CN106867469A - A kind of low coking fire-resistant L QB300 organic heat carrier compositions of environment-friendly synthesis type - Google Patents
A kind of low coking fire-resistant L QB300 organic heat carrier compositions of environment-friendly synthesis type Download PDFInfo
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- CN106867469A CN106867469A CN201710093359.1A CN201710093359A CN106867469A CN 106867469 A CN106867469 A CN 106867469A CN 201710093359 A CN201710093359 A CN 201710093359A CN 106867469 A CN106867469 A CN 106867469A
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- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 238000004939 coking Methods 0.000 title claims abstract description 24
- 238000003786 synthesis reaction Methods 0.000 title claims description 4
- 230000015572 biosynthetic process Effects 0.000 title claims 3
- 230000009970 fire resistant effect Effects 0.000 title 1
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000006078 metal deactivator Substances 0.000 claims abstract description 6
- 239000003112 inhibitor Substances 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims abstract description 4
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims abstract description 4
- 229920013639 polyalphaolefin Polymers 0.000 claims abstract description 4
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 4
- 239000003755 preservative agent Substances 0.000 claims abstract description 3
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 10
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 6
- 229960002317 succinimide Drugs 0.000 claims description 6
- -1 phenolic ester Chemical class 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002367 Polyisobutene Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- OFUAIAKLWWIPTC-UHFFFAOYSA-L magnesium;naphthalene-2-carboxylate Chemical group [Mg+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 OFUAIAKLWWIPTC-UHFFFAOYSA-L 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 3
- 150000004867 thiadiazoles Chemical class 0.000 claims description 3
- JFSBTWPIEZSDPR-UHFFFAOYSA-N 5-methyl-2h-triazole-4-carbaldehyde Chemical class CC=1N=NNC=1C=O JFSBTWPIEZSDPR-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 2
- 239000012990 dithiocarbamate Substances 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- 235000006708 antioxidants Nutrition 0.000 claims 4
- KSAPYRIVHFAQGR-UHFFFAOYSA-N 1-sulfanylbenzimidazole Chemical compound C1=CC=C2N(S)C=NC2=C1 KSAPYRIVHFAQGR-UHFFFAOYSA-N 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical group 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000001384 succinic acid Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- IYUBCLHILARKQB-UHFFFAOYSA-N 2-sulfonylbenzimidazole Chemical compound C1=CC=CC2=NC(=S(=O)=O)N=C21 IYUBCLHILARKQB-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
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- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种环境友好合成型低结焦抗燃L‑QB300有机热载体组合物，其采用50％(m)的聚α‑烯烃与50％(m)的三芳基膦酸酯的复合作为基础油，配合多种复合添加剂。它包括：抗氧防腐剂、高温抗氧剂、抗氧剂、金属钝化剂、金属减活剂、阻焦剂、防锈剂、碱值保持剂、抗泡剂、补强剂、增活剂。其优点在于：热稳定性好，系列产品使用温度范围‑60～400℃，使用寿命长，可再生，可生物降解。The invention discloses an environmentally friendly synthetic low-coking and flame-resistant L-QB300 organic heat carrier composition, which uses a compound of 50% (m) polyalpha-olefin and 50% (m) triaryl phosphonate as the composition. Base oil, with a variety of compound additives. It includes: antioxidant preservatives, high-temperature antioxidants, antioxidants, metal deactivators, metal deactivators, scorch inhibitors, rust inhibitors, alkali value retainers, antifoam agents, reinforcing agents, and activation agent. Its advantages are: good thermal stability, the use temperature range of the series products is -60-400°C, long service life, renewable and biodegradable.
Description
技术领域technical field
本发明涉及一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物。The invention relates to an environmentally friendly synthetic low-coking and flame-resistant L-QB300 organic heat carrier composition.
背景技术Background technique
合成型有机热载体是以化学合成工艺生产的，具有一定化学结构和确定的化学名称的产品。根据最高允许使用温度，合成型有机热载体可分为普通合成型和具有特殊稳定性的合成型两类。其特点是热稳定性好，系列产品使用温度范围-60～400℃，使用寿命长，可再生，可生物降解。适用闭式和开式传热系统Synthetic organic heat transfer material is produced by chemical synthesis process and has a certain chemical structure and definite chemical name. According to the maximum allowable use temperature, synthetic organic heat transfer materials can be divided into ordinary synthetic type and synthetic type with special stability. It is characterized by good thermal stability, the temperature range of the series products is -60 ~ 400 ℃, long service life, renewable and biodegradable. Suitable for closed and open heat transfer systems
通常热载体传热有两种基本方式，一种是在初馏点或沸点温度以下液相传热，另一种是在沸点温度以上的气相传热。大部分的热载体为液相传热介质，最高使用温度分别为320℃和350℃。小部分热载体为气液相传热介质，最高使用温度可达400℃。液相传热气压低、安全性好，使用更为广泛；而气相传热性能满足更高的温度和控温精度要求，但不能完全为液相系统取代。Generally, there are two basic ways of heat transfer of heat carrier, one is liquid phase heat transfer below the initial boiling point or boiling point temperature, and the other is gas phase heat transfer above boiling point temperature. Most of the heat carriers are liquid-phase heat transfer media, and the maximum operating temperatures are 320°C and 350°C respectively. A small part of the heat carrier is a gas-liquid phase heat transfer medium, and the maximum operating temperature can reach 400°C. Liquid-phase heat transfer has low pressure, good safety, and is more widely used; while gas-phase heat transfer performance meets higher temperature and temperature control accuracy requirements, but it cannot be completely replaced by liquid-phase systems.
