CN106771765A - A kind of multidimensional parameter appraisal procedure of operating composite insulator degree of aging - Google Patents
A kind of multidimensional parameter appraisal procedure of operating composite insulator degree of aging Download PDFInfo
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Abstract
一种运行中的复合绝缘子老化程度的多维参量评估方法,所述方法首先测量目标复合绝缘子伞裙的高温硫化硅橡胶试样的硬度、憎水性、表面缺陷面积、Si‑O‑Si基团对应的红外吸收峰值、陷阱电荷量和闪络电压;然后对所测数据进行量化处理,并对处理后的特征参量进行老化程度的打分;再对各特征参量的分值进行加权求和,得到表征复合绝缘子老化程度的综合特征量;最后根据综合特征量的大小与老化程度等级的对应关系确定绝缘子的老化程度。本发明将复合绝缘子伞裙材料的微观电特性及微观物化特性与宏观特性相结合,实现了对复合绝缘子老化程度的综合评估。该方法避免了传统评估方法的片面性,从而保证了评估结果的准确性。
A multi-dimensional parameter evaluation method for the aging degree of a composite insulator in operation. The method first measures the hardness, hydrophobicity, surface defect area, and Si-O-Si group correspondence of the high-temperature vulcanized silicone rubber sample of the shed of the target composite insulator. Infrared absorption peak value, trap charge and flashover voltage; then quantify the measured data, and score the aging degree of the processed characteristic parameters; then weight and sum the scores of each characteristic parameter to obtain the characterization The comprehensive characteristic quantity of the aging degree of the composite insulator; finally, the aging degree of the insulator is determined according to the corresponding relationship between the comprehensive characteristic quantity and the aging degree grade. The invention combines the microscopic electrical characteristics, microscopic physical and chemical characteristics and macroscopic characteristics of the shed material of the composite insulator, and realizes the comprehensive evaluation of the aging degree of the composite insulator. This method avoids the one-sidedness of traditional evaluation methods, thereby ensuring the accuracy of evaluation results.
Description
技术领域technical field
本发明涉及一种能够准确评估运行中的复合绝缘子老化程度的方法,属于绝缘体技术领域。The invention relates to a method capable of accurately evaluating the aging degree of a composite insulator in operation, and belongs to the technical field of insulators.
背景技术Background technique
目前,高压输电线路杆塔大都通过复合绝缘子与线路绝缘,复合绝缘子的伞裙和护套的材质一般为高温硫化硅橡胶。在长期挂网运行过程中,高温硫化硅橡胶受到高强度电场及环境中光、热、雨、污秽等的影响,会出现严重的老化问题。为确保高压输电线路的可靠运行,有必要对复合绝缘子的老化程度进行检测。At present, most of the poles and towers of high-voltage transmission lines are insulated from the lines by composite insulators, and the shed and sheath of composite insulators are generally made of high-temperature vulcanized silicone rubber. During the long-term hanging network operation, high-temperature vulcanized silicone rubber is affected by high-intensity electric fields and light, heat, rain, pollution, etc. in the environment, and serious aging problems will occur. In order to ensure the reliable operation of high-voltage transmission lines, it is necessary to detect the aging degree of composite insulators.
现有的硅橡胶复合绝缘子老化程度检测方法有多种,如根据材料的物理特性(如材料外观、憎水性、等值盐密、灰密、热重等)分析绝缘子的老化程度;根据材料的微观物化特性分析绝缘子的老化程度;根据材料的电特性(如闪络电压、泄漏电流、热刺激电流等)分析绝缘子的老化程度;根据材料的介电特性和电阻特性分析绝缘子的老化程度。这些方法大都是根据单一的老化指标进行评估,导致其评估结果具有一定的片面性。例如申请号为201210386969.8的发明专利公开了一种复合绝缘子运行状态评估方法,该方法利用扫描电镜(SEM)、傅里叶红外光谱分析仪(FTIR)和热刺激电流测量仪(TSC)的测试结果从微观的角度对复合绝缘子进行评估,并基于BP神经网络算法对各参量进行权值优化,最后计算出复合绝缘子的运行状态,但其并未考虑材料宏观特性对老化状态的影响。There are many methods for detecting the aging degree of silicone rubber composite insulators, such as analyzing the aging degree of the insulator according to the physical properties of the material (such as material appearance, hydrophobicity, equivalent salt density, gray density, thermal weight, etc.); Analyze the aging degree of insulators based on microscopic physical and chemical characteristics; analyze the aging degree of insulators according to the electrical characteristics of materials (such as flashover voltage, leakage current, thermal stimulation current, etc.); analyze the aging degree of insulators based on the dielectric properties and resistance properties of materials. Most of these methods are evaluated based on a single aging index, resulting in a certain one-sidedness in the evaluation results. For example, the invention patent with application number 201210386969.8 discloses a method for evaluating the operating state of composite insulators, which uses the test results of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and thermal stimulation current measurement (TSC) The composite insulator is evaluated from a microscopic point of view, and the weight of each parameter is optimized based on the BP neural network algorithm. Finally, the operating state of the composite insulator is calculated, but it does not consider the influence of the macroscopic properties of the material on the aging state.
