CN106901991A - A kind of polyalcohol bag oily gel composition with gentle cleaning action - Google Patents
A kind of polyalcohol bag oily gel composition with gentle cleaning action Download PDFInfo
- Publication number
- CN106901991A CN106901991A CN201510955731.6A CN201510955731A CN106901991A CN 106901991 A CN106901991 A CN 106901991A CN 201510955731 A CN201510955731 A CN 201510955731A CN 106901991 A CN106901991 A CN 106901991A
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- CN
- China
- Prior art keywords
- polyalcohol
- oil
- composition
- gel composition
- oily gel
- Prior art date
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000035614 depigmentation Effects 0.000 description 1
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- PKPOVTYZGGYDIJ-UHFFFAOYSA-N dioctyl carbonate Chemical compound CCCCCCCCOC(=O)OCCCCCCCC PKPOVTYZGGYDIJ-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005447 environmental material Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000036449 good health Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229940023564 hydroxylated lanolin Drugs 0.000 description 1
- 230000000640 hydroxylating effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N isooctadecyl alcohol Natural products CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical group CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940057905 laureth-3 Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 235000019488 nut oil Nutrition 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000001702 nutmeg Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003791 organic solvent mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003961 penetration enhancing agent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000012056 semi-solid material Substances 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000008591 skin barrier function Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical class CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/602—Glycosides, e.g. rutin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
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- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
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Abstract
The invention discloses a kind of polyalcohol bag oily gel composition with gentle cleaning action, with the gross weight meter of the composition, the composition is included：The polyalcohol of 20 70 weight %；The emulsifying agent of 0.4 10 weight %；The grease of 20 80 weight %；Wherein, each component sum is 100 weight % in the composition.
Description
Technical field
The present invention relates to cosmetic field, and in particular to a kind of polyalcohol bag with gentle cleaning action
Oily gel composition, cleans and nurses for skin.
Background technology
The pH of gentle Cleasing compositions is generally near or less than 7.Even if the pH of such composition is alkalescence,
It is generally also less than 8.Reason is strong alkaline cleaner, and such as traditional soap bar and liquid cleaner containing soap are usual
It is considered as stimulating.On the other hand, the traditional SLES-CAPB bases cleaning group with about 5 to 7 pH
Compound is typically considered to softly gently, therefore these surfactants constitute the base of many such compositions
Plinth.
Commercially available cleaning class product usually contains substantial amounts of surfactant.The master of surfactant in cleaning products
It is dissolving grease and sebum to want function, when lipid is excessively lost, Stratum corneum lipids double-decker can be made to lose surely
Qualitative, skin barrier function is damaged, and increased the chance that pungent infiltrates through skin, meanwhile, through table
Skin water loss increases, and skin becomes drying.And during cleaning, surfactant is through penetrating into
Skin, changes the compatibility between the prototype structure state of skin and adjacent molecule, causes skin irritatin and draws
Play allergic reaction, it is considered to be trigger one of dermopathic reason.He Li etc.,《Skin disease and venereal disease》,
2011,33(3)。
Although in commercially available cleaning products stearic acid, vegetable fat can be included by adding skin nourishment composition
With glycerine etc., reach the gentle, purpose of nourishes rough skin.But experience known to industry, table work content in product
Still it is higher by generally higher than 8%, and the grease type skin nourishment component content that system can be carried is limited, generally
Cannot be higher than 10%.
The use of preservative, is also one of irritating source of cosmetics.General cosmetics are required for addition anti-
Rotten agent prevents product breed bacteria from going mouldy.There is researcher to anti-corrosion the most frequently used in daily chemical products over nearly 10 years
Agent, and included its LD50 value.Generally speaking, the LD50 values of preservative are not very low, are in
The scope of low toxicity or micro- poison.The oxicity analysis of Li Cheng upright stone tablets etc., preservative and daily chemical products related component,《Day
Use chemicals science》2014,37 (8).
Sum it up, commercially available general cleaning products are few to sebum secretion amount, skin sensitivity or impaired crowd,
Particularly infant, dry sensitivity skin adult etc. have potential stimulation risk.
Therefore, people earnestly wish to a kind of skin cleaning products with gentle cleaning action, the product
, skin sensitivity few for sebum secretion amount or impaired crowd are equally applicable.
The content of the invention
It is an object of the invention to provide the cleaning products with gentle cleaning action.The product should
After skin, excitant is low.Meanwhile, product of the invention can also assign skin after cleaning skin
Appropriate grease.
Polyalcohol bag oily gel composition of the invention can be formed with certain viscosity and texture, have
Preferable stability, gentle gel-like substance；Meet water can emulsify rapidly, so as to reach cleaning (or
Person clean while can assign skin grease) purpose.
Polyalcohol bag oily gel composition of the invention does not gently stimulate feature, Ke Yiwen with prominent
Surely unexpected high content (for example, more than 10%) grease is carried；Alone grease profit can be eliminated
The strong greasy feeling that skin brings.