发明内容Contents of the invention
本发明提供了一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于：采用50％(m)的聚α-烯烃与50％(m)的三芳基膦酸酯的复合基础油作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：The invention provides an environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition, which is characterized in that: 50% (m) of polyalpha-olefin and 50% (m) of triaryl phosphonate Composite base oil is used as base oil, combined with a variety of composite additives, the composition of their respective mass percentages:
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于采用50％(m)的聚α-烯烃与50％(m)的三芳基膦酸酯的复合基础油作为基础油；Described a kind of environmental friendliness synthetic type low coking flame-resistant L-QB300 organic heat carrier composition, it is characterized in that adopting the composite of 50% (m) polyalpha-olefin and 50% (m) triaryl phosphonate base oil as base oil;
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于抗氧防腐剂是二烷基二硫代氨基甲酸酯；The environmentally friendly synthetic low-coking and flame-resistant L-QB300 organic heat carrier composition is characterized in that the antioxidant preservative is a dialkyl dithiocarbamate;
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于高温抗氧剂是高相对分子质量酚酯型(KT5135)；抗氧剂是胺类和高相对分子质量酚混合物(IrganoxL150)；Described a kind of environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the high-temperature antioxidant is a high relative molecular mass phenolic ester type (KT5135); the antioxidant is an amine and a high relative Molecular mass phenol mixture (IrganoxL150);
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于金属钝化剂是50％(m)的甲基甲酰三唑衍生物与50％(m)的硫基苯并咪唑；Described a kind of environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the metal deactivator is 50% (m) methyl formyl triazole derivatives and 50% (m) Sulfuryl benzimidazole;
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于金属减活剂是50％(m)的苯三唑衍生物(T551)与50％(m)的噻二唑衍生物(T561)；Described a kind of environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the metal deactivator is 50% (m) of benzotriazole derivatives (T551) and 50% (m) Thiadiazole derivatives (T561);
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于阻焦剂是50％(m)的硼化聚异丁烯双丁二酰亚胺(T154B)与50％(m)的聚丁烯丁二酰亚胺(T161)；防锈剂是50％(m)的石油碳酸钡(T701)与50％(m)的烯基丁二酸半酯(T747)；Described a kind of environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the scorch retarder is 50% (m) of borated polyisobutylene bis-succinimide (T154B) and 50 %(m) of polybutene succinimide (T161); rust inhibitor is 50% (m) of petroleum barium carbonate (T701) and 50% (m) of alkenyl succinate half ester (T747) ;
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于碱值保持剂是环烷酸镁(T111)；抗泡剂是甲基硅油(T901)；The environment-friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the alkali value retaining agent is magnesium naphthenate (T111); the antifoaming agent is methyl silicone oil (T901);
所述的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，其特征在于补强剂是二烷基二苯胺(T534)；增活剂是双烯基丁二酰亚胺(T152)。Described a kind of environmentally friendly synthetic low-coking flame-resistant L-QB300 organic heat carrier composition is characterized in that the reinforcing agent is dialkyl diphenylamine (T534); the activator is dienyl succinimide (T152).
本发明的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，热稳定性好，系列产品使用温度范围-60～400℃，使用寿命长，可再生，可生物降解。The environment-friendly synthetic low-coking and flame-resistant L-QB300 organic heat carrier composition of the present invention has good thermal stability, the service temperature range of the series products is -60-400°C, long service life, renewable and biodegradable.
具体实施方式detailed description
实施例1：Example 1:
将下列质量百分比调和而成：Blend the following mass percentages:
以上组分总和为100％。The sum of the above components is 100%.
实施例2：Example 2:
将下列质量百分比调和而成：Blend the following mass percentages:
以上组分总和为100％。The sum of the above components is 100%.
实施例3：Example 3:
将下列质量百分比调和而成：Blend the following mass percentages:
以上组分总和为100％。The sum of the above components is 100%.
实施例1、2、3产品的主要理化指标：The main physical and chemical index of embodiment 1,2,3 product:
本发明的一种环境友好合成型低结焦抗燃L-QB300有机热载体组合物，热稳定性好，系列产品使用温度范围-60～400℃，使用寿命长，可再生，可生物降解。The environment-friendly synthetic low-coking and flame-resistant L-QB300 organic heat carrier composition of the present invention has good thermal stability, the service temperature range of the series products is -60-400°C, long service life, renewable and biodegradable.
Claims (10)
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| WO2016044975A1 (en) * | 2014-09-22 | 2016-03-31 | Dow Global Technologies Llc | Thermal grease based on hyperbranched olefinic fluid |
| CN106010464A (en) * | 2016-06-14 | 2016-10-12 | 山东沾化莱斯特石油化工有限公司 | Environment-friendly conduction oil and preparation method thereof |
| CN106133109A (en) * | 2014-03-18 | 2016-11-16 | 旭硝子株式会社 | Heat circulating system compositions and heat circulating system |
-
2017
- 2017-02-21 CN CN201710093359.1A patent/CN106867469A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1955271A (en) * | 2001-01-04 | 2007-05-02 | 国际壳牌研究有限公司 | lubricating oil composition |
| CN102925256A (en) * | 2011-08-10 | 2013-02-13 | 中国石油化工股份有限公司 | Heat-conductive oil composition having high temperature oxidation resistance |
| CN103232837A (en) * | 2013-04-12 | 2013-08-07 | 广西大学 | Environment friendly energy-efficient heat conduction oil |
| CN106133109A (en) * | 2014-03-18 | 2016-11-16 | 旭硝子株式会社 | Heat circulating system compositions and heat circulating system |
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