CN106756202A - A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof - Google Patents
A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof Download PDFInfo
- Publication number
- CN106756202A CN106756202A CN201611036950.5A CN201611036950A CN106756202A CN 106756202 A CN106756202 A CN 106756202A CN 201611036950 A CN201611036950 A CN 201611036950A CN 106756202 A CN106756202 A CN 106756202A
- Authority
- CN
- China
- Prior art keywords
- copper
- alloy
- annealing
- temperature
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 112
- 239000000463 material Substances 0.000 title claims abstract description 43
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000000137 annealing Methods 0.000 claims abstract description 114
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 95
- 238000005096 rolling process Methods 0.000 claims abstract description 56
- 238000002844 melting Methods 0.000 claims abstract description 52
- 230000008018 melting Effects 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 40
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 35
- 229910052718 tin Inorganic materials 0.000 claims abstract description 34
- 238000005266 casting Methods 0.000 claims abstract description 32
- 238000005554 pickling Methods 0.000 claims abstract description 32
- 229910052742 iron Inorganic materials 0.000 claims abstract description 21
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 14
- 229910052796 boron Inorganic materials 0.000 claims abstract description 7
- 238000005098 hot rolling Methods 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 64
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 57
- 239000010949 copper Substances 0.000 claims description 44
- 229910052802 copper Inorganic materials 0.000 claims description 41
- RIRXDDRGHVUXNJ-UHFFFAOYSA-N [Cu].[P] Chemical compound [Cu].[P] RIRXDDRGHVUXNJ-UHFFFAOYSA-N 0.000 claims description 26
- 238000009749 continuous casting Methods 0.000 claims description 26
- RYTYSMSQNNBZDP-UHFFFAOYSA-N cobalt copper Chemical compound [Co].[Cu] RYTYSMSQNNBZDP-UHFFFAOYSA-N 0.000 claims description 25
- 238000003801 milling Methods 0.000 claims description 19
- 230000006698 induction Effects 0.000 claims description 16
- FZQBLSFKFKIKJI-UHFFFAOYSA-N boron copper Chemical compound [B].[Cu] FZQBLSFKFKIKJI-UHFFFAOYSA-N 0.000 claims description 14
- 238000001354 calcination Methods 0.000 claims description 14
- 239000003610 charcoal Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000009966 trimming Methods 0.000 claims description 4
- 238000005452 bending Methods 0.000 claims description 3
- 235000021050 feed intake Nutrition 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 62
- 239000011574 phosphorus Substances 0.000 abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000243 solution Substances 0.000 description 78
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 29
- 238000004519 manufacturing process Methods 0.000 description 18
- 239000000203 mixture Substances 0.000 description 15
- 238000005097 cold rolling Methods 0.000 description 13
- 238000005507 spraying Methods 0.000 description 13
- 229910000521 B alloy Inorganic materials 0.000 description 12
- 229910001096 P alloy Inorganic materials 0.000 description 12
- 230000005611 electricity Effects 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 229910000531 Co alloy Inorganic materials 0.000 description 11
- 239000006104 solid solution Substances 0.000 description 10
- 238000005275 alloying Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- 229910017824 Cu—Fe—P Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910018104 Ni-P Inorganic materials 0.000 description 1
- 229910018536 Ni—P Inorganic materials 0.000 description 1
- -1 Phosphorus compound Chemical class 0.000 description 1
- 229910020810 Sn-Co Inorganic materials 0.000 description 1
- 229910018757 Sn—Co Inorganic materials 0.000 description 1
- YTAHJIFKAKIKAV-XNMGPUDCSA-N [(1R)-3-morpholin-4-yl-1-phenylpropyl] N-[(3S)-2-oxo-5-phenyl-1,3-dihydro-1,4-benzodiazepin-3-yl]carbamate Chemical compound O=C1[C@H](N=C(C2=C(N1)C=CC=C2)C1=CC=CC=C1)NC(O[C@H](CCN1CCOCC1)C1=CC=CC=C1)=O YTAHJIFKAKIKAV-XNMGPUDCSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WDHWFGNRFMPTQS-UHFFFAOYSA-N cobalt tin Chemical compound [Co].[Sn] WDHWFGNRFMPTQS-UHFFFAOYSA-N 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001803 electron scattering Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000005713 exacerbation Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- DPTATFGPDCLUTF-UHFFFAOYSA-N phosphanylidyneiron Chemical compound [Fe]#P DPTATFGPDCLUTF-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/02—Alloys based on copper with tin as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Conductive Materials (AREA)
