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CN106756721B - A kind of method and device based on laser processing technology prepares coating - Google Patents

A kind of method and device based on laser processing technology prepares coating Download PDF

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CN106756721B
CN106756721B CN201710001748.7A CN201710001748A CN106756721B CN 106756721 B CN106756721 B CN 106756721B CN 201710001748 A CN201710001748 A CN 201710001748A CN 106756721 B CN106756721 B CN 106756721B
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workpiece
laser
nut
wire
water
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CN106756721A (en
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张兴权
李欢
李明明
李龙
童宝宏
裴善报
时礼平
韩蒙蒙
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Anhui University of Technology AHUT
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Laser Beam Processing (AREA)

Abstract

本发明公开一种基于激光加工技术制备涂层的方法及装置,属于零件再制造技术领域。该方法首先将工件表面涂覆一薄层黑色有机物,作为激光能量吸收层,用功率密度为GW/cm2级的脉冲激光辐照工件表面,以在工件表面产生塑性凹坑,再对处理后的工件表面清洗、干燥,用功率密度为104~106W/cm2的激光脉冲束照射喷涂丝使其熔化成为液态,液态在高压保护气吹送下高速撞击工件表面,形成涂层。本发明采用可调激光器,可以控制激光脉冲束直径和输出的能量,本发明方法制备的涂层具有界面结合力强、质量高的特点,本发明具有喷涂用时短、能耗少及无污染等技术特点。

The invention discloses a method and a device for preparing a coating based on laser processing technology, and belongs to the technical field of parts remanufacturing. In this method, a thin layer of black organic matter is firstly coated on the surface of the workpiece as a laser energy absorption layer, and the surface of the workpiece is irradiated with a pulsed laser with a power density of GW/cm 2 to produce plastic pits on the surface of the workpiece, and then the processed The surface of the workpiece is cleaned and dried, and the spraying wire is irradiated with a laser pulse beam with a power density of 10 4 ~ 10 6 W/cm 2 to melt it into a liquid state, and the liquid state hits the surface of the workpiece at high speed under the blown high-pressure protective gas to form a coating. The invention adopts an adjustable laser, which can control the diameter of the laser pulse beam and the output energy. The coating prepared by the method of the invention has the characteristics of strong interface bonding force and high quality. The invention has the advantages of short spraying time, less energy consumption and no pollution. technical features.

Description

一种基于激光加工技术制备涂层的方法及装置A method and device for preparing a coating based on laser processing technology

技术领域:Technical field:

本发明属于零件再制造技术领域,具体涉及一种基于激光加工技术制备热喷涂涂层的方法和装置。本方法首先采用激光冲击的方法在待喷涂的工件表面形成微凹坑,再使用激光熔化喷涂丝的方法在冲击处理后的工件表面形成涂层。使用该方法提高了涂层与基体界面的结合强度,提高了涂层的质量,从而大大延长了工件的使用寿命。The invention belongs to the technical field of parts remanufacturing, and in particular relates to a method and a device for preparing a thermal spray coating based on laser processing technology. The method first adopts the method of laser shock to form micro pits on the surface of the workpiece to be sprayed, and then uses the method of laser melting spraying wire to form a coating on the surface of the workpiece after shock treatment. Using this method improves the bonding strength of the coating and the substrate interface, improves the quality of the coating, and thus greatly prolongs the service life of the workpiece.

背景技术:Background technique:

涂层是涂覆在工件表面的一薄层物质,起着隔热、防腐和抗磨损等作用。热喷涂涂层在使用过程中的多种失效形式,如涂层的层离、脱落、开裂等,都和涂层与基体的结合力以及残余应力状态有关。影响涂层与工件表面的结合力主要因素有:工件表面状态、结合面积、残余应力等。工件表面状态包括表面的清洁度和表面粗糙度,表面的油污、锈迹和氧化物都会降低涂层质量和结合强度。在热喷涂过程中,由于涂层和工件基材间热物理性能的差异及高温急冷急热等原因,得到的涂层中会形成残余拉应力,拉应力的存在对涂层的使用性能是非常有害的,过大的拉应力不仅会导致涂层开裂,还会使涂层从基体上剥落下来。为了增大涂层与基体的结合力,有效地提高涂层的性能和使用寿命。在喷涂前,对工件表面进行粗化处理预处理,增大其表面的不平度,从而增加涂层与基体的结合面积,使喷涂颗粒形成交叠连锁状态,以增强结合力。目前,待喷涂工件表面粗化处理主要方法有喷砂、电火花拉毛等。The coating is a thin layer of substance coated on the surface of the workpiece, which plays the role of heat insulation, corrosion resistance and wear resistance. Various failure modes of thermal spray coatings during use, such as coating delamination, peeling, cracking, etc., are all related to the bonding force between the coating and the substrate and the state of residual stress. The main factors affecting the bonding force between the coating and the surface of the workpiece are: the surface state of the workpiece, the bonding area, and the residual stress. The surface state of the workpiece includes surface cleanliness and surface roughness, and surface oil, rust and oxides will reduce the coating quality and bonding strength. In the process of thermal spraying, due to the difference in thermal physical properties between the coating and the substrate of the workpiece and the reasons such as high temperature rapid cooling and rapid heating, residual tensile stress will be formed in the obtained coating, and the existence of tensile stress is very important to the performance of the coating. Harmful, excessive tensile stress will not only cause the coating to crack, but also cause the coating to peel off from the substrate. In order to increase the bonding force between the coating and the substrate, effectively improve the performance and service life of the coating. Before spraying, roughen the surface of the workpiece to increase the roughness of the surface, thereby increasing the bonding area between the coating and the substrate, so that the sprayed particles form an overlapping chain state to enhance the bonding force. At present, the main methods of roughening the surface of workpieces to be sprayed include sandblasting and EDM roughening.

