CN106943429A - The preparation method of hypochlorite solution a kind of and its clinical medicine application - Google Patents
The preparation method of hypochlorite solution a kind of and its clinical medicine application Download PDFInfo
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- CN106943429A CN106943429A CN201610556448.0A CN201610556448A CN106943429A CN 106943429 A CN106943429 A CN 106943429A CN 201610556448 A CN201610556448 A CN 201610556448A CN 106943429 A CN106943429 A CN 106943429A
- Authority
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- China
- Prior art keywords
- solution
- wound
- cleaning agent
- gauze
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003814 drug Substances 0.000 title claims abstract description 6
- 206010052428 Wound Diseases 0.000 claims abstract description 31
- 208000027418 Wounds and injury Diseases 0.000 claims abstract description 31
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims abstract description 17
- 208000025865 Ulcer Diseases 0.000 claims abstract description 12
- 231100000397 ulcer Toxicity 0.000 claims abstract description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 239000007836 KH2PO4 Substances 0.000 claims abstract description 6
- 229910000397 disodium phosphate Inorganic materials 0.000 claims abstract description 6
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 210000004400 mucous membrane Anatomy 0.000 claims abstract description 5
- 239000011780 sodium chloride Substances 0.000 claims abstract description 5
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims abstract description 4
- -1 HOCl solubility Chemical compound 0.000 claims abstract 2
- 239000012459 cleaning agent Substances 0.000 claims description 15
- 206010011985 Decubitus ulcer Diseases 0.000 claims description 3
- 208000013935 Electric injury Diseases 0.000 claims description 3
- 206010053615 Thermal burn Diseases 0.000 claims description 3
- 206010046996 Varicose vein Diseases 0.000 claims description 3
- 239000003899 bactericide agent Substances 0.000 claims description 3
- 206010012601 diabetes mellitus Diseases 0.000 claims description 3
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 3
- 210000003141 lower extremity Anatomy 0.000 claims description 3
- 210000001519 tissue Anatomy 0.000 claims description 3
- 230000000472 traumatic effect Effects 0.000 claims description 3
- 208000027185 varicose disease Diseases 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims 1
- 230000006641 stabilisation Effects 0.000 abstract description 3
- 238000011105 stabilization Methods 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 241000894006 Bacteria Species 0.000 abstract description 2
- 241000233866 Fungi Species 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 210000000795 conjunctiva Anatomy 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 210000003491 skin Anatomy 0.000 abstract description 2
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 2
- 230000003612 virological effect Effects 0.000 abstract 1
- 230000035876 healing Effects 0.000 description 8
- 206010048038 Wound infection Diseases 0.000 description 6
- 244000000010 microbial pathogen Species 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910019093 NaOCl Inorganic materials 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 210000004493 neutrocyte Anatomy 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/20—Elemental chlorine; Inorganic compounds releasing chlorine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Materials Engineering (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Dermatology (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention discloses the preparation method of hypochlorite solution a kind of and its clinical medicine application.The preparation method of the solution is：Reaction solution, i.e. 20~40g/L of NaCl solution are added in an electrochemical appliance, pH1~2, the solution that reaction is produced is 100ppm~150ppm containing hypochlorous acid, i.e. HOCl solubility, and the pH of solution is 3.5~4.5, and oxidation potential value ORP is between 800mV~1200mV；Add Na2HPO4·2H2O0.10%~0.15%, KH2PO48.00~10.00%, solution ph is maintained between 4.9~5.2, and be filled into vial.It is a kind of stabilization, the HOCl solution close to neutrality, bacterium, fungi, spore, viral effect are killed with quick, these functions can apply to body surface and various surface wounds and ulcer cleaning, the sterilization of people, nontoxic non-stimulated to human body skin, mucous membrane, conjunctiva.
Description
Technical field
The present invention relates to chemical solution and its application, the preparation method of specifically a kind of hypochlorous acid (HOCl) solution and its doctor
Learn clinical practice.