Abstract
A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof, its mass percent constitutes and is：Fe：0.1~0.3%, Ni：0.1~0.25%, Sn：0.05~0.2%, P：0.03~0.08%, B：0.005~0.015%, Co：0.02 0.10%, remaining is Cu.In addition, the alloy it further provides that iron is 0.5~4.0 with the atomic ratio of phosphorus.Wherein, the complicated pluralism Cu alloy material by melting and casting, hot rolling, breaking down, intermediate annealing, pickling, in roll, on-line solution treatment, finish rolling, obtain after the working process such as process annealing treatment.Its 450~520MPa of tensile strength, electrical conductivity is more than 75%IACS, thermal conductivity 313W/ (m.k), elongation is more than or equal to 3%, stress relaxation rate (H states, 100 DEG C of temperature, time 100h) reaches 20%, can meet use requirement of the large scale integrated circuit to middle and high end blaster fuse frame material.
Description
Technical field
The present invention relates to a kind of Copper Alloys for Lead Frame of complicated pluralism and preparation method thereof, belong to non-ferrous metal and add
Work field.
Background technology
Hyundai electronicses information technology core component is integrated circuit, and it is mainly formed by chip and lead frame are encapsulated,
Wherein lead frame mainly plays support chip, protection inner member, connection external circuit and outwards distributes the work of elements heat
With being the critical material in integrated circuit.Copper alloy is widely used in materials of lead frame by its excellent conduction, heat conductivility
Material.Exploitation and preparation for high property copper alloy rely primarily on alloying and fixation rates to realize, will low solid solution
The alloy of degree is added in copper, and by higher temperature solid solution, alloying element forms supersaturated solid solution in copper, and intensity increases,
Conductance declines, and then carries out Ageing Treatment, and a large amount of alloying elements are separated out in precipitated phase form, and even dispersion is distributed in Copper substrate
In, electrical conductivity is lifted rapidly, simultaneously because the invigoration effect of precipitated phase, intensity further gets a promotion, in conjunction with working hardening,
Finally give intensity and high conductive high property copper alloy.
Copper-based lead frame mainly has Cu-Fe-P (representative products have KFC and C194) and Cu-Ni- on domestic market
Si (representative products have C7025) series, reaches performance requirement using solid solution+Ageing Treatment.By the alloying element for controlling
Species and addition, different types of precipitated phase, content and shape characteristic can be obtained, the intensity of alloy and led so as to determine
Electric rate.Generally, as the species and content that alloying element is added increase, intensity can be lifted gradually, conductance is gradually reduced.
As KFC alloys Fe, P content are respectively 0.1% and 0.03%, alloy conductive rate is more than 80%IACS, and intensity has 400MPa or so,
But as Fe contents gradually increase, during the Fe contents 2.4% of such as C19400, strength of alloy increases to 420~520MPa, but
The conductance of alloy is reduced to 60%IACS or so.Therefore, suitable alloying element is added, rational production technology is made,
The more excellent frame material of production combination property, promotes the fast development of product in China's Copper fabrication Domain Framework, is existing rank
One of important topic of each Copper fabrication research of section and production unit.
The content of the invention
It is contemplated that the element-specific of copper-based middle addition, make and a set of be suitable for blaster fuse frame material complicated pluralism
Cu alloy material and preparation method thereof, its conductance reaches 450~530MPa more than 75%IACS, tensile strength, and its is comprehensive
Can be better than between KFC and C194 alloys.