喷砂处理是把砂粒或磨料定向喷射到待喷涂的工件表面,通过磨料的冲刷、凿削和锤击作用,使得工件表面粗化。喷砂的操作产生较大的粉尘和噪声,对环境污染较大;喷砂的强度不易控制,沙粒大小不一致,得到的凹坑深度不一致,容易导致表面粗糙度难以符合要求,深坑还会导致应力集中,产生有害的残余拉应力,使涂层的疲劳特性降低,特别是带有尖角的异型沙粒对工件表面损伤更大,严重地损害了涂层质量。Sand blasting is to spray sand or abrasives onto the surface of the workpiece to be sprayed, and roughen the surface of the workpiece through the scouring, chiseling and hammering of abrasives. The operation of sand blasting produces a lot of dust and noise, which pollutes the environment more; the intensity of sand blasting is not easy to control, the size of sand particles is inconsistent, and the depth of pits obtained is inconsistent, which easily leads to the difficulty in meeting the requirements of surface roughness, and deep pits will also It leads to stress concentration, produces harmful residual tensile stress, and reduces the fatigue properties of the coating. Especially, the special-shaped sand particles with sharp angles can cause greater damage to the surface of the workpiece, which seriously damages the coating quality.

电火花拉毛粗化是在工件表面净化后,用镍(或铝)片或丝束作电极,以工件表面作为另一电极,用手工电弧焊进行轻微焊接,在工件表面形成粗糙的薄焊层而达到粗化目的。虽然电火花拉毛粗化处理的设备简单,操作简便,但其手工操作效率较低,在焊接放电的毛化的过程中会形成拉应力,降低工件的抗疲劳性能。EDM roughening is to use nickel (or aluminum) sheets or wire bundles as electrodes after the surface of the workpiece is purified, and use the surface of the workpiece as another electrode to perform slight welding with manual arc welding to form a rough and thin welding layer on the surface of the workpiece. To achieve the purpose of coarsening. Although the equipment for EDM roughening treatment is simple and easy to operate, its manual operation efficiency is low, and tensile stress will be formed during the roughening process of welding discharge, which will reduce the fatigue resistance of the workpiece.

热喷涂是借助某种热源将喷涂材料加热至熔融状态或半熔融状态,再通过高速气流使之雾化,并以一定速度喷射和沉积到工件表面,形成具有各种功能的覆盖层的一种表面工程技术。目前主要的热喷涂方法有火焰线材喷涂、电弧喷涂等。Thermal spraying is to heat the sprayed material to a molten state or a semi-molten state by means of a certain heat source, and then atomize it through a high-speed airflow, and spray and deposit it on the surface of the workpiece at a certain speed to form a covering layer with various functions. Surface Engineering Technology. At present, the main thermal spraying methods include flame wire spraying and arc spraying.

火焰线材喷涂是较早出现的喷涂方法,其喷涂原理是以合适的速度将线材送入燃烧的火焰中,受热的线材端部熔化,并由压缩空气对熔流喷射雾化、加速,然后喷射到工件表面形成涂层。该喷涂方法由于熔融微粒所携带的热量不足,致使涂层与工件表面以机械结合为主,结合强度偏低;另外,线材的熔断、喷射不均匀造成涂层的组织不均匀,使得喷涂层的组织疏松、多孔,涂层内部的应力较大。Flame wire spraying is an earlier spraying method. Its spraying principle is to send the wire into the burning flame at a suitable speed, and the heated wire end is melted, and the molten stream is sprayed and accelerated by compressed air, and then sprayed Form a coating on the surface of the workpiece. In this spraying method, due to the lack of heat carried by the molten particles, the coating and the surface of the workpiece are mainly mechanically bonded, and the bonding strength is low; The tissue is loose and porous, and the stress inside the coating is relatively large.

电弧喷涂是将两根被喷涂的金属丝作为自耗性电极,输送直流或交流电,利用丝材端部产生的电弧作热源来熔化金属,用压缩气流雾化熔滴并喷射到基材表面形成涂层。电弧喷涂只能喷涂导电材料,在线材的熔断处产生积垢,使喷涂颗粒大小悬殊,涂层质地不均;另外,由于电弧热源温度高,造成元素的烧损量比采用火焰喷涂大,易导致涂层硬度有所下降。Arc spraying is to use two sprayed metal wires as consumable electrodes, transmit DC or AC, use the arc generated at the end of the wire as a heat source to melt the metal, use compressed air to atomize the molten droplets and spray them on the surface of the substrate to form coating. Arc spraying can only spray conductive materials, and fouling occurs at the fusing part of the wire, which makes the sprayed particle size different and the coating texture uneven; in addition, due to the high temperature of the arc heat source, the burning loss of elements is larger than that of flame spraying, which is easy resulting in a decrease in coating hardness.

