CN106893226A - A kind of high resiliency high temperature resistant elastomeric material and preparation method - Google Patents
A kind of high resiliency high temperature resistant elastomeric material and preparation method Download PDFInfo
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- CN106893226A CN106893226A CN201710131884.8A CN201710131884A CN106893226A CN 106893226 A CN106893226 A CN 106893226A CN 201710131884 A CN201710131884 A CN 201710131884A CN 106893226 A CN106893226 A CN 106893226A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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Abstract
A kind of high resiliency high temperature resistant elastomeric material, it is made up of following component and weight percent proportioning：The resins 50% of PVC 1300, UN488（DOTP）5%, ESO soybean oil 1%, PDOP 0.1%, GF78 0.05%, Has fam silver system antibacterial mildew inhibitor 0.6%, PP.PA modifying agent 0.1%, TPU102 powder 10%, carbon black slurry 0.1%, manganese stearate 0.01%, calcium stearate 0.15%, SBS superfines 2%, activated calcium carbonate 2%, the proportioning of above-mentioned component is defined by a hundred per cent；Described preparation method includes：The resins of PVC 1300 and activated calcium carbonate and SBS superfines and TPU powder are mixed in proportion, and various auxiliary agents are proportionally added into mixing are mediated, by beginning to pratise, after banburying and open refining modeling, then by pelletizing, finished product will be made after pellet feeding extruder granulation.
Description
Technical field
The present invention relates to a kind of high resiliency high temperature resistant elastomeric material and preparation method, belong to macromolecular elastomer material
Material and preparing technical field.
Background technology
Flexible foamed material is, with raw material such as plastics (PE, EVA etc.), rubber (SBR, CR etc.), to be subject to catalyst, bubble
The auxiliary materials such as foam stabilizers, foaming agent, by physical blowing or crosslinked foaming, make a large amount of trickle foams occur in plastics and rubber,
Volume increases, and density is reduced, and flexible foamed quality of materials is light, pliability is good, possesses buffering, sound-absorbing, shock-absorbing, insulation, filtering etc.
Function, is widely used in the industries such as electronics, household electrical appliances, automobile, Leisure Sport.
The poor performances such as current some conventional elastomeric material generally existing high temperature resistant, ageing-resistant, wearabilities, and do not have
High resiliency, thus more special application places cannot be met, with constantly widening for high resiliency application field, it is badly in need of some property
Can be excellent, application field is wide, low cost, meets the highly elastic material of national and international nontoxic standard requirement.
The content of the invention
It is an object of the invention to overcome the shortcomings of that prior art is present, and provide a kind of high temperature resistant, ageing-resistant, wearability
Good etc. performance, generation efficiency is high, low cost, function admirable, high resiliency high temperature resistant elastomeric material applied widely and preparation
Method.
The purpose of the present invention is completed by following technical solution, a kind of high resiliency high temperature resistant elastomeric material, its
It is characterised by：It is made up of following component and weight percent proportioning：
PVC-1300 resins 50-70%
UN488（DOTP） 5-15%
ESO soybean oils 1-5%
PDOP 0.1-0.3%
KY-405 0.05-0.15%
Has-fam silver system antibacterial mildew inhibitor 0.6-1.0%
PP.PA modifying agent 0.1-1.0%
TPU102 powder 10-20%
Carbon black slurry 0.1-1.0%
Manganese stearate 0.05-0.1%
Calcium stearate 0.1-0.6%
SBS superfines 2-8%
Activated calcium carbonate 2-7%
The proportioning of above-mentioned component is defined by a hundred per cent.
Preferably, it is made up of following component and weight percent proportioning：
PVC-1300 resins 60%
UN488（DOTP） 10%
ESO soybean oils 3%
PDOP 0.2%
KY-405 0.1%
Has-fam silver system antibacterial mildew inhibitor 0.5%
PP.PA modifying agent 0.5%
TPU102 powder 15%
Carbon black slurry 0.5%
Manganese stearate 0.05%
Calcium stearate 0.5%
SBS superfines 5%
Activated calcium carbonate 4.35%
A kind of preparation method of high resiliency high temperature resistant elastomeric material as described above, described preparation method includes：By PVC-
1300 resins and activated calcium carbonate and SBS superfines and TPU powder mix in proportion, and are proportionally added into mixing various
Auxiliary agent is mediated, by beginning to pratise, after banburying and open refining modeling, then by pelletizing, after pellet feeding extruder granulation
It is made finished product；
Described activated calcium carbonate is first to carry out following activation process before raw material proportioning addition：First by the carbon of 1500 mesh
Sour calcium is added in homogenizer, and then bridging agent is configured to 25% neat solvent, with mixer high-speed rotation, uniformly
Be added in pearl filler, stirring 20 minutes after, use low rate mixing instead 30 minutes, dynamic dry after i.e. can be used.