On the one hand, the invention provides a kind of polyalcohol bag oleogel combination with gentle cleaning action
Thing, with the gross weight meter of the composition, the composition is included：
The polyalcohol of 20-70 weight %；
The emulsifying agent of 0.4-10 weight %；
The grease of 20-80 weight %；
Wherein, each component sum is 100 weight % in the composition.
In a specific embodiment, polyalcohol in polyalcohol bag oily gel composition of the present invention
Consumption can be 20-60 weight %.In a specific embodiment, polyalcohol bag oil of the present invention is solidifying
The consumption of polyalcohol can be 20-50 weight % in glue composition.In a specific embodiment,
The consumption of polyalcohol can be 20-40 weight % in polyalcohol bag oily gel composition of the present invention.At one
In specific embodiment, the consumption of polyalcohol can be in polyalcohol bag oily gel composition of the present invention
20-30 weight %.
In a specific embodiment, emulsifying agent in polyalcohol bag oily gel composition of the present invention
Consumption can be 0.4-10 weight %.In a specific embodiment, polyalcohol bag oil of the present invention
The consumption of emulsifying agent can be 0.4-8 weight % in gel combination.In a specific embodiment,
The consumption of emulsifying agent can be 0.4-5 weight % in polyalcohol bag oily gel composition of the present invention.At one
In specific embodiment, the consumption of emulsifying agent can be in polyalcohol bag oily gel composition of the present invention
0.4-3 weight %.
In a specific embodiment, the use of grease in polyalcohol bag oily gel composition of the present invention
Amount can be 30-80 weight %.In a specific embodiment, polyalcohol bag oleogel of the present invention
The consumption of grease can be 40-80 weight % in composition.In a specific embodiment, this hair
The consumption of grease can be 50-80 weight % in bright polyalcohol bag oily gel composition.It is specific at one
In implementation method, the consumption of grease can be 50-70 weights in polyalcohol bag oily gel composition of the present invention
Amount %.
In a specific embodiment, described in polyalcohol bag oily gel composition of the present invention
The content of polyalcohol is 18-70 weight %, and the content of the emulsifying agent is 0.4-8 weight %, the oil
The content of fat is 29.6-80 weight %.In an especially preferred implementation method, the content of emulsifying agent
It is 1-5 weight %.
For polyalcohol bag oily gel composition of the present invention, fat content is higher and emulsifier
It is relatively low.Compared with conventional cleaning products, gel combination of the invention can avoid excessively washing away skin
The original grease of skin, or even the grease of skin appropriateness can also be assigned while cleaning, so as to reach temperature
With the purpose for cleaning and assigning fat.
In one preferred embodiment, the polyalcohol choosing in the polyalcohol bag oily gel composition
From：Glycerine, propane diols, butanediol or combinations thereof.
In one preferred embodiment, the emulsifying agent choosing in the polyalcohol bag oily gel composition
From：APG class, sucrose-fatty esters, lecithin lipid or combinations thereof.At one preferably
Implementation method in, the emulsifying agent in the polyalcohol bag oily gel composition is selected from：Sucrose lauric acid
Ester, hydrolecithin, 16 octadecyl glycosides, inulin lauryl carbamate or their group
Close or combinations thereof.
Grease can form hydrophobic film in skin surface, assign the same of skin emolliency, lubrication and glossiness
When, moreover it is possible to a certain extent, prevent the intrusion of harmful environmental material and resist from nature many factors
Invasion and attack.According to the similar principle that mixes, grease can also dissolve the oil-soluble dirt of skin surface, so that conduct
Main composition is used in the cleaning products of skin surface.Grease can suppress the evaporation of moisture, prevent skin
Skin is dry and cracked, make dry skin and the cuticula of hardening again water and, cuticula is recovered soft and elasticity.Make
Skin smooth, soft and moist, high resilience, make skin be maintained under good health status.
The modifying agent of grease or cosmetics spreadability, largely determines the skin sense of skin care item, example
Such as spreadability, lubricity, moisten degree, moisture retention, gas permeability.Meanwhile, outward appearance, viscosity to lotion,
Emulsified particles size, product stability, effect and excitant all have a significant impact.
The main chemical compositions of grease are all the glyceryl ester compounds of aliphatic acid.A variety of aliphatic acid with
The combination of glycerine, just turns into various greases of different nature.Aliphatic acid present in natural oil, except pole
It is entirely almost the straight chain mono aliphatic acid containing even-numbered carbon atom beyond indivedual.Grease is insoluble in water
Lyophobic dust, its state understands the change of temperature and reversible change occurs.In general, it is liquid under normal temperature
The referred to as fat for being referred to as oil, under normal temperature being solid-state of state.
, can be divided into for grease by the difference in source and chemical composition according to grease：Vegetative grease, animality
Grease, mineral grease and Synthetic Oil.
