CN106935800A - For the protective layer of serondary lithium battery negative pole - Google Patents
For the protective layer of serondary lithium battery negative pole Download PDFInfo
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- CN106935800A CN106935800A CN201511008718.6A CN201511008718A CN106935800A CN 106935800 A CN106935800 A CN 106935800A CN 201511008718 A CN201511008718 A CN 201511008718A CN 106935800 A CN106935800 A CN 106935800A
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- Prior art keywords
- lithium
- protective layer
- cathode
- solvent
- negative pole
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- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 75
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000011241 protective layer Substances 0.000 title claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 6
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical class [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 150000003457 sulfones Chemical class 0.000 claims description 6
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 claims description 4
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 3
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 2
- YBJCDTIWNDBNTM-UHFFFAOYSA-N 1-methylsulfonylethane Chemical compound CCS(C)(=O)=O YBJCDTIWNDBNTM-UHFFFAOYSA-N 0.000 claims description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical group COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 2
- AOJJSUZBOXZQNB-TZSSRYMLSA-N Doxorubicin Chemical compound O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-TZSSRYMLSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical group COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- 229920001021 polysulfide Polymers 0.000 claims description 2
- 239000005077 polysulfide Substances 0.000 claims description 2
- 150000008117 polysulfides Polymers 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- 238000004073 vulcanization Methods 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 210000001787 dendrite Anatomy 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 239000010410 layer Substances 0.000 abstract description 4
- 229910000733 Li alloy Inorganic materials 0.000 abstract 2
- 239000001989 lithium alloy Substances 0.000 abstract 2
- 239000012530 fluid Substances 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 3
- 229910000521 B alloy Inorganic materials 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- PPTSBERGOGHCHC-UHFFFAOYSA-N boron lithium Chemical compound [Li].[B] PPTSBERGOGHCHC-UHFFFAOYSA-N 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The present invention relates to a kind of protective layer for serondary lithium battery negative pole, layer protective layer can be conveniently effectively formed on cathode of lithium, so as to effectively extend the cycle life of cathode of lithium, realize the high-energy-density of lithium secondary battery.Lithium anode in lithium secondary battery includes the negative pole of all types lithium metal, including metal lithium sheet, lithium paper tinsel, lithium powder, lithium grain, including lithium alloys negative pole, including lithium alloy piece, paper tinsel, powder, grain.The method that protective layer is formed on cathode of lithium is soaked or is electrolysed in a kind of special solution by by lithium metal；Wherein involved special solution is a kind of solution containing many lithium sulfides.The Li dendrite of cathode of lithium, the safety problem of cathode of lithium and cycle life problem effectively are solved the problems, such as, the high-energy-density of lithium secondary battery is achieved.
Description
Technical field
The present invention relates to a kind of protective layer for serondary lithium battery negative pole.Belong to electrochemical field.
Background technology
With the development of science and technology people adapt to the miniaturization of various batteries, lightweight in the urgent need to a kind of high energy density cells
Trend, at this moment, lithium ion battery is difficult to meet needs.Due to the limitation of the theoretical specific energy of graphite, lithium ion battery is difficult
As high energy density cells.Battery in theory with lithium metal as negative pole can turn into the battery of higher energy density.Metal
The specific capacity of lithium is up to 3860mAh/g, and the exchange current density of lithium electrode is big, polarizes small, is ideal electrode material
Material.But because metal lithium electrode will produce Li dendrite in charge and discharge process.When Li dendrite comes off from pole plate, battery can be caused to hold
The loss of amount, if Li dendrite is gradually given birth to, may pierce through barrier film and cause internal short-circuit of battery, trigger battery catches fire or blast.
This problem ultimately results in lithium secondary battery and commercially not yet succeeds.
For protection cathode of lithium, it is also proposed that kinds of schemes perhaps in document, including being applied with protective layers such as polymer, ceramics or glass
Overlay on cathode of lithium.United States Patent (USP) USP5460905, USP5462566 describes a kind of method, in the battery cathode of lithium and electricity
Mix a conjugated polymer film between solution matter, and USP5648187 and USP 5961672 describe cathode of lithium in the battery and
One layer of polymer film of conduction and preparation method thereof is pressed from both sides between electrolyte；United States Patent (USP) USP5314765 is also described on cathode of lithium
One layer of ceramic coating of covering.Also certain methods, United States Patent (USP) USP5387479, USP5487959, CN1297588A,
It is described in CN1726608A, CN1894821A, CN1938895A, CN101313426A etc..