The chemical composition of this alloy is：Fe：0.1~0.3%, Ni：0.1~0.25%, Sn：0.05~0.2%, P：0.03
~0.08%, B：0.005~0.015%, Co：0.02-0.10%, remaining is Cu.
The reasons why illustrating this design of alloy, illustrates the effect of every element.
Iron：Can with p-shaped is into iron phosphorus precipitated phase or forms simple substance iron phase, can effective crystal grain thinning, delay to recrystallize
Process, improves the intensity and hardness of copper alloy.Content is less than 0.1%, and the precipitation strength phasor of formation not enough, does not reach needs
Reinforcing effect, too high levels, the Fe elements of solid solution in Copper substrate are excessive, can reduce the electrical conductivity of copper alloy, and the analysis for being formed
Go out to strengthen phase morphology and size is partially coarse, the reinforcing to alloy is adversely affected.
Nickel element：Solution strengthening can be played a part of and promote hardening constituent to separate out, the addition of nickel element in addition can be with
Increase the wetability of alloy, improve the welded encapsulation of blaster fuse frame material.
Tin element：Because tin atom differs larger with copper atom radius, a small amount of tin element is added in copper alloy, can caused
Larger distortion of lattice, the motion of effective obstruction dislocation, especially in alloy stress relaxation, can effectively wind position
Mistake, improves alloy stress relaxation-resistant.Additionally, the addition of tin element can also significantly improve the resistance to heat release performance of alloy.But work as Sn
Constituent content, can severe exacerbation alloy conductive rate more than 0.5%.
P elements：Effect with solution strengthening, and nickel, while can be combined with nickel element, can be formed with deoxidation
Phosphorus compound, can effectively hinder the motion of dislocation, improve the stress relaxation resistance of alloy.The intermetallic formed with iron
Thing, precipitated phase dispersion-strengtherning is the main reinforcing means for lifting alloy strength, when phosphorus content is higher, the phosphorus of solid solution in Copper substrate
Element is excessive, can significantly reduce the electrical conductivity of copper alloy.
Boron element：Increase the mobility of melt, crystal grain thinning tissue improves the intensity of alloy and improves alloy conductive
Can, it is considered to which solubility of the boron element in copper is relatively low, B content scope preferably 0.005~0.015%.
Cobalt：The a small amount of cobalt of addition can form cobalt tin compound with tin, increase alloy strength, improve elastic limit.Meanwhile, it is bright
The aobvious electric conductivity and fatigue performance for improving alloy, cobalt is close with copper atom radius in addition, acts on small to electron scattering.Consider
Cobalt valency is higher, and cobalt content general control is 0.5~1.0%.
In addition to above-mentioned effect, the metallic compound formed between element and element also rises the element of addition to the performance of alloy
Important influence, especially for such copper alloy for needing and carrying out fixation rates, the species of precipitation, is contained
Amount, distribution and shape characteristic and remain in the performance to alloy of constituent content in copper-based solid solution and play decisive role, analyse
Go out thing more, distribution more disperses, reinforcing effect is more obvious, and the iron, phosphorus element content in Copper substrate are more, and conductance is lower.This
The main precipitate in ag(e)ing process of the alloy of Patent exploitation is Fe-P systems and Fe-Ni-P systems, and most Fe and P is first
Element exists all in the form of intermetallic compound, and only a small amount of is solid-solution in Copper substrate, high-strength required for finally preparing
Degree high-conductivity copper alloy.
In addition, it is of the invention in addition to being defined to Fe, P content, also to its atomicity percentage (i.e. Fe/P)
Ratio is limited, i.e., and 0.5~4.0.When Fe/P values are less than 0.5, the P Excessive lysis for containing cause alloy in Copper substrate
Conductance declines, and when Fe/P values are more than 4.0, the Fe excess for containing generates simple coarse Fe particles in the alloy, causes
Alloy strength reduction.Therefore, most the scope of Fe/P is defined as 0.5~4.0 at last.
In addition, the present invention also provides the preparation method of above-mentioned complicated pluralism blaster fuse frame material.
