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CN106833523B - Anti frozen liquid for bituminous paving and preparation method thereof - Google Patents

Anti frozen liquid for bituminous paving and preparation method thereof Download PDF

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CN106833523B
CN106833523B CN201611228046.4A CN201611228046A CN106833523B CN 106833523 B CN106833523 B CN 106833523B CN 201611228046 A CN201611228046 A CN 201611228046A CN 106833523 B CN106833523 B CN 106833523B
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asphalt pavement
sodium chloride
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CN106833523A (en
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陈渊召
李振霞
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North China University of Water Resources and Electric Power
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North China University of Water Resources and Electric Power
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C09K3/185Thawing materials

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Abstract

The invention discloses a kind of anti frozen liquids for bituminous paving, are made of the raw material of following parts by weight:10~20 parts of potassium formate, 5~10 parts of sodium chloride, 5~10 parts of ethylene glycol, 1~3 part of dipotassium hydrogen phosphate, 1~2 part of croscarmellose sodium, 0.1~0.5 part of sodium lignin sulfonate, 0.1~0.5 part of EDETATE SODIUM, 0.02~0.05 part of acrylate copolymer, 0.1~0.5 part of potassium hydroxide, 0.1~0.2 part of dimethyl silicone polymer, 60~80 parts of water.The present invention is less than 30 DEG C for the freezing point of the anti frozen liquid of bituminous paving; it can be good at carrying out anti-frost protection to bituminous paving; and be largely the organic material that can be degraded by microorganisms in material used, the content of inorganic salts is low, smaller to the harm brought of bituminous paving and environment.

Description

用于沥青路面的抗冻液及其制备方法Antifreeze liquid for asphalt pavement and preparation method thereof

技术领域technical field

本发明涉及道路路面防冻除冰技术领域,具体涉及一种用于沥青路面的抗冻液及其制备方法。The invention relates to the field of road pavement antifreeze and deicing technology, in particular to an antifreeze liquid for asphalt pavement and a preparation method thereof.

背景技术Background technique

交通运输是国民经济的动脉,对整个国民经济发展起着不可估量的作用,然而冬季降雪结冰严重的影响了道路的运输效率以及交通安全,有时甚至会导致封闭交通。Transportation is the artery of the national economy and plays an inestimable role in the development of the entire national economy. However, snow and ice in winter seriously affect the efficiency of road transportation and traffic safety, and sometimes even lead to closed traffic.

传统清除沥青路面积雪的方法主要是采用人工、机械铲除或撒布融雪盐等被动除冰技术,不仅劳动强度大、使用效果滞后,而且融雪盐也对道路结构、植被和生态环境造成严重破坏。主动的除冰雪技术一般是在沥青混拌料中添加防冻除冰材料,但是由于这种材料永久性的存在于路面,在气温较高时,容易快速挥发失效,从而导致沥青路面的抗冻功能减弱,作用时间变短。Traditional methods of removing snow on asphalt roads mainly use passive deicing techniques such as manual, mechanical removal or spraying snow-melting salt, which is not only labor-intensive and the effect is lagging behind, but also snow-melting salt also causes serious damage to the road structure, vegetation and ecological environment. Active snow and ice removal technology generally adds antifreeze and deicing materials to the asphalt mixture. However, since this material permanently exists on the road surface, it is easy to evaporate quickly and fail when the temperature is high, resulting in the antifreeze function of the asphalt pavement. weakened, and the duration of action is shortened.

发明内容Contents of the invention

本发明提供了一种用于沥青路面的抗冻液及其制备方法,解决了现有被动的除冰雪技术中沥青路面的抗冻材料对道路以及生态环境破坏严重的问题,以及主动的除冰雪技术中,沥青路面的抗冻材料容易高温失效,持效期短的问题。The invention provides an antifreeze liquid for asphalt pavement and a preparation method thereof, which solves the problem that the antifreeze material of asphalt pavement seriously damages the road and the ecological environment in the existing passive snow and ice removal technology, and actively removes ice and snow In technology, the antifreeze material of asphalt pavement is easy to fail at high temperature and has a short duration.

为解决上述技术问题,本发明采用如下技术方案:In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:

设计一种用于沥青路面的抗冻液,由以下重量份的原料制成:甲酸钾10~20份、氯化钠5~10份、乙二醇5~10份、磷酸氢二钾1~3份、交联羧甲基纤维素钠1~2份、木质素磺酸钠0.1~0.5份、EDTA二钠0.1~0.5份、丙烯酸聚合物0.02~0.05份、氢氧化钾0.1~0.5份、聚二甲基硅氧烷0.1~0.2份、水60~80份。Design an antifreeze solution for asphalt pavement, which is made of the following raw materials in parts by weight: 10-20 parts of potassium formate, 5-10 parts of sodium chloride, 5-10 parts of ethylene glycol, and 1-20 parts of dipotassium hydrogen phosphate 3 parts, 1-2 parts of croscarmellose sodium, 0.1-0.5 parts of sodium lignosulfonate, 0.1-0.5 parts of disodium EDTA, 0.02-0.05 parts of acrylic acid polymer, 0.1-0.5 parts of potassium hydroxide, 0.1-0.2 parts of polydimethylsiloxane, 60-80 parts of water.

在上述技术方案中,盐氯化钠作为无机融雪剂,对沥青道路具备一定的抗冻防冰保护能力,但是它对大型公共基础设施具有一定的腐蚀作用,还容易造成生态环境的破坏,这里氯化钠的用量较少;同时,添加了作为缓蚀剂的磷酸氢二钾来降低减缓这种破坏作用,并且磷酸氢二钾中含有植物生长所需的营养元素磷和钾,在抗冻液随雨水或融雪流到道路两边使,还会为路边的绿化植物提供养分。In the above technical solution, salt sodium chloride is used as an inorganic snow-melting agent, which has a certain anti-freeze and anti-icing protection ability for asphalt roads, but it has a certain corrosion effect on large-scale public infrastructure, and it is easy to cause damage to the ecological environment. Here The amount of sodium chloride is less; at the same time, dipotassium hydrogen phosphate as a corrosion inhibitor is added to reduce and slow down this damage, and dipotassium hydrogen phosphate contains the nutrients phosphorus and potassium required for plant growth, which are important in frost resistance. The liquid flows to both sides of the road with rainwater or snowmelt, and also provides nutrients for the green plants on the roadside.