绝缘材料的宏观特性对老化程度的检测具有重要意义。国家电网公司现场运行复合绝缘子的数据显示,绝缘子硅橡胶老化主要表现在表面憎水性下降、硬度增加等现象,进而影响绝缘子的耐污闪性能。因此,在进行复合绝缘子老化程度评估时,只分析材料的微观特性是片面的,有必要将材料的宏观特性考虑在内。一方面,憎水性作为复合绝缘子耐污闪性能的重要指标,能够直观表征材料的老化程度。闪络电压作为衡量硅橡胶电气性能的重要标准之一,是绝缘材料宏观电特性的体现,而硬度则体现了材料的宏观机械性能。另一方面,材料的微观性能的变化将导致宏观性能的改变,而宏观性能更能直观地体现材料的老化状态。因此,有必要寻求一种能够将复合绝缘子伞裙材料的微观电特性及微观物化特性与材料宏观特性相结合的方法,以实现复合绝缘子老化程度的准确评估。The macroscopic properties of insulating materials are of great significance to the detection of aging. The data of composite insulators operated by the State Grid Corporation of China show that the aging of insulator silicone rubber is mainly manifested in the decrease of surface hydrophobicity and increase of hardness, which in turn affects the pollution flashover resistance of insulators. Therefore, when evaluating the aging degree of composite insulators, it is one-sided to only analyze the microscopic properties of the material, and it is necessary to take the macroscopic properties of the material into consideration. On the one hand, as an important indicator of the pollution flashover resistance performance of composite insulators, hydrophobicity can directly represent the aging degree of materials. As one of the important standards to measure the electrical properties of silicone rubber, flashover voltage is the embodiment of the macroscopic electrical properties of insulating materials, while the hardness reflects the macroscopic mechanical properties of materials. On the other hand, changes in the microscopic properties of the material will lead to changes in the macroscopic properties, and the macroscopic properties can more intuitively reflect the aging state of the material. Therefore, it is necessary to find a method that can combine the microscopic electrical properties and microscopic physical and chemical properties of composite insulator shed materials with the macroscopic properties of the material to achieve accurate assessment of the aging degree of composite insulators.
发明内容Contents of the invention
本发明的目的在于针对现有技术之弊端,提供一种运行中的复合绝缘子老化程度的多维参量评估方法,以更加精确地评估硅橡胶的老化程度,保证高压输电线路的正常运行。The purpose of the present invention is to provide a multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation to more accurately evaluate the aging degree of silicone rubber to ensure the normal operation of high-voltage transmission lines.
本发明所述问题是以下述技术方案解决的:Problem described in the present invention is solved with following technical scheme:
一种运行中的复合绝缘子老化程度的多维参量评估方法,所述方法首先测量目标复合绝缘子伞裙的高温硫化硅橡胶试样的硬度、憎水性、表面缺陷面积、Si-O-Si基团对应的红外吸收峰值、陷阱电荷量和闪络电压;然后对所测数据进行量化处理,并对处理后的特征参量进行老化程度的打分;再对各特征参量的分值进行加权求和,得到表征复合绝缘子老化程度的综合特征量;最后根据综合特征量的大小与老化程度等级的对应关系确定绝缘子的老化程度。A multi-dimensional parameter evaluation method for the aging degree of a composite insulator in operation. The method first measures the hardness, hydrophobicity, surface defect area, and Si-O-Si group correspondence of the high-temperature vulcanized silicone rubber sample of the target composite insulator shed Infrared absorption peak value, trap charge and flashover voltage; then quantify the measured data, and score the aging degree of the processed characteristic parameters; then weight and sum the scores of each characteristic parameter to obtain the characterization The comprehensive characteristic quantity of the aging degree of the composite insulator; finally, the aging degree of the insulator is determined according to the corresponding relationship between the comprehensive characteristic quantity and the aging degree grade.
