Except rate is 99.18%.
Embodiment 2
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Three Symclosene 20%, potassium ferrate 9%, magnesium hydroxide 14%, disodium hydrogen phosphate 12%, polyacrylamide 1%, activated carbon 8%th, activated alumina 11%, calcium chloride 10%, citric acid 8%, sodium acid carbonate 7%；Each component is mixed by said ratio and stirred Mix and uniformly produce ammonia nitrogen removal agent.
In the food nitrogen-containing wastewater of the 200mg/l containing ammonia nitrogen, 700mg/l ammonia nitrogen removal agent, 5min after reaction are added (how long is specific needsPlease supplement) residual ammonia-nitrogen content is 5.8mg/l in water outlet waste water, reaches national integrated wastewater discharge The clearance of ammonia nitrogen is 97.1% in primary standard, waste water.
Embodiment 3
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Two Symclosene sodium 13%, potassium ferrate 13%, polyaluminium sulfate 16%, iron chloride 10%, polyacrylamide 1%, bentonite 14%th, ferromanganese filtrate 9%, calcium oxide 11%, tartaric acid 7%, sodium acid carbonate 6%；Each component is mixed by said ratio Uniformly produce ammonia nitrogen removal agent.
In the chemical fertilizer nitrogen-containing wastewater of the 1050mg/l containing ammonia nitrogen, 2600mg/l ammonia nitrogen removal agent is added, 10min is reacted (how long is specific needs afterwardsPlease supplement) residual ammonia-nitrogen content is 12.6mg/l in water outlet waste water, reaches national integrated wastewater The clearance for discharging ammonia nitrogen in primary standard, waste water is 98.8%.
Embodiment 4
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Drift White powder 25%, sodium peroxydisulfate 6%, poly-ferric chloride 19%, magnesium chloride 10%, potassium dihydrogen phosphate 9%, activated carbon 5%, bentonite 6%th, calcium hydroxide 6%, fumaric acid 7%, sodium carbonate 7%；Each component mixing and stirring is produced into ammonia nitrogen by said ratio Except agent.
In the river course nitrogen-containing wastewater of the 45mg/l containing ammonia nitrogen, 100mg/l ammonia nitrogen removal agent, 5min after reaction are added (how long is specific needsPlease supplement) residual ammonia-nitrogen content is 0.75mg/l in river, reaches national surface water environment quality The clearance of ammonia nitrogen is 98.33% in the class standard of standard III, waste water.
Embodiment 5
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：It is secondary Calcium chlorate 14%, chlorine dioxide 14%, aluminum sulfate 18%, magnesium hydroxide 11%, sodium carboxymethylcellulose 1%, chitosan 10%, Diatomite 8%, calcium dihydrogen phosphate 10%, boric acid 8%, sodium acid carbonate 6%；It is by each component mixing and stirring by said ratio Obtain ammonia nitrogen removal agent.
In the life in the countryside nitrogen-containing wastewater of the 80mg/l containing ammonia nitrogen, 250mg/l ammonia nitrogen removal agent is added, 5min is reacted (how long is specific needs afterwardsPlease supplement) residual ammonia-nitrogen content is 2.1mg/l in river, reaches national integrated wastewater discharge one The clearance of ammonia nitrogen is 97.38% in level standard, waste water.
Embodiment 6
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Three Symclosene 15%, bleaching powder 18%, magnesium hydroxide 12%, dipotassium hydrogen phosphate 10%, polyacrylamide 1%, bentonite 12%th, activated alumina 13%, calcium chlorate 7%, citric acid 6%, sodium acid carbonate 6%；Each component is mixed by said ratio and stirred Mix and uniformly produce ammonia nitrogen removal agent.
In the pharmacy nitrogen-containing wastewater of the 350mg/l containing ammonia nitrogen, 1000mg/l ammonia nitrogen removal agent is added, 10min is reacted (how long is specific needs afterwardsPlease supplement) residual ammonia-nitrogen content is 6.1mg/l in water outlet waste water, reaches national integrated wastewater The clearance for discharging ammonia nitrogen in primary standard, waste water is 98.26%.