Background technology
Hypochlorous acid is human endogenous's property material, when being inflamed reaction, is killed by neutrocyte secretion in invasion body
Pathogen.NaCl solution can be electrolysed with electrochemistry (Electrochemistry) method, produce NaOCl and HOCl mixing
Solution, the solution has stronger sterilising, but its acid (pH1~2) and unstability (term of validity 1~2 hour) are limited
Application, is only used for corrosion-resistant disinfecting utensils or environment disinfected.
The content of the invention
The present invention provides preparation method and its clinical medicine application of a kind of hypochlorite solution, to solve it acid and unstable
It is qualitative to cause the problem of application is limited.
The preparation method for the hypochlorite solution that the present invention is provided is as follows：
A, add reaction solution, i.e. 20~40g/L of NaCl solution in an electrochemical appliance, pH1~2, reaction is produced
Solution containing hypochlorous acid, i.e. HOCl solubility be 100ppm~150ppm, the pH of solution is 3.5~4.5, and oxidation potential value ORP exists
Between 800mV~1200mV；
B, addition Na2HPO4·2H2O 0.10%~0.15%, KH2PO48.00~10.00%, it is maintained at solution ph
Between 4.9~5.2, and it is filled into vial.
Existed by product basic parameter stabilization made from the above method：100~120ppm of HOCl solubility, pH value 4.9~
5.2nd, oxidation potential value ORP is in 900mV~1100mV, Na2HPO40.10~0.15%, KH2PO48.00~10.00%.
The clinical medicine application for the hypochlorite solution that the present invention is provided is as follows：
A, can be as skin and the cleaning agent of mucous membrane, cleaning agent that can be as hand, vaginal cleaning agent are rushed after without water
Wash；
B, can as traumatic wounds cleaning agent, irrigate and edge skin histology dirt, kill pathogenic microorganism,
Gauze can be infiltrated or similar dressing is covered in wound, wound infection is prevented and treated, promote healing；
C, can be used for burn and scald including electric injury wound, irrigate and surrounding skin tissue dirt, kill cause of disease
Microorganism, can infiltrate gauze or similar dressing is covered in wound, prevent and treat wound infection, promote healing；
D, can be used for diabetes, ulcer caused by varix of lower limb, rinse ulcer wound, kill pathogenic microorganism,
And wound is covered in infiltration gauze or similar dressing, control ulcer and promote ulcer healing；
E, can apply to decubitus chronicus wound, irrigate and its deep slough, kill wound and surrounding skin
Skin pathogenic microorganism, can also infiltrate gauze or similar dressing is covered in wound, prevent and treat wound infection, promote healing；
F, pet is can apply to, be used as the body surface and surface wound cleaning agent and bactericidal agent of a kind of pet.
This hypochlorite solution that the present invention is provided is a kind of stabilization, close to neutral HOCl solution, and the solution has fast
Speed kills bacterium, fungi, spore, the effect of virus, and these functions can apply to the body surface and various surface wounds of people with bursting
Ulcer cleaning, sterilization, it is nontoxic non-stimulated to human body skin, mucous membrane, conjunctiva, it is medicinal sealing under the condition of storage of room temperature lucifuge
2 years terms of validity can be kept in bottle.
Embodiment
The preparation method for the hypochlorite solution that the present invention is provided is as follows：
A, add reaction solution, i.e. 20~40g/L of NaCl solution in an electrochemical appliance, pH1~2, reaction is produced
Solution containing hypochlorous acid, i.e. HOCl solubility be 100ppm~150ppm, the pH of solution is 3.5~4.5, and oxidation potential value ORP exists
Between 800mV~1200mV；
B, addition Na2HPO4·2H2O 0.10%~0.15%, KH2PO48.00~10.00%, it is maintained at solution ph
Between 4.9~5.2, and it is filled into vial.
