CN106883479B - A kind of rubber and preparation method thereof - Google Patents
A kind of rubber and preparation method thereof Download PDFInfo
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- CN106883479B CN106883479B CN201710230698.XA CN201710230698A CN106883479B CN 106883479 B CN106883479 B CN 106883479B CN 201710230698 A CN201710230698 A CN 201710230698A CN 106883479 B CN106883479 B CN 106883479B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
- C08L2207/24—Recycled plastic recycling of old tyres and caoutchouc and addition of caoutchouc particles
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The present invention provides a kind of rubber and preparation method thereof, the rubber is prepared from the following raw materials in parts by weight：5-80 parts of paper money residual ink powder of print；0-80 parts of natural rubber；Rubber powder 10-80 parts of recycling；0.5-2 parts of antiaging agent；0.5-2 parts of promotor；5-15 parts of carbon black；0.5-1 parts of antiscorching agent；1-4 parts of vulcanizing agent；Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or prints the waste ink slag generated in paper money wastewater treatment process, and the print paper money residual ink powder includes at least tung oil, calcium carbonate, paraffin and titanium dioxide.The present invention turns waste into wealth paper money ink residue is printed, due to containing tung oil, calcium carbonate, paraffin and titanium dioxide in print paper money ink residue, it can be used as the raw material of rubber, and to print paper money residual ink as rubber made from raw material, it has excellent performance, can satisfy actual demand, to reach under the premise of not reducing rubber quality, the production cost of rubber is reduced, while solving the problems, such as the waste of print paper money residual ink and pollution environment.
Description
Technical field
The present invention relates to technical field of rubber material, more particularly to a kind of rubber and preparation method thereof.
Background technique
Rubber be with elasticity, insulating properties, impermeable water and air high-molecular compound, have very extensive purposes.Rubber
Glue is divided into natural rubber and two kinds of synthetic rubber, and natural rubber is the extraction colloid post-processing from the plants such as rubber tree, kok-saghyz
It is made, accounts for 92%-95% containing rubber hydrocarbon in general natural rubber, basic chemical component is cis- polyisoprene, rather than rubber hydrocarbon
Account for 5%-8%；Synthetic rubber is then obtained by the aggregated reaction of various monomers.Wherein the consumption of natural rubber accounts for 1/3, synthesizes rubber
The consumption of glue accounts for 2/3, and synthetic rubber purposes due to being formulated difference is different.Under the premise of not reducing product quality, rubber is reduced
The production cost of glue is the developing direction of synthetic rubber.
It is useless to generate the spent ink generated in print paper money residual ink, such as banknote printing process, print paper money in printing process for banknote
The waste ink slag generated in water treatment procedure, at present in banknote printing industry, the processing method to print paper money residual ink is usually directly to report
Useless processing, not only polluted environment, but also waste resource.
Summary of the invention
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, one object of the present invention
Be to propose it is a kind of will print paper money residual ink as the rubber of raw material, under the premise of not reducing rubber quality, reduce the production of rubber
Cost, while solving the problems, such as the waste of print paper money residual ink and pollution environment.
The present invention provides a kind of rubber, is prepared from the following raw materials in parts by weight：
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or print paper money wastewater treatment process
The waste ink slag of middle generation, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide.
The rubber provided according to the present invention turns waste into wealth print paper money ink residue, due to containing tung oil, carbonic acid in print paper money ink residue
Calcium, paraffin and titanium dioxide can be used as the raw material of rubber, and to print paper money residual ink as rubber made from raw material, have excellent performance,
It can satisfy actual demand, to reach under the premise of not reducing rubber quality, reduce the production cost of rubber, solve simultaneously
The problem of certainly print paper money residual ink wastes and pollutes environment.
In addition, the rubber provided according to the present invention, can also have following additional technical characteristic：
Further, the rubber is prepared from the following raw materials in parts by weight：
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or print paper money wastewater treatment process
The waste ink slag of middle generation, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide.
Further, the print paper money residual ink powder is the powder that partial size is less than or equal to 10cm, and the recycling rubber powder is mesh number
More than or equal to 30 mesh powders.