Embodiment 7
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Drift White powder 19%, sodium peroxydisulfate 11%, poly-ferric chloride 22%, aluminum sulfate 6%, polyacrylamide 1.5%, bentonite 12%, powder Coal ash 6.5%, calcium oxide 9%, citric acid 7%, sodium acid carbonate 6%；Each component mixing and stirring is produced by said ratio Ammonia nitrogen removal agent.
In the coking nitrogen-containing wastewater of the 550mg/l containing ammonia nitrogen, 1500mg/l ammonia nitrogen removal agent is added, 10min is reacted It is 14.3mg/l that ammonia-nitrogen content is remained in water outlet waste water afterwards, reaches ammonia nitrogen in national integrated wastewater discharge primary standard, waste water Clearance is 97.4%.
Embodiment 8
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：Three Symclosene 20%, potassium ferrate 9%, magnesium hydroxide 14%, disodium hydrogen phosphate 12%, polyacrylamide 1%, activated carbon 8%th, activated alumina 11%, calcium chloride 10%, citric acid 8%, sodium acid carbonate 7%；Each component is mixed by said ratio and stirred Mix and uniformly produce ammonia nitrogen removal agent.
In the coking nitrogen-containing wastewater of the 550mg/l containing ammonia nitrogen, 1500mg/l ammonia nitrogen removal agent is added, 10min is reacted It is 6.72mg/l that ammonia-nitrogen content is remained in water outlet waste water afterwards, reaches ammonia nitrogen in national integrated wastewater discharge primary standard, waste water Clearance is 98.78%.
Embodiment 9
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：It is secondary Calcium chlorate 14%, chlorine dioxide 14%, aluminum sulfate 18%, magnesium hydroxide 11%, sodium carboxymethylcellulose 1%, chitosan 10%, Diatomite 8%, calcium dihydrogen phosphate 10%, boric acid 8%, sodium acid carbonate 6%；It is by each component mixing and stirring by said ratio Obtain ammonia nitrogen removal agent.
In the coking nitrogen-containing wastewater of the 550mg/l containing ammonia nitrogen, 1500mg/l ammonia nitrogen removal agent is added, 10min is reacted It is 11.8mg/l that ammonia-nitrogen content is remained in water outlet waste water afterwards, reaches ammonia nitrogen in national integrated wastewater discharge primary standard, waste water Clearance is 97.85%.
Embodiment 10
A kind of rapidly and efficiently ammonia nitrogen removal agent, the ammonia nitrogen removal agent is made up of the component of following weight/mass percentage compositions：It is secondary Sodium chlorate 5%, magnesium sulfate 5%, sodium dihydrogen phosphate 35%, aluminum sulfate 5%, bentonite 30%, zeolite 5%, calcium hydroxide 2%, Citric acid 3%, sodium acid carbonate 10%；Each component mixing and stirring is produced into ammonia nitrogen removal agent by said ratio.
In the coking nitrogen-containing wastewater of the 550mg/l containing ammonia nitrogen, 1500mg/l ammonia nitrogen removal agent is added, 10min is reacted It is 12.2mg/l that ammonia-nitrogen content is remained in water outlet waste water afterwards, reaches ammonia nitrogen in national integrated wastewater discharge primary standard, waste water Clearance is 97.78%.

Claims (10)

1. a kind of rapidly and efficiently ammonia nitrogen removal agent, it is characterised in that：The ammonia nitrogen removal agent includes following weight/mass percentage compositions Component：Oxidant 5~35%, inorganic coagulant 5~50%, sorbing material 2~40%, calcium salt 1~15%, gas-producing disintegrant 1 ~20%.