As preferred：Described SBS superfines is by following treatment：1 part of CPE is added in 30 parts of SBS powder systems；
It is solvent with 60 parts of hexamethylenes, adds adhesive to make diluent in a solvent, using 6 parts of unsaturated, vulcanizable liquid high scores
Sub- material and 0.5 part of vulcanizing agent and 0.35 part of catalyst blending, the SBS rubber cements to being blended are heated to 60 degree and are stirred continuously uniformly,
SBS powder is obtained using high temperature spray-drying legal system.
The method can be widely used in inner tube extruded material heat-barrier materials, encapsulant, insulation material, buffering spacer, sound absorption
The fields such as sheet material, medical material utensil, Aero-Space, good with the performance such as high temperature resistant, ageing-resistant, wearability, generation efficiency is high,
Low cost, function admirable, the features such as applied widely.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail：A kind of high resiliency high temperature resistant of the present invention
Elastomeric material, it is characterised in that：It is made up of following component and weight percent proportioning：
PVC-1300 resins 50-70%
UN488（DOTP） 5-15%
ESO soybean oils 1-5%
PDOP 0.1-0.3%
KY-405 0.05-0.15%
Has-fam silver system antibacterial mildew inhibitor 0.6-1.0%
PP.PA modifying agent 0.1-1.0%
TPU102 powder 10-20%
Carbon black slurry 0.1-1.0%
Manganese stearate 0.01-0.1%
Calcium stearate 0.1-0.6%
SBS superfines 2-8%
Activated calcium carbonate 2-7%
The proportioning of above-mentioned component is defined by a hundred per cent.
Preparation method of the present invention includes：By PVC-1300 resins and activated calcium carbonate and SBS superfines and TPU
Powder mixes in proportion, and various auxiliary agents are proportionally added into mixing are mediated, by beginning to pratise, banburying and open refining
After modeling, then by pelletizing, finished product will be made after pellet feeding extruder granulation；
Described activated calcium carbonate is first to carry out following activation process before raw material proportioning addition：First by the carbon of 1500 mesh
Sour calcium is added in homogenizer, and then bridging agent is configured to 25% neat solvent, with mixer high-speed rotation, uniformly
Be added in pearl filler, stirring 20 minutes after, use low rate mixing instead 30 minutes, dynamic dry after i.e. can be used.
SBS superfines of the present invention is by following treatment：1 part of CPE is added in 30 parts of SBS powder systems；With
60 parts of hexamethylenes are solvent, add adhesive to make diluent in a solvent, using 6 parts of unsaturated, vulcanizable Liquid polymerics
Material and 0.5 part of vulcanizing agent and 0.35 part of catalyst blending, the SBS rubber cements to being blended are heated to 60 degree and are stirred continuously uniformly, adopt
SBS powder is obtained with high temperature spray-drying legal system.
Embodiments of the invention can obtain countless by carrying out in number range disclosed above replacement simply
Individual embodiment, and including following three embodiment.