Vegetative grease is mainly derived from the fruit and seed of plant, also have part come from the leaf of plant, stem,
Root, flower etc..In vegetable fat in addition to glyceryl ester, also contain a small amount of phosphatide, sterol and vitamin
Deng, the content of these materials, can be reduced with the raising of the refined degree of vegetable fat.In addition, vegetalitas
Grease is oxidized easily, and the storage for product needs strict control.Common vegetative grease has：
Sunflower oil, rapeseed oil, walnut oil, jojoba oil, olive oil, castor oil, coconut oil, palm oil,
Palm-kernel oil, avocado oil, wheat-germ oil, apricot kernel oil, sher butter, pot marigold oil, evening primrose oil,
Tea oil, aloe, Seabuckthorn Oil, macadimia nut oil, rice bran oil, corn oil etc..
Animal raw fat, in general, its iodine number is low compared with vegetative grease, but saponification number is higher, and sweet
Saturated fatty acid content is higher in grease.Animal raw fat all carries special odor in various degree, seldom directly
It is used in cosmetics, is mainly used as soapmaking raw material.And through the animal raw fat for refining, can be daily use chemicals
Field quality raw materials.Common animal raw fat has：Mink oil, snake oil, natural saualane, tallow, sheep
Hair fat etc..
Mineral grease is usually nonpolar, high-carbon catenanes of the boiling point more than 300 DEG C, wherein with straight chain
Saturated hydrocarbons is in the majority.Mineral oil is difficult to become sour, and heat-resistant stability is high, abundance, is household chemicals field thing U.S. valency
Honest and clean glyceride stock.But mineral grease is of less types, and absorbability is poor, belong to inertia grease.Common
Mineral grease has：White Mineral Oil or white oil, vaseline etc..
Synthetic Oil is usually the modified grease of processed synthesis from various greases or raw material, not only composition with
Raw oil material is similar, and maintains its advantage, and assigns its new characteristic by modified.Common synthesis
Grease has：Lanolin derivative (liquid lanolin, lanolin wax, lanoceric acid, acetylated lanolin,
Ethoxylation lanonol, hydrogenated lanolin, ethoxylated lanolin, hydroxylated lanolin, acetylated lanolin
Fat, propoxylated lanolin alcohol, alcohol-soluble lanolin alcohol), polysiloxanes refer to dimethyl silicone polymer and
Its derivative, synthesis saualane, carbonic acid dioctyl ester, propionic acid nutmeg alcohol ester, isopropyl myristate,
It is isopropyl palmitate, isobutyl palmitate, caprylic/capric glyceryl ester, capric acid/caprinoyl glyceryl ester, different
The different monooctyl ester of octanoic acid, Dermol 105 (silk ester) etc..
In one preferred embodiment, the grease in the polyalcohol bag oily gel composition can be with
Any oily components, such as natural or synthetic oils.The oils may be selected from：Mineral oil, vegetable oil,
Animal oil or combinations thereof.For example, in a specific embodiment, grease choosing of the invention
From：Fat and wax, fatty acid ester, fatty acid alcohol, aliphatic acid and their mixture.
In one preferred embodiment, the grease in the polyalcohol bag oily gel composition is selected from：
Rice bran oil, olive oil, jojoba oil, sunflower seed oil, isononyl isononanoate, isobutyl palmitate,
Ring five dimethyl silicone polymer, three Miglyol 812s or combinations thereof.
On the other hand, polyalcohol bag oily gel composition of the present invention is included the invention further relates to one kind
The skin preparations for extenal use with gentle cleaning action, the skin preparations for extenal use also include cosmetics, skin
Disease is learned or pharmaceutically acceptable excipient.
In one preferred embodiment, the polyalcohol bag oily gel composition also has comprising other
Beneficial to the additive of skin.For example, can be comprising water-soluble or oil soluble additive and/or insoluble in combination
The additive of thing.In a specific embodiment, described water-soluble or oil soluble additive is selected from：
Antioxidant, NMF, antiinflammatory.It is described insoluble in combination in a specific embodiment
Other additives of thing are selected from：Carbohydrate particle, pearl powder, sponge gourd particle.
Composition of the present invention can carry the acceptable any functional additive of cosmetic field, example
Such as those have the additive of the effect of anti-aging/whitening/beneficial skin of massage exfoliating.It is specific and
Speech, water-soluble good but alcohol-soluble difference material such as carbohydrate particle can in the present compositions still with the shape of particle
Formula is present, and being touched with water can gradually dissolve disappearance using process.
On the other hand, polyalcohol bag oily gel composition of the invention is prepared present invention also offers one kind
Method, the described method comprises the following steps：
A) polyols blend component, prepares alcohol phase,
B) compound lard component, prepares oil phase,
C) by oil phase addition alcohol phase, transparent homogeneous gel combination is formed.
On the other hand, present invention also offers a kind of cosmetics with skin cleaning action, describedization
Cosmetic includes gel combination of the invention and cosmetic field acceptable carrier.