Including following technological process：A. according to mass percent carry out dispensing, feed intake, melting and casting, b. hot rollings, c. millings
Face, d. roughing, e. trimmings, f. bell jars annealing, g. pickling is rolled in h., and i. on-line solutions treatment, j. finish rolling, k. low temperature tension force is moved back
Fire, l. stretch-bending straightenings, n. sub-cuts storage.
In step a, founding is carried out under non-vacuum environment using power frequency induction furnace, 60% corner is added in induction furnace
Material and 40% virgin material, wherein virgin material are included in the middle of cathode copper, electrolytic nickel, copper phosphorus and copper boron, copper cobalt intermediate alloy, by temperature liter
To 1220~1250 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, after being sufficiently stirred for, standing 15~
25min, carries out D.C.casting casting, and the temperature control of casting is at 1190~1215 DEG C.
In step b, semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 830-870 DEG C, hot-working
Rate is 80-90%, and carries out solution treatment by the way of chilling of spraying water.
In step c, hot rolling blank material is carried out into the treatment of milling face, upper and lower milling face is measured about 7mm, mainly removes surface oxide layer.
In step d, the ingot blank behind milling face is carried out into cold rolling cogging, deflection is 70~85%.
In step f, bell jar annealing is carried out during the cold-reduced sheet after trimming is placed into bell-type annealing furnace, annealing temperature is 500
~550 DEG C, annealing soaking time is 5~8h, while there is the effect of recrystallization softening and Precipitation second phase particles, can be big
Amplitude improves the effective effect of conductance.
In step h, rolled during the sheet material after pickling is carried out, deflection is 60~80%.
In step i, the Strip after being rolled by carries out on-line solution treatment, using the continuous annealing line with solid solution aging function
Annealed, while carrying out online surface clean, solid solubility temperature is 850/1090/650 DEG C, and speed control is in 40-60m/min.
In step j, the band after pickling is carried out into finish rolling, deflection is 20~40%.、
In step k, to carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/380 DEG C, speed
It is 15-25m/min to spend.
Advantages of the present invention：The present invention carries out composition design and optimization by copper alloy, and strength of alloy reaches 450
~520MPa, conductance is more than 75%IACS, thermal conductivity 313W/ (m.k), stress relaxation rate (H states, 100 DEG C of temperature, time
100h) reach 20%, its combination property be better than between KFC and C194, with obvious performance and cost advantage.Its chemistry into
It is divided into：Fe 0.1~0.3%, Ni 0.1~0.25%, Sn 0.0.5~0.2%, P 0.03~0.08%, B 0.005~
0.015%, remaining is copper.In addition, the present invention have developed a kind of preparation method suitable for above-mentioned copper alloy, at processed heat
Blaster fuse frame material after reason can significantly drop through the group technology of the quick solid solution+cold working+low temperature tension Annealing of online high temperature
Low-dislocation-density, is wound between promoting dislocation, and the stress relaxation ability of material, complicated pluralism Cu-Fe-P- are significantly improved afterwards
450~the 520MPa of tensile strength of Ni-Sn-Co systems alloy, electrical conductivity is, more than 75%IACS, thermal conductivity 313W/ (m.k), to stretch
Rate long is more than or equal to 3%, and stress relaxation rate (H states, 100 DEG C of temperature, time 100h) reaches 20%, can meet extensive collection
Into circuit to the use requirement of middle and high end blaster fuse frame material.
Below by specific embodiment, the present invention will be further described, but is not meant to the scope of the present invention
Limitation.
Specific embodiment
A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof of the invention, it contains following weight
Measure the chemical composition of percentage：Fe：0.1~0.3%, Ni：0.1~0.25%, Sn：0.05~0.2%, P：0.03~
0.08%, B：0.005~0.015%, remaining is Cu.It is above-mentioned low cost, the preparation of high-conductivity copper alloy blaster fuse frame material and
Processing method, including following technological process：A. according to mass percent carry out dispensing, feed intake, melting and casting, b. hot rollings, c.