甲酸钾是一种有机融雪剂,对沥青道路基本没有腐蚀损害,但其冰点较高,不易在气温偏低地区使用;而添加乙二醇作为防冻剂,一方面可以可氯化钠和甲酸钠协同作用,起到更好的抗冻效果,另一方面其作为一种有机的具备一定黏度的液体,与氯化钠和甲酸钠混合在一起,可以起到缓释的作用。添加少量的丙烯酸聚合物可以增加粘性,使各有效成分缓慢释放,进一步增加了抗冻液的缓释性;在配方中添加氢氧化钾来中和丙烯酸聚合物的酸性,并添加了EDTA二钠来降低黏度,使其黏度保持在一个合适的范围内。Potassium formate is an organic deicing agent, which basically has no corrosion damage to asphalt roads, but its freezing point is high, so it is not easy to use in low temperature areas; adding ethylene glycol as antifreeze, on the one hand, can synergize with sodium chloride and sodium formate It has a better antifreeze effect. On the other hand, as an organic liquid with a certain viscosity, it can be mixed with sodium chloride and sodium formate to play a slow-release role. Adding a small amount of acrylic polymer can increase the viscosity, so that the active ingredients can be released slowly, further increasing the slow release of antifreeze; adding potassium hydroxide to the formula to neutralize the acidity of the acrylic polymer, and adding disodium EDTA To reduce the viscosity and keep its viscosity in an appropriate range.

交联羧甲基纤维素钠具有一定的保水性和缓释性,能够使产品中有效成分缓慢释放,长久的发生功效;木质素磺酸钠是一种阴离子表面活性剂,能够使配方中的无机物和有机物均匀的混合在一起;聚二甲基硅氧烷是一种消泡剂,能够降低产品表面张力,使其在使用时更容易渗透进入沥青内,长久的发生功效。Croscarmellose sodium has certain water retention and slow-release properties, which can slowly release the active ingredients in the product and produce long-term effects; sodium lignosulfonate is an anionic surfactant, which can make the active ingredients in the formula Inorganic matter and organic matter are evenly mixed together; polydimethylsiloxane is a kind of defoamer, which can reduce the surface tension of the product, making it easier to penetrate into the asphalt during use, and have a long-term effect.

优选的,由以下重量份的原料制成:甲酸钾10份、氯化钠5份、乙二醇10份、磷酸氢二钾1份、交联羧甲基纤维素钠2份、木质素磺酸钠0.5份、EDTA二钠0.1份、丙烯酸聚合物0.02份、氢氧化钾0.2份、聚二甲基硅氧烷0.2份、水60份。Preferably, it is made from the following raw materials in parts by weight: 10 parts of potassium formate, 5 parts of sodium chloride, 10 parts of ethylene glycol, 1 part of dipotassium hydrogen phosphate, 2 parts of croscarmellose sodium, lignin sulfonate 0.5 parts of sodium phosphate, 0.1 parts of disodium EDTA, 0.02 parts of acrylic acid polymer, 0.2 parts of potassium hydroxide, 0.2 parts of polydimethylsiloxane, and 60 parts of water.

优选的,由以下重量份的原料制成:甲酸钾20份、氯化钠8份、乙二醇5份、磷酸氢二钾2份、交联羧甲基纤维素钠1份、木质素磺酸钠0.3份、EDTA二钠0.3份、丙烯酸聚合物0.05份、氢氧化钾0.5份、聚二甲基硅氧烷0.15份、水80份。Preferably, it is made from the following raw materials in parts by weight: 20 parts of potassium formate, 8 parts of sodium chloride, 5 parts of ethylene glycol, 2 parts of dipotassium hydrogen phosphate, 1 part of croscarmellose sodium, lignin sulfonate 0.3 parts of sodium phosphate, 0.3 parts of disodium EDTA, 0.05 parts of acrylic acid polymer, 0.5 parts of potassium hydroxide, 0.15 parts of polydimethylsiloxane, and 80 parts of water.

优选的,由以下重量份的原料制成:甲酸钾15份、氯化钠10份、乙二醇8份、磷酸氢二钾3份、交联羧甲基纤维素钠2份、木质素磺酸钠0.1份、EDTA二钠0.5份、丙烯酸聚合物0.03份、氢氧化钾0.3份、聚二甲基硅氧烷0.1份、水70份。Preferably, it is made from the following raw materials in parts by weight: 15 parts of potassium formate, 10 parts of sodium chloride, 8 parts of ethylene glycol, 3 parts of dipotassium hydrogen phosphate, 2 parts of croscarmellose sodium, lignin sulfonate 0.1 part of sodium phosphate, 0.5 part of disodium EDTA, 0.03 part of acrylic acid polymer, 0.3 part of potassium hydroxide, 0.1 part of polydimethylsiloxane, and 70 parts of water.

本发明还涉及上述用于沥青路面的抗冻液的制备方法,包括下列步骤:The present invention also relates to the preparation method of the above-mentioned antifreeze liquid for asphalt pavement, comprising the following steps:

(1)按以下重量份称取各原料:甲酸钾10~20份、氯化钠5~10份、乙二醇5~10份、磷酸氢二钾1~3份、交联羧甲基纤维素钠1~2份、木质素磺酸钠0.1~0.5份、EDTA二钠0.1~0.5份、丙烯酸聚合物0.02~0.05份、氢氧化钾0.1~0.5份、聚二甲基硅氧烷0.1~0.2份、水60~80份;(1) Weigh each raw material according to the following parts by weight: 10-20 parts of potassium formate, 5-10 parts of sodium chloride, 5-10 parts of ethylene glycol, 1-3 parts of dipotassium hydrogen phosphate, cross-linked carboxymethyl fiber 1-2 parts of sodium sulfonate, 0.1-0.5 parts of sodium lignosulfonate, 0.1-0.5 parts of disodium EDTA, 0.02-0.05 parts of acrylic acid polymer, 0.1-0.5 parts of potassium hydroxide, 0.1-0.5 parts of polydimethylsiloxane 0.2 parts, 60-80 parts of water;