The gel combination of polyalcohol bag oil of the invention both can directly be used as final products,
Other functions raw material can be added as semi-finished product, form the final product with gentle cleaning action
Product.This composition is met water and can quickly form white emulsion droplet.While washing away skin foul, can
So that a certain amount of grease is stopped (can adjust the height for assigning fat amount by formula) on skin.Should
System can also be applied directly to skin, cutin-softening layer, and can carry a certain amount of granule for massage and reach
To the effect of massage clean skin.
The occupation mode of inventive gel composition is included but is not limited to：Being smeared on the skin of moistening makes
With then with washing away；Smeared on dry skin and used, then drawn；Or be directly diluted in
Used in water；The system can also directly be smeared stayed in and used on skin.
The Dermatologic preparation composition is typically used for the general designation concept of all the components outside skin,
For example can be cosmetic combination or pharmaceutical compositions.It can be basis in the cosmetic combination
Cosmetic preparation, facial dressing cosmetic preparation, body cosmetic preparation, hair nursing cosmetic preparation etc., to its agent
Type, can reasonable selection according to different purposes without specifically limited.
Different cosmeceuticals layers is Bu Tong also contained according to formulation and purpose in the cosmetic combination
Medium or matrix excipients that face allows.
Can be used for the cosmetics of Dermatologic preparation composition of the present invention, dermatology or can pharmaceutically connect
The excipient received is water phase, oil phase, gel, water bag wax pattern emulsion, emulsion oil-in-water or Water-In-Oil
The form of type emulsion.Water is mutually one or more mixture of water-soluble or dispersed component, and it is in room
Can be liquid, semi-solid or solid under warm (25 DEG C).Excipient include or can be water or water-
The form of suspension, dispersion liquid or solution in alcohol excipient, it can contain thickener or gel.
Those skilled in the art can be based on the suitable product shape of knowledge-chosen that those skilled in the art grasp
Formula, wherein the component for including.
Described composition can include water phase, and the water mutually can be hydrophilic with least one containing water or water
Property organic solvent mixture, described hydrophilic organic solvent such as alcohol especially contains 2-5
The straight or branched low-grade monobasic alcohol of carbon atom, such as ethanol or propyl alcohol；Polyalcohol, such as propane diols, mountain
Pears alcohol, glycerine, panthenol or polyethylene glycol and its mixture.
When the composition of invention is emulsion form, said composition can also optionally include surfactant.
Described composition can also include film forming polymer, and such as polyurethanes, polyacrylic acid is equal
Polymers or copolymer, polyester, resin and/or silicone resin based on hydrocarbon.Can dissolve a polymer in
Or be scattered in the acceptable excipient of cosmetics and optionally merge with plasticizer.
Composition of the invention can also include oil phase, and described oil phase contains under room temperature (25 DEG C)
For liquid oil-soluble or oil-dispersing property component and/or at room temperature be oily or wax-like material, such as wax,
Semi-solid, natural gum and its mixture.The oil phase can also contain organic solvent.
Generally it is at room temperature liquid, suitable oily matter includes：From animal based on hydrocarbon
Oil, such as perhydro-squalene；The glycerine three of the C4-10 aliphatic acid of the vegetable oil based on hydrocarbon, such as liquid
Esters, such as enanthic acid or Trivent OCG class, or oil, such as sunflower oil, corn oil, soybean
Oil, grape-kernel oil, castor oil, avocado oil, caprylic/capric triglyceride class, jojoba oil；Mineral
Or the straight or branched hydro carbons of synthesis source, such as liquid paraffin and its derivant, vaseline；Synthesis
The esters of esters and ethers, particularly fatty alcohol, such as isopropyl myristate, palmitic acid 2- ethyls
Own ester, stearic acid 2- octyldodecyls, isostearyl isostearate ester；Hydroxylating esters, example
Such as lactic acid isooctadecanol ester, octyl hydroxystearate, octyl hydroxystearate, hydroxy stearic acid octyl group
Dodecyl ester, the enanthic acid esters of fatty alcohol, sad esters and capric acid lipid；Polyalcohol esters, example
Such as propylene, the heptanoate of neopentyl glycol two, the isononoate of diethylene glycol (DEG) two and pentaerythritol ester
Class；Aliphatic alcohols containing C12-26, such as octyldodecanol, 2- butyl octanol, the 2- hexyl last of the ten Heavenly stems
Alcohol, 2- undecylpentadecanols, oleyl alcohol；Fluorocarbon oil and/or fluorosilicon oil based on part hydrocarbon, silicone oil,
It is at room temperature liquid or semisolid volatility or non-volatile straight chain or cyclomethicones silica
Alkane, such as X 2-1401 and dimethyl silicone polymer, it optionally includes phenyl, for example
Silicone DC 556, siloxanes and its mixture.