上述运行中的复合绝缘子老化程度的多维参量评估方法,所述方法包括以下步骤:The multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation above includes the following steps:
a.确定特征量:a. Determine the characteristic quantity:
选择六个特征参量作为评价复合绝缘子老化程度的特征量,分别为硬度、憎水性、表面缺陷面积、Si-O-Si基团对应的红外吸收峰值、陷阱电荷量和闪络电压,其中,憎水性由静态接触角表示,表面缺陷面积为裂纹面积与析出物面积之和;Six characteristic parameters are selected as the characteristic quantities to evaluate the aging degree of composite insulators, which are hardness, hydrophobicity, surface defect area, infrared absorption peak corresponding to Si-O-Si group, trap charge and flashover voltage. Among them, hydrophobicity The water property is represented by the static contact angle, and the surface defect area is the sum of the crack area and the precipitate area;
b.使用切片器从目标复合绝缘子伞裙表面切下圆片型高温硫化硅橡胶试样;b. Use a slicer to cut a disc-shaped high-temperature vulcanized silicone rubber sample from the surface of the shed of the target composite insulator;
c.利用邵氏硬度计、扫描电镜、傅里叶红外光谱分析仪、热刺激电流测量仪和指型电极分别测量高温硫化硅橡胶试样的硬度、表面缺陷面积、Si-O-Si基团对应的红外吸收峰值、陷阱电荷量和闪络电压,并采用静态接触角法测量试样的憎水性;c. Use Shore hardness tester, scanning electron microscope, Fourier transform infrared spectrometer, thermal stimulation current measuring instrument and finger electrode to measure the hardness, surface defect area and Si-O-Si group of high-temperature vulcanized silicone rubber samples respectively The corresponding infrared absorption peak, trap charge and flashover voltage, and the hydrophobicity of the sample is measured by the static contact angle method;
d.量化原始特征量:首先对各种方法所测得的特征参量进行归一化处理,其中,表面缺陷面积的归一化处理公式为: 其余特征参量的归一化处理公式为: 然后根据每个归一化的特征参量值,对目标复合绝缘子进行老化程度的打分,得到与各个特征参量相对应的老化程度分值;d. Quantify the original characteristic quantity: first, normalize the characteristic parameters measured by various methods, and the normalization treatment formula of the surface defect area is: The normalization formula of the remaining characteristic parameters is: Then, according to each normalized characteristic parameter value, the aging degree of the target composite insulator is scored, and the aging degree score corresponding to each characteristic parameter is obtained;
e.评估试样老化程度:设定各特征参量的权重,对试样的六个特征参量所对应的老化程度分值进行加权求和,得到表征复合绝缘子老化程度的综合特征量,最后根据综合特征量的大小与老化程度等级的对应关系判定目标绝缘子的老化程度。e. Evaluate the aging degree of the sample: set the weight of each characteristic parameter, carry out weighted summation of the aging degree scores corresponding to the six characteristic parameters of the sample, and obtain the comprehensive characteristic quantity representing the aging degree of the composite insulator, and finally according to the comprehensive The corresponding relationship between the size of the characteristic quantity and the aging degree grade determines the aging degree of the target insulator.
上述运行中的复合绝缘子老化程度的多维参量评估方法,评估试样的老化程度时,也可以利用神经网络进行评估,具体方法为:The multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation above can also be evaluated by neural network when evaluating the aging degree of samples. The specific method is as follows:
采集多个老化程度已知的高温硫化硅橡胶样本,获取样本的归一化特征参量值,组成训练样本集,利用训练样本集对BP神经网络进行训练,然后利用训练的BP神经网络对高温硫化硅橡胶试样的老化程度进行评估。Collect multiple high-temperature vulcanized silicone rubber samples with known aging degrees, obtain the normalized characteristic parameter values of the samples, form a training sample set, use the training sample set to train the BP neural network, and then use the trained BP neural network to perform high-temperature vulcanization The aging degree of the silicone rubber samples was evaluated.
上述运行中的复合绝缘子老化程度的多维参量评估方法,各特征参量的权重设定为:硬度:0.2,憎水性:0.4,表面缺陷面积:0.4,Si-O-Si基团对应的红外吸收峰值:0.6,陷阱电荷量:1,闪络电压:0.4。The multi-dimensional parameter evaluation method for the aging degree of composite insulators in the above operation, the weight of each characteristic parameter is set as: hardness: 0.2, hydrophobicity: 0.4, surface defect area: 0.4, infrared absorption peak corresponding to Si-O-Si group : 0.6, trap charge: 1, flashover voltage: 0.4.
