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CN106866066A - It is non-burning brick that special soil body stabilizing agent recycling treatment municipal sludge is manufactured - Google Patents

It is non-burning brick that special soil body stabilizing agent recycling treatment municipal sludge is manufactured Download PDF

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Publication number
CN106866066A
CN106866066A CN201710034392.7A CN201710034392A CN106866066A CN 106866066 A CN106866066 A CN 106866066A CN 201710034392 A CN201710034392 A CN 201710034392A CN 106866066 A CN106866066 A CN 106866066A
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weight portions
burning brick
soil body
stabilizing agent
body stabilizing
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CN201710034392.7A
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CN106866066B (en
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包宗义
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a kind of the non-burning brick of special soil body stabilizing agent recycling treatment municipal sludge manufacture, this is non-burning brick to prepare primary compound of the material by 100 weight portions, the soil body stabilizing agent composition of the cement of 5 10 weight portions and 0.01 0.1 weight portions, the primary compound by 100 weight portions municipal wet mud, the quick lime of 15 20 weight portions, and solid waste composition, the soil body stabilizing agent by 100 weight portions water, the surfactant of 1 15 weight portions, boric acid or the borate composition of 0.1 10 weight portions, the consumption of the solid waste is 7 13 times of municipal wet mud and the mixed cumulative volume of quick lime.What is prepared is non-burning brick with good compression strength and water resistance.