发明内容:Invention content:

本发明针对现有技术存在的上述技术问题,提供一种基于激光加工技术制备涂层的方法和装置。本发明所述提供的一种基于激光加工技术制备涂层的方法具体步骤如下:The present invention aims at the above-mentioned technical problems existing in the prior art, and provides a method and device for preparing a coating based on laser processing technology. The specific steps of a method for preparing a coating based on laser processing technology provided by the present invention are as follows:

(1)在干燥洁净的工件11待喷涂的表面涂覆厚度0.05mm的黑色有机物,作为吸收层。再将工件11固定在工作台12上,开启水喷头17的水阀18,在工件11待喷涂的表面形成2mm厚的流动水层,水流速度为2~5m/s;激光脉冲束7经过聚焦透镜33后会聚,通过工作台12及聚焦透镜33的上下运动,在工件11表面形成直径为0.2~1.5mm的光斑,功率密度为GW/cm2的激光脉冲束7穿过流动的水层照射到工件11待处理表面的吸收层上,吸收层吸收激光能量后气化、电离,形成高温高压等离子体,等离子体在极短时间内膨胀,并受到水层的约束作用,产生GPa量级的冲击波。冲击波使工件11表面发生塑性变形,产生残余压应力和塑性变形的微凹坑;在水平面内移动工作台12,在工件11待处理表面的另一位置产生塑性变形的微凹坑和残余压应力,工作台12移动的速度由激光脉冲束7的频率和相邻冲击坑的距离确定,因此在待喷涂的工件11表面产生呈现一定密度点阵分布的微凹坑。(1) Coat the surface of the dry and clean workpiece 11 to be sprayed with a black organic matter with a thickness of 0.05 mm as an absorbing layer. Then the workpiece 11 is fixed on the workbench 12, the water valve 18 of the water nozzle 17 is opened, and a 2mm thick flowing water layer is formed on the surface of the workpiece 11 to be sprayed, and the water velocity is 2 to 5m/s; the laser pulse beam 7 is focused After the lens 33 converges, through the up and down movement of the worktable 12 and the focusing lens 33, a spot with a diameter of 0.2-1.5 mm is formed on the surface of the workpiece 11, and the laser pulse beam 7 with a power density of GW/cm 2 passes through the flowing water layer to irradiate On the absorbing layer on the surface of the workpiece 11 to be treated, the absorbing layer absorbs the laser energy and then vaporizes and ionizes to form a high-temperature and high-pressure plasma. The plasma expands in a very short time and is bound by the water layer to generate GPa-level plasma shock wave. The shock wave causes plastic deformation on the surface of the workpiece 11, resulting in residual compressive stress and plastically deformed micro pits; moving the worktable 12 in the horizontal plane produces plastically deformed micro pits and residual compressive stress at another position on the surface of the workpiece 11 to be processed , the moving speed of the table 12 is determined by the frequency of the laser pulse beam 7 and the distance between adjacent impact pits, so micro pits showing a certain density lattice distribution are generated on the surface of the workpiece 11 to be sprayed.

(2)开启储气罐5的气阀9,使压力为0.5-1.5MPa的保护气体进入喷枪8内,并调节水阀18的开合度,使水流速度在30m/s以上,通过气体和高压水流共同冲刷和冲洗,清除工件11表面残余的未被烧蚀的吸收层,随后关闭水阀18,等气体吹干工件11待喷涂的表面后,移动聚焦透镜的底座39,调节聚焦透镜33位置,使激光脉冲束7聚焦在左右对称设置的喷涂丝15交汇的位置上,喷涂丝15由送丝电机20带动减速器19通过送丝滚轮14送入,调整激光脉冲束7的脉冲能量,使其功率密度为104~106W/cm2,喷涂丝15被激光脉冲束7辐照后,迅速熔化为液态熔滴,高压保护气将液态熔滴迅速雾化成颗粒,形成高速运动的粒子流10撞击工件11表面,在表面形成涂层21,实现一次喷涂。通过工作台12的水平面运动进行多次喷涂,从而完成工件11整个表面的喷涂。(2) Open the gas valve 9 of the gas storage tank 5, so that the protective gas with a pressure of 0.5-1.5 MPa enters the spray gun 8, and adjust the opening and closing degree of the water valve 18, so that the water flow speed is above 30m/s, and the gas and high pressure The water flow washes and rinses together to remove the remaining unablated absorbing layer on the surface of the workpiece 11, then close the water valve 18, wait for the gas to dry the surface of the workpiece 11 to be sprayed, move the base 39 of the focusing lens, and adjust the position of the focusing lens 33 , the laser pulse beam 7 is focused on the position where the left and right symmetrically arranged spraying wires 15 meet, the spraying wire 15 is driven by the wire feeding motor 20 to drive the reducer 19 through the wire feeding roller 14, and the pulse energy of the laser pulse beam 7 is adjusted so that Its power density is 10 4 ~ 10 6 W/cm 2 . After the spraying wire 15 is irradiated by the laser pulse beam 7, it is rapidly melted into liquid droplets, and the high-pressure protective gas quickly atomizes the liquid droplets into particles to form high-speed moving particles. The flow 10 hits the surface of the workpiece 11 to form a coating 21 on the surface, realizing one-time spraying. Multiple times of spraying are performed through the horizontal movement of the worktable 12 , so as to complete the spraying of the entire surface of the workpiece 11 .