上述运行中的复合绝缘子老化程度的多维参量评估方法,根据每个归一化的特征参量值,对目标复合绝缘子进行老化程度打分的具体方法为:The multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation above, according to each normalized characteristic parameter value, the specific method of scoring the aging degree of the target composite insulator is as follows:
将每种归一化特征参量的取值范围分为多个区间,每个区间给定一个数值,绝缘子的老化程度越高,对应的数值也越大;某归一化特征参量值所在区间的给定数值即为该特征参量所对应的老化程度分值。The value range of each normalized characteristic parameter is divided into multiple intervals, each interval is given a value, the higher the aging degree of the insulator, the larger the corresponding value; the interval of a certain normalized characteristic parameter value The given value is the aging degree score corresponding to the characteristic parameter.
上述运行中的复合绝缘子老化程度的多维参量评估方法,所述圆片型高温硫化硅橡胶试样的规格有两种,测量陷阱电荷量时所用试样的直径为20mm,厚1.3mm,测量其它特征参量时所用试样的直径为20mm,厚度为3mm。The multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation above, there are two types of disc-shaped high-temperature vulcanized silicone rubber samples. The diameter of the sample used in the characteristic parameters is 20mm and the thickness is 3mm.
上述运行中的复合绝缘子老化程度的多维参量评估方法,利用邵氏硬度计测量高温硫化硅橡胶试样的硬度时,将两片高温硫化硅橡胶试样叠放后测量5次,将5个测量值的中位数作为高温硫化硅橡胶试样的硬度值。The multi-dimensional parameter evaluation method for the aging degree of composite insulators in the above operation, when using the Shore hardness tester to measure the hardness of high-temperature vulcanized silicone rubber samples, stack two high-temperature vulcanized silicone rubber samples and measure them 5 times. The median value of the value is used as the hardness value of the high temperature vulcanized silicone rubber sample.
上述运行中的复合绝缘子老化程度的多维参量评估方法,所述指型电极的放电端为半圆形,其半径为8mm,利用指型电极测量高温硫化硅橡胶试样的闪络电压时,两指型电极间距离为10mm,将制备好的试样放置在两指型电极中央,在两指型电极之间施加电压,施加电压的梯度为1kV,在施加电压过程中对试样的沿面闪络电压进行测量,每片试样进行5次闪络电压的测量,相邻两次测量之间间隔10min,将5次测量值的平均值作为高温硫化硅橡胶试样的闪络电压。In the multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation, the discharge end of the finger electrode is semicircular, and its radius is 8mm. When using the finger electrode to measure the flashover voltage of the high-temperature vulcanized silicone rubber sample, two The distance between the finger-shaped electrodes is 10mm. The prepared sample is placed in the center of the two finger-shaped electrodes, and a voltage is applied between the two finger-shaped electrodes. The gradient of the applied voltage is 1kV. The flashover voltage of each sample is measured five times, with an interval of 10 minutes between two adjacent measurements, and the average value of the five measurements is taken as the flashover voltage of the high-temperature vulcanized silicone rubber sample.
本发明将复合绝缘子伞裙材料的微观电特性及微观物化特性与宏观特性相结合,实现了对复合绝缘子老化程度的综合评估。该方法避免了传统评估方法的片面性,从而保证了评估结果的准确性。The invention combines the microscopic electrical characteristics, microscopic physical and chemical characteristics and macroscopic characteristics of the shed material of the composite insulator, and realizes the comprehensive evaluation of the aging degree of the composite insulator. This method avoids the one-sidedness of traditional evaluation methods, thereby ensuring the accuracy of evaluation results.
附图说明Description of drawings
图1是BP神经网络结构图。Figure 1 is a structural diagram of the BP neural network.
具体实施方式detailed description
下面结合附图对本发明作进一步说明。The present invention will be further described below in conjunction with accompanying drawing.
