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CN106906004A - Pulverized coal gasification control method and pulverized coal gasification device - Google Patents

Pulverized coal gasification control method and pulverized coal gasification device Download PDF

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Publication number
CN106906004A
CN106906004A CN201710177501.0A CN201710177501A CN106906004A CN 106906004 A CN106906004 A CN 106906004A CN 201710177501 A CN201710177501 A CN 201710177501A CN 106906004 A CN106906004 A CN 106906004A
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China
Prior art keywords
oxygen
pipeline
burner
point
coal
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Granted
Application number
CN201710177501.0A
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Chinese (zh)
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CN106906004B (en
Inventor
孙志田
李光
任冰涛
高发坤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Mingquan New Material Technology Co ltd
Original Assignee
Shandong Jinmei Mingshui Chemical Group Co ltd
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Priority to CN201710177501.0A priority Critical patent/CN106906004B/en
Publication of CN106906004A publication Critical patent/CN106906004A/en
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Publication of CN106906004B publication Critical patent/CN106906004B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/723Controlling or regulating the gasification process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)

Abstract

The invention discloses a pulverized coal gasification control method and a pulverized coal gasification device, and belongs to the field of pulverized coal gasification. The method and the device are characterized in that each process burner is respectively provided with a gasifying agent branch pipeline and a pulverized coal branch pipeline, the gasifying agent branch pipeline consists of an oxygen branch pipeline and a steam branch pipeline, and the ratio of the gasifying agent flow of a single process burner to the pulverized coal flow is in a proper range by adjusting the gasifying agent flow of the gasifying agent branch pipeline and the pulverized coal flow of the pulverized coal branch pipeline. Compared with the prior art, the pulverized coal gasification control method and the pulverized coal gasification device can enable the burners to achieve consistent oxygen load, better protect the start-up burner and the process burner and prevent the gasification device from stopping due to the fluctuation of a pulverized coal quantity pipeline.