(2)将所述丙烯酸聚合物浸泡在步骤(1)中称取的水中,静置1~2h,然后以1000r/min的速度搅拌30~60min,得到胶液;(2) Soak the acrylic acid polymer in the water weighed in step (1), let it stand for 1-2 hours, and then stir at a speed of 1000r/min for 30-60 minutes to obtain glue;

(3)在500r/min的搅拌速度下,向步骤(2)所得的胶液中加入所述乙二醇,搅拌10~30min后再加入所述氢氧化钾,待氢氧化钾完全溶解后再加入EDTA二钠,待EDTA二钠完全溶解后再搅拌10~30min,得到醇、水混合液;(3) At a stirring speed of 500r/min, add the ethylene glycol to the glue obtained in step (2), stir for 10 to 30 minutes, then add the potassium hydroxide, and wait until the potassium hydroxide is completely dissolved. Add disodium EDTA, and stir for 10-30 minutes after the disodium EDTA is completely dissolved to obtain a mixture of alcohol and water;

(4)在100r/min的搅拌速度下,向步骤(3)所得的醇、水混合液中加入所述甲酸钾和氯化钠,待甲酸钾、氯化钠完全溶解后再搅拌10~30min,得到醇、盐混合液;(4) At a stirring speed of 100r/min, add the potassium formate and sodium chloride to the alcohol-water mixture obtained in step (3), and stir for 10 to 30 minutes after the potassium formate and sodium chloride are completely dissolved , to obtain alcohol-salt mixture;

(5)向步骤(4)所得的醇、盐混合液中加入磷酸氢二钾、交联羧甲基纤维素钠、木质素磺酸钠和聚二甲基硅氧烷,再以100r/min的速度搅拌30~60min,即得到所述用于沥青路面的抗冻液。(5) Add dipotassium hydrogen phosphate, croscarmellose sodium, sodium lignin sulfonate and polydimethylsiloxane to the alcohol-salt mixture obtained in step (4), and then use 100r/min Stir at a speed of 30-60 minutes to obtain the antifreeze liquid for asphalt pavement.

本发明的有益效果在于:The beneficial effects of the present invention are:

1.本发明用于沥青路面的抗冻液,采用无机冰点降低剂和有机冰点降低剂相结合来抗冻防冰,抗冻防冰效果优于单纯的有机抗冻剂,而且相对于无机抗冻剂来说,对沥青道路的损害小,对环境的危害也小。1. The present invention is used for the antifreeze liquid of asphalt pavement, adopts inorganic freezing point depressant and organic freezing point depressant to combine antifreeze and antiicing, antifreezing and antiicing effect is better than simple organic antifreezing agent, and with respect to inorganic antifreezing agent As for the refrigerant, the damage to the asphalt road is small, and the harm to the environment is also small.

2.本发明用于沥青路面的抗冻液的冰点小于-30℃,能够很好的对沥青路面进行防冻保护,且所用的材料中大部分是可以被微生物降解的有机材料,无机盐的含量低,对沥青道路以及环境的带来的危害较小。2. The freezing point of the antifreeze liquid used for asphalt pavement of the present invention is less than -30°C, which can effectively protect asphalt pavement from freezing, and most of the materials used are organic materials that can be degraded by microorganisms, and the content of inorganic salts Low, less harm to asphalt roads and the environment.

3.本发明用于沥青路面的抗冻液只需要在气温降低、路面容易结冰的时候喷洒,避免了高温失效的风险,解决了现有技术中在沥青混拌料中添加防冻除冰材料容易在高温条件下失效的问题,并且由于添加了乙二醇、丙烯酸聚合物以及交联羧甲基纤维素钠,能够使产品中的有效成分缓慢释放,效用持久。3. The antifreeze liquid used in the asphalt pavement of the present invention only needs to be sprayed when the temperature drops and the road surface is easy to freeze, which avoids the risk of high temperature failure and solves the problem of adding antifreeze and deicing materials to the asphalt mixture in the prior art The problem that it is easy to fail under high temperature conditions, and because of the addition of ethylene glycol, acrylic acid polymer and cross-linked carmellose sodium, the active ingredients in the product can be released slowly and the effect is long-lasting.

具体实施方式Detailed ways

下面结合实施例来说明本发明的具体实施方式,但以下实施例只是用来详细说明本发明,并不以任何方式限制本发明的范围。在以下实施例中所涉及的仪器设备如无特别说明,均为常规仪器设备;所涉及的工业原料如无特别说明,均为市售常规工业原料。The specific implementation of the present invention will be described below in conjunction with the examples, but the following examples are only used to describe the present invention in detail, and do not limit the scope of the present invention in any way. Unless otherwise specified, the instruments and equipment involved in the following examples are conventional instruments and equipment; the involved industrial raw materials are commercially available conventional industrial raw materials unless otherwise specified.

实施例1:一种用于沥青路面的抗冻液,由以下重量份的原料制成:甲酸钾10份、氯化钠5份、乙二醇10份、磷酸氢二钾1份、交联羧甲基纤维素钠2份、木质素磺酸钠0.5份、EDTA二钠0.1份、丙烯酸聚合物0.02份、氢氧化钾0.2份、聚二甲基硅氧烷0.2份、水60份。Embodiment 1: A kind of antifreeze liquid for asphalt pavement is made of the following raw materials in parts by weight: 10 parts of potassium formate, 5 parts of sodium chloride, 10 parts of ethylene glycol, 1 part of dipotassium hydrogen phosphate, cross-linked 2 parts of sodium carboxymethyl cellulose, 0.5 parts of sodium lignosulfonate, 0.1 part of disodium EDTA, 0.02 parts of acrylic acid polymer, 0.2 parts of potassium hydroxide, 0.2 parts of polydimethylsiloxane, and 60 parts of water.