Composition of the invention can further comprising any component being usually used in cosmetic field.This
A little components include preservative, water phase thickener (extract biopolymer, synthetic polymer) and fat
Fat phase thickener, aromatic, hydrophily and lipophilic active agent and its mixture.
Composition of the invention can also include other particle phase, and described particle can be mutually cosmetic
The pigment and/or pearling agent and/or filler used in product composition.
Pigment may reside in composition, and suitable inorganic pigment includes titanium oxide, zirconium oxide and oxygen
Change cerium and zinc oxide, iron oxide and barba hispanica；Suitable organic pigment includes barium, strontium, calcium and aluminium color
Form sediment and carbon black.
Pearling agent may reside in composition, and suitable pearling agent includes being coated with titanium oxide, oxidation
The mica of iron or natural pigment.
Filler may reside in composition, suitable filler include talcum powder, silica,
Zinc stearate, mica, kaolin, nylon powder, polyethylene powders, Teflon, starch, a nitrogen
Change boron, such as copolymer microsphere, silicone resin microballon.
The oil phase of the present composition can be comprising one or more wax, natural gum or its mixture.Wax bag
Include the wax based on hydrocarbon, fluorine wax and/or siloxane wax, and can from plant, mineral, animal and/
Or synthesis source.Suitable wax include beeswax, Brazil wax, candelila wax, paraffin, microwax,
Ceresine；Synthetic wax includes Tissuemat E, the siloxane wax containing C16-45.Natural gum is generally poly- diformazan
Radical siloxane or sodium carboxymethylcellulose extract species, and semi-solid material is generally based on hydrocarbon
Compound, such as lanolin and its derivative.
Composition of the invention can be configured to any suitable product form.This kind of product form bag
Include, but be not limited to aerosol spray, creme, emulsion, solid, liquid, dispersion, foam,
Gel, toner, mousse, ointment, pulvis, patch, brilliantine, solution, hand are sprayed by pump-type
Agent, club, facial mask and hygenic towelette.Can by composition of the invention pass through it is well known in the art that
Various methods be advantageously available for prepare or as cosmetics, dermatology or medicine local application product.
Dermatologic preparation composition of the invention can include one or more following ingredients：Anti-allergic agent,
Antimicrobial, antioxidant, chelating agent, colouring agent depigmentation, emollient, emulsifying agent, table
Skin agents for defoliating, film forming agent, spices, NMF, insect repellent, lubricant, pharmaceutically active agents,
Humidizer, photostabilizer, preservative, skin conditioner, skin penetration enhancer, sun-screening agent, stabilizer,
Surfactant, thickener, viscosity modifier, vitamin or its any combination.
Specific embodiment
The present invention is expanded on further with reference to specific embodiment.It should be appreciated, however, that these realities
Example is applied to be merely to illustrate the present invention and be not meant to limit the scope of the invention.Do not noted in the following example
The test method of bright actual conditions, generally according to normal condition, or according to the bar proposed by manufacturer
Part.Unless otherwise indicated, all of percentage and number be by weight.
The Surfhope SE Cosme C 1216 used in following examples is purchased from Mitsubishi chemical Co., Ltd, rice bran oil purchase
From Li Putai chemical companies；26# Dormant oils is purchased from Tianjin Kai Weiyongli joints Chemical Co., Ltd., remaining
It is common commercially available prod.
Embodiment 1：Prepare the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 0.4 part of Surfhope SE Cosme C 1216 is put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 69.6 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Comparative example 1 prepares the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 10 parts of docosyl alcohol polyethers -30 are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 60 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 2：Prepare the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 3 parts of six/octadecyl alcolol ethers of APEO (20) 10 are put into beaker, mix
After conjunction, 50-85 DEG C is heated with stirring to, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 67 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 3：Prepare the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 3 parts of monoglycerides be put into beaker, after mixing, be heated with stirring to 50-85 DEG C,
Until system dissolves homogeneous, it is standby as alcohol phase.
Take 67 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 4：Prepare the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 3 parts of sodium sulfovinates of laureth -3 are put into beaker, after mixing, stirring
50-85 DEG C is heated to, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 67 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 5：Prepare the polyalcohol bag oily gel composition containing different emulsifiers
Take 30 parts of glycerine and 1 part of octadecyl sodium glutamate is put into beaker, after mixing, agitating heating
To 50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 69 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Summary experimental result understands, in the composition prepared by embodiment 1 and comparative example 1-5,
In addition to embodiment 1, the gel of stable homogeneous cannot be formed.
What table 1 below summarized prepared by embodiment 1 and comparative example 1-5 contains the polynary of different emulsifiers
Each component and its consumption included in alcohol bag oily gel composition, show polyalcohol of the present invention
Bag oily gel composition can select different greases to constitute.