Description

Coal gasification control method and gasifying powder coal device
Technical field
The present invention relates to coal gasification field, specifically a kind of coal gasification control method and gasifying powder coal device.
Background technology
Coal gasification process is coal or coal tar and gasifying agent(Oxygen and vapor etc.)The reaction generation oxide of carbon, hydrogen, The process of the clean gas fuel such as methane, is the core technology and leading technology of generally acknowledged Modern Coal-based Chemical technique, and gasification furnace It is then the core in coal gasification process technology.Entrained flow bed gasification technology is then the extensive coal gasifying process skill for using universal at present Art, and the gasification furnace early stage in its core uses spray technique under single burners on top, but because its coal gasification scale and gasification efficiency are received To limitation, many burner air-flow bed techniques are occurred in that, i.e., many burners are vertically disposed to gasification furnace top, and material is vertically down into gas Change in stove.Because burner quantity increases, furnace flame area increase, material increases with the collision area of gasifying agent, so as to improve gas Change efficiency and ability.
But the gasification process there is also many deficiencies:The oxygen flow of multiple process burners is carried out by an oxygen regulating valve Regulation, in the design just for the oxygen flow balance of many burners hides some dangers for;In addition, in the fine coal delivery system based on two-phase transportation In system, fine coal pipeline easily fluctuates, but in the case, then the gasification furnace that must interlock carries out parking process;Startup burner Still run after process burner input, period can consume fuel gas and oxygen, increase consumption.
The content of the invention
Technical assignment of the invention is directed to above-mentioned the deficiencies in the prior art, there is provided a kind of coal gasification control method, should Method can make burner accomplish that oxygen load is consistent, and preferably protection startup burner and process burner, prevents because of fine coal coal buret line Fluctuate and cause gasification installation to stop, even the damage of process burner.
Further technical assignment of the invention is to provide a kind of gasifying powder coal device that can realize the above method.
Technical assignment of the invention is realized in the following manner:Coal gasification control method, for the gas of coal gasification Makeup is put and is provided with startup burner and at least two process burners, startup burner connection fuelgas pipeline and oxygen pipeline, work Skill burner connects fine coal pipeline and gasifying agent pipeline, and the gasifying agent pipeline is made up of oxygen pipeline and steam pipe line, its feature It is:
Each process burner is respectively provided with gasifying agent tap line and fine coal tap line(That is, the gasifying agent of each process burner Pipeline is corresponded with fine coal pipeline and set), the gasifying agent tap line is by oxygen tap line and steam tap line group Into the fine coal flow of gasify agent flux and fine coal pipeline by adjusting gasifying agent pipeline makes the gasifying agent of single process burner The ratio of flow and fine coal flow is in proper range.
Preferably, oxygen is 0.6-1.1, most preferably 0.8-0.9 with fine coal mass flow ratio;The matter of vapor and oxygen Amount is than being 0.03-0.07, most preferably 0.05.
The water vapour is used to adjust effective Gas content in process burner head counter-fire face temperature and a little raising synthesis gas. Water vapour need not enter process burner and jump car interlocking with the ratio of oxygen.
Further, fuel gas emptying point can be set on the fuelgas pipeline of startup burner and high-pressure carbon dioxide blows Sweep a little, fuel gas is vented the demarcation of fuel gas flow before point feeds intake for startup burner;High-pressure carbon dioxide purging point is for opening Work burner exits the controlled atmosphere of fuelgas pipeline during process burner runs.
Further, can also be set on the oxygen pipeline of startup burner the first oxygen emptying point, the second oxygen emptying point, Cleaning high pressure nitrogen purging point, the first oxygen emptying point fed intake for startup burner before oxygen flow demarcation;Second oxygen is put Null point ensures that oxygen is thoroughly isolated with gasification installation;Cleaning high pressure nitrogen purging point is for startup burner in the process burner runtime Between exit the controlled atmosphere of oxygen pipeline.
For the ease of demarcating valve position, on the oxygen pipeline of startup burner, oxygen regulating valve is preferably provided at oxygen emptying Point front end.
Before gasification installation prepares operation, startup burner fuel gas and oxygen can be vented point and oxygen and put by fuel gas Null point is vented, while by the governor valve control emptying flow being vented before point, playing a part of to demarcate valve position.
After startup burner puts into operation, period can be according to startup burner ruuning situation and gasification installation boosting situation pair Process burner is put into.
Preferably, when startup burner is run to 3.0-3.6MPa, process burner proceeds by input, with utmost The synthesis gas that avoids be vented, save expense;
Or, when startup burner is run to 1.0MPa, process burner comes into operation, and to reduce startup burner run time, protection goes into operation Burner.
After process burner puts into operation, for the fluctuation of operating conditions for happening suddenly, the fine coal flow of manually adjustable process burner And oxygen flow, making the ratio of the gasification agent flux of single process burner and fine coal flow in the reasonable scope, control technique is burnt Mouth head temperature protects process burner in normal range (NR);For the severe service fluctuation for happening suddenly, can be in a short time(10 points Within clock)Parking process are carried out to a certain process burner.Startup burner can choose whether to continue to transport according to gasifier operation situation OK, such as ruuning situation is stable(Such as 2 hours of even running or more), startup burner can be stopped, while to fuel gas Pipeline be passed through high-pressure carbon dioxide, to oxygen pipeline be passed through cleaning high pressure nitrogen carry out purging protection.
Gasifying powder coal device of the invention, including startup burner and at least two process burners, startup burner connection fuel Gas pipeline and oxygen pipeline, process burner connection fine coal pipeline and gasifying agent pipeline, the gasifying agent pipeline by oxygen pipeline and Steam pipe line is constituted, and is characterized in that each process burner is respectively provided with gasifying agent tap line and fine coal tap line, the gas Agent tap line is made up of oxygen tap line and steam tap line.
Preferably, being set on the fuelgas pipeline of startup burner, fuel gas is vented point and high-pressure carbon dioxide blows Sweep a little, fuel gas emptying point is arranged between fuel flow control valve and the stop valve of fuel gas first, high-pressure carbon dioxide purging Point is arranged on the first stop valve of fuel gas downstream, and high-pressure carbon dioxide is directly entered gasification furnace.