其制备方法包括下列步骤:Its preparation method comprises the following steps:

(1)按以下重量份称取各原料:甲酸钾10份、氯化钠5份、乙二醇10份、磷酸氢二钾1份、交联羧甲基纤维素钠2份、木质素磺酸钠0.5份、EDTA二钠0.1份、丙烯酸聚合物0.02份、氢氧化钾0.2份、聚二甲基硅氧烷0.2份、水60份。(1) Weigh each raw material according to the following parts by weight: 10 parts of potassium formate, 5 parts of sodium chloride, 10 parts of ethylene glycol, 1 part of dipotassium hydrogen phosphate, 2 parts of croscarmellose sodium, lignin sulfonate 0.5 parts of sodium phosphate, 0.1 parts of disodium EDTA, 0.02 parts of acrylic acid polymer, 0.2 parts of potassium hydroxide, 0.2 parts of polydimethylsiloxane, and 60 parts of water.

(2)将所述丙烯酸聚合物浸泡在步骤(1)中称取的水中,静置1h,然后以1000r/min的速度搅拌30min,得到胶液。(2) Soak the acrylic acid polymer in the water weighed in step (1), let it stand for 1 hour, and then stir it at a speed of 1000 r/min for 30 minutes to obtain a glue solution.

(3)在500r/min的搅拌速度下,向步骤(2)所得的胶液中加入所述乙二醇,搅拌10min后再加入所述氢氧化钾,待氢氧化钾完全溶解后再加入EDTA二钠,待EDTA二钠完全溶解后再搅拌30min,得到醇、水混合液。(3) At a stirring speed of 500r/min, add the ethylene glycol to the glue obtained in step (2), stir for 10 minutes, then add the potassium hydroxide, and then add EDTA after the potassium hydroxide is completely dissolved Disodium, after the disodium EDTA is completely dissolved, stir for 30 minutes to obtain a mixture of alcohol and water.

(4)在100r/min的搅拌速度下,向步骤(3)所得的醇、水混合液中加入所述甲酸钾和氯化钠,待甲酸钾、氯化钠完全溶解后再搅拌30min,得到醇、盐混合液。(4) At a stirring speed of 100r/min, add the potassium formate and sodium chloride to the alcohol-water mixture obtained in step (3), and stir for 30 minutes after the potassium formate and sodium chloride are completely dissolved to obtain Alcohol, salt mixture.

(5)向步骤(4)所得的醇、盐混合液中加入磷酸氢二钾、交联羧甲基纤维素钠、木质素磺酸钠和聚二甲基硅氧烷,再以100r/min的速度搅拌30min,即得到所述用于沥青路面的抗冻液。(5) Add dipotassium hydrogen phosphate, croscarmellose sodium, sodium lignin sulfonate and polydimethylsiloxane to the alcohol-salt mixture obtained in step (4), and then use 100r/min Stir at a speed of 30 minutes to obtain the antifreeze solution for asphalt pavement.

实施例2:一种用于沥青路面的抗冻液,由以下重量份数的原料制成:甲酸钾20份、氯化钠8份、乙二醇5份、磷酸氢二钾2份、交联羧甲基纤维素钠1份、木质素磺酸钠0.3份、EDTA二钠0.3份、丙烯酸聚合物0.05份、氢氧化钾0.5份、聚二甲基硅氧烷0.15份、水80份。Embodiment 2: a kind of antifreeze liquid for asphalt pavement is made of the following raw materials in parts by weight: 20 parts of potassium formate, 8 parts of sodium chloride, 5 parts of ethylene glycol, 2 parts of dipotassium hydrogen phosphate, 1 part of sodium carboxymethylcellulose, 0.3 parts of sodium lignosulfonate, 0.3 parts of disodium EDTA, 0.05 parts of acrylic acid polymer, 0.5 parts of potassium hydroxide, 0.15 parts of polydimethylsiloxane, and 80 parts of water.

其制备方法包括下列步骤:Its preparation method comprises the following steps:

(1)按以下重量份称取各原料:甲酸钾20份、氯化钠8份、乙二醇5份、磷酸氢二钾2份、交联羧甲基纤维素钠1份、木质素磺酸钠0.3份、EDTA二钠0.3份、丙烯酸聚合物0.05份、氢氧化钾0.5份、聚二甲基硅氧烷0.15份、水80份。(1) Weigh each raw material according to the following parts by weight: 20 parts of potassium formate, 8 parts of sodium chloride, 5 parts of ethylene glycol, 2 parts of dipotassium hydrogen phosphate, 1 part of croscarmellose sodium, lignin sulfonate 0.3 parts of sodium phosphate, 0.3 parts of disodium EDTA, 0.05 parts of acrylic acid polymer, 0.5 parts of potassium hydroxide, 0.15 parts of polydimethylsiloxane, and 80 parts of water.

(2)将所述丙烯酸聚合物浸泡在步骤(1)中称取的水中,静置2h,然后以1000r/min的速度搅拌60min,得到胶液。(2) Soak the acrylic acid polymer in the water weighed in step (1), let it stand for 2 hours, and then stir it at a speed of 1000r/min for 60 minutes to obtain a glue solution.

(3)在500r/min的搅拌速度下,向步骤(2)所得的胶液中加入所述乙二醇,搅拌30min后再加入所述氢氧化钾,待氢氧化钾完全溶解后再加入EDTA二钠,待EDTA二钠完全溶解后再搅拌20min,得到醇、水混合液。(3) At a stirring speed of 500r/min, add the ethylene glycol to the glue obtained in step (2), stir for 30 minutes, then add the potassium hydroxide, and then add EDTA after the potassium hydroxide is completely dissolved Disodium, after the disodium EDTA is completely dissolved, stir for 20 minutes to obtain a mixture of alcohol and water.