本发明提供一种基于激光加工技术制备涂层的装置,该装置包括激光发生器1、导光及调焦系统、控制系统、储气系统、喷水系统、工件装夹系统及送丝系统;所述激光发生器1能够发出短脉冲激光和连续激光;所述导光及调焦系统包括全反镜6、聚焦透镜33、底座39、上固定板32、双头螺柱41、带台肩双头螺柱29、第一薄螺母30、第二薄螺母37、第二螺母38、第三螺母40、第一螺母35、第三垫片31、第四垫片34、开合螺母36、丝杠13、电机27、电机安装支架24、螺栓25、第二垫片26及电机底座28;所述聚焦透镜33放入底座39中,通过上固定板32与底座39的螺纹连接,将聚焦透镜33固定在底座39上,所述带台肩双头螺柱29的一端通过螺纹与所述底座39连接,通过第二螺母38和第三垫片31拧紧,所述带台肩双头螺柱29的另一端设有第一薄螺母30和第二薄螺母37,第一薄螺母30和第二薄螺母37依靠它们之间的摩擦力相互并紧并使它们位置固定,喷枪8壁与带台肩双头螺柱29的台肩及第二薄螺母37之间留有间隙,使带台肩双头螺柱29能够上下自由运动;双头螺柱41的一端通过螺纹与底座39连接,通过第三螺母40和第四垫片34拧紧,双头螺柱41的另一端通过螺纹连接着开合螺母36,并通过第一螺母35拧紧固定,丝杠13与开合螺母36螺纹连接,丝杠13的另一端与电机27连接并受它驱动,电机底座28通过螺栓25和第二垫片26将电机27固定在直角状的电机安装支架24上,电机安装支架24通过螺钉23和第一垫片22固定在喷枪8壁上,聚焦透镜33的位置通过电机27和丝杠13转动驱动开合螺母36的上下移动来调节。The invention provides a device for preparing a coating based on laser processing technology, the device includes a laser generator 1, a light guiding and focusing system, a control system, a gas storage system, a water spray system, a workpiece clamping system and a wire feeding system; The laser generator 1 can emit short-pulse laser and continuous laser; the light guiding and focusing system includes a total reflection mirror 6, a focusing lens 33, a base 39, an upper fixing plate 32, a double-ended stud 41, a shouldered Stud stud 29, first thin nut 30, second thin nut 37, second nut 38, third nut 40, first nut 35, third washer 31, fourth washer 34, split nut 36, Lead screw 13, motor 27, motor mounting bracket 24, bolt 25, second spacer 26 and motor base 28; Described focusing lens 33 is put into base 39, is threaded by upper fixed plate 32 and base 39, will focus The lens 33 is fixed on the base 39, and one end of the shoulder stud 29 is connected to the base 39 by threads, and is tightened by the second nut 38 and the third gasket 31. The other end of column 29 is provided with first thin nut 30 and second thin nut 37, and first thin nut 30 and second thin nut 37 rely on the frictional force between them to be close together and make their position fixed, spray gun 8 wall and There is a gap between the shoulder of the shoulder stud 29 and the second thin nut 37, so that the stud 29 with the shoulder can move freely up and down; one end of the stud 41 is connected with the base 39 by threads , tightened by the third nut 40 and the fourth washer 34, the other end of the stud 41 is threadedly connected to the split nut 36, and is tightened and fixed by the first nut 35, the lead screw 13 is threaded to the split nut 36 , the other end of leading screw 13 is connected with motor 27 and is driven by it, and motor base 28 fixes motor 27 on the right-angled motor mounting bracket 24 by bolt 25 and second gasket 26, and motor mounting bracket 24 passes screw 23 and The first gasket 22 is fixed on the wall of the spray gun 8, and the position of the focusing lens 33 is adjusted by the motor 27 and the lead screw 13 rotating to drive the split nut 36 to move up and down.

所述储气系统包括储气罐5、气阀9及导气管4;导气管4的一端连接储气罐5,导气管4的另一端通过气阀9连接喷枪8,气阀9开启后,保护气由储气罐5经导气管4进入喷枪8内。The gas storage system includes an air storage tank 5, an air valve 9 and an air guide pipe 4; one end of the air guide pipe 4 is connected to the air storage tank 5, and the other end of the air guide pipe 4 is connected to the spray gun 8 through the air valve 9. After the air valve 9 is opened, The shielding gas enters the spray gun 8 from the gas storage tank 5 through the air guide pipe 4 .

所述喷水系统由水喷头17、水阀18及连接它们的水管组成;所述喷水系统设置在工作台12的上方。The water spray system is made up of a water spray head 17, a water valve 18 and the water pipes connecting them; the water spray system is arranged above the workbench 12.

所述送丝系统包括左右对称的送丝电机20、减速器19、喷涂丝15、送丝滚轮14及丝盘16;送丝电机20开启后,输出的转速经减速器19降速后,带动送丝滚轮14转动,将绕在丝盘16中的喷涂丝15向前移动,实现送丝。The wire feeding system includes a left-right symmetrical wire feeding motor 20, a speed reducer 19, a spray wire 15, a wire feeding roller 14 and a wire reel 16; The wire feeding roller 14 rotates to move the spraying wire 15 wound in the wire reel 16 forward to realize wire feeding.

所述工件装夹系统包括喷枪8、工件11及工作台12,喷枪8位于工作台12的正上方,且两侧开有窄槽,便于带台肩双头螺柱29和双头螺柱41通过,工件11固定在工作台12上,并随同工作台12一起运动。The workpiece clamping system includes a spray gun 8, a workpiece 11 and a workbench 12. The spray gun 8 is located directly above the workbench 12, and narrow grooves are opened on both sides, so that the shoulder studs 29 and stud studs 41 Through this, the workpiece 11 is fixed on the worktable 12 and moves together with the worktable 12 .