Further, the recycling rubber powder is recycling tire glue powder, recycling shoes rubber powder, recycles in leftover pieces rubber powder
At least one or more of mixing.
Further, the vulcanizing agent is one of sulphur, magnesia, tetramethylthiuram disulfide.
Further, the antiaging agent is antiaging agent 264.
Further, the promotor is captax.
Further, the antiscorching agent is anti-scorching agent CTP.
It is another object of the present invention to propose a kind of method for preparing above-mentioned rubber, include the following steps：
(1) raw material described in claims 1 is weighed, is sufficiently mixed after hopper is added；
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, to generate rubber.
Further, the mixture after the reaction is sent into temperature when being kneaded in kneading machine is 60-200 DEG C, the time
For 0.1-1h.
Specific embodiment
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention
Technical solution be clearly and completely described, it is clear that described embodiments are some of the embodiments of the present invention, rather than
Whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work premise
Under every other embodiment obtained, shall fall within the protection scope of the present invention.
On the one hand embodiments of the present invention provide a kind of rubber, be prepared from the following raw materials in parts by weight：
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or print paper money wastewater treatment process
The waste ink slag of middle generation, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide.
The another aspect of embodiments of the present invention provides the preparation method of above-mentioned rubber, includes the following steps：
(1) raw material for weighing above-mentioned parts by weight, is sufficiently mixed after hopper is added；
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, to generate rubber.
Wherein, the moisture content for solving print paper money residual ink by heating and negative pressure is higher, and partial size problem bigger than normal will be inexpensive
Residual ink be applied in rubber manufacturing process, reduce the cost of manufacture of rubber.
In addition, the another aspect for the embodiment that should be invented provides the application method for rising rubber always, including will
Above-mentioned rubber applications are in rubber cable, sealant, tire sealant, conveyer belt glue, V-type band, rubber rollers etc..
Divide multiple embodiments that the embodiment of the present invention is further detailed below.The embodiment of the present invention be not limited to
Under specific embodiment.Within the scope of the unchanged main rights, implementation can appropriate be changed.
Embodiment 1
(1) prepare raw material by following parts by weight：
It is sufficiently mixed after hopper is added in ready raw material.
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process, and the print paper money residual ink powder at least wraps
Tung oil, calcium carbonate, paraffin and titanium dioxide are included, the print paper money residual ink powder specifically can be by useless by what is generated in banknote printing process
Ink is smashed to pieces, and to obtain the powder that partial size is less than or equal to 10cm, the recycling rubber powder is recycling tire glue powder and recycling shoes
The mixture of rubber powder, the recycling rubber powder are that mesh number is more than or equal to 30 mesh powders, and the vulcanizing agent is sulphur, described anti-old
Agent is antiaging agent 264.The promotor is captax, and the antiscorching agent is anti-scorching agent CTP.
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, temperature when mixing is 60-200 DEG C, and the time is
0.1h, to generate rubber.
Embodiment 2
(1) prepare raw material by following parts by weight：
It is sufficiently mixed after hopper is added in ready raw material.
Wherein, the print paper money residual ink powder is to print the waste ink slag generated in paper money wastewater treatment process, and the print paper money residual ink powder is extremely
It include less tung oil, calcium carbonate, paraffin and titanium dioxide, the print paper money residual ink powder specifically can be by that will print in paper money wastewater treatment process
The waste ink slag of generation is smashed to pieces, and to obtain the powder that partial size is less than or equal to 10cm, the recycling rubber powder is recycling leftover pieces glue
Powder, the recycling rubber powder are that mesh number is more than or equal to 30 mesh powders, and the vulcanizing agent is sulphur, and the antiaging agent is anti-old
Agent 264.The promotor is captax, and the antiscorching agent is anti-scorching agent CTP.
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, temperature when mixing is 60-200 DEG C, and the time is
0.1h, to generate rubber.
Embodiment 3
(1) prepare raw material by following parts by weight：
It is sufficiently mixed after hopper is added in ready raw material.