本方法是将多种老化评估方法按照不同权重综合考虑来评估运行复合绝缘子的老化程度,不仅能够将材料微观性能和宏观性能结合起来考虑材料的老化程度,而且可以给出定量的判别结果,保证了评估结果的准确性。本专利的特点是将6种老化程度评级指标根据其之间的内在联系,以及对老化的影响程度不同,分为不同权重综合评估绝缘子老化程度,并给出了适用于评估各种运行复合绝缘子的BP神经网络模型。单一因素评估指标评估复合绝缘子的局限性在于:This method evaluates the aging degree of operating composite insulators by comprehensively considering various aging evaluation methods according to different weights. It can not only combine the microscopic properties and macroscopic properties of materials to consider the aging degree of materials, but also give quantitative discrimination results to ensure the accuracy of the assessment results. The feature of this patent is that according to the internal relationship between them and the different degrees of influence on aging, the six aging rating indicators are divided into different weights to comprehensively evaluate the aging degree of insulators, and it is suitable for evaluating various operating composite insulators. BP neural network model. The limitations of single factor evaluation index to evaluate composite insulators are:
硬度指标:硬度是硅橡胶材料的宏观物理性能,硅橡胶运行过程中,表面受到老化因素的影响,材料会先发生过度交联,发生硬化现象,使得硬度上升,随着老化时间的增长,电晕老化使得材料化学键不断被打断,硝酸不断腐蚀材料表面,使得材料表面出现裂纹、粉化等现象,造成硬度下降,因此,硬度随着运行年限的增加呈现先上升后减小的趋势,导致很难区分材料的老化状态。Hardness index: Hardness is the macroscopic physical property of silicone rubber materials. During the operation of silicone rubber, the surface is affected by aging factors, and the material will first undergo excessive cross-linking and hardening, which will increase the hardness. Halo aging causes the chemical bonds of the material to be continuously interrupted, and the nitric acid continues to corrode the surface of the material, causing cracks and pulverization on the surface of the material, resulting in a decrease in hardness. It is difficult to distinguish the aging state of the material.
憎水性:影响复合绝缘子性能的主要因素是憎水性的丧失与否,憎水性的破坏更是绝缘子老化的重要特征。材料表面的憎水性是由于硅橡胶侧链的非极性基团屏蔽了主链的强极性作用,使得材料表面憎水性增强,运行复合绝缘子随着运行年限的增加,侧链甲基基团被打断,憎水性会降低,但同时会生成LMW小分子,LMW迁移到材料表面,使得憎水性相对增加,因此,憎水性也不能准确评估材料的老化状态。Hydrophobicity: The main factor affecting the performance of composite insulators is the loss of hydrophobicity, and the destruction of hydrophobicity is an important feature of insulator aging. The hydrophobicity of the surface of the material is due to the fact that the non-polar group of the side chain of the silicone rubber shields the strong polarity of the main chain, which enhances the hydrophobicity of the surface of the material. As the service life of the composite insulator increases, the side chain methyl group If it is interrupted, the hydrophobicity will decrease, but at the same time, small LMW molecules will be generated, and LMW will migrate to the surface of the material, making the hydrophobicity relatively increase. Therefore, the hydrophobicity cannot accurately evaluate the aging state of the material.
SEM:扫描电镜适用于观察材料的表面形貌变化,其测试结果能够表征硅橡胶材料表面的物理缺陷,随着运行年限的增加,材料表面生成大量絮状物、裂纹和孔洞,其测试结果仅能定性分析材料的老化状况,并且受主观判断影响很大,很难给出准确的定量的评估结果。SEM: Scanning electron microscope is suitable for observing the surface morphology changes of materials. The test results can characterize the physical defects on the surface of silicone rubber materials. It can qualitatively analyze the aging status of materials, and is greatly affected by subjective judgments, so it is difficult to give accurate quantitative evaluation results.
FTIR:傅里叶红外光谱测试适用于分析材料表面化学结构的变化,其测试结果仅能够表征硅橡胶材料表面的化学结构缺陷,复合绝缘子在运行过程中,由于放电粒子的撞击将导致材料化学键的断裂和活性基团的生成,表现在FTIR上为甲基基团和Si-O-Si基团等特征基团的下降,-OH活性基团的增加。但其不能够表征材料受到物理撞击等机械作用导致的物理缺陷。FTIR: Fourier transform infrared spectroscopy test is suitable for analyzing the change of chemical structure on the surface of materials. The test results can only characterize the chemical structure defects on the surface of silicone rubber materials. During the operation of composite insulators, the impact of discharge particles will cause the chemical bonds of materials to break down. Breakage and generation of active groups are manifested in FTIR as the decrease of characteristic groups such as methyl groups and Si-O-Si groups, and the increase of -OH active groups. However, it cannot characterize the physical defects of materials caused by mechanical effects such as physical impact.