Embodiment 1：High resiliency high temperature resistant elastomeric material of the present invention, it is matched by following component and weight percent
Composition：
PVC-1300 resins 60%
UN488（DOTP） 10%
ESO soybean oils 3%
PDOP 0.2%
KY-405 0.1%
Has-fam silver system antibacterial mildew inhibitor 0.5%
PP.PA modifying agent 0.5%
TPU102 powder 15%
Carbon black slurry 0.5%
Manganese stearate 0.05%
Calcium stearate 0.5%
SBS superfines 5%
Activated calcium carbonate 4.35%
Embodiment 2：A kind of high resiliency high temperature resistant elastomeric material of the present invention, it is matched by following component and weight percent
Composition：
PVC-1300 resins 50%
UN488（DOTP） 15%
ESO soybean oils 5%
PDOP 0.3%
KY-405 0.15%
Has-fam silver system antibacterial mildew inhibitor 1.0%
PP.PA modifying agent 1.0%
TPU102 powder 20%
Carbon black slurry 1.0%
Manganese stearate 0.1%
Calcium stearate 0.25%
SBS superfines 4.2%
Activated calcium carbonate 2%
Embodiment 3：A kind of high resiliency high temperature resistant elastomeric material of the present invention, it is matched by following component and weight percent
Composition：
PVC-1300 resins 70%
UN488（DOTP） 5%
ESO soybean oils 1%
PDOP 0.1%
KY-405 0.05%
Has-fam silver system antibacterial mildew inhibitor 0.6%
PP.PA modifying agent 0.1%
TPU102 powder 10%
Carbon black slurry 0.1%
Manganese stearate 0.01%
Calcium stearate 0.15%
SBS superfines 6.11%
The % of activated calcium carbonate 6
Flexible chain is alternately connected into macromolecular by the present invention using the method for block copolymerization with rigid chain, is in the small soft silk of normal temperature
Rubbery state, hard section is gathered together in glassy state or crystalline state, forms physics crosslinking points, and material has the numerous characteristics of rubber,
Elastomer product is at -50 DEG C -- there is good toughness, tear-proof and Flex-Fatigue within the temperature range of 140 DEG C.
Most of it is a kind of thermoplastic heat molten type superfines present invention adds TPU powder, i.e. polyurethane powder, with
Material has good cohesive force, and temperature range while have initial stage peel strength and heat resistance high and wider is with suitable
Different processing are answered to want, high rigidity, high resiliency, low temperature laminating, bonding is rapid, and production efficiency is high, bonding scope extensively, can be bonded many
Kind of material, can be heated repeatedly, repeatedly bonding, and TPU powder is added in polyvinyl chloride resin, and both are well mixed, good penetrability, can be with
Improve the elasticity and heat-resisting quantity of material.
The present invention is by CaCO3（Calcium carbonate）Inserts carries out following special activation process, directly adds with general inserts
Enter different, activation process is carried out before composition of raw materials, the technique and flow for the treatment of have particularity, first 1500 purposes
CaCO3 is added in mixer high, then bridging agent（Can make by oneself）25% pure solution is configured to, with mixer at a high speed
Rotate, be homogeneously added into CaCO3 inserts, after stirring 20 minutes, use low rate mixing instead 30 minutes, after dynamic is dried, i.e.,
Can be used；CaCO3 dispersivenesses after treatment increase, and increase with polyvinyl chloride resin binding ability, and being added to can reduces cost in being formulated
Enhancing and dispersion effect can be played again.
Also using the SBS superfines of specially treated, SBS is the block copolymer of styrene and butadiene to the present invention.Tool
There is two phase structure：Polybutadiene phase-continuous phase, polystyrene phase-dispersed phase.It is similar to butadiene-styrene rubber, SBS can with water,
Weak acid, alkali etc. are contacted, with excellent tensile strength, big surface friction coefficient, low temperature performance well, excellent electrical properties, processability
The thermoplastic elastomer (TPE) of characteristic can well be waited.Ultra-fine SBS powder is processed by special processing and special modified technique, with non-
Often good mobility, is greatly improved its performance.Do not lump at normal temperatures, thoroughly widened the range of application of SBS.And benzene
Ethene-butadiene-styrene (SBS) triblock polymer is one of maximum thermoplastic elastomer (TPE) of current yield in the world,
The elasticity with rubber, is melt into the material of plasticity under normal temperature under high temperature.Because it has excellent tensile property, good resistance to
The skid resistance of low temperature properties, gas permeability, dissolubility and uniqueness and be widely used in the fields such as shoemaking, modifying plastics, asphalt modification.
Because SBS polarity is small and oil resistivity is poor, use it and be restricted.Polar group can be introduced on SBS chains by functionalization
Group, drastically increases the heat-resisting of SBS, resistance to oxidation, adhesive property and water absorbing properties.1 part is added in 30 parts of SBS powder systems
CPE improves compatibilities of the SBS to polar polymer first, improves SBS polarity.It is solvent with 60 parts of hexamethylenes, adds in a solvent
Enter adhesive and make diluent, using 6 parts of undersaturated vulcanizable liquid polymer materials（Liquid NBR）With 0.5 part of vulcanizing agent
And 0.35 part of catalyst is blended, the SBS rubber cements to being blended are heated to 60 degree and are stirred continuously uniformly, using high temperature spray-drying legal system
Specially treated SBS powder, the rubber powder of system can be such that it is crosslinked well with other materials, and can be the oil resistant of elastomer
Property, cold resistance and the ozone aging resistance of the diaphragm, elasticity and wearability greatly strengthen.