所述控制系统包括计算机2和控制器3;控制器3信息由计算机2输入,控制激光发生器1的发出的激光脉冲束7的频率和能量,控制工作台12移动的方向和速度,控制送丝电机20和电机27的转速及转数,控制水阀18和气阀9的开关及开合度的大小。The control system includes a computer 2 and a controller 3; the information of the controller 3 is input by the computer 2 to control the frequency and energy of the laser pulse beam 7 sent by the laser generator 1, to control the direction and speed of the movement of the worktable 12, and to control the delivery The rotating speed and the number of revolutions of silk motor 20 and motor 27 control the switch and the size of the degree of opening and closing of water valve 18 and air valve 9.

本发明具有以下技术特点:The present invention has the following technical characteristics:

1、利用激光冲击进行工件表面预处理,由于激光参数精确可控,光斑直径尺寸可以精确到微米量级,在预处理时可以根据要求产生塑性的凹坑,而且凹坑的大小和深度以及凹坑的分布密度可以控制,不会对工件表面产生划伤,从而有效地控制基材表面粗糙度,增大涂层与基体的结合面积。1. Use laser shock to pretreat the surface of the workpiece. Due to the precise and controllable laser parameters, the diameter of the spot can be accurate to the order of microns. During pretreatment, plastic pits can be produced according to requirements, and the size and depth of the pits and the pits The distribution density of the pits can be controlled without scratching the surface of the workpiece, thereby effectively controlling the surface roughness of the substrate and increasing the bonding area between the coating and the substrate.

2、利用激光冲击对工件表面进行预处理,在工件表面发生塑性变形,形成了一定厚度分布的残余压应力层,能够有效地抵消在热喷涂形成涂层的过程产生的残余拉应力,能大大降低残余拉应力对涂层质量的危害。2. The surface of the workpiece is pretreated by laser shock, plastic deformation occurs on the surface of the workpiece, and a residual compressive stress layer with a certain thickness distribution is formed, which can effectively offset the residual tensile stress generated in the process of forming a coating by thermal spraying, and can greatly Reduce the harm of residual tensile stress to coating quality.

3、激光冲击作为预处理的手段,能够细化工件表层的晶粒。在热喷涂时,基体表层细化的晶粒受热长大,但成才的速度变缓,降低了热喷涂过程中基体晶粒粗大的倾向,提高了涂层的质量。3. As a means of pretreatment, laser shock can refine the grains on the surface of the workpiece. During thermal spraying, the refined crystal grains on the surface of the substrate grow up when heated, but the growth rate slows down, which reduces the tendency of the substrate grains to become coarse during thermal spraying and improves the quality of the coating.

4、采用激光对线材加热,由于激光输出的能量精确可控,光斑的大小精确可调。因此线材的加热位置精确可调,加热的温度精确可控。既可实现粗大的线材加热,也可实现微细的线材加热,实现精细化操作;既可实现高熔点材料的加热,也可实现低熔点材料的加热,具有较大的加工的柔性。4. Laser is used to heat the wire. Since the energy output by the laser is precisely controllable, the size of the spot is precisely adjustable. Therefore, the heating position of the wire is precisely adjustable, and the heating temperature is precisely and controllable. It can not only realize the heating of thick wire rods, but also realize the heating of fine wire rods, and achieve fine operation; it can realize the heating of both high melting point materials and low melting point materials, and has greater processing flexibility.

5、本发明采用激光加工技术将预处理和喷涂工序等多个工序集中起来,代替了繁琐的表面喷砂粗化处理工序再喷涂,不仅装置简单,操作简单方便,容易实现自动化生产,而且可以精确控制,加工速度快,大大提高喷涂的加工效率。5. The present invention uses laser processing technology to integrate multiple processes such as pretreatment and spraying processes, replacing the cumbersome surface sandblasting and roughening process and then spraying. Not only is the device simple, the operation is simple and convenient, it is easy to realize automatic production, and it can Precise control, fast processing speed, greatly improve the processing efficiency of spraying.

附图说明:Description of drawings:

图1是本发明装置结构示意图;Fig. 1 is a schematic diagram of the device structure of the present invention;

图2是图1中I局部放大结构示意图;Fig. 2 is a schematic diagram of a partially enlarged structure of I in Fig. 1;

图3是图1中Ⅱ局部放大结构示意图;Fig. 3 is a schematic diagram of a partially enlarged structure of II in Fig. 1;

图4是图3中A-A向剖视结构示意图图。Fig. 4 is a schematic diagram of the cross-sectional structure along the line A-A in Fig. 3 .