(4)在100r/min的搅拌速度下,向步骤(3)所得的醇、水混合液中加入所述甲酸钾和氯化钠,待甲酸钾、氯化钠完全溶解后再搅拌20min,得到醇、盐混合液。(4) At a stirring speed of 100r/min, add the potassium formate and sodium chloride to the alcohol-water mixture obtained in step (3), and stir for 20 minutes after the potassium formate and sodium chloride are completely dissolved to obtain Alcohol, salt mixture.

(5)向步骤(4)所得的醇、盐混合液中加入磷酸氢二钾、交联羧甲基纤维素钠、木质素磺酸钠和聚二甲基硅氧烷,再以100r/min的速度搅拌40min,即得到所述用于沥青路面的抗冻液。(5) Add dipotassium hydrogen phosphate, croscarmellose sodium, sodium lignin sulfonate and polydimethylsiloxane to the alcohol-salt mixture obtained in step (4), and then use 100r/min Stir at a speed of 40 min to obtain the antifreeze solution for asphalt pavement.

实施例3:一种用于沥青路面的抗冻液,由以下重量份的原料制成:甲酸钾15份、氯化钠10份、乙二醇8份、磷酸氢二钾3份、交联羧甲基纤维素钠2份、木质素磺酸钠0.1份、EDTA二钠0.5份、丙烯酸聚合物0.03份、氢氧化钾0.3份、聚二甲基硅氧烷0.1份、水70份。Embodiment 3: a kind of antifreeze liquid that is used for asphalt pavement, is made of the raw material of following parts by weight: 15 parts of potassium formate, 10 parts of sodium chloride, 8 parts of ethylene glycol, 3 parts of dipotassium hydrogen phosphate, cross-linked 2 parts of sodium carboxymethyl cellulose, 0.1 part of sodium lignosulfonate, 0.5 part of disodium EDTA, 0.03 part of acrylic acid polymer, 0.3 part of potassium hydroxide, 0.1 part of polydimethylsiloxane, and 70 parts of water.

其制备方法包括下列步骤:Its preparation method comprises the following steps:

(1)按以下重量份称取各原料:甲酸钾15份、氯化钠10份、乙二醇8份、磷酸氢二钾3份、交联羧甲基纤维素钠2份、木质素磺酸钠0.1份、EDTA二钠0.5份、丙烯酸聚合物0.03份、氢氧化钾0.3份、聚二甲基硅氧烷0.1份、水70份。(1) Weigh each raw material according to the following parts by weight: 15 parts of potassium formate, 10 parts of sodium chloride, 8 parts of ethylene glycol, 3 parts of dipotassium hydrogen phosphate, 2 parts of croscarmellose sodium, lignin sulfonate 0.1 part of sodium phosphate, 0.5 part of disodium EDTA, 0.03 part of acrylic acid polymer, 0.3 part of potassium hydroxide, 0.1 part of polydimethylsiloxane, and 70 parts of water.

(2)将所述丙烯酸聚合物浸泡在步骤(1)中称取的水中,静置1.5h,然后以1000r/min的速度搅拌50min,得到胶液.(2) Soak the acrylic acid polymer in the water weighed in step (1), let it stand for 1.5h, and then stir at a speed of 1000r/min for 50min to obtain a glue solution.

(3)在500r/min的搅拌速度下,向步骤(2)所得的胶液中加入所述乙二醇,搅拌20min后再加入所述氢氧化钾,待氢氧化钾完全溶解后再加入EDTA二钠,待EDTA二钠完全溶解后再搅拌10min,得到醇、水混合液。(3) At a stirring speed of 500r/min, add the ethylene glycol to the glue obtained in step (2), stir for 20 minutes, then add the potassium hydroxide, and then add EDTA after the potassium hydroxide is completely dissolved Disodium, after the disodium EDTA is completely dissolved, stir for 10 minutes to obtain a mixture of alcohol and water.

(4)在100r/min的搅拌速度下,向步骤(3)所得的醇、水混合液中加入所述甲酸钾和氯化钠,待甲酸钾、氯化钠完全溶解后再搅拌10min,得到醇、盐混合液;(4) At a stirring speed of 100r/min, add the potassium formate and sodium chloride to the alcohol-water mixture obtained in step (3), and stir for 10 minutes after the potassium formate and sodium chloride are completely dissolved to obtain Alcohol, salt mixture;

(5)向步骤(4)所得的醇、盐混合液中加入磷酸氢二钾、交联羧甲基纤维素钠、木质素磺酸钠和聚二甲基硅氧烷,再以100r/min的速度搅拌60min,即得到所述用于沥青路面的抗冻液。(5) Add dipotassium hydrogen phosphate, croscarmellose sodium, sodium lignin sulfonate and polydimethylsiloxane to the alcohol-salt mixture obtained in step (4), and then use 100r/min Stir at a speed of 60 min to obtain the antifreeze solution for asphalt pavement.

实施例1-3制备出的用于沥青路面的抗冻液,对沥青路面均有较好的抗冻效果,检测实施例1-3制备出的用于沥青路面的抗冻液的各项性能参数,结果如下表1所示,喷洒抗冻液前后的沥青混合料的抗冻性能测试结果如下表2所示。The antifreeze liquid used for asphalt pavement prepared in Example 1-3 has a good antifreeze effect on asphalt pavement, and the various performances of the antifreeze liquid used for asphalt pavement prepared in Example 1-3 are tested The parameters and results are shown in Table 1 below, and the test results of antifreeze performance of asphalt mixture before and after spraying antifreeze are shown in Table 2 below.

从表1可以看出,本实施例1-3制备出的用于沥青路面的抗冻液的冰点低于-30℃,适用于大部分地区冬季的沥青路面防冻;黏度在450mpa.s左右,喷洒在沥青路面上的时候,一方面不会因为黏度过大导致路面摩擦力变小而导致交通事故,另一方面减缓了抗冻液的流动性,使其能够缓慢渗透进沥青路面本身带有的孔隙中,形成保护层;pH值维持在中性,不会对沥青路面和周围环境造成破坏;表面张力较小,在30mN/m左右,能够促进抗冻液渗透进沥青路面表层。As can be seen from Table 1, the freezing point of the antifreeze liquid for asphalt pavement prepared in Examples 1-3 is lower than -30°C, which is suitable for antifreezing asphalt pavement in winter in most areas; the viscosity is about 450mpa.s, When spraying on the asphalt pavement, on the one hand, it will not cause traffic accidents due to the decrease of road friction due to excessive viscosity, and on the other hand, it will slow down the fluidity of the antifreeze so that it can slowly penetrate into the asphalt pavement itself. In the pores, a protective layer is formed; the pH value is maintained at neutral, which will not cause damage to the asphalt pavement and the surrounding environment; the surface tension is small, around 30mN/m, which can promote the penetration of antifreeze into the surface of the asphalt pavement.