Milling face, d. roughing, e. trimmings, f. bell jars annealing, g. pickling is rolled in h., i. on-line solution aging anneals, j. finish rolling, k. pickling,
L. stretch-bending straightening, n. sub-cuts storage.
Embodiment 1
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 1.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1220 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 20min, is partly connected
Continuous casting, casting temperature is controlled to 1190 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 830 DEG C, hot-working rate is 85%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 80%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 500 DEG C, and annealing time is 8h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 70%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 55m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 25%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 23m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 1 in 2.
Embodiment 2
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 2.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1240 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 15min, is partly connected
Continuous casting, casting temperature is controlled to 1190 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 850 DEG C, hot-working rate is 88%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 75%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 520 DEG C, and annealing time is 7h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 80%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 50m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 30%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 20m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 2 in 2.
Embodiment 3
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 3.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1250 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 25min, is partly connected
Continuous casting, casting temperature is controlled to 1205 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 860 DEG C, hot-working rate is 80%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 70%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 530 DEG C, and annealing time is 6h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 60%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 45m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 30%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 19m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 3 in 2.
Embodiment 4
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 4.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, then adds tin at low temperature, and temperature is risen into 1250 DEG C,
After copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 25min, carries out semi-continuous casting, is cast
Temperature control is made for 1200 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 860 DEG C, hot-working rate is 90%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 75%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 540 DEG C, and annealing time is 6h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 75%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 40m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 35%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 17m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 4 in 2.
Embodiment 5
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 5.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1240 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 20min, is partly connected
Continuous casting, casting temperature is controlled to 1210 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 835 DEG C, hot-working rate is 86%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 80%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 550 DEG C, and annealing time is 5h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 70%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 40m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 40%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 15m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 5 in 2.
Embodiment 6
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 6.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1230 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 25min, is partly connected
Continuous casting, casting temperature is controlled to 1215 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 845 DEG C, hot-working rate is 82%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 85%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 540 DEG C, and annealing time is 6h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 65%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 60m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 35%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 16m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 6 in 2.
Embodiment 7
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 6.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1220 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 20min, is partly connected
Continuous casting, casting temperature is controlled to 1200 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 850 DEG C, hot-working rate is 86%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 75%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 540 DEG C, and annealing time is 6h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 60%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 50m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 40%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 16m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 7 in 2.
Embodiment 8
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 8.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1230 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 25min, is partly connected
Continuous casting, casting temperature is controlled to 1210 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 865 DEG C, hot-working rate is 89%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 75%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 530 DEG C, and annealing time is 7h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 65%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 45m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 35%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 17m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 8 in 2.
Embodiment 9
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 9.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1240 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 15min, is partly connected
Continuous casting, casting temperature is controlled to 1200 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 855 DEG C, hot-working rate is 85%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 80%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 510 DEG C, and annealing time is 8h.
E. rolled in：Strip to making annealing treatment by bell jar, after pickling rolls in carrying out, and working modulus is 70%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 40m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 30%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 21m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 9 in 2.
Embodiment 10
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 10.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1250 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 20min, is partly connected
Continuous casting, casting temperature is controlled to 1190 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 845 DEG C, hot-working rate is 80%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 80%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 520 DEG C, and annealing time is 7h.
E. rolled in：Strip to making annealing treatment by bell jar, after pickling rolls in carrying out, and working modulus is 75%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 45m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 25%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 24m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 10 in 2.
Embodiment 11
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 11.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1230 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 25min, is partly connected
Continuous casting, casting temperature is controlled to 1200 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 840 DEG C, hot-working rate is 82%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 85%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 500 DEG C, and annealing time is 8h.
E. rolled in：Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 75%.
R. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 50m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 20%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 15m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 11 in 2.
Embodiment 12
Alloy of the invention uses following raw material melting：Old leftover pieces, cathode copper, pure tin, pure iron, electrolytic nickel, copper phosphorus and
In the middle of copper boron, copper cobalt intermediate alloy.The composition of alloy is shown in Table 1 embodiment 12.