Table 1
Embodiment 2：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 30 parts of glycerine and 1 part of Surfhope SE Cosme C 1216 is put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 69 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Embodiment 3：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 30 parts of glycerine and 8 parts of Surfhope SE Cosme C 1216s are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 62 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Comparative example 6：Prepare the polyalcohol bag oily gel composition of the emulsifying agent containing different amounts
Take 30 parts of glycerine and 0.1 part of Surfhope SE Cosme C 1216 is put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 69.9 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 7：Prepare the polyalcohol bag oily gel composition of the emulsifying agent containing different amounts
Take 30 parts of glycerine and 0.3 part of Surfhope SE Cosme C 1216 is put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 69.7 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Comparative example 8：Prepare the polyalcohol bag oily gel composition of the emulsifying agent containing different amounts
Take 30 parts of glycerine and 50 parts of Surfhope SE Cosme C 1216s are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 20 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Comparative example 9：Prepare the polyalcohol bag oily gel composition of the oil phase containing different amounts
Take 90 parts of glycerine and 0.3 part of Surfhope SE Cosme C 1216 is put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 9.7 portions of rice bran oils and be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase keeps for 50-85 DEG C, in the case where rotating speed is 3000rpm-5000rpm processing conditions, by oil phase plus
Enter in alcohol phase, after homogeneous 5-10 minutes, be down to room temperature, it is impossible to form the gel of stable homogeneous.
Table 2 below summarize prepared by embodiment 2-3 and comparative example 6-9 with many of gentle cleaning action
Each component and its consumption included in first alcohol bag oily gel composition.
Table 2
Embodiment 4：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 2 parts of Surfhope SE Cosme C 1216s and 30 parts of glycerine are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 68 parts of olive oil to be put into beaker, be mixed and heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Embodiment 5：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 5 parts of Surfhope SE Cosme C 1216s and 30 parts of glycerine are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
33 parts of sunflower seed oils, 16 parts of isononyl isononanoates, 16 parts of 26# Dormant oils are taken to be put into beaker,
50-85 DEG C is mixed and heated to, it is standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
The oil of the polyalcohol bag with gentle cleaning action that table 3 below summarizes embodiment 4-5 preparations is solidifying
Each component and its consumption included in glue composition, show polyalcohol bag oleogel of the present invention
Composition can select different greases to constitute.
Table 3
Embodiment 6：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 2 parts of Surfhope SE Cosme C 1216s and 18 parts of glycerine are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 7 parts of olive oil and 28 parts of jojoba oils, 25 parts of isobutyl palmitates, 20 parts of rings five poly- two
Methylsiloxane is put into beaker, is mixed and heated to 50-85 DEG C, standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Embodiment 7：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 0.4 part of Surfhope SE Cosme C 1216 and 70 parts of glycerine are put into beaker, after mixing, be heated with stirring to
50-85 DEG C, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 29.6 parts of sunflower seed oils to be put into beaker, be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Embodiment 8：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 8 parts of Surfhope SE Cosme C 1216s and 30 parts of glycerine, 2 parts of propane diols are put into beaker, after mixing,
50-85 DEG C is heated with stirring to, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 60 parts of olive oil to be put into beaker, be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
Embodiment 9：Prepare the polyalcohol bag oily gel composition with gentle cleaning action
Take 8 parts of Surfhope SE Cosme C 1216s and 30 parts of glycerine, 2 parts of butanediols are put into beaker, after mixing,
50-85 DEG C is heated with stirring to, until system dissolving is homogeneous, it is standby as alcohol phase.
Take 60 parts of olive oil to be put into beaker, be heated to 50-85 DEG C, it is standby as oil phase.
Alcohol phase 50-85 DEG C, rotating speed be 3000rpm-5000rpm processing conditions under oil phase is added to
In alcohol phase, until then homogeneous is down to room temperature into transparent homogeneous gel, it is standby.
The oil of the polyalcohol bag with gentle cleaning action that table 4 below summarizes embodiment 6-9 preparations is solidifying
Each component and its consumption included in glue composition, it is shown that polynary in composition of the present invention
Alcohol can be constituted from glycerine with other polyalcohols, and the ratio of alcohol phase and oil phase can be adjusted.
Table 4
Embodiment 10：Security verification
Study subject
Company healthy volunteer 33, the wherein people of male 9, the people of women 24, age 23-49 Sui,
All volunteers are without anaphylactic disease history.During experiment, experiment position disable any external application thing and (or)
Cosmetics, nothing takes any corticosteroid hormone and (or) antihistamine drug history.
Test specimen：The gel that embodiment 1-9 and comparative example 7 are prepared.
Test method (24hr patch)
Test specimen 0.03ml is inserted into the small interior of Finn patch successively before experiment.
It is the closed patch tests of 24hr to test, will tested material patch in subject back, removing
0.5h observations result after patch, and in observing once result after 24hr again.Result of the test is as shown in table 5.
Table 5
Result shows that stimulating does not occur in sample prepared by embodiment 1-9 and comparative example 7, all logical
Cross the irritating investigation of safety.