从表2可以看出,喷洒抗冻液后沥青混合料的低温弯曲破坏应变远大于未喷洒抗冻液沥青混合料的低温弯曲破坏应变,且满足《公路沥青路面施工技术规范》JTGF40-2004的要求,喷洒抗冻液后沥青混合料的抗冻性能有了很大程度的提高。It can be seen from Table 2 that the low-temperature bending failure strain of the asphalt mixture sprayed with antifreeze fluid is much greater than that of the asphalt mixture without antifreeze fluid sprayed, and meets the "Technical Specifications for Highway Asphalt Pavement Construction" JTGF40-2004 The antifreeze performance of asphalt mixture has been greatly improved after spraying antifreeze.

在实际使用中,可以根据实际需要用水稀释10~100倍后,再采用喷洒车对沥青路面进行喷洒,以防止沥青路面结冰,其具体的工作原理如下:In actual use, it can be diluted 10 to 100 times with water according to actual needs, and then spray the asphalt pavement with a sprayer to prevent the asphalt pavement from freezing. The specific working principle is as follows:

在气温低于0℃的时候,往沥青路面喷洒本发明抗冻液,由于本发明抗冻液中添加了少量的丙烯酸聚合物,因此具有一定的黏度,流动性差,再加上沥青本身具有的大量孔隙,因此其不会在沥青道路上汇集、漫流,而是随着孔隙慢慢渗透到沥青路面表层的一定深度内,形成一个保护层,当下雪时,路面冰雪与保护层相接触,保护层中的无机和有机的冰点降低剂与冰雪接触,将其迅速融化成雪水,并且渗透到沥青路面深层中的冰点降低剂也会随时浓度差的变化逐渐向上移动,释放到雪水中,随着雪水中冰点降低机浓度增加,水的液相蒸气压下降,而冰的固态蒸气压不变,为了达到冰水混合物固液蒸气压平衡的状态,越来越多的冰便开始融化,从而可以防止和延缓冬季沥青路面结冰的现象。当降雪过大,喷洒的抗冻液不足以将路面冰雪全部融化时,可以直接往冰雪上喷洒抗冻液来除冰雪。When the air temperature is lower than 0°C, the antifreeze solution of the present invention is sprayed on the asphalt pavement. Because a small amount of acrylic acid polymer is added to the antifreeze solution of the present invention, it has a certain viscosity and poor fluidity. A large number of pores, so it will not gather and flow on the asphalt road, but slowly penetrate into a certain depth of the surface of the asphalt pavement with the pores to form a protective layer. When it snows, the ice and snow on the road contact with the protective layer to protect The inorganic and organic freezing point depressants in the layer come into contact with ice and snow and quickly melt it into snow water, and the freezing point depressants that penetrate into the deep layer of the asphalt pavement will also gradually move upward with the change of concentration difference and be released into the snow water. As the concentration of the freezing point depression machine in the snowwater increases, the liquid-phase vapor pressure of the water decreases, while the solid-state vapor pressure of the ice remains unchanged. In order to achieve the equilibrium state of the solid-liquid vapor pressure of the ice-water mixture, more and more ice begins to melt, thus It can prevent and delay the freezing of asphalt pavement in winter. When the snowfall is too heavy and the sprayed antifreeze is not enough to melt all the ice and snow on the road surface, you can directly spray the antifreeze on the ice and snow to remove the ice and snow.