Description

It is non-burning brick that special soil body stabilizing agent recycling treatment municipal sludge is manufactured
Technical field
The present invention relates to field of Environment Protection, in particular it relates to using special soil body stabilizing agent recycling treatment municipal sludge system That makes is non-burning brick.
Background technology
Municipal sludge refers to the clod or mud cake of discharge after the concentrated dehydration in municipal sewage plant, and general moisture content exists 80% or so, and containing nutrients such as abundant organic matters and N, P, K, also contain the nuisance such as heavy metal and pathogen Matter, if mishandling, not only easily causes environmental pollution, also can waste of resources is caused.With China's economy and urbanization Fast development, the generation of municipal wastewater and its quantity are sharply increased.
With being further exacerbated by for urbanization, the municipal sludge of China is more and more, is badly in need of a kind of new technique and technology, So that municipal sludge obtains disposal of resources.
The content of the invention
In order to solve the above problems, special soil body stabilizing agent recycling treatment municipal sludge is used the invention provides one kind Manufacture it is non-burning brick, it is described it is non-burning brick prepare material by the primary compound of 100 weight portions, the cement of 5-10 weight portions and The soil body stabilizing agent composition of 0.01-0.1 weight portions, municipal wet mud, 15-20 weight of the primary compound by 100 weight portions Measure part quick lime and solid waste composition, the soil body stabilizing agent by 100 weight portions water, the table of 1-15 weight portions Face activating agent, boric acid or the borate composition of 0.1-10 weight portions, the consumption of the solid waste is municipal wet mud and life 7-13 times of the mixed cumulative volume of lime.
The moisture content of the municipal wet mud is 70-85%.
The cement is 425# Portland cements.
The pH value of the soil body stabilizing agent is adjusted to 8-10.
The solid waste is one or more in metal tailings, industrial residue, building waste.
The surfactant is butyl naphthalene sulfonate.
Surfactant of the invention can be adsorbed in the surface of bulky grain, change the hydrophily of particle surface so that Grain has the effect of shield water, reduces the water imbibition of particle, and what is prepared is non-burning brick with good permeability resistance, and then has There is good compression strength.Present invention employs a small amount of cement, boric acid or borate are added, substantially increased non-burning brick Compression strength, employs soil body stabilizing agent of the invention, and the usage amount that can in large quantities reduce cement is unburned without reducing shaping The compression strength of brick.
The non-burning brick material for preparing also includes terminal hydroxy group siloxanes and the 0.001-0.005 weight of 0.01-0.8 weight portions Measure the curing agent of part.The curing agent is alpha-amido silane coupler, and terminal hydroxy group siloxanes, curing agent and soil body stabilizing agent are simultaneously Add to the second blending bunker.Using the solution of the present invention prepare it is non-burning brick be destitute of smell substantially, because sludge contains greatly The organic matter of amount, and oxygen-containing ratio is high, such organic matter easily sends corruption and discharges stink.Present invention employs can The terminal hydroxy group siloxanes of solidification can avoid mud organic substance that aminocarbonyl reaction occurs.
A kind of non-burning brick preparation method, comprises the following steps:
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, non-burning brick compound is obtained;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Due to containing substantial amounts of harmful bacteria, heavy metal in municipal sludge, it is impossible to used as agricultural fertilizer source.This hair It is bright directly to make non-burning brick using municipal wet mud, wet mud concentration, dewatering process are eliminated, high temperature sintering brickmaker is not used Skill, cost is substantially reduced.Making obtain it is non-burning brick meet national standard requirement, excellent mechanical.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Specific embodiment
Unless otherwise defined, all technologies used herein and scientific terminology have and the common skill of art of the present invention The identical implication that art personnel are generally understood that.When there is contradiction, the definition in this specification is defined.
Those methods that non-burning brick forming method of the invention can be commonly used using other prior arts are molded.City Particle diameter after the crushing of political affairs sludge is 0.1-2mm, when municipal sludge level is unfavorable for obtaining more preferable resistance to compression with powder particle size more than 2mm Intensity.The method mixed using two benches can improve non-burning brick mechanical strength.Compared with being mixed together, can improve and exempt from Bake bricks the compression strength of 10%-25% or so.
Hereinafter, the present invention is explained in more detail by embodiment, it should be appreciated that these embodiments are only Illustrate and it is nonrestrictive.If without other explanations, raw materials used is all commercially available.
The present invention is described in detail referring to several examples.
Embodiment 1
Municipal wet mud, the quick lime of 18 weight portions of 100 weight portions are added in the first blending bunker, sludge mixing is mixed to get Material;The water content of municipal wet mud is 70%, is the second pond sludge of Shanghai sewage treatment plant.
The solid waste of 9 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 21 days;
After the cement of primary compound, 6 weight portions after 100 weight portions are stacked mixes 10 minutes in the second blending bunker, then Add the soil body stabilizing agent of 0.018 weight portion to mix 10 minutes, obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Non-burning brick finished product(240×115×90)According to GB8239-97 test 5 pieces of non-burning brick compression strength average values and Monolithic compression strength minimum and water resistance.
Embodiment 2
Municipal wet mud, the quick lime of 18 weight portions of 100 weight portions are added in the first blending bunker, sludge mixing is mixed to get Material;The water content of municipal wet mud is 80%, is the second pond sludge of Xuzhou sewage treatment plant.
The solid waste of 9 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 21 days;
After the cement of primary compound, 6 weight portions after 100 weight portions are stacked mixes 10 minutes in the second blending bunker, then Add the soil body stabilizing agent of 0.018 weight portion to mix 10 minutes, obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Non-burning brick finished product(240×115×90)According to GB8239-97 test 5 pieces of non-burning brick compression strength average values and Monolithic compression strength minimum and water resistance.
Embodiment 3
Municipal wet mud, the quick lime of 18 weight portions of 100 weight portions are added in the first blending bunker, sludge mixing is mixed to get Material;The water content of municipal wet mud is 80%, is the primary sludge of Hangzhou sewage treatment plant.
The solid waste of 9 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 21 days;
After the cement of primary compound, 6 weight portions after 100 weight portions are stacked mixes 10 minutes in the second blending bunker, then Add the soil body stabilizing agent of 0.018 weight portion to mix 10 minutes, obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Non-burning brick finished product(240×115×90)According to GB8239-97 test 5 pieces of non-burning brick compression strength average values and Monolithic compression strength minimum and water resistance.
Embodiment 4
Municipal wet mud, the quick lime of 18 weight portions of 100 weight portions are added in the first blending bunker, sludge mixing is mixed to get Material;The water content of municipal wet mud is 80%, the sludge of the preliminary sedimentation tank of Yiwu sewage treatment plant.
The solid waste of 9 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 21 days;
After the cement of primary compound, 6 weight portions after 100 weight portions are stacked mixes 10 minutes in the second blending bunker, then Add the soil body stabilizing agent of 0.018 weight portion to mix 10 minutes, obtain non-burning brick compound;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
Non-burning brick finished product(240×115×90)According to GB8239-97 test 5 pieces of non-burning brick compression strength average values and Monolithic compression strength minimum and water resistance.
Embodiment 5-8
Identical with embodiment 1-4 respectively, different places is to add 0.3 weight in the lump in the second blending bunker and soil body stabilizing agent The terminal hydroxy group siloxanes of part and the anilinomethyl trimethoxy silane of 0.003 weight portion, the mixing time of the second blending bunker is 30 Minute.Non-burning brick finished product(240×115×90)5 pieces of non-burning brick compression strength average values and list are tested according to GB8239-97 Block compression strength minimum and water resistance.
Comparative example 1, it is same as Example 5, by the terminal hydroxy group siloxanes of 0.3 weight portion and the aniline first of 0.003 weight portion Base trimethoxy silane replaces with methyl-silicone oil.
As can be seen that the non-burning brick tool that the present invention is prepared using special soil body stabilizing agent disposal of resources municipal sludge There are good compression strength and water resistance, without using soil body stabilizing agent of the invention, the non-burning brick Mean Crush for preparing Intensity is 9.34, and coefficient of softing is 0.53.In addition after adding terminal hydroxy group siloxanes, be made it is non-burning brick go out mould after base Originally be destitute of smell, and prepared by embodiment 1-4 and comparative example 4 it is non-burning brick go out mould after all same with obvious stink.It is logical Comparative example is crossed it can also be seen that terminal hydroxy group siloxanes can avoid mud organic substance that aminocarbonyl reaction occurs.
The above, only presently preferred embodiments of the present invention is not intended to limit the scope of the present invention.It is every The impartial change done according to present invention and modification, are encompassed by the scope of the claims of the invention.