Embodiment 11：Stability experiment
Laboratory high temperature low tempertaure storage stability test can be carried out using following methods：(1) in 48 DEG C of perseverances
Placed 90 days in warm incubator, observed after recovering room temperature, (2) place 90 in 25 DEG C of constant incubators
My god, its stability is observed after recovering room temperature, observe its stability；(3) placed in 4 DEG C of insulating boxs
90 days, observe its stability (4) after recovery room temperature and 2 weeks, recovery room are placed in temperature cycling incubator
Observed after temperature.Cyclic culture case imposes a condition：- 10 DEG C of holding 24h, are then warming up to 48 in 4 hours
DEG C and keep 24h, be then cooled in 4 hours -10 DEG C holding 24h, so circulation.(5) -10
Deposited 90 days at DEG C, its stability is observed after recovering room temperature.
If sample, without obvious mildew bacterium long, becomes without obvious water-oil separating without obvious smell color and luster
Change, then study on the stability passes through.Result is as shown in table 6.
Table 6
| Sample investigate temperature | 48℃ | 25℃ | 4℃ | Circulation | -10℃ |
| Embodiment 1 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 3 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 4 | 0 | 0 | 0 | 0 | 0 |
| Comparative example 7 | 0 | 0 | 0 | X | 0 |
| Embodiment 5 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 6 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 7 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 8 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 9 | 0 | 0 | 0 | 0 | 0 |
0 representative passes through, and X is represented and do not passed through
Result shows that embodiment 1 and comparative example 1-5 have investigated different classes of emulsifying agent to polyalcohol
The carrying situation of bag oily gel composition, as a result shows, Surfhope SE Cosme C 1216 can form homogeneous gel
Composition, and the emulsifying agent that comparative example 1-5 is used cannot form homogeneous gel combination.
Embodiment 2-3 and comparative example 6-9 have investigated the Surfhope SE Cosme C 1216 of different content to polyalcohol bag oil
The carrying situation of gel combination, result is except embodiment 2-3 and comparative example 7 can form homogeneous solidifying
Outside glue composition, remaining cannot form homogeneous gel combination.Therefore, it is of the present invention polynary
Alcohol bag oily gel composition preferably contains the Surfhope SE Cosme C 1216 of 0.4-8 weight %.
Embodiment 4-5 has investigated different classes of grease to polyalcohol bag oleogel group of the present invention
The influence of the mildness and stability of compound, wherein, single vegetable fat, such as olive oil, or plant
Thing grease (sunflower seed oil), mineral grease (26# Dormant oils) and Synthetic Oil (isononyl isononanoate)
Combination when, while passed through mildness and stability test and, individually make in 1-3 in conjunction with the embodiments
In rice bran oil, embodiment 8-9 be used alone olive oil and embodiment 7 in be used alone to
Day seed oil of sunflower, it can be seen that, polyalcohol bag oily gel composition of the present invention can be comprising simple
Vegetative grease content be 29.6-69 weight %, the vegetable fat that can be included, animal fat,
The content of mineral grease or combinations thereof is 65-80 weight %.Therefore, simple grease group it is not
Closing just can obtain effect of the invention.
Embodiment 6-9 has investigated different polyalcohols to polyalcohol bag oily gel composition of the present invention
Mildness and stability influence, wherein, single glycerine (18-70W%) has passed through mildness
And stability test.
Claims (10)
1. a kind of polyalcohol bag oily gel composition with gentle cleaning action, with the composition
Gross weight meter, the composition is included：
The polyalcohol of 20-70 weight %；
The emulsifying agent of 0.4-10 weight %；
The grease of 20-80 weight %；
Wherein, each component sum is 100 weight % in the composition.
2. polyalcohol bag oily gel composition as claimed in claim 1, it is characterised in that with described
The gross weight meter of composition, the content of the polyalcohol is 18-70 weight %, the content of the emulsifying agent
It is 0.4-8 weight %, the content of the grease is 29.6-80 weight %, wherein, in the composition
Each component sum is 100 weight %.
3. polyalcohol bag oily gel composition as claimed in claim 2, it is characterised in that the breast
The content of agent is 0.4-5 weight %.
4. the polyalcohol bag oily gel composition as described in claim any one of 1-3, it is characterised in that
The polyalcohol is selected from：Glycerine, propane diols, butanediol or combinations thereof.
5. the polyalcohol bag oily gel composition as described in claim any one of 1-3, it is characterised in that
The emulsifying agent is selected from：APG class, sucrose-fatty esters, lecithin lipid or combinations thereof.
6. the polyalcohol bag oily gel composition as described in claim any one of 1-3, it is characterised in that
The emulsifying agent is selected from：Surfhope SE Cosme C 1216, hydrolecithin, 16 octadecyl glycosides, inulin
Lauryl carbamate or combinations thereof.
7. the polyalcohol bag oily gel composition as described in claim any one of 1-3, it is characterised in that
The grease is selected from：Vegetable fat, animal fat, mineral grease or combinations thereof.
