CN106854257A - A kind of hydrate colour adhesive agent emulsion - Google Patents
A kind of hydrate colour adhesive agent emulsion Download PDFInfo
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- CN106854257A CN106854257A CN201510901755.3A CN201510901755A CN106854257A CN 106854257 A CN106854257 A CN 106854257A CN 201510901755 A CN201510901755 A CN 201510901755A CN 106854257 A CN106854257 A CN 106854257A
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- adhesive agent
- hydrate colour
- agent emulsion
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Abstract
The present invention relates to the gluing Laminating adhesive technical field of composite paper-plastic material, more particularly to hydrate colour adhesive agent emulsion, its parts by weight of raw materials proportioning is soft monomer：5~9%；Hard monomer：31~38%；Polyvinyl alcohol：5~6%；Defoamer：0.9~1.2%；Crosslinking agent：0.04~0.1%；PH buffers modulator：0.6~7%；Organic toner：15~30%；The aqueous solution：30~45%；Technical solution of the present invention hydrate colour adhesive agent emulsion has viscous force strong, and rate of drying is fast, and peel strength is high, glossiness is good, nontoxic, tasteless, non-ignitable, energy-conservation the features such as, product combination property stabilization of the present invention；It is easy to manufacture and promotes the use of, with wide market prospects.
Description
Technical field
The present invention relates to the gluing Laminating adhesive technical field of composite paper-plastic material, more particularly to a kind of hydrate colour adhesive agent emulsion.
Background technology
Paper-plastic stick is combined with each other polypropylene screen or polyester film with paper printing piece using adhesive so that printed matter is attractive in appearance, brightness is high, and with waterproof, protection against the tide, folding, it is wear-resisting the features such as.Paper-plastic lamination adhesive currently used in the market is divided into two kinds：Solvent-borne type and emulsion type.The subject matter of solvent-type film-covered adhesive is, still largely using toxic solvent and diluents such as toluene, dimethylbenzene, not only the healthy of operator to be caused serious harm, and inflammable, explosive, and transport and storage are extremely inconvenient.Emulsion type Laminating adhesive is with low cost with water as continuous phase, environment-friendly, using progressively extensively, but initial bonding strength is small, and water resistance and alkali resistance are poor, and adhesive strength is not high.
Meanwhile, current laminating adhesive technique includes pre-coating film, dry laminating, wet method complex technique.Wherein pre-coating film is because high cost less use at present, the cold patch technique of wet method compound use water soluble adhesive, dry laminating tradition laminating adhesive technique is that solvent-borne type glue is directly applied in BOPP film, after being dried through drying tunnel, pressed with printed matter in the case of temperature-pressure, due to using inflammable, toxic solvent, larger harm is brought to workman and environment, and easily trigger fire.
With the fast development of printing technology, the application field of laminating adhesive technique is increasingly extensive, and its post-press finishing technique is also faced with increasing technological challenge.Improve the performance and reduces cost of Laminating adhesive, it has also become the task of top priority of numerous domestic producer.At present, the production technology of Laminating adhesive is highly developed, and its performance and cost are closely related, therefore can not be to reduce performance as cost while reduces cost.
The content of the invention
The present invention is in view of above-mentioned technical problem, there is provided a kind of a kind of hydrate colour adhesive agent emulsion for being applied to hydrate colour Laminating adhesive；Adhesive agent emulsion has viscous force strong in technical solution of the present invention, and rate of drying is fast, and peel strength is high, glossiness is good, nontoxic, tasteless, non-ignitable, energy-conservation the features such as, product combination property stabilization of the present invention；It is easy to manufacture and promotes the use of, with wide market prospects.