Wherein, the print paper money residual ink powder is to print the waste ink slag generated in paper money wastewater treatment process, and the print paper money residual ink powder is extremely
It include less tung oil, calcium carbonate, paraffin and titanium dioxide, the print paper money residual ink powder specifically can be by that will print in paper money wastewater treatment process
The waste ink slag of generation is smashed to pieces, with obtain partial size be less than or equal to 10cm powder, the recycling rubber powder be recycling shoes rubber powder with
The mixture of leftover pieces rubber powder is recycled, the recycling rubber powder is that mesh number is more than or equal to 30 mesh powders, and the vulcanizing agent is oxygen
Change magnesium, the antiaging agent is antiaging agent 264.The promotor is captax, and the antiscorching agent is anti-scorching agent CTP.
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, temperature when mixing is 60-200 DEG C, and the time is
0.5h, to generate rubber.
Embodiment 4
(1) prepare raw material by following parts by weight：
It is sufficiently mixed after hopper is added in ready raw material.
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and produces in print paper money wastewater treatment process
Raw waste ink slag, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide, the print paper money residual ink powder tool
Body can be by smashing the waste ink slag generated in the spent ink generated in banknote printing process and print paper money wastewater treatment process to pieces, to obtain
It is less than or equal to the powder of 10cm to partial size, the recycling rubber powder is recycling tire glue powder, and the recycling rubber powder is mesh number
More than or equal to 30 mesh powders, the vulcanizing agent is tetramethylthiuram disulfide, and the antiaging agent is antiaging agent 264.
The promotor is captax, and the antiscorching agent is anti-scorching agent CTP.
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, add negative pressure, in being stirred container to take the water being stirred in container away
Steam, the mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, temperature when mixing is 60-200 DEG C, and the time is
1h, to generate rubber.
The comparison of the test result of luminescent material made from the various embodiments described above and the synthetic rubber of the prior art is as follows：
From upper table as it can be seen that compared with prior art, rubber performance made from embodiment 1,2,3,4 is excellent, and volatility gas
Taste is lower, is fully able to replace synthetic rubber in the prior art, this is because the tung oil in print paper money residual ink powder has well
Bridging property improves the intensity and patience of rubber, reduces volatile flavor instead of some volatile organic matters.
To sum up, propose one will print paper money residual ink carry out resource utilization road, the rubber provided according to the present invention and
Preparation method turns waste into wealth print paper money ink residue, can be with due to containing tung oil, calcium carbonate, paraffin and titanium dioxide in print paper money ink residue
As the raw material of rubber, and to print paper money residual ink as rubber made from raw material, it has excellent performance, can satisfy actual demand, thus
Reach under the premise of not reducing rubber quality, reduced the production cost of rubber, while having solved the waste of print paper money residual ink and pollution
The problem of environment.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of rubber, which is characterized in that be prepared from the following raw materials in parts by weight：
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or produces in print paper money wastewater treatment process
Raw waste ink slag, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide.
2. rubber according to claim 1, which is characterized in that be prepared from the following raw materials in parts by weight：
Wherein, the print paper money residual ink powder is the spent ink generated in banknote printing process and/or produces in print paper money wastewater treatment process
Raw waste ink slag, the print paper money residual ink powder include at least tung oil, calcium carbonate, paraffin and titanium dioxide.
3. rubber according to claim 1, which is characterized in that the print paper money residual ink powder is the powder that partial size is less than or equal to 10cm
End, the recycling rubber powder are that mesh number is more than or equal to 30 mesh powders.
4. rubber according to claim 1, which is characterized in that the recycling rubber powder is recycling tire glue powder, recycling
At least one of shoes rubber powder, recycling leftover pieces rubber powder or a variety of mixing.
5. rubber according to claim 1, which is characterized in that the vulcanizing agent is sulphur, magnesia, tetramethyl
One of thiuram.
6. rubber according to claim 1, which is characterized in that the antiaging agent is antiaging agent 264.
7. rubber according to claim 1, which is characterized in that the promotor is captax.
8. rubber according to claim 1, which is characterized in that the antiscorching agent is anti-scorching agent CTP.