TSC:热刺激电流测试是材料的微观电性能。能够体现由于材料物化缺陷而导致的陷阱特性,这些陷阱可以捕获载流子使其积累,使得局部场强畸变,导致固体介质表面可能发生闪络,加剧材料老化性能。尽管TSC测试可以反映材料的物理和化学缺陷,但TSC测试的重复性很差,一方面由于电介质试样与电极接触及其界面的影响,如果两次试验载流子注入的电极与试样接触不同(接触势垒、电极面积、杂质污染、界面态),那么在同样条件下注入载流子的数量及其分布就可能不同,对陷阱的填充也就不同,导致陷阱电荷的分布和内电场的不同,因而所引起的热刺激过程也就不同。另一方面,材料所经历的热历史以及吸收的水分、杂质等都会改变其物理或化学结构,进而改变陷阱状态。因此,不能仅利用TSC测试技术评估运行复合绝缘子的老化状态。TSC: Thermally stimulated current test is the microscopic electrical properties of materials. It can reflect the characteristics of traps caused by material physical and chemical defects. These traps can trap carriers and accumulate them, distorting the local field strength, causing flashover on the surface of solid media, and aggravating the aging performance of materials. Although the TSC test can reflect the physical and chemical defects of the material, the repeatability of the TSC test is very poor. Different (contact barrier, electrode area, impurity contamination, interface state), then the number and distribution of injected carriers may be different under the same conditions, and the filling of traps is also different, resulting in the distribution of trap charges and the internal electric field The difference of the thermal stimulation process caused by it is also different. On the other hand, the thermal history experienced by the material and the absorbed moisture, impurities, etc. will change its physical or chemical structure, and then change the trap state. Therefore, the aging state of service composite insulators cannot be evaluated only by TSC testing technology.
闪络电压:闪络电压作为衡量硅橡胶电气性能的重要标准之一,是绝缘材料宏观电特性的体现,但其由于受环境影响及材料表面状态的影响很大,试验结果分散性和误差均较大,仅将其作为评估复合绝缘子老化状态的手段,失去了试验的真实准确性。Flashover voltage: As one of the important standards to measure the electrical performance of silicone rubber, flashover voltage is the embodiment of the macroscopic electrical properties of insulating materials. However, due to the influence of the environment and the surface state of the material, the dispersion and error of the test results are uniform. Larger, it is only used as a means to evaluate the aging state of composite insulators, which loses the true accuracy of the test.
因此,在判断复合绝缘子老化状态时,若将上述6种方法按照一定权重综合评估材料的老化程度,将是一种准确度高行之有效的手段。Therefore, when judging the aging state of composite insulators, if the above six methods are used to comprehensively evaluate the aging degree of materials according to a certain weight, it will be an effective means with high accuracy.
以下结合实例具体阐述运行中的复合绝缘子老化程度的多维参量评估方法的具体内容。The specific content of the multi-dimensional parameter evaluation method for the aging degree of composite insulators in operation will be described in detail below with examples.
1.确定特征量:试样硬度采用邵氏硬度,憎水性以静态接触角进行表征,表面缺陷面积采用裂纹面积与析出物面积之和,根据FTIR光谱图特征键的相对变化率,确定Si-O-Si基团对应的吸收峰,由于陷阱电荷量更能定量反应材料的陷阱特性,确定热刺激电流(TSC)以陷阱电荷量作为特征量。1. Determine the characteristic quantity: the hardness of the sample is characterized by Shore hardness, the hydrophobicity is characterized by the static contact angle, the surface defect area is the sum of the crack area and the precipitate area, and the Si- The absorption peak corresponding to the O-Si group, because the trap charge can more quantitatively reflect the trap characteristics of the material, the thermally stimulated current (TSC) is determined to use the trap charge as a characteristic quantity.
2.采集试样:使用切片器从挂网运行过的待评估复合绝缘子伞裙表面切下圆片型高温硫化硅橡胶试样,直径为20mm,厚度3mm。2. Sample collection: Use a slicer to cut out a disc-shaped high-temperature vulcanized silicone rubber sample from the surface of the shed shed of the composite insulator to be evaluated that has been run on the hanging net, with a diameter of 20mm and a thickness of 3mm.
3.硬度试验:硬度计为邵氏硬度计,将两片硅橡胶叠加后厚度为6毫米,然后测试其硬度5次,取5次测量结果中位数。3. Hardness test: The hardness tester is a Shore hardness tester. The thickness of two pieces of silicone rubber is superimposed to 6 mm, and then the hardness is tested 5 times, and the median of the 5 measurement results is taken.