A kind of hydrate colour adhesive agent emulsion, wherein, the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：5~9%；
Hard monomer：31~38%；
Polyvinyl alcohol：5~6%；
Defoamer：0.9~1.2%；
Crosslinking agent：0.04~0.1%；
PH buffers modulator：0.6~7%；
Organic toner：15~30%；
The aqueous solution：30~45%.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：4~7%；
Hard monomer：34~36%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.09%；
PH buffers modulator：0.8~3%；
Organic toner：25~30%；
The aqueous solution：35~44%.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：5%；
Hard monomer：35%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.08%；
PH buffers modulator：0.8~2.8%；
Organic toner：23~29%；
The aqueous solution：37~43%.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, the soft monomer includes methyl methacrylate or vinylacetate.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, the hard monomer includes butyl acrylate or ethyl acrylate or Isooctyl acrylate monomer.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, the defoamer is organosiloxane.
Preferably, above-mentioned hydrate colour adhesive agent emulsion, wherein, crosslinking agent is organic dibasic acid, polyalcohol, N- methylene-bisacrylamides or diisocyanate.
Above-mentioned technical proposal has the following advantages that or beneficial effect：
（1）Hydrate colour adhesive agent emulsion viscous force is strong, and peel strength is high, and glossiness is good and is easily dried；
（2）Easy melt water, nontoxic without organic solvents such as benzene, dichloroethanes, no pollution discharge, environmental protection in production process；
（3）Brightness is good, can impression, embossing, concavo-convex etc., bubble-free, good toughness is smooth attractive in appearance, makes moist and do not come unglued, combination property stabilization.
Specific embodiment
The present invention is further illustrated with specific embodiment below in conjunction with the accompanying drawings, but not as limiting to the invention.
Embodiment 1：
In view of paper-plastic lamination adhesive currently used in the market is divided into two kinds：Solvent-borne type and emulsion type.The subject matter of solvent-type film-covered adhesive is, still largely using toxic solvent and diluents such as toluene, dimethylbenzene, not only the healthy of operator to be caused serious harm, and inflammable, explosive, and transport and storage are extremely inconvenient.Emulsion type Laminating adhesive is with low cost with water as continuous phase, environment-friendly, using progressively extensively, but initial bonding strength is small, and water resistance and alkali resistance are poor, and adhesive strength is not high.In consideration of it, the invention provides a kind of novel aqueous colored adhesive emulsion, the hydrate colour adhesive agent emulsion has viscous force strong, rate of drying is fast, peel strength is high, glossiness is good, nontoxic, tasteless, non-ignitable, energy-conservation the features such as, product combination property of the present invention stabilization；It is easy to manufacture and promotes the use of, it is specific as follows with wide market prospects.
A kind of hydrate colour adhesive agent emulsion mainly includes the raw materials such as soft monomer, hard monomer, polyvinyl alcohol, defoamer, crosslinking agent, PH bufferings modulator, organic toner and the aqueous solution and constitutes, specifically, the parts by weight of raw materials of the hydrate colour Laminating adhesive is matched, unit（g）：
Soft monomer：5~9%；
Hard monomer：31~38%；
Polyvinyl alcohol：5~6%；
Defoamer：0.9~1.2%；
Crosslinking agent：0.04~0.1%；
PH buffers modulator：0.6~7%；
Organic toner：15~30%；
The aqueous solution：30~45%.
For example, soft monomer：5g；Hard monomer：31g；Polyvinyl alcohol：5g；Defoamer：0.9g；
Crosslinking agent：0.04g；PH buffers modulator：0.6g；Organic toner：15g；The aqueous solution：30g.Again for example, soft monomer：9g；Hard monomer：38g；Polyvinyl alcohol：6g；Defoamer：1.2g；Crosslinking agent：0.1g；PH buffers modulator：7g；Organic toner：30g；The aqueous solution：40g.
In an embodiment of the present invention, soft monomer includes any one in methyl methacrylate or vinylacetate.Described hard monomer includes any one in butyl acrylate, ethyl acrylate, Isooctyl acrylate monomer.Preferably, described defoamer be organosiloxane, or organosiloxane, polyethers, silicon and ether grafting, the mix preparation containing amine, imines and amide-type.Simultaneously
Crosslinking agent is the compound that organic dibasic acid, polyalcohol, N- methylene-bisacrylamides or diisocyanate equimolecular are contained within multiple unsaturated double-bonds.