本发明用于沥青路面的抗冻液中,添加无机盐氯化钠作为融雪剂,对沥青道路具备一定的抗冻防冰保护能力,并且原料易得、价格低廉,但是它对大型公共基础设施的腐蚀和生态环境的破坏很严重,所以本发明中氯化钠的用量较少。同时,添加有缓蚀剂磷酸氢二钾来降低减缓这种破坏作用,并且磷酸氢二钾含有植物生长所需的营养元素磷和钾,在抗冻液被雨水或融雪冲走,进入道路两边时,不会对生态环境造成破坏,而且会成为路边绿化植物的肥料。甲酸钾是一种有机融雪剂,对沥青道路基本没有腐蚀损害,但由于其冰点较高,不易在气温偏低地区使用,极大地限制了其应用范围和地域;而本发明添加乙二醇作为防冻剂,一方面可以和氯化钠和甲酸钠协同作用,起到更好的抗冻效果,另一方面其作为一种有机的具备一定黏度的液体,在体系中和氯化钠和甲酸钠混合在一起,起到缓释的作用。为了加强这种缓释性,本发明还添加了少量的丙烯酸聚合物来增加粘性,使各有效成分缓慢释放。但丙烯酸聚合物的水溶液为酸性,因此为了使最终制备出的产品pH值维持中性,在配方中添加了氢氧化钾来中和丙烯酸聚合物,但是丙烯酸聚合物的水溶液和氢氧化钾反应后体系的黏度会骤然增大,而产品黏度过大,喷洒在沥青路面时则会减小沥青道路的摩擦力,容易导致事故发生,所以本发明中添加了EDTA二钠来降低黏度,使其黏度保持在一个合适的范围内。交联羧甲基纤维素钠具有一定的保水性和缓释性,能够使产品中有效成分缓慢释放,长久的发生功效;木质素磺酸钠是一种阴离子表面活性剂,能够使配方中的无机物和有机物均匀的混合在一起;聚二甲基硅氧烷是一种消泡剂,能够降低产品表面张力,使其在使用时更容易渗透进入沥青内,长久的发生功效。The present invention is used in the antifreeze liquid for asphalt pavement, adding inorganic salt sodium chloride as a deicing agent, which has certain antifreeze and anti-icing protection ability for asphalt roads, and the raw materials are easy to obtain and low in price, but it is not suitable for large-scale public infrastructure The corrosion and the destruction of ecological environment are very serious, so the consumption of sodium chloride is less among the present invention. At the same time, the corrosion inhibitor dipotassium hydrogen phosphate is added to reduce and slow down this damage, and dipotassium hydrogen phosphate contains the nutrients phosphorus and potassium needed for plant growth. When the antifreeze is washed away by rain or snowmelt, it enters both sides of the road When it is used, it will not cause damage to the ecological environment, and it will become a fertilizer for roadside greening plants. Potassium formate is a kind of organic deicing agent, basically does not have corrosion damage to asphalt road, but because its freezing point is higher, it is difficult to use in the low temperature area, greatly limits its scope of application and region; and the present invention adds ethylene glycol as Antifreeze, on the one hand, can work synergistically with sodium chloride and sodium formate to achieve a better antifreeze effect; on the other hand, as an organic liquid with a certain viscosity, it is mixed with sodium chloride and sodium formate in the system Together, it acts as a slow release. In order to strengthen the sustained release, the present invention also adds a small amount of acrylic acid polymer to increase the viscosity, so that the active ingredients can be released slowly. However, the aqueous solution of acrylic acid polymer is acidic, so in order to maintain the neutral pH of the final product, potassium hydroxide is added to the formula to neutralize the acrylic polymer, but after the reaction of the aqueous solution of acrylic polymer and potassium hydroxide The viscosity of the system will suddenly increase, and if the product viscosity is too high, it will reduce the friction of the asphalt road when it is sprayed on the asphalt road, which will easily lead to accidents. Therefore, disodium EDTA is added in the present invention to reduce the viscosity and make it more viscous. stay within a suitable range. Croscarmellose sodium has certain water retention and slow-release properties, which can slowly release the active ingredients in the product and produce long-term effects; sodium lignosulfonate is an anionic surfactant, which can make the active ingredients in the formula Inorganic matter and organic matter are evenly mixed together; polydimethylsiloxane is a kind of defoamer, which can reduce the surface tension of the product, making it easier to penetrate into the asphalt during use, and have a long-term effect.

本发明的用于沥青路面的抗冻液将无机冰点降低剂和有机冰点降低剂结合起来防冻除冰,不仅具有很好的抗冻除冰效果,而且既克服了无机冰点降低剂对路面腐蚀,对环境污染的缺点,又克服了有机冰点结合剂价格昂贵的缺点。The antifreeze liquid for asphalt pavement of the present invention combines inorganic freezing point depressants and organic freezing point depressants to prevent freezing and deicing, not only has a good antifreezing and deicing effect, but also overcomes the corrosion of inorganic freezing point depressants on the road surface, The shortcoming of environmental pollution overcomes the shortcoming of expensive organic freezing point binders.

尽管已描述了本发明的优选实施例,但本领域内的技术人员一旦得知了基本创造性概念,则可对这些实施例作出另外的变更和修改。所以,所附权利要求意欲解释为包括优选实施例以及落入本发明范围的所有变更和修改。显然,本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样,倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内也意图包含这些改动和变型在内。While preferred embodiments of the invention have been described, additional changes and modifications to these embodiments can be made by those skilled in the art once the basic inventive concept is appreciated. Therefore, it is intended that the appended claims be construed to cover the preferred embodiment as well as all changes and modifications which fall within the scope of the invention. Obviously, those skilled in the art can make various changes and modifications to the present invention without departing from the spirit and scope of the present invention. In this way, if these modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalent technologies, it is also intended to include these modifications and variations.

Claims (5)