4.表面缺陷面积和红外吸收峰值的测试:利用扫描电镜(SEM)和傅里叶红外光谱(FTIR)仪进行硅橡胶材料的物化结构分析,观察其表面形貌和Si-O-Si基团峰值变化。4. Test of surface defect area and infrared absorption peak: Use scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FTIR) to analyze the physical and chemical structure of silicone rubber materials, and observe its surface morphology and Si-O-Si groups peak change.
5.憎水性试验:采用静态接触角法测量憎水角,每个试样测量5次,取其平均值。5. Hydrophobic test: The static contact angle method is used to measure the hydrophobic angle, and each sample is measured 5 times, and the average value is taken.
6.热刺激电流(TSC)试验:使用专门的切片机对圆形试样进行切片,得到用于TSC试验的直径为20mm,厚1.3mm的圆形薄片试样,通过热刺激电流技术测试陷阱电荷量。6. Thermally stimulated current (TSC) test: Use a special slicer to slice the circular sample to obtain a circular thin slice sample with a diameter of 20 mm and a thickness of 1.3 mm for the TSC test, and test the trap through thermally stimulated current technology amount of charge.
7.沿面闪络试验:采用指型电极,电极半径为8mm,电极间距离为10mm。将制备好的试样放入指型电极中央,对其施加电压,施加电压的梯度为1kV。在施加电压过程中对沿面闪络电压进行测量。每片试样进行5次闪络试验,每次试验间隔10min,闪络电压取5次的平均值。7. Flashover test along the surface: use finger electrodes, the electrode radius is 8mm, and the distance between electrodes is 10mm. Put the prepared sample into the center of the finger electrode and apply a voltage to it with a gradient of 1kV. The creepage flashover voltage is measured during the voltage application. Each sample is subjected to 5 flashover tests with an interval of 10 minutes between each test, and the flashover voltage is the average value of 5 times.
8.量化原始特征量:各测试方法所测得结果参量的单位不一致,不同参量之间数值差别较大,为了便于建立复合绝缘子的微观性能评估系统,因此对各种方法所测结果参量进行归一化处理。表面缺陷面积的归一化处理公式为:其余特征参量的归一化处理公式为:然后根据表1给出的老化程度打分信息对各特征量进行打分。8. Quantify the original characteristic quantity: the units of the measured result parameters of each test method are inconsistent, and the values of different parameters are quite different. One treatment. The normalization formula for surface defect area is: The normalization formula of the remaining characteristic parameters is: Then score each feature quantity according to the aging degree scoring information given in Table 1.
表1老化程度打分信息Table 1 Aging degree scoring information
9.评估试样老化程度:根据微观电特性和宏观特性的联系,各老化特征量的重要程度不同,因而在老化评估中其所占权重不同。微观物化特性决定了宏观物理特性及电特性,鉴于此,将微观物化特性所测结果,即扫描电镜(SEM)和傅里叶红外光谱(FTIR)测试结果的权重之和初定位1。SEM中可以观察到颗粒物生成及裂纹等缺陷形成,FTIR中反映了材料化学结构的变化。考虑到FTIR易于量化,且SEM图像中观察到的大颗粒,在FTIR测试结果中可以找到分子键断链和新键的生成,故FTIR测试结果的权重大于SEM。初步将FTIR的测试结果和SEM的测试结果权重设置为0.6、0.4。硬度的变化主要原因在于其氢氧化铝等的含量;憎水性的变化由微观物理特性和微观化学特性共同影响,即扫描电镜(SEM)和傅里叶红外光谱(FTIR)测试结果共同影响,由于FTIR中化学结构以Si-O-Si基团峰值为基准,因此憎水性的权重设定比FTIR测试结果小。憎水性影响沿面闪络电压,考虑憎水性测试结果的权重为0.4,闪络电压为0.4,硬度的权重为0.2。TSC中陷阱能级的加深原因在于内部缺陷的增多,即裂纹的形成及新的化学基团的生成,而FTIR中化学结构的变化并非均能引起陷阱能级的加深,故将TSC测试结果权重设置为与SEM和FTIR之和大体相当,考虑TSC测试结果的权重为1。9. Evaluate the aging degree of the sample: According to the relationship between the microscopic electrical characteristics and the macroscopic characteristics, the importance of each aging characteristic is different, so its weight in the aging evaluation is different. The microscopic physical and chemical properties determine the macroscopic physical and electrical properties. In view of this, the weighted sum of the measured results of the microscopic physical and chemical properties, that is, the results of scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) is initially positioned as 1. The generation of particles and the formation of defects such as cracks can be observed in SEM, and the changes in the chemical structure of materials are reflected in FTIR. Considering that FTIR is easy to quantify, and the large particles observed in SEM images, molecular bond breakage and new bond generation can be found in FTIR test results, so the weight of FTIR test results is greater than that of SEM. Preliminarily set the weights of FTIR test results and SEM test results to 0.6 and 0.4. The main reason for the change of hardness is the content of aluminum hydroxide, etc.; the change of hydrophobicity is jointly affected by microscopic physical properties and microchemical properties, that is, the results of scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) are jointly affected, due to The chemical structure in FTIR is based on the Si-O-Si group peak, so the weight setting of hydrophobicity is smaller than that of FTIR test results. Hydrophobicity affects the flashover voltage along the surface. Considering the weight of hydrophobicity test results is 0.4, the weight of flashover voltage is 0.4, and the weight of hardness is 0.2. The reason for the deepening of the trap energy level in TSC is the increase of internal defects, that is, the formation of cracks and the generation of new chemical groups, and the changes in the chemical structure in FTIR can not all cause the deepening of the trap energy level, so the TSC test results are weighted Set to roughly equal to the sum of SEM and FTIR, considering the weight of TSC test results as 1.