Embodiment 2：
A kind of hydrate colour adhesive agent emulsion mainly includes the raw materials such as soft monomer, hard monomer, polyvinyl alcohol, defoamer, crosslinking agent, PH bufferings modulator, organic toner and the aqueous solution and constitutes, specifically, the parts by weight of raw materials of the hydrate colour Laminating adhesive is matched, unit（g）：
Soft monomer：4~7%；
Hard monomer：34~36%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.09%；
PH buffers modulator：0.8~3%；
Organic toner：25~30%；
The aqueous solution：35~44%.
For example, soft monomer：4g；Hard monomer：34g；Polyvinyl alcohol：5g；Defoamer：0.9g；
Crosslinking agent：0.07g；PH buffers modulator：0.8g；Organic toner：25g；The aqueous solution：35g.Again for example, soft monomer：6g；Hard monomer：35g；Polyvinyl alcohol：5g；Defoamer：1.0g；Crosslinking agent：0.09g；PH buffers modulator：3g；Organic toner：30g；The aqueous solution：37g.
Embodiment 3：
A kind of hydrate colour adhesive agent emulsion mainly includes the raw materials such as soft monomer, hard monomer, polyvinyl alcohol, defoamer, crosslinking agent, PH bufferings modulator, organic toner and the aqueous solution and constitutes, specifically, the parts by weight of raw materials of the hydrate colour Laminating adhesive is matched, unit（g）：
Soft monomer：5%；
Hard monomer：35%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.08%；
PH buffers modulator：0.8~2.8%；
Organic toner：23~29%；
The aqueous solution：37~43%.
For example, soft monomer：5g；Hard monomer：35g；Polyvinyl alcohol：5g；Defoamer：0.9g；
Crosslinking agent：0.07g；PH buffers modulator：0.8g；Organic toner：23g；The aqueous solution：37g.Again for example, soft monomer：5g；Hard monomer：35g；Polyvinyl alcohol：5g；Defoamer：1.1g；Crosslinking agent：0.08g；PH buffers modulator：2.3g；Organic toner：25g；The aqueous solution：40g.
It is of the invention to be had the following advantages that compared with traditional hydrate colour adhesive agent emulsion：
（1）Hydrate colour adhesive agent emulsion viscous force is strong, and peel strength is high, and glossiness is good and is easily dried；
（2）Easy melt water, nontoxic without organic solvents such as benzene, dichloroethanes, no pollution discharge, environmental protection in production process；
（3）Brightness is good, can impression, embossing, concavo-convex etc., bubble-free, good toughness is smooth attractive in appearance, makes moist and do not come unglued, combination property stabilization.
It should be appreciated by those skilled in the art that those skilled in the art can realize the change case in combination prior art and above-described embodiment, will not be described here.Such change case has no effect on substance of the invention, will not be described here.
Presently preferred embodiments of the present invention is described above.It is to be appreciated that the present invention is not limited to the above specific embodiments, wherein the equipment and structure that do not describe in detail to the greatest extent are construed as being practiced with the common mode in this area；Any those of ordinary skill in the art, in the case where technical solution of the present invention ambit is not departed from, many possible variations and modification are all made to technical solution of the present invention using the methods and techniques content of the disclosure above, or the Equivalent embodiments of equivalent variations are revised as, this has no effect on substance of the invention.Therefore, every content without departing from technical solution of the present invention, according to technical spirit of the invention to any simple modification, equivalent variation and modification made for any of the above embodiments, still falls within the range of technical solution of the present invention protection.
Claims (7)
1. a kind of hydrate colour adhesive agent emulsion, it is characterised in that the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：5~9%；
Hard monomer：31~38%；
Polyvinyl alcohol：5~6%；
Defoamer：0.9~1.2%；
Crosslinking agent：0.04~0.1%；
PH buffers modulator：0.6~7%；
Organic toner：15~30%；
The aqueous solution：30~45%.
2. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：4~7%；
Hard monomer：34~36%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.09%；
PH buffers modulator：0.8~3%；
Organic toner：25~30%；
The aqueous solution：35~44%.
3. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that the parts by weight of raw materials proportioning of the hydrate colour adhesive agent emulsion is：
Soft monomer：5%；
Hard monomer：35%；
Polyvinyl alcohol：5%；
Defoamer：0.9~1.1%；
Crosslinking agent：0.07~0.08%；
PH buffers modulator：0.8~2.8%；
Organic toner：23~29%；
The aqueous solution：37~43%.
4. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that the soft monomer includes methyl methacrylate or vinylacetate.
5. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that the hard monomer includes butyl acrylate or ethyl acrylate or Isooctyl acrylate monomer.
6. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that the defoamer is organosiloxane.
7. hydrate colour adhesive agent emulsion according to claim 1, it is characterised in that crosslinking agent is organic dibasic acid, polyalcohol, N- methylene-bisacrylamides or diisocyanate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510901755.3A CN106854257A (en) | 2015-12-09 | 2015-12-09 | A kind of hydrate colour adhesive agent emulsion |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510901755.3A CN106854257A (en) | 2015-12-09 | 2015-12-09 | A kind of hydrate colour adhesive agent emulsion |
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| CN106854257A true CN106854257A (en) | 2017-06-16 |
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| CN201510901755.3A Pending CN106854257A (en) | 2015-12-09 | 2015-12-09 | A kind of hydrate colour adhesive agent emulsion |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577040A (en) * | 2018-11-05 | 2019-04-05 | 合肥聚合辐化技术有限公司 | A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness |
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|---|---|---|---|---|
| CN1651539A (en) * | 2004-12-15 | 2005-08-10 | 上海大学 | Polymerized polyisocyanate crosslinked water-based vinyl emulsion adhesive and preparation method thereof |
| CN101565593A (en) * | 2009-05-21 | 2009-10-28 | 上海东和胶粘剂有限公司 | Integrated material wood-splicing adhesive and preparation method thereof |
| CN101717467A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for pearlized film composite materials and preparation method thereof |
| CN101984010A (en) * | 2010-10-20 | 2011-03-09 | 韩志龙 | Multipurpose environmental protection adhesive for industrial use |
| CN103275655A (en) * | 2013-05-29 | 2013-09-04 | 廊坊三利木业有限公司 | One-component laminating glue |
| CN103289610A (en) * | 2013-06-13 | 2013-09-11 | 廊坊三利木业有限公司 | Environmentally-friendly quick-drying waterproof veneering glue |
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2015
- 2015-12-09 CN CN201510901755.3A patent/CN106854257A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1651539A (en) * | 2004-12-15 | 2005-08-10 | 上海大学 | Polymerized polyisocyanate crosslinked water-based vinyl emulsion adhesive and preparation method thereof |
| CN101565593A (en) * | 2009-05-21 | 2009-10-28 | 上海东和胶粘剂有限公司 | Integrated material wood-splicing adhesive and preparation method thereof |
| CN101717467A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for pearlized film composite materials and preparation method thereof |
| CN101984010A (en) * | 2010-10-20 | 2011-03-09 | 韩志龙 | Multipurpose environmental protection adhesive for industrial use |
| CN103275655A (en) * | 2013-05-29 | 2013-09-04 | 廊坊三利木业有限公司 | One-component laminating glue |
| CN103289610A (en) * | 2013-06-13 | 2013-09-11 | 廊坊三利木业有限公司 | Environmentally-friendly quick-drying waterproof veneering glue |
Non-Patent Citations (1)
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| 杨玉昆: "《压敏胶制品技术手册》", 30 September 2004, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109577040A (en) * | 2018-11-05 | 2019-04-05 | 合肥聚合辐化技术有限公司 | A kind of pigment printing binding agent and preparation method thereof bright in luster and excellent fastness |
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Application publication date: 20170616 |