1.一种用于沥青路面的抗冻液,其特征在于,由以下重量份的原料制成:甲酸钾10~20份、氯化钠5~10份、乙二醇5~10份、磷酸氢二钾1~3份、交联羧甲基纤维素钠1~2份、木质素磺酸钠0.1~0.5份、EDTA二钠0.1~0.5份、丙烯酸聚合物0.02~0.05份、氢氧化钾0.1~0.5份、聚二甲基硅氧烷0.1~0.2份、水60~80份。1. An antifreeze liquid for asphalt pavement is characterized in that it is made of the following raw materials in parts by weight: 10 to 20 parts of potassium formate, 5 to 10 parts of sodium chloride, 5 to 10 parts of ethylene glycol, phosphoric acid 1-3 parts of dipotassium hydrogen, 1-2 parts of croscarmellose sodium, 0.1-0.5 parts of sodium lignosulfonate, 0.1-0.5 parts of disodium EDTA, 0.02-0.05 parts of acrylic acid polymer, potassium hydroxide 0.1-0.5 parts, 0.1-0.2 parts of polydimethylsiloxane, 60-80 parts of water. 2.根据权利要求1所述的用于沥青路面的抗冻液,其特征在于,由以下重量份的原料制成:甲酸钾10份、氯化钠5份、乙二醇10份、磷酸氢二钾1份、交联羧甲基纤维素钠2份、木质素磺酸钠0.5份、EDTA二钠0.1份、丙烯酸聚合物0.02份、氢氧化钾0.2份、聚二甲基硅氧烷0.2份、水60份。2. The antifreeze liquid for asphalt pavement according to claim 1, characterized in that it is made of the following raw materials in parts by weight: 10 parts of potassium formate, 5 parts of sodium chloride, 10 parts of ethylene glycol, hydrogen phosphate 1 part of dipotassium, 2 parts of croscarmellose sodium, 0.5 part of sodium lignosulfonate, 0.1 part of disodium EDTA, 0.02 part of acrylic acid polymer, 0.2 part of potassium hydroxide, 0.2 part of polydimethylsiloxane part, 60 parts of water. 3.根据权利要求1所述的用于沥青路面的抗冻液,其特征在于,由以下重量份的原料制成:甲酸钾20份、氯化钠8份、乙二醇5份、磷酸氢二钾2份、交联羧甲基纤维素钠1份、木质素磺酸钠0.3份、EDTA二钠0.3份、丙烯酸聚合物0.05份、氢氧化钾0.5份、聚二甲基硅氧烷0.15份、水80份。3. The antifreeze liquid for asphalt pavement according to claim 1, characterized in that it is made of the following raw materials in parts by weight: 20 parts of potassium formate, 8 parts of sodium chloride, 5 parts of ethylene glycol, hydrogen phosphate 2 parts of dipotassium, 1 part of croscarmellose sodium, 0.3 parts of sodium lignosulfonate, 0.3 parts of disodium EDTA, 0.05 parts of acrylic acid polymer, 0.5 parts of potassium hydroxide, 0.15 parts of polydimethylsiloxane part, 80 parts of water. 4.根据权利要求1所述的用于沥青路面的抗冻液,其特征在于,由以下重量份的原料制成:甲酸钾15份、氯化钠10份、乙二醇8份、磷酸氢二钾3份、交联羧甲基纤维素钠2份、木质素磺酸钠0.1份、EDTA二钠0.5份、丙烯酸聚合物0.03份、氢氧化钾0.3份、聚二甲基硅氧烷0.1份、水70份。4. The antifreeze liquid for asphalt pavement according to claim 1, characterized in that it is made of the following raw materials in parts by weight: 15 parts of potassium formate, 10 parts of sodium chloride, 8 parts of ethylene glycol, hydrogen phosphate Dipotassium 3 parts, croscarmellose sodium 2 parts, sodium lignosulfonate 0.1 part, disodium EDTA 0.5 part, acrylic acid polymer 0.03 part, potassium hydroxide 0.3 part, polydimethylsiloxane 0.1 part parts, 70 parts of water. 5.一种权利要求1所述的用于沥青路面的抗冻液的制备方法,其特征在于,包括下列步骤:5. a preparation method for the antifreeze liquid of asphalt pavement as claimed in claim 1, is characterized in that, comprises the following steps: (1)按以下重量份称取各原料:甲酸钾10~20份、氯化钠5~10份、乙二醇5~10份、磷酸氢二钾1~3份、交联羧甲基纤维素钠1~2份、木质素磺酸钠0.1~0.5份、EDTA二钠0.1~0.5份、丙烯酸聚合物0.02~0.05份、氢氧化钾0.1~0.5份、聚二甲基硅氧烷0.1~0.2份、水60~80份;(1) Weigh each raw material according to the following parts by weight: 10-20 parts of potassium formate, 5-10 parts of sodium chloride, 5-10 parts of ethylene glycol, 1-3 parts of dipotassium hydrogen phosphate, cross-linked carboxymethyl fiber 1-2 parts of sodium sulfonate, 0.1-0.5 parts of sodium lignosulfonate, 0.1-0.5 parts of disodium EDTA, 0.02-0.05 parts of acrylic acid polymer, 0.1-0.5 parts of potassium hydroxide, 0.1-0.5 parts of polydimethylsiloxane 0.2 parts, 60-80 parts of water; (2)将所述丙烯酸聚合物浸泡在步骤(1)中称取的水中,静置1~2h,然后以1000r/min的速度搅拌30~60min,得到胶液;(2) Soak the acrylic acid polymer in the water weighed in step (1), let it stand for 1-2 hours, and then stir at a speed of 1000r/min for 30-60 minutes to obtain glue; (3)在500r/min的搅拌速度下,向步骤(2)所得的胶液中加入所述乙二醇,搅拌10~30min后再加入所述氢氧化钾,待氢氧化钾完全溶解后再加入EDTA二钠,待EDTA二钠完全溶解后再搅拌10~30min,得到醇、水混合液;(3) At a stirring speed of 500r/min, add the ethylene glycol to the glue obtained in step (2), stir for 10 to 30 minutes, then add the potassium hydroxide, and wait until the potassium hydroxide is completely dissolved. Add disodium EDTA, and stir for 10-30 minutes after the disodium EDTA is completely dissolved to obtain a mixture of alcohol and water; (4)在100r/min的搅拌速度下,向步骤(3)所得的醇、水混合液中加入所述甲酸钾和氯化钠,待甲酸钾、氯化钠完全溶解后再搅拌10~30min,得到醇、盐混合液;(4) At a stirring speed of 100r/min, add the potassium formate and sodium chloride to the alcohol-water mixture obtained in step (3), and stir for 10 to 30 minutes after the potassium formate and sodium chloride are completely dissolved , to obtain alcohol-salt mixture; (5)向步骤(4)所得的醇、盐混合液中加入磷酸氢二钾、交联羧甲基纤维素钠、木质素磺酸钠和聚二甲基硅氧烷,再以100r/min的速度搅拌30~60min,即得到所述用于沥青路面的抗冻液。(5) Add dipotassium hydrogen phosphate, croscarmellose sodium, sodium lignin sulfonate and polydimethylsiloxane to the alcohol-salt mixture obtained in step (4), and then use 100r/min Stir at a speed of 30-60 minutes to obtain the antifreeze liquid for asphalt pavement.
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CN102031089B (en) * 2010-11-23 2013-06-26 长春金宝特生物化工有限公司 Non-chlorine environmentally-friendly snow melting agent
CN103582686A (en) * 2011-06-08 2014-02-12 阿克佐诺贝尔化学国际公司 Deicing composition
CN103666393A (en) * 2013-11-20 2014-03-26 青岛晨讯通商贸有限公司 Novel motor vehicle antifreeze fluid

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Publication number Priority date Publication date Assignee Title
CN102031089B (en) * 2010-11-23 2013-06-26 长春金宝特生物化工有限公司 Non-chlorine environmentally-friendly snow melting agent
CN103582686A (en) * 2011-06-08 2014-02-12 阿克佐诺贝尔化学国际公司 Deicing composition
CN103666393A (en) * 2013-11-20 2014-03-26 青岛晨讯通商贸有限公司 Novel motor vehicle antifreeze fluid

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