图中:1:激光发生器;2:计算机;3:控制器;4:导气管;5:储气罐;6:全反镜;7:激光脉冲束;8:喷枪;9:气阀;10:粒子流;11:工件;12:工作台;13:丝杠;14:送丝滚轮;15:喷涂丝;16:丝盘;17:水喷头;18:水阀;19:减速器;20:送丝电机;21:涂层;22:第一垫片;23:螺钉;24:电机安装支架;25:螺栓;26:第二垫片;27:电机;28:电机底座;29:带台肩双头螺柱;30:第一薄螺母;31:第三垫片;32:上固定板;33:聚焦透镜;34:第四垫片;35:第一螺母;36:开合螺母;37:第二薄螺母;38:第二螺母;39:底座;40:第三螺母;41:双头螺柱。In the figure: 1: laser generator; 2: computer; 3: controller; 4: air duct; 5: gas storage tank; 6: full mirror; 7: laser pulse beam; 8: spray gun; 9: air valve; 10: particle flow; 11: workpiece; 12: workbench; 13: lead screw; 14: wire feed roller; 15: spray wire; 16: wire disc; 17: water nozzle; 18: water valve; 19: reducer; 20: wire feeding motor; 21: coating; 22: first gasket; 23: screw; 24: motor mounting bracket; 25: bolt; 26: second gasket; 27: motor; 28: motor base; 29: Stud stud with shoulder; 30: first thin nut; 31: third gasket; 32: upper fixing plate; 33: focusing lens; 34: fourth gasket; 35: first nut; 36: opening and closing Nut; 37: second thin nut; 38: second nut; 39: base; 40: third nut; 41: stud.

具体实施方式:Detailed ways:

本发明装置包括激光发生器1、导光及调焦系统、控制系统、储气系统、喷水系统、工件装夹系统及送丝系统。其中所述导光及调焦系统包括全反镜6、聚焦透镜33、底座39、上固定板32、双头螺柱41、带台肩双头螺柱29、第一薄螺母30、第二薄螺母37、第二螺母38、第三螺母40、第一螺母35、第三垫片31、第四垫片34、开合螺母36、丝杠13、电机27、电机安装支架24、螺栓25、第二垫片26及电机底座28。所述储气系统包括储气罐5、气阀9、导气管4。所述喷水系统由水喷头17、水阀18以及连接它们的水管组成。所述送丝系统包括左右对称的送丝电机20、减速器19、喷涂丝15、送丝滚轮14及丝盘16。所述工件装夹系统包括喷枪8、工件11和工作台12。所述控制系统包括计算机2和控制器3。电机27通过丝杠13、开合螺母36和双头螺柱41能够带动底座39和聚焦透镜33等上下运动自如。The device of the present invention includes a laser generator 1, a light guiding and focusing system, a control system, a gas storage system, a water spray system, a workpiece clamping system and a wire feeding system. Wherein said light guiding and focusing system comprises total reflection mirror 6, focusing lens 33, base 39, upper fixed plate 32, stud 41, stud 29 with shoulder, the first thin nut 30, the second Thin nut 37, second nut 38, third nut 40, first nut 35, third gasket 31, fourth gasket 34, split nut 36, lead screw 13, motor 27, motor mounting bracket 24, bolt 25 , the second gasket 26 and the motor base 28 . The gas storage system includes a gas storage tank 5 , a gas valve 9 , and an air guide tube 4 . Described sprinkler system is made up of sprinkler head 17, water valve 18 and the water pipe that connects them. The wire feeding system includes a symmetrical wire feeding motor 20 , a speed reducer 19 , a spraying wire 15 , a wire feeding roller 14 and a wire reel 16 . The workpiece clamping system includes a spray gun 8 , a workpiece 11 and a workbench 12 . The control system includes a computer 2 and a controller 3 . The motor 27 can drive the base 39 and the focusing lens 33 etc. to move up and down freely through the lead screw 13, the split nut 36 and the stud 41.

上述系统各部件安装完毕后,对工件11待喷涂的表面进行洁净化处理,除去表面的油脂、氧化皮和其他污物。在洁净后的工件11表面涂覆一层厚度约为100μm黑色有机物,作为激光能量吸收层,再将带有吸收层的工件11固定安装在工作台12上,能量吸收层对着喷枪8口。After the above-mentioned components of the system are installed, the surface of the workpiece 11 to be sprayed is cleaned to remove grease, scale and other dirt on the surface. Coat a layer of black organic matter with a thickness of about 100 μm on the surface of the cleaned workpiece 11 as a laser energy absorbing layer, and then fix the workpiece 11 with the absorbing layer on the workbench 12, and the energy absorbing layer faces the spray gun 8 ports.

控制器3接受计算机2指令,电机27通过丝杠13的转动来驱动开合螺母36上下移动,以调节聚焦透镜33的高度,使激光脉冲束7通过聚焦透镜33后辐照在吸收层的表面形成直径在0.2~1.5mm范围内的光斑,并开启水喷头17,以在工件11待处理的表面形成2mm厚度的流动水层。激光发生器1发出经过优化的激光脉冲束7,激光脉冲束7的光束模式可以是基模、多模等各种模式,光束模式、输出的能量和频率受控制器3调节和控制。激光脉冲束7经过全反镜6改变传播方向,通过聚焦透镜33、喷枪8和流动的水层后,照射到吸收层上,吸收层材料迅速气化、电离,形成高温高压等离子体,等离子体受到约束层作用,在工件11待喷涂的表面产生压力为GPa量级的冲击波,使工件11表面发生塑性变形,形成微凹坑,并在产生一定厚度的残余压应力层。工作台12接受控制器3的指令后在水平面内移动,保证在整个工件11待喷涂的表面形成一定间距的微凹坑。The controller 3 accepts the instructions from the computer 2, and the motor 27 drives the split nut 36 to move up and down through the rotation of the lead screw 13 to adjust the height of the focusing lens 33, so that the laser pulse beam 7 passes through the focusing lens 33 and irradiates on the surface of the absorbing layer A light spot with a diameter in the range of 0.2-1.5 mm is formed, and the water nozzle 17 is turned on to form a flowing water layer with a thickness of 2 mm on the surface of the workpiece 11 to be treated. The laser generator 1 emits an optimized laser pulse beam 7 , the beam mode of the laser pulse beam 7 can be various modes such as fundamental mode and multi-mode, and the beam mode, output energy and frequency are regulated and controlled by the controller 3 . The laser pulse beam 7 passes through the total reflection mirror 6 to change the propagation direction, passes through the focusing lens 33, the spray gun 8 and the flowing water layer, and then irradiates the absorbing layer. Under the action of the constrained layer, a shock wave with a pressure of GPa level is generated on the surface of the workpiece 11 to be sprayed, causing plastic deformation on the surface of the workpiece 11, forming micro pits, and producing a certain thickness of residual compressive stress layer. The workbench 12 moves in the horizontal plane after receiving the instruction from the controller 3 , so as to ensure that micro pits with a certain interval are formed on the entire surface of the workpiece 11 to be sprayed.