The settable two oxygen emptying points of the oxygen pipeline of startup burner, cleaning high pressure nitrogen purging point, first oxygen Emptying point is arranged between startup burner oxygen regulating valve and the stop valve of oxygen second, oxygen flow before being fed intake for startup burner Demarcate, can more accurately to control the ratio of oxygen and fuel gas when startup burner feeds intake, protect burner;Second oxygen Gas emptying point be arranged between the stop valve of oxygen first and the stop valve of oxygen second, for after startup burner stops with first Oxygen emptying point opens atmospheric valve simultaneously, it is ensured that oxygen is thoroughly isolated with gasification furnace;High pressure nitrogen purging point is arranged on into stokehold Between last one stop valve and oxygen air inlet.
On the oxygen pipeline of startup burner, oxygen regulating valve is preferably provided at oxygen emptying point front end, in order to demarcate Valve position.
Compared with prior art, coal gasification control method of the invention and gasifying powder coal device have and following prominent have Beneficial effect:
(One)The gasifying agent pipeline of each process burner is corresponded with fine coal pipeline and set, i.e. each process burner correspondence is a set of Gasifying agent tap line and fine coal tap line, process burner can rapidly carry out gasifying agent stream when operating condition fluctuates Amount and the proportion adjustment of fine coal flow, make the ratio of gasification agent flux and fine coal flow in fine coal combustion nozzle system in safe range It is interior, protect process burner;In the case where there are serious problems in the fine coal induction system for being easier to fluctuate, can be to corresponding Process burner carry out short time parking process, after the completion of issue handling, the process burner is put into rapidly, can avoid because rise The gasification furnace stops.
(Two)After being put into operation within the process burner short time, startup burner can be artificial according to the ruuning situation of process burner Parking process are judged whether to, if now process burner running status is not very good or process burner occurs to jump car, is opened In the case that work burner does not stop also, gasification furnace is simply to be purged, and without pressure release in stove, treats that furnace gas analysis takes Coming into operation for process burner can be again carried out after sample is qualified, it is time-consuming, car is jumped to running time again about 30 from process burner Minute, driving expense can be once saved for 800,000 yuan.
(Three)After process burner puts into operation, manually can be determined whether to stop startup burner according to operating condition Car, the cleaning high pressure nitrogen after gasifying agent pipeline is by filtering after its parking is protected, fuelgas pipeline is by high-pressure carbon dioxide Protected, startup burner gasifying agent pipeline cuts off with main system, and carries out emptying isolation, the stabilization of operation can either be ensured Property, extend form burner service life, the waste of the energy can be avoided again, hourly rate is about 1200 yuan.
Brief description of the drawings
Accompanying drawing 1 is embodiment gasifying powder coal device structural representation;
Accompanying drawing 2 is each burner position view of gasification installation shown in Fig. 1;
Accompanying drawing 3 is process burner fine coal pipeline and gasifying agent pipeline process flow diagram in embodiment;
Accompanying drawing 4 is startup burner fuelgas pipeline and oxygen pipeline process flow diagram in embodiment.
Specific embodiment
Coal gasification control method of the invention and gasifying powder coal device are made with specific embodiment with reference to Figure of description It is explained in detail below.
Embodiment:
【Gasification installation】
As shown in accompanying drawing 1,2, gasifying powder coal device of the invention includes body of heater 1, startup burner 2 and three process burners 3.Go into operation Burner 2, process burner 3 are vertically disposed to the top of body of heater 1.Startup burner 2 is assemblied in the center on the top of body of heater 1.Three Process burner 3 is evenly distributed on around startup burner 2.
As shown in Figure 3, each process burner 3 is respectively by respective fine coal tap line 4, gasifying agent tap line (Including oxygen tap line 5 and steam tap line 6)It is connected with fine coal house steward 7, oxygen house steward 8 and main steam range 9.
In fine coal tap line 4, oxygen tap line 5 and steam tap line 6 method for arranging of each control valve with it is existing Control the method for arranging of valve identical in technology on corresponding main pipe line.
As shown in Figure 4, startup burner 2 is connected with fuelgas pipeline 10 and oxygen pipeline 11.
Pressure-regulating valve 12, flow control valve 13 and the first stop valve of fuel gas 14 are serially connected with the burning line 10. Fuel gas emptying point 18 is provided between flow control valve 13 and the first stop valve of fuel gas 14.The first stop valve of fuel gas 14 and combustion High-pressure carbon dioxide purging point 19 is provided between material air inlet.
Flow control valve 15, the second stop valve of oxygen 16, the first stop valve of oxygen 17 are serially connected with the oxygen pipeline 11. The front end of the second stop valve of oxygen 16, rear end are respectively equipped with the first oxygen emptying point 20, the second oxygen emptying point 21.Oxygen first The high pressure nitrogen purging point set between stop valve 17 and oxygen air inlet.
【Control method】
Before gasification installation prepares operation, startup burner fuel gas and oxygen are vented point by the fuel gas in its respective lines It is vented with oxygen emptying point, while by the flow control valve 13, the control emptying stream of flow control valve 15 that are vented before point Amount, plays a part of to demarcate valve position.
After startup burner puts into operation, period can boost situation to work according to startup burner ruuning situation and gasification furnace Skill burner is put into, and when startup burner is run to 3.0-3.6MPa, process burner proceeds by input.
The initial stage is put into process burner, the input failure of single process burner short time will not cause the parking of gasification furnace.
After process burner puts into operation, for the fluctuation of operating conditions for happening suddenly, the fine coal flow of manually adjustable process burner And oxygen flow, make single process burner oxygen be 0.8-0.9 with fine coal mass flow ratio;Vapor is with the mass ratio of oxygen 0.04-0.06, control process burner head temperature protects process burner in normal range (NR);For the severe service ripple for happening suddenly It is dynamic, parking process can be carried out to a process burner in a short time, put into operation after being disposed.
After process burner puts into operation, startup burner can choose whether to continue to run with according to gasifier operation situation, such as Ruuning situation stabilization, can stop to startup burner, and the first oxygen emptying point, the second oxygen emptying point open emptying simultaneously Valve, it is ensured that oxygen is thoroughly isolated with gasification furnace, while being passed through high-pressure carbon dioxide to fuelgas pipeline, being passed through clearly to oxygen pipeline Clean high pressure nitrogen carries out purging protection, with save the operation of fuel gas with oxygen input when startup burner normally runs into This.