8. the polyalcohol bag oily gel composition as described in claim any one of 1-3, it is characterised in that
The grease is selected from：Rice bran oil, olive oil, jojoba oil, sunflower seed oil, isononyl isononanoate,
Isobutyl palmitate, ring five dimethyl silicone polymer, three Miglyol 812s or combinations thereof.
9. a kind of tool of the polyalcohol bag oily gel composition comprising as described in claim any one of 1-8
There is the skin preparations for extenal use of gentle cleaning action, it is characterised in that the skin preparations for extenal use is also comprising cosmetic
Product, dermatology or pharmaceutically acceptable excipient.
10. a kind of polyalcohol bag oily gel composition prepared as described in claim any one of 1-8
Method, the described method comprises the following steps：
A) polyols blend component, prepares alcohol phase,
B) compound lard component, prepares oil phase,
C) by oil phase addition alcohol phase, transparent homogeneous gel combination is formed.
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| CN201510955731.6A CN106901991A (en) | 2015-12-17 | 2015-12-17 | A kind of polyalcohol bag oily gel composition with gentle cleaning action |
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| CN201510955731.6A CN106901991A (en) | 2015-12-17 | 2015-12-17 | A kind of polyalcohol bag oily gel composition with gentle cleaning action |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107519098A (en) * | 2017-09-28 | 2017-12-29 | 广州暨南生物医药研究开发基地有限公司 | A kind of anti-acne facial treatment milk and preparation method thereof |
| CN107997996A (en) * | 2017-12-12 | 2018-05-08 | 广州市仙婷贸易有限公司 | A kind of bilayer mildy wash and preparation method thereof |
| CN109700698A (en) * | 2019-02-27 | 2019-05-03 | 邹红媚 | A kind of whitening spot-removing essence facial mask |
| CN111904920A (en) * | 2020-09-18 | 2020-11-10 | 上海煦轼生物科技有限公司 | Cleansing milk with cutin removing effect and preparation method thereof |
| CN114642600A (en) * | 2022-03-12 | 2022-06-21 | 广州悦荟化妆品有限公司 | Oil gel composition, non-emulsified mask liquid composition, and preparation method and use method thereof |
| CN115006270A (en) * | 2022-01-28 | 2022-09-06 | 广东轻工职业技术学院 | A kind of facial mask with cleaning effect and preparation method thereof |
| CN115475118A (en) * | 2021-06-16 | 2022-12-16 | 广州悦荟化妆品有限公司 | Cleansing gel with low irritation and skin barrier repairing function and preparation method thereof |
| CN115969733A (en) * | 2022-12-29 | 2023-04-18 | 羽楠(广州)化妆品有限公司 | A kind of double-layer cleansing oil with warm sense and preparation method thereof |
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| CN1304713A (en) * | 1999-11-15 | 2001-07-25 | 株式会社资生堂 | Oil in polyol type warm substrate |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1304713A (en) * | 1999-11-15 | 2001-07-25 | 株式会社资生堂 | Oil in polyol type warm substrate |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107519098A (en) * | 2017-09-28 | 2017-12-29 | 广州暨南生物医药研究开发基地有限公司 | A kind of anti-acne facial treatment milk and preparation method thereof |
| CN107997996A (en) * | 2017-12-12 | 2018-05-08 | 广州市仙婷贸易有限公司 | A kind of bilayer mildy wash and preparation method thereof |
| CN107997996B (en) * | 2017-12-12 | 2021-07-09 | 仙婷(广州)科技研发有限公司 | Double-layer facial cleanser and preparation method thereof |
| CN109700698A (en) * | 2019-02-27 | 2019-05-03 | 邹红媚 | A kind of whitening spot-removing essence facial mask |
| CN111904920A (en) * | 2020-09-18 | 2020-11-10 | 上海煦轼生物科技有限公司 | Cleansing milk with cutin removing effect and preparation method thereof |
| CN115475118A (en) * | 2021-06-16 | 2022-12-16 | 广州悦荟化妆品有限公司 | Cleansing gel with low irritation and skin barrier repairing function and preparation method thereof |
| CN115006270A (en) * | 2022-01-28 | 2022-09-06 | 广东轻工职业技术学院 | A kind of facial mask with cleaning effect and preparation method thereof |
| CN115006270B (en) * | 2022-01-28 | 2023-09-05 | 广州环亚化妆品科技股份有限公司 | Facial mask with cleaning effect and preparation method thereof |
| CN114642600A (en) * | 2022-03-12 | 2022-06-21 | 广州悦荟化妆品有限公司 | Oil gel composition, non-emulsified mask liquid composition, and preparation method and use method thereof |
| CN115969733A (en) * | 2022-12-29 | 2023-04-18 | 羽楠(广州)化妆品有限公司 | A kind of double-layer cleansing oil with warm sense and preparation method thereof |
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