Claims (8)

1. it is a kind of using the non-burning brick of special soil body stabilizing agent recycling treatment municipal sludge manufacture, it is characterised in that described to exempt from Bake bricks prepare material by 100 weight portions primary compound, the cement of 5-10 weight portions and 0.01-0.1 weight portions soil Body stabilizer constitute, the primary compound by 100 weight portions municipal wet mud, the quick lime of 15-20 weight portions, Yi Jigu Body discarded object constitute, the soil body stabilizing agent by 100 weight portions water, the surfactant of 1-15 weight portions, 0.1-10 weight Boric acid or the borate composition of part, the consumption of the solid waste is municipal wet mud and the mixed cumulative volume of quick lime 7-13 times.
2. according to claim 1 a kind of using the unburned of special soil body stabilizing agent recycling treatment municipal sludge manufacture Brick, it is characterised in that the moisture content of the municipal wet mud is 70-85%.
3. according to a kind of the non-burning brick of use special soil body stabilizing agent recycling treatment municipal sludge manufacture described in claim 1, Characterized in that, the cement is 425# Portland cements.
4. according to a kind of the non-burning brick of use special soil body stabilizing agent recycling treatment municipal sludge manufacture described in claim 1, Characterized in that, the pH value of the soil body stabilizing agent is adjusted to 8-10.
5. according to a kind of the non-burning brick of use special soil body stabilizing agent recycling treatment municipal sludge manufacture described in claim 1, Characterized in that, the solid waste is one or more in metal tailings, industrial residue, building waste.
6. according to a kind of the non-burning brick of use special soil body stabilizing agent recycling treatment municipal sludge manufacture described in claim 1, Characterized in that, the surfactant is butyl naphthalene sulfonate.
7. according to a kind of the non-burning brick of use special soil body stabilizing agent recycling treatment municipal sludge manufacture described in claim 1, Characterized in that, the non-burning brick material for preparing also includes the terminal hydroxy group siloxanes and 0.001- of 0.01-0.8 weight portions The curing agent of 0.005 weight portion, the curing agent is alpha-amido silane coupler.
8. a kind of non-burning brick preparation method, it is characterised in that comprise the following steps:
Municipal wet mud, the quick lime of 15-20 weight portions of 100 weight portions are added in the first blending bunker, sludge is mixed to get Compound;
The solid waste of 7-13 times of sludge mixture volume is added in the first blending bunker, primary compound is mixed to get;
The primary compound is stacked 5-30 days;
The cement of primary compound, 5-10 weight portions after 100 weight portions are stacked mixes 3-15 minutes in the second blending bunker Afterwards, the soil body stabilizing agent mixing of 0.01-0.1 weight portions 3-15 minutes is added, non-burning brick compound is obtained;
Compressing, natural curing under non-burning brick compound normal temperature is obtained into non-burning brick finished product.
CN201710034392.7A 2017-01-18 2017-01-18 Baking-free brick manufactured by treating municipal sludge through special soil stabilizer resource Active CN106866066B (en)