Claims (9)

1. coal gasification control method, burns for being provided with startup burner and at least two techniques on the gasification installation of coal gasification Mouth, startup burner connection fuelgas pipeline and oxygen pipeline, process burner connection fine coal pipeline and gasifying agent pipeline, the gasification Agent pipeline is made up of oxygen pipeline and steam pipe line, it is characterised in that:
Each process burner is respectively provided with gasifying agent tap line and fine coal tap line, and the gasifying agent tap line is by oxygen Tap line and steam tap line are constituted, by the gasification agent flux and fine coal tap line that adjust gasifying agent tap line Fine coal flow, makes the agent flux that gasifies of single process burner with the ratio of fine coal flow in proper range.
2. coal gasification control method according to claim 1, it is characterised in that:Oxygen in single process burner gasifying agent Gas is 0.6-1.1 with fine coal mass flow ratio;Vapor and the mass ratio of oxygen in gasifying agent are 0.03-0.07.
3. coal gasification control method according to claim 1 and 2, it is characterised in that:The fuelgas pipeline of startup burner On be provided with fuel gas emptying point and high-pressure carbon dioxide purging point,
Fuel gas is vented the demarcation of fuel gas flow before point feeds intake for startup burner;
High-pressure carbon dioxide purging point is protected for the indifferent gas that startup burner exits fuelgas pipeline during process burner runs Shield.
4. coal gasification control method according to claim 1 and 2, it is characterised in that:The oxygen pipeline of startup burner sets The first oxygen emptying point, the second oxygen emptying point, cleaning high pressure nitrogen purging point are equipped with,
First oxygen emptying point fed intake for startup burner before oxygen flow demarcation;
Second oxygen emptying point ensures that oxygen is thoroughly isolated with gasification installation;
Cleaning high pressure nitrogen purging point exits the controlled atmosphere of oxygen pipeline for startup burner during process burner runs.
5. coal gasification control method according to claim 4, it is characterised in that:On the oxygen pipeline of startup burner, oxygen Gas regulating valve is arranged on oxygen emptying point front end.
6. gasifying powder coal device, including startup burner and at least two process burners, startup burner connection fuelgas pipeline and oxygen Gas pipeline, process burner connection fine coal pipeline and gasifying agent pipeline, the gasifying agent pipeline is by oxygen pipeline and steam pipe line group Into, it is characterised in that:Each process burner is respectively provided with gasifying agent tap line and fine coal tap line.
7. gasifying powder coal device according to claim 6, it is characterised in that:It is provided with the fuelgas pipeline of startup burner Fuel gas emptying point and high-pressure carbon dioxide purging point, fuel gas emptying point are arranged on fuel flow control valve and fuel gas first Between stop valve, high-pressure carbon dioxide purging point is arranged on the first stop valve of fuel gas downstream, and high-pressure carbon dioxide is directly entered Gasification furnace.
8. the gasifying powder coal device according to claim 6 or 7, it is characterised in that:The oxygen pipeline of startup burner is provided with Two oxygen emptying points, cleaning high pressure nitrogen purging points, first oxygen emptying point be arranged on startup burner oxygen regulating valve with Between the stop valve of oxygen second, oxygen flow is demarcated before being fed intake for startup burner;Second oxygen emptying point is arranged on oxygen Between first stop valve and the stop valve of oxygen second, for being opened with first oxygen emptying point after startup burner stops simultaneously Atmospheric valve, it is ensured that oxygen is thoroughly isolated with gasification furnace;High pressure nitrogen purging point is arranged on into last one stop valve in stokehold and oxygen Between gas air inlet.
9. gasifying powder coal device according to claim 8, it is characterised in that:On the oxygen pipeline of startup burner, oxygen is adjusted Section valve is arranged on oxygen emptying point front end.
CN201710177501.0A 2017-03-23 2017-03-23 Pulverized coal gasification control method and pulverized coal gasification device Active CN106906004B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107937036A (en) * 2017-11-30 2018-04-20 陕西延长石油(集团)有限责任公司 The system and method for oxygen concentration in a kind of circle fluidized-bed gasification furnace control gasifying agent
CN110295062A (en) * 2018-03-23 2019-10-01 中国石化扬子石油化工有限公司 A kind of part seam jumps the control method of gasification installation stable operation after vehicle
CN110408435A (en) * 2018-04-27 2019-11-05 中安联合煤化有限责任公司 A kind of online switching method of single injector overhead type air flow bed powder coal gasification furnace
CN112779055A (en) * 2019-11-07 2021-05-11 国家能源投资集团有限责任公司 Plug flow gasifier and gasification method of carbon-containing raw material
CN112831353A (en) * 2021-01-09 2021-05-25 中国华能集团清洁能源技术研究院有限公司 A gasification efficiency adjustment system of a gasifier and its working method