9. a kind of method for preparing rubber described in claim 1, which is characterized in that include the following steps：
(1) raw material described in claim 1 is weighed, is sufficiently mixed after hopper is added；
(2) after the completion of mixing, feeding is stirred vessel in heating stirring；
(3) when being heated to 85-95 DEG C, negative pressure is added in being stirred container, to take the vapor being stirred in container away,
Mixture after being reacted；
(4) mixture after the reaction is sent into kneading machine and is kneaded, to generate rubber.
10. according to the method described in claim 9, being mixed it is characterized in that, the mixture after the reaction is sent into kneading machine
Temperature when refining is 60-200 DEG C, time 0.1-1h.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710230698.XA CN106883479B (en) | 2017-04-11 | 2017-04-11 | A kind of rubber and preparation method thereof |
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| CN201710230698.XA CN106883479B (en) | 2017-04-11 | 2017-04-11 | A kind of rubber and preparation method thereof |
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| CN106883479B true CN106883479B (en) | 2018-11-20 |
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| CN114262472B (en) * | 2021-12-16 | 2022-12-20 | 江苏康普印刷科技有限公司 | Banknote printing cloth and process thereof |
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|---|---|---|---|---|
| US4391638A (en) * | 1982-04-22 | 1983-07-05 | J. M. Huber Corporation | Method for reclaiming ink waste |
| CA2065256A1 (en) * | 1989-08-31 | 1991-03-01 | Herbert Fischer | Use of at least partly water-soluble polymers for removing printing ink from printed waste paper and or recycling water in the papermaking industry |
| BR9206967A (en) * | 1991-12-20 | 1995-12-05 | Lawrence Paper Co | Recovery process for printing ink waste |
| CN101181994A (en) * | 2007-11-22 | 2008-05-21 | 中国印钞造币总公司 | Activating agent for manufacturing activated charcoal by banknote printing ink slag and uses thereof |
| CN102092985A (en) * | 2011-01-12 | 2011-06-15 | 铜川市耀州区秦力水泥外加剂有限公司 | Treatment method for modifying money printing ink waste liquid into cement or concrete admixture |
| CN103204597A (en) * | 2013-04-24 | 2013-07-17 | 李莉 | Method for processing water-based ink wastewater |
| CN105907164A (en) * | 2016-05-19 | 2016-08-31 | 南昌印钞有限公司 | Printing ink prepared from waste banknote printing gravure plate wiping liquid and preparation method of printing ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5879508A (en) * | 1981-11-05 | 1983-05-13 | Mitsubishi Heavy Ind Ltd | Recovering method for pigment in waste ink |
| JPS5880367A (en) * | 1981-11-10 | 1983-05-14 | Mitsubishi Heavy Ind Ltd | Method for reclaiming waste ink |
| JPS5881406A (en) * | 1981-11-10 | 1983-05-16 | Mitsubishi Heavy Ind Ltd | Pecovery of pigment from waste ink |
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2017
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|---|---|---|---|---|
| US4391638A (en) * | 1982-04-22 | 1983-07-05 | J. M. Huber Corporation | Method for reclaiming ink waste |
| CA2065256A1 (en) * | 1989-08-31 | 1991-03-01 | Herbert Fischer | Use of at least partly water-soluble polymers for removing printing ink from printed waste paper and or recycling water in the papermaking industry |
| BR9206967A (en) * | 1991-12-20 | 1995-12-05 | Lawrence Paper Co | Recovery process for printing ink waste |
| CN101181994A (en) * | 2007-11-22 | 2008-05-21 | 中国印钞造币总公司 | Activating agent for manufacturing activated charcoal by banknote printing ink slag and uses thereof |
| CN102092985A (en) * | 2011-01-12 | 2011-06-15 | 铜川市耀州区秦力水泥外加剂有限公司 | Treatment method for modifying money printing ink waste liquid into cement or concrete admixture |
| CN103204597A (en) * | 2013-04-24 | 2013-07-17 | 李莉 | Method for processing water-based ink wastewater |
| CN105907164A (en) * | 2016-05-19 | 2016-08-31 | 南昌印钞有限公司 | Printing ink prepared from waste banknote printing gravure plate wiping liquid and preparation method of printing ink |
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