Although proposing the various methods that protective layer is formed on cathode of lithium, the Li dendrite of cathode of lithium is not solved still at present
Problem.Still need to propose safety problem and cycle life of the more efficiently solution to solve the problems, such as cathode of lithium, so that
The high-energy-density of lithium secondary battery is achieved.
The content of the invention
It is an object of the invention to provide a kind of protective layer for serondary lithium battery negative pole, one is conveniently effectively formed on cathode of lithium
Layer protective layer.
The technical solution adopted by the present invention, the preparation method step for the protective layer of serondary lithium battery negative pole is as follows：
Lithium anode is placed in protection solution and is stood, vibrated, shaken, stirred or electrolysis treatment, treatment temperature is
- 20~120 DEG C, pressure is 0.1~10dtm, and process time is 0.1~5h.Wherein, when carrying out electrolysis treatment, voltage is
0~5V, 0~10A of electric current；
The preparation of cathode of lithium protective layer is before battery assembling or after battery assembling；
Lithium anode is metal lithium sheet, lithium paper tinsel, lithium powder, lithium grain or lithium metal alloy, and lithium metal alloy is lithium metal alloy
Piece, paper tinsel, powder or grain.
Protection solution includes inorganic agent and solution two parts, and inorganic agent is curing lithium, four lithium sulfides, six lithium sulfides or eight vulcanizations
Lithium；Solvent is ether solvent, esters solvent, varsol or sulfone class solvent, and ether solvent is glycol dimethyl ether, diethyl two
Diethylene glycol dimethyl ether, tetraethyleneglycol dimethyl ether or DOX；Esters solvent is dimethyl carbonate, diethyl carbonate, carbonic acid
Methyl ethyl ester or vinylene carbonate support ester；Varsol is normal butane, toluene or dimethylbenzene；Sulfone class solvent is dimethyl sulfoxide (DMSO), ring
Fourth sulfone or Methylethyl sulfone；
Composition for the cathode of lithium protective layer of serondary lithium battery is polysulfide, oxide, cyanide, sulfate, sulfonic acid
One or more of salt, nitrate.
Beneficial effects of the present invention：Effectively solve the problems, such as that the Li dendrite of cathode of lithium, the safety problem of cathode of lithium and cycle life are asked
Topic, is achieved the high-energy-density of lithium secondary battery.
Specific embodiment
Embodiment 1
Metallic lithium foil is statically placed in the Li of 0.2mol/L2S61h in/DOX processing solution, with 1,3- dioxies penta after taking-up
Ring neat solvent washes off the treatment fluid of metallic lithium foil excess surface, obtains the metallic lithium foil with protective layer.
Metallic lithium foil with protective layer is applied in lithium-sulfur cell, under 100mA/g current densities, positive electrode is put first
Capacitance 1550mAh/g, specific discharge capacity is 1000mAh/g after 50 circulations.
Embodiment 2
Metal lithium sheet is placed in the Li of 0.50mol/L2S4In/methyl ethyl carbonate treatment fluid, ultrasonic vibration 2h uses second two after taking-up
Diethylene glycol dimethyl ether neat solvent washes off the treatment fluid of metal lithium sheet excess surface, obtains the metal lithium sheet with protective layer.
Embodiment 3
Lithium boron alloy piece is sandwiched on copper electrode, the Li of 0.50mol/L is subsequently placed in2S2In/sulfolane treatment fluid, separately in treatment
Platinum electrode is inserted in liquid as to electrode, setting electric current 2mA, voltage 3V carry out electrolysis treatment 2h, obtain with protective layer
Lithium boron alloy piece.