2. rapidly and efficiently ammonia nitrogen removal agent according to claim 1, it is characterised in that：The oxidant be sodium hypochlorite, Calcium hypochlorite, chlorine dioxide, hydrogen peroxide, sym-closene, sodium dichloro cyanurate, bleaching powder, potassium hyperchlorate, ferric acid One or two or more kinds of any combination in potassium, sodium peroxydisulfate.
3. rapidly and efficiently ammonia nitrogen removal agent according to claim 1, it is characterised in that：The inorganic coagulant is sulfuric acid Aluminium, polyaluminium sulfate, iron chloride, poly-ferric chloride, magnesium hydroxide, magnesium chloride, magnesium sulfate, potassium dihydrogen phosphate, sodium dihydrogen phosphate, Two kinds of any of the above combination in dipotassium hydrogen phosphate, disodium hydrogen phosphate, polyacrylamide, sodium carboxymethylcellulose.
4. rapidly and efficiently ammonia nitrogen removal agent according to claim 1, it is characterised in that：The sorbing material be activated carbon, Bentonite, diatomite, chitosan, zeolite, activated alumina, Emathlite, flyash, one kind in ferromanganese filtrate or two kinds with Upper any combination.
5. rapidly and efficiently ammonia nitrogen removal agent according to claim 1, it is characterised in that：The calcium salt is calcium hydroxide, oxygen Change one or two or more kinds of any combination in calcium, calcium chloride, calcium chlorate, Calcium perchlorate, calcium dihydrogen phosphate.
6. rapidly and efficiently ammonia nitrogen removal agent according to claim 1, it is characterised in that：The gas-producing disintegrant includes acid source And alkali source, the acid source is one kind or two in citric acid, malic acid, boric acid, tartaric acid, fumaric acid, citric acid, inorganic ore deposit acid Plant any of the above combination；The alkali source is sodium acid carbonate, sodium carbonate and its mixture of the two；Acid source, the weight ratio of alkali source are 1 ~2：1.
7. the preparation method of rapidly and efficiently ammonia nitrogen removal agent described in a kind of claim 1, it is characterised in that：By proportioning by each component Mixing and stirring is produced.
8. the application of rapidly and efficiently ammonia nitrogen removal agent described in a kind of claim 1, it is characterised in that：Place for nitrogen-containing wastewater Reason.
9. the application of rapidly and efficiently ammonia nitrogen removal agent according to claim 8, it is characterised in that：Under the nitrogen-containing wastewater is One of state：Coking nitrogen-containing wastewater, food nitrogen-containing wastewater, chemical fertilizer nitrogen-containing wastewater, river course nitrogen-containing wastewater, life in the countryside contain Ammonia nitrogen waste water, pharmacy nitrogen-containing wastewater.
10. the application of rapidly and efficiently ammonia nitrogen removal agent according to claim 9, it is characterised in that：The nitrogen-containing wastewater Concentration is 15~1500mg/l.
CN201710165507.6A 2017-03-20 2017-03-20 A kind of rapidly and efficiently ammonia nitrogen removal agent and its preparation method and application Pending CN106957070A (en)

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CN107434290A (en) * 2017-08-31 2017-12-05 苏州他山石环保科技有限公司 A kind of ammonia nitrogen removal agent and its preparation method and application
CN107473322A (en) * 2017-09-18 2017-12-15 清远绿由环保科技有限公司 A kind of filtering agent and its manufacture method produced with printing and dyeing sludge for handling sewage
CN107473355A (en) * 2017-08-31 2017-12-15 苏州他山石环保科技有限公司 A kind of preparation method and application of spacetabs type ammonia nitrogen removal agent
CN107512746A (en) * 2017-09-14 2017-12-26 清远绿由环保科技有限公司 A kind of filtering agent and its manufacture method produced with municipal sludge for handling sewage
CN107522250A (en) * 2017-09-19 2017-12-29 清远绿由环保科技有限公司 A kind of filtering decolorising agent produced with oily sludge and its manufacture method
CN107601599A (en) * 2017-10-31 2018-01-19 四川行之智汇知识产权运营有限公司 Suitable for the formula of fish pond sewage disposal
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