此后,气阀9收到指令后开启,保护气体进入喷枪8,水阀18的开度也增加,使水流速度在30m/s以上,在气体和高压水流共同冲刷和冲洗下,工件11表面残留的吸收层被清除干净,随后水阀18关闭,气体吹干工件11待喷涂的表面后,电机27收到控制器3的指令后转动,驱动丝杠13的转动使开合螺母36上下移动,用以调节聚焦透镜33的高度,使激光脉冲束7通过聚焦透镜33后聚焦在喷涂丝15交汇的位置,根据喷涂丝15的直径和材料的熔点,调节激光脉冲束7的能量,由控制器3调节激光的功率密度为104~106W/cm2,调整工作台12上下位置,使工件11待喷涂的表面与喷枪8的出口距离为10~15mm。送丝电机20开启,喷涂丝15由送丝电机20带动减速器19通过送丝滚轮14不断送至喷枪8出口。喷涂丝15被激光脉冲束7辐照后,迅速熔化为液态熔滴,高压保护气将液态熔滴迅速雾化,并吹动雾化的粒子流10高速撞击到工件11表面上,在工件11表面形成涂层21,实现喷涂。工作台12在水平面内运动,完成一层涂层的喷涂,根据涂层21厚度要求,增加工作台12运动循环次数以增加其厚度,当其厚度满足要求后,关闭激光发生器1、送丝电机20和气阀9,取下工件11,完成喷涂。Afterwards, the air valve 9 opens after receiving the instruction, the protective gas enters the spray gun 8, and the opening of the water valve 18 also increases, so that the water flow velocity is above 30m/s. The absorbing layer is removed, then the water valve 18 is closed, and after the gas dries the surface of the workpiece 11 to be sprayed, the motor 27 rotates after receiving the instruction of the controller 3, and the rotation of the driving screw 13 makes the split nut 36 move up and down. It is used to adjust the height of the focusing lens 33, so that the laser pulse beam 7 is focused on the position where the spraying wire 15 meets after passing through the focusing lens 33. According to the diameter of the spraying wire 15 and the melting point of the material, the energy of the laser pulse beam 7 is adjusted by the controller 3 Adjust the power density of the laser to 10 4 -10 6 W/cm 2 , and adjust the upper and lower positions of the workbench 12 so that the distance between the surface of the workpiece 11 to be sprayed and the outlet of the spray gun 8 is 10-15 mm. The wire-feeding motor 20 is turned on, and the spraying wire 15 is driven by the wire-feeding motor 20 to drive the reducer 19 to be continuously sent to the outlet of the spray gun 8 through the wire-feeding roller 14 . After the spraying wire 15 is irradiated by the laser pulse beam 7, it is rapidly melted into liquid droplets, and the high-pressure protective gas atomizes the liquid droplets rapidly, and blows the atomized particle stream 10 to hit the surface of the workpiece 11 at high speed. A coating 21 is formed on the surface to realize spraying. The workbench 12 moves in the horizontal plane to complete the spraying of a layer of coating. According to the thickness requirements of the coating 21, increase the number of movement cycles of the workbench 12 to increase its thickness. When the thickness meets the requirements, turn off the laser generator 1 and wire feeding Motor 20 and air valve 9, take off workpiece 11, finish spraying.

Claims (2)