Claims (1)
1. a kind of protective layer for serondary lithium battery negative pole, it is characterised in that the preparation method step of the protective layer is as follows：
Lithium anode is placed in protection solution and is stood, vibrated, shaken, stirred or electrolysis treatment, treatment temperature is
- 20~120 DEG C, pressure is 0.1~10dtm, and the time is 0.1~5h；Wherein, when carrying out electrolysis treatment, voltage is 0~5V, electric current
0~10A；
The preparation of cathode of lithium protective layer is before battery assembling or after battery assembling；
Lithium anode is metal lithium sheet, lithium paper tinsel, lithium powder, lithium grain or lithium metal alloy, and lithium metal alloy is lithium metal alloy
Piece, paper tinsel, powder or grain；
Protection solution includes inorganic agent and solution two parts, and inorganic agent is curing lithium, four lithium sulfides, six lithium sulfides or eight vulcanizations
Lithium；Solvent includes ether solvent, esters solvent, varsol or sulfone class solvent, and ether solvent is glycol dimethyl ether, diethyl
Glycol dimethyl ether, tetraethyleneglycol dimethyl ether or DOX；Esters solvent is dimethyl carbonate, diethyl carbonate, carbonic acid
Methyl ethyl ester or vinylene carbonate support ester；Varsol is normal butane, toluene or dimethylbenzene；Sulfone class solvent is dimethyl sulfoxide (DMSO), ring
Fourth sulfone or Methylethyl sulfone；
For serondary lithium battery cathode of lithium protective layer composition for polysulfide, oxide, cyanide, sulfate, sulfonate,
One or more of nitrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511008718.6A CN106935800A (en) | 2015-12-31 | 2015-12-31 | For the protective layer of serondary lithium battery negative pole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511008718.6A CN106935800A (en) | 2015-12-31 | 2015-12-31 | For the protective layer of serondary lithium battery negative pole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106935800A true CN106935800A (en) | 2017-07-07 |
Family
ID=59457424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511008718.6A Pending CN106935800A (en) | 2015-12-31 | 2015-12-31 | For the protective layer of serondary lithium battery negative pole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106935800A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109273664A (en) * | 2018-09-13 | 2019-01-25 | 中国电子科技集团公司第十八研究所 | Electrochemical preparation method of ultrathin lithium foil |
| CN109461886A (en) * | 2018-11-19 | 2019-03-12 | 江西迪比科股份有限公司 | A kind of composite metal lithium titanate cathode material and preparation method |
| CN109786692A (en) * | 2018-12-25 | 2019-05-21 | 中国电子科技集团公司第十八研究所 | A kind of surface nitridation modification method of metal lithium electrode and obtained metal lithium negative electrode and use |
| CN111952571A (en) * | 2020-08-24 | 2020-11-17 | 上海空间电源研究所 | Lithium/lithium alloy composite negative electrode for high-power primary battery, preparation method and battery |
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| KR20020018393A (en) * | 2000-09-01 | 2002-03-08 | 김순택 | A Lithium Sulfur Secondary batteries using multi-layer separator |
| US20020045102A1 (en) * | 2000-08-02 | 2002-04-18 | Youngiu Jung | Lithium-sulfur batteries |
| CN1612377A (en) * | 2003-10-31 | 2005-05-04 | 三星Sdi株式会社 | Negative electrode for lithium metal battery and lithium metal battery comprising the same |
| CN101501897A (en) * | 2006-08-10 | 2009-08-05 | 奥克斯能源有限公司 | A cell or battery with a metal lithium electrode and electrolytes therefor |
| CN103855349A (en) * | 2012-12-04 | 2014-06-11 | 中国科学院大连化学物理研究所 | Diaphragm of lithium-sulfur battery |
| CN105140449A (en) * | 2015-08-14 | 2015-12-09 | 中国人民解放军63971部队 | Method for protecting anode of lithium sulfur battery |
-
2015
- 2015-12-31 CN CN201511008718.6A patent/CN106935800A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20020045102A1 (en) * | 2000-08-02 | 2002-04-18 | Youngiu Jung | Lithium-sulfur batteries |
| KR20020018393A (en) * | 2000-09-01 | 2002-03-08 | 김순택 | A Lithium Sulfur Secondary batteries using multi-layer separator |
| CN1612377A (en) * | 2003-10-31 | 2005-05-04 | 三星Sdi株式会社 | Negative electrode for lithium metal battery and lithium metal battery comprising the same |
| CN101501897A (en) * | 2006-08-10 | 2009-08-05 | 奥克斯能源有限公司 | A cell or battery with a metal lithium electrode and electrolytes therefor |
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| CN105140449A (en) * | 2015-08-14 | 2015-12-09 | 中国人民解放军63971部队 | Method for protecting anode of lithium sulfur battery |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109273664A (en) * | 2018-09-13 | 2019-01-25 | 中国电子科技集团公司第十八研究所 | Electrochemical preparation method of ultrathin lithium foil |
| CN109461886A (en) * | 2018-11-19 | 2019-03-12 | 江西迪比科股份有限公司 | A kind of composite metal lithium titanate cathode material and preparation method |
| CN109786692A (en) * | 2018-12-25 | 2019-05-21 | 中国电子科技集团公司第十八研究所 | A kind of surface nitridation modification method of metal lithium electrode and obtained metal lithium negative electrode and use |
| CN111952571A (en) * | 2020-08-24 | 2020-11-17 | 上海空间电源研究所 | Lithium/lithium alloy composite negative electrode for high-power primary battery, preparation method and battery |
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