对试样的六个特征参量所对应的老化程度分值进行加权求和,得到表征复合绝缘子老化程度的综合特征量,根据综合特征量的大小与老化程度等级的对应关系判定目标绝缘子的老化程度。The aging degree scores corresponding to the six characteristic parameters of the sample are weighted and summed to obtain the comprehensive characteristic quantity representing the aging degree of the composite insulator, and the aging degree of the target insulator is determined according to the corresponding relationship between the comprehensive characteristic quantity and the aging degree grade .
试样老化程度也可以利用图1所示的BP神经网络进行评估,具体步骤为:The aging degree of the sample can also be evaluated using the BP neural network shown in Figure 1. The specific steps are:
a.BP神经网络训练:a.BP neural network training:
1)在Matlab中创建神经网络,可以用newff函数创建也可以在Network/Datamanager界面创建网络。1) To create a neural network in Matlab, you can use the newff function to create a network or create a network on the Network/Datamanager interface.
2)将试样特征量x1~x6和试样输出量y赋值input和output。2) Assign sample feature quantities x1 to x6 and sample output quantity y as input and output.
3)设置模型参数:神经网络为一个三层网络:输入层-隐藏层-输出层,隐藏层中神经元数目的选定一般是通过不断的改进得到,通过比较误差和输入结果等综合考虑而得,选用10个神经元,因此选定其隐含层神经元为10个,隐藏层的权值由系统随机设定,初始权值是(-1,1)之间的随机数,在BP神经网络中,神经元所采用的激活函数必须是处处可导的,大多数设计者选择使用S型函数,在这里可以采用tansig’和‘purline’函数。最大训练次数设定为5000次,误差精度设定为10-2。3) Setting model parameters: the neural network is a three-layer network: input layer-hidden layer-output layer, the selection of the number of neurons in the hidden layer is generally obtained through continuous improvement, and is determined by comprehensive consideration of comparison errors and input results. Therefore, 10 neurons are selected, so 10 neurons in the hidden layer are selected, and the weight of the hidden layer is randomly set by the system. The initial weight is a random number between (-1, 1). In neural networks, the activation function used by neurons must be derivable everywhere. Most designers choose to use Sigmoid functions, where tansig' and 'purline' functions can be used. The maximum number of training times is set to 5000, and the error precision is set to 10 -2 .
将训练好的BP神经网络存储起来,方便测试试样时调用。Store the trained BP neural network for easy calling when testing samples.
对某地区现场十余串复合绝缘子的老化特性进行测量,对TSC、FTIR、SEM、憎水性、硬度、闪络电压测试结果进行了量化和打分,结果分别为:2、3、2、1、1和1,将试样特征参量x1~x6(2、3、2、1、1、1)输入已训练好的BP神经网络,得出对应的输出y=10,因此可判断该试样为中度老化试样,符合试样主观判断结果。The aging characteristics of more than ten strings of composite insulators in a certain area were measured, and the test results of TSC, FTIR, SEM, hydrophobicity, hardness, and flashover voltage were quantified and scored. The results were: 2, 3, 2, 1, 1 and 1, input the sample characteristic parameters x1~x6 (2, 3, 2, 1, 1, 1) into the trained BP neural network, and obtain the corresponding output y=10, so it can be judged that the sample is The moderately aged sample is in line with the subjective judgment result of the sample.
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