1. a kind of method based on laser processing technology prepares coating, it is characterised in that specific step is as follows for this method:
(1) the black organic matter of a layer thickness 0.05mm is coated on the workpiece of dried and clean (11) surface to be sprayed, it is described black Color organic matter is fixed on workbench (12) as absorbed layer, then by the workpiece (11), opens the water valve of sprinkler head (17) (18), the flowing water layer of 2mm thickness is formed on the workpiece (11) surface to be sprayed, water velocity is 2~5m/s;Laser pulse Beam (7) passes through condenser lens (33) post-concentration, by the up and down motion of the workbench (12) and the condenser lens (33), The surface of the workpiece (11) forms the hot spot that diameter is 0.2~1.5mm, power density GW/cm2The laser pulse beam (7) it passes through flowing water layer to be irradiated on the absorbed layer, the absorbed layer absorbs gasification, ionization after laser energy, is formed high Warm high pressure plasma, the high temperature and pressure plasma expands in a very short period of time, and the effect of contraction by water layer, generates The shock wave of GPa magnitude, the shock wave make the workpiece (11) surface form the dimple hole being plastically deformed and residual compressive stress; The workbench (12) is move in the horizontal plane, forms plastic deformation in the another location of the workpiece (11) surface to be treated Dimple hole and residual compressive stress, the dimple hole that the distribution of certain density dot matrix is presented is generated on the workpiece (11) surface;
(2) air valve (9) for opening air accumulator (5), enters the protective gas of pressure 0.5-1.5MPa in spray gun (8), adjusts The opening degree of the water valve (18), makes water velocity reach 30m/s or more, washes away He Chong jointly by gas and high pressure water flow It washes, removes the not ablated absorbed layer of the workpiece (11) surface residual, be then turned off the water valve (18), gases is waited to dry up Behind the workpiece (11) surface to be sprayed, mobile focusing lens pedestal (39) adjusts the position of the condenser lens (33), makes institute It states laser pulse beam (7) to focus on the position that the Spray Wire (15) being symmetrical set crosses, the Spray Wire (15) is by sending Silk motor (20) drives retarder (19) to be sent by wire pushing roller (14), adjusts the pulse energy of the laser pulse beam (7), Make its power density 104~106W/cm2, the Spray Wire (15) by the laser pulse beam (7) irradiate after be molten into rapidly Liquid droplets are atomized into rapidly particle by liquid droplets, high voltage protective gas, and work described in particle high-speed impact is moved in high voltage protective air-blowing Part (11) surface forms coating (21) on the workpiece (11) surface, realizes primary spraying, pass through the water of the workbench (12) Flat movement is repeatedly sprayed, to complete the spraying of the workpiece (11) whole surface.
2. a kind of device based on laser processing technology prepares coating, it is characterised in that the device includes laser generator (1), leads Light and focusing system, control system, gas storage system, water injection system, clamping workpiece system and wire feed system;The laser generator (1) short-pulse laser and continuous laser can be issued;Described guide-lighting and focusing system include total reflective mirror (6), condenser lens (33), Pedestal (39), upper mounted plate (32), studs (41), band shoulder studs (29), the first thin nut (30), the second thin spiral shell Female (37), the second nut (38), third nut (40), the first nut (35), third gasket (31), the 4th gasket (34), folding Nut (36), lead screw (13), motor (27), motor mounting rack (24), bolt (25), the second gasket (26) and motor base (28), the condenser lens (33) is arranged in the pedestal (39), passes through fixed plate (32) and the pedestal (39) Threaded connection, the condenser lens (33) is fixed on the pedestal (39), the one of the band shoulder studs (29) End is connect by screw thread with the pedestal (39), is tightened by second nut (38) and the third gasket (31), described The other end with shoulder studs (29) is equipped with the first thin nut (30) and the second thin nut (37), first thin nut (30) it relies on the frictional force between them mutual and tight with second thin nut (37) and fixes their positions, spray gun (8) There are gaps between wall and the shoulder and second thin nut (37) of the band shoulder studs (29), make the band shoulder Studs (29) can be moved freely up and down, and one end of the studs (41) is connected by screw thread and the pedestal (39) It connects, is tightened by the third nut (40) and the 4th gasket (34), the other end of the studs (41) passes through spiral shell Line connects clasp nut (36), and tightens fixation by the first nut (35), the lead screw (13) and the clasp nut (36) It is threadedly coupled, the other end of the lead screw (13) connect with the motor (27) and driven by it, and the motor base (28) is logical It crosses bolt (25) and the motor (27) is fixed on rectangular-shaped motor mounting rack (24) by the second gasket (26), the electricity Machine mounting bracket (24) is fixed on the spray gun (8) wall by screw (23) and the first gasket (22), the condenser lens (33) position by clasp nut (36) described in the motor (27) and the lead screw (13) rotate driving move up and down into Row is adjusted;The gas storage system includes air accumulator (5), air valve (9) and gas-guide tube (4), and one end of the gas-guide tube (4) connects storage The other end of gas tank (5), the gas-guide tube (4) connects the spray gun (8) by the air valve (9), and the air valve (9) is opened Afterwards, protection gas is entered in the spray gun (8) by the air accumulator (5) through the gas-guide tube (4);The water injection system includes water spray The top of workbench 12 is arranged in head (17), water valve (18) and connection water pipe, the water injection system;The wire feed system includes a left side Right symmetrical wire feeding motor (20), retarder (19), Spray Wire (15), wire pushing roller (14) and wire tray (16), the wire feed electricity After machine (20) is opened, the revolving speed of output drives the wire pushing roller (14) to rotate, will be wound on after the retarder (19) reduction of speed The Spray Wire (15) in the wire tray (16) moves forward, and realizes wire feed;The clamping workpiece system include spray gun (8), Workpiece (11) and workbench (12), the spray gun (8) are located at the surface of workbench (12), and the two sides of the spray gun (8) are equipped with Narrow slot passes through convenient for the band shoulder studs (29) and the studs (41), and the workpiece (11) is fixed on described in work Make on platform (12), the workpiece (11) moves together in company with the workbench (12);The control system include computer (2) and Controller (3), controller (3) information are inputted by the computer (2), and the controller (3) is for controlling the laser The frequency and energy of the laser pulse beam (7) of the sending of generator (1) control the workbench (12) mobile direction and speed Degree, controls the revolving speed and revolution of the wire feeding motor (20) and the motor (27), controls the water valve (18) and the air valve (9) size of switch and opening degree.
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