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104974798A (en) * 2015-07-07 2015-10-14 航天长征化学工程股份有限公司 Control method for operation of pulverized coal burner of pulverized coal pressure gasification reaction device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104974798A (en) * 2015-07-07 2015-10-14 航天长征化学工程股份有限公司 Control method for operation of pulverized coal burner of pulverized coal pressure gasification reaction device

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107937036A (en) * 2017-11-30 2018-04-20 陕西延长石油(集团)有限责任公司 The system and method for oxygen concentration in a kind of circle fluidized-bed gasification furnace control gasifying agent
CN107937036B (en) * 2017-11-30 2023-08-04 陕西延长石油(集团)有限责任公司 System and method for controlling oxygen concentration in gasifying agent by circulating fluidized bed gasifier
CN110295062A (en) * 2018-03-23 2019-10-01 中国石化扬子石油化工有限公司 A kind of part seam jumps the control method of gasification installation stable operation after vehicle
CN110408435A (en) * 2018-04-27 2019-11-05 中安联合煤化有限责任公司 A kind of online switching method of single injector overhead type air flow bed powder coal gasification furnace
CN112779055A (en) * 2019-11-07 2021-05-11 国家能源投资集团有限责任公司 Plug flow gasifier and gasification method of carbon-containing raw material
CN112831353A (en) * 2021-01-09 2021-05-25 中国华能集团清洁能源技术研究院有限公司 A gasification efficiency adjustment system of a gasifier and its working method
CN112831353B (en) * 2021-01-09 2022-03-04 中国华能集团清洁能源技术研究院有限公司 A gasification efficiency adjustment system of a gasifier and its working method

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