The chemical formula of the above method：
Under room temperature environment, it is packaged in the brown medicinal bottle of closing, its effective chlorine composition is maintained at original concentration after 2 years
80~95%.Packaging Bottle is opened and suctions out 1ml with pipette and fastens Packaging Bottle again, is repeated 3 times, after two weeks, the HOCl of solution
The change of content, pH value and ORP value is within 10%.
Pass through product design parameter made from the above method：HOCl solubility 100ppm, pH value 5.0, oxidation potential value
ORP980mV、Na2HPO40.12%th, KH2PO48.61%, the application of the product is as follows：
A, can be as skin and the cleaning agent of mucous membrane, cleaning agent that can be as hand, vaginal cleaning agent are rushed after without water
Wash；
B, can as traumatic wounds cleaning agent, irrigate and edge skin histology dirt, kill pathogenic microorganism,
Gauze can be infiltrated or similar dressing is covered in wound, wound infection is prevented and treated, promote healing；
C, can be used for burn and scald including electric injury wound, irrigate and surrounding skin tissue dirt, kill cause of disease
Microorganism, can infiltrate gauze or similar dressing is covered in wound, prevent and treat wound infection, promote healing；
D, can be used for diabetes, ulcer caused by varix of lower limb, rinse ulcer wound, kill pathogenic microorganism,
And wound is covered in infiltration gauze or similar dressing, control ulcer and promote ulcer healing；
E, can apply to decubitus chronicus wound, irrigate and its deep slough, kill wound and surrounding skin
Skin pathogenic microorganism, can also infiltrate gauze or similar dressing is covered in wound, prevent and treat wound infection, promote healing；
F, pet is can apply to, be used as the body surface and surface wound cleaning agent and bactericidal agent of a kind of pet.
Claims (2)
1. a kind of preparation method of hypochlorite solution, it is characterised in that pass through following steps：
A, add reaction solution, i.e. 20~40g/L of NaCl solution in an electrochemical appliance, pH1~2, it is molten that reaction is produced
Liquid is 100ppm~150ppm containing hypochlorous acid, i.e. HOCl solubility, and the pH of solution is 3.5~4.5, and oxidation potential value ORP is in 800mV
Between~1200mV；
B, addition Na2HPO4·2H2O 0.10%~0.15%, KH2PO48.00~10.00%, solution ph is maintained at 4.9
Between~5.2, and it is filled into vial.
2. a kind of clinical medicine application of hypochlorite solution, it is characterised in that following application：
A, the cleaning agent as skin and mucous membrane, are used as the cleaning agent of hand, vaginal cleaning agent；
B, as traumatic wounds cleaning agent, irrigate and edge skin histology dirt, gauze or similar dressing can be infiltrated
It is covered in wound；
C, for burn and scald include electric injury wound, irrigate and surrounding skin tissue dirt, gauze or class can be infiltrated
Wound is covered in like dressing；
D, for ulcer caused by diabetes, varix of lower limb, rinse ulcer wound, and with infiltrating gauze or similar dressing covers
It is placed on wound；
E, applied to decubitus chronicus wound, irrigate and its deep slough, gauze or similar dressing can also be infiltrated
It is covered in wound；
F, applied to pet, be used as the body surface and surface wound cleaning agent and bactericidal agent of a kind of pet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610556448.0A CN106943429A (en) | 2016-06-28 | 2016-06-28 | The preparation method of hypochlorite solution a kind of and its clinical medicine application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610556448.0A CN106943429A (en) | 2016-06-28 | 2016-06-28 | The preparation method of hypochlorite solution a kind of and its clinical medicine application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106943429A true CN106943429A (en) | 2017-07-14 |