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Application Number Priority Date Filing Date Title
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CN106866066B CN106866066B (en) 2020-01-17

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473661A (en) * 2017-08-31 2017-12-15 中冶华天工程技术有限公司 It is a kind of that non-burning brick method is produced as raw material using municipal sludge
CN110092614A (en) * 2019-05-14 2019-08-06 王青元 A kind of method of pressing civil engineering block from sludge solidification material
CN110655364A (en) * 2019-10-28 2020-01-07 长安大学 A kind of concrete containing pyrolyzed sludge and preparation method thereof
CN110981365A (en) * 2019-12-27 2020-04-10 山东易路建通环保新技术有限公司 Baking-free brick manufactured by sand washing mud and manufacturing method thereof
CN111018444A (en) * 2019-12-27 2020-04-17 山东易路建通环保新技术有限公司 Baking-free brick manufactured by adopting Xinjiang saline-alkali soil and manufacturing method thereof
CN111574131A (en) * 2020-06-12 2020-08-25 北京土木禾天环保科技有限公司 Baking-free brick for recycling saline-alkali soil by using soil curing agent and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104004525A (en) * 2014-06-09 2014-08-27 包宗义 Soil body stabilizer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104004525A (en) * 2014-06-09 2014-08-27 包宗义 Soil body stabilizer

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
赵丰毅: "城市污水处理厂污泥处置工艺分析与研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473661A (en) * 2017-08-31 2017-12-15 中冶华天工程技术有限公司 It is a kind of that non-burning brick method is produced as raw material using municipal sludge
CN110092614A (en) * 2019-05-14 2019-08-06 王青元 A kind of method of pressing civil engineering block from sludge solidification material
CN110655364A (en) * 2019-10-28 2020-01-07 长安大学 A kind of concrete containing pyrolyzed sludge and preparation method thereof
CN110981365A (en) * 2019-12-27 2020-04-10 山东易路建通环保新技术有限公司 Baking-free brick manufactured by sand washing mud and manufacturing method thereof
CN111018444A (en) * 2019-12-27 2020-04-17 山东易路建通环保新技术有限公司 Baking-free brick manufactured by adopting Xinjiang saline-alkali soil and manufacturing method thereof
CN111574131A (en) * 2020-06-12 2020-08-25 北京土木禾天环保科技有限公司 Baking-free brick for recycling saline-alkali soil by using soil curing agent and preparation method thereof

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