The present invention produces product and reaches following technical indicator：
1）Shore hardness A：70—85
2）Tensile strength：15—20 MPa
3）Stretching strength retentivity：95%
4）Elongation at break：More than 250%
5）Extension at break conservation rate：90%
6）Permanent deformation：5—8%
7）100% stretching strength：4.2—4.6 MPa
8）Tearing strength（Right angle）：50—55 KN/m
9）Elastic viscous force（1200/sec）80 Pa—sec
10）Elastic recovery rate 95%
11）Ozone resistance O3test23 DEG C of 100ppm, 72h, flawless.
12）Compressive deformation（ASTM, D395,22H/70 DEG C）：30-35%
13）Material product can be used -150 DEG C of temperature range -50 DEG C.
Claims (4)
1. a kind of high resiliency high temperature resistant elastomeric material, it is characterised in that：It is made up of following component and weight percent proportioning：
PVC-1300 resins 50-70%
UN488（DOTP） 5-15%
ESO soybean oils 1-5%
PDOP 0.1-0.3%
KY-405 0.05-0.15%
Has-fam silver system antibacterial mildew inhibitor 0.6-1.0%
PP.PA modifying agent 0.1-1.0%
TPU102 powder 10-20%
Carbon black slurry 0.1-1.0%
Manganese stearate 0.01-0.1%
Calcium stearate 0.10-0.6%
SBS superfines 2-8%
Activated calcium carbonate 2-7%
The proportioning of above-mentioned component is defined by a hundred per cent.
2. high resiliency high temperature resistant elastomeric material according to claim 1, it is characterised in that：It is by following component and weight
Per distribution ratio is constituted：
PVC-1300 resins 60%
UN488（DOTP） 10%
ESO soybean oils 3%
PDOP 0.2%
KY-405 0.1%
Has-fam silver system antibacterial mildew inhibitor 0.8%
PP.PA modifying agent 0.5%
TPU102 powder 15%
Carbon black slurry 0.5%
Manganese stearate 0.05%
Calcium stearate 0.5%
SBS superfines 5%
Activated calcium carbonate 4.35%.
3. a kind of preparation method of high resiliency high temperature resistant elastomeric material as claimed in claim 1 or 2, it is characterised in that described
Preparation method includes：PVC-1300 resins and activated calcium carbonate and SBS superfines and TPU powder are mixed in proportion, and
Various auxiliary agents are proportionally added into mixing to be mediated, by beginning to pratise, after banburying and open refining modeling, then by pelletizing, will
Finished product is made after pellet feeding extruder granulation；
Described activated calcium carbonate is first to carry out following activation process before raw material proportioning addition：First by the carbon of 1500 mesh
Sour calcium is added in homogenizer, and then bridging agent is configured to 25% neat solvent, with mixer high-speed rotation, uniformly
Be added in pearl filler, stirring 20 minutes after, use low rate mixing instead 30 minutes, dynamic dry after i.e. can be used.
4. the preparation method of high resiliency high temperature resistant elastomeric material according to claim 3, it is characterised in that described SBS surpasses
Fine powder is by following treatment：1 part of CPE is added in 30 parts of SBS powder systems；It is solvent with 60 parts of hexamethylenes, in a solvent
Adhesive is added to make diluent, using 6 parts of unsaturated, vulcanizable liquid polymer materials and 0.5 part of vulcanizing agent and 0.35 part
Catalyst is blended, and the SBS rubber cements to being blended are heated to 60 degree and are stirred continuously uniformly, and SBS powder is obtained using high temperature spray-drying legal system
End.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110066482A (en) * | 2019-05-17 | 2019-07-30 | 莱恩佳辰(苏州)纳米科技有限公司 | A kind of medical flame-proof PVC rubber mat of long acting antibiotic, formula and preparation method thereof |
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2017
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| JP2006265373A (en) * | 2005-03-24 | 2006-10-05 | Denki Kagaku Kogyo Kk | Vinyl chloride resin composition having maleimide copolymer and vinyl chloride polymer |
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Application publication date: 20170627 |