Family
ID=59466184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610556448.0A Pending CN106943429A (en) | 2016-06-28 | 2016-06-28 | The preparation method of hypochlorite solution a kind of and its clinical medicine application |
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| CN (1) | CN106943429A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108849971A (en) * | 2018-07-15 | 2018-11-23 | 西安青叶生物科技有限公司 | A kind of preparation and its application method using acidulous hypochlorous acid's type thimerosal |
| CN109200326A (en) * | 2018-07-19 | 2019-01-15 | 丁力行 | Dressing and adhesive bandage for wound healing |
| CN112374582A (en) * | 2020-10-09 | 2021-02-19 | 山东青洁能环保有限公司 | Neutral positive potential water preparation method, neutral positive potential water and preparation system |
| CN112587422A (en) * | 2020-11-11 | 2021-04-02 | 山东青洁能环保有限公司 | Preparation method of electric potential skin cleaning water and electric potential skin cleaning water |
| CN113244264A (en) * | 2021-06-07 | 2021-08-13 | 青岛威巴克生物技术有限公司 | Novel protective agent for promoting healing of ulcer surface |
| CN114080230A (en) * | 2019-07-03 | 2022-02-22 | 应用药品研究公司 | Therapeutic uses of oxidized hypotonic acid solutions |
| CN115702949A (en) * | 2021-08-05 | 2023-02-17 | 卫盾生物科技(广州)有限公司 | A kind of wound sterile liquid dressing for blocking and inactivating SARS-COV-2 virus |
| CN115707473A (en) * | 2021-08-18 | 2023-02-21 | 卫盾生物科技(广州)有限公司 | Infant skin mucosa antibacterial liquid |
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|---|---|---|---|---|
| CN1680627A (en) * | 2005-02-02 | 2005-10-12 | 华东理工大学 | The preparation method of hypochlorous acid disinfection water |
| CN102480972A (en) * | 2009-06-15 | 2012-05-30 | 奥古露丝创新科学公司 | Solutions containing hypochlorous acid and methods of use thereof |
| CN103774172A (en) * | 2014-02-20 | 2014-05-07 | 厦门和利鑫源氢能科技有限公司 | Production method and device of high-stability hypochlorous acid |
-
2016
- 2016-06-28 CN CN201610556448.0A patent/CN106943429A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1680627A (en) * | 2005-02-02 | 2005-10-12 | 华东理工大学 | The preparation method of hypochlorous acid disinfection water |
| CN102480972A (en) * | 2009-06-15 | 2012-05-30 | 奥古露丝创新科学公司 | Solutions containing hypochlorous acid and methods of use thereof |
| CN103774172A (en) * | 2014-02-20 | 2014-05-07 | 厦门和利鑫源氢能科技有限公司 | Production method and device of high-stability hypochlorous acid |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108849971A (en) * | 2018-07-15 | 2018-11-23 | 西安青叶生物科技有限公司 | A kind of preparation and its application method using acidulous hypochlorous acid's type thimerosal |
| CN109200326A (en) * | 2018-07-19 | 2019-01-15 | 丁力行 | Dressing and adhesive bandage for wound healing |
| CN114080230A (en) * | 2019-07-03 | 2022-02-22 | 应用药品研究公司 | Therapeutic uses of oxidized hypotonic acid solutions |
| CN112374582A (en) * | 2020-10-09 | 2021-02-19 | 山东青洁能环保有限公司 | Neutral positive potential water preparation method, neutral positive potential water and preparation system |
| CN112587422A (en) * | 2020-11-11 | 2021-04-02 | 山东青洁能环保有限公司 | Preparation method of electric potential skin cleaning water and electric potential skin cleaning water |
| CN113244264A (en) * | 2021-06-07 | 2021-08-13 | 青岛威巴克生物技术有限公司 | Novel protective agent for promoting healing of ulcer surface |
| CN115702949A (en) * | 2021-08-05 | 2023-02-17 | 卫盾生物科技(广州)有限公司 | A kind of wound sterile liquid dressing for blocking and inactivating SARS-COV-2 virus |
| CN115707473A (en) * | 2021-08-18 | 2023-02-21 | 卫盾生物科技(广州)有限公司 | Infant skin mucosa antibacterial liquid |
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Application publication date: 20170714 |