A. melting：Melting is carried out under non-vacuum environment using power frequency induction furnace.The addition sequence of alloy is：First add electricity
Solution copper, after fusing, adds nickel, iron, copper-phosphorus alloy, Cu-B alloy, copper-cobalt alloy, then adds tin at low temperature, by temperature liter
To 1240 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 15min, is partly connected
Continuous casting, casting temperature is controlled to 1190 DEG C.
B. semi-continuous casting production strand is carried out into stepping stove heat, hot-rolled temperature is 870 DEG C, hot-working rate is 86%,
And carry out solution treatment by the way of chilling of spraying water
C. roughing：Cold rolling cogging is carried out to the alloy behind milling face, working modulus is 85%.
D. bell jar annealing：Bell jar annealing is carried out to slab after roughing, annealing temperature is 540 DEG C, and annealing time is 5h.
E. rolled in：Strip to making annealing treatment by bell jar, after pickling rolls in carrying out, and working modulus is 80%.
F. on-line solution treatment：Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/
650 DEG C, speed is 60m/min, while carrying out online surface clean.
G. finish rolling：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 20%.
H. low temperature tension Annealing：To carrying out low temperature tension Annealing by the band after finish rolling, low-temperature anneal temperature is 350/
380 DEG C, speed is 16m/min.
By above melting and casting, roughing, intermediate annealing process, pickling, in roll, on-line solution is processed, finish rolling
After working process, its performance is shown in Table the embodiment 12 in 2.
The alloy property table of the embodiment 1-12 of table 1
The alloy property table of the embodiment 1-12 of table 2
Claims (11)
1. a kind of blaster fuse frame material complicated pluralism Cu alloy material, it is characterised in that：It contains the change of following mass fraction
Study point：Fe：0.1~0.3%, Ni：0.1~0.25%, Sn：0.05~0.2%, P：0.03~0.08%, B：0.005~
0.015%, Co：0.02-0.10%, remaining is Cu.
2. blaster fuse frame material according to claim 1 complicated pluralism Cu alloy material, it is characterised in that：Fe and P's
Atomic ratio is 0.5~4.0.
3. a kind of blaster fuse frame material preparation method of complicated pluralism Cu alloy material, comprises the following steps：A. according to quality
Percentage carry out dispensing, feed intake, melting and casting, b. hot rollings, c. milling faces, d. roughing, e. trimmings, the annealing of f. bell jars, g. pickling,
H. rolled in, the treatment of i. on-line solutions, j. finish rolling, k. low temperature tension Annealings, l. stretch-bending straightenings, n. sub-cuts storage.
4. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Founding is carried out under non-vacuum environment using power frequency induction furnace, adds 60% workshop to return corner material and 40% in power frequency induction furnace
Virgin material, wherein virgin material include in the middle of cathode copper, electrolytic nickel, copper phosphorus and copper boron, copper cobalt intermediate alloy, temperature is risen to 1220~
1250 DEG C, after copper fusing to be electrolysed, the charcoal for adding calcination is covered, and after being sufficiently stirred for, stands 15~25min, carries out half
Continuous Casting, the temperature control of casting is at 1190~1215 DEG C.
5. blaster fuse frame material according to claim 4 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Ingot casting is carried out into stepping stove heat, hot-rolled temperature is 830-870 DEG C, hot-working rate is 80-90%, and using the side of water spray chilling
Formula carries out solution treatment.
6. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Roughing is carried out to the alloy behind milling face, working modulus is 70~85%.
7. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Bell jar annealing is carried out to slab after roughing, annealing temperature is 500~550 DEG C, and annealing soaking time is 5~8h.
8. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Rolled in being carried out by the Strip after intermediate annealing process, a pickling, working modulus is 60~80%.
9. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, it is characterised in that：
Strip after being rolled by carries out on-line solution treatment, and solid solubility temperature is 850/1090/650 DEG C, and speed control is in 40-60m/
Min, while carrying out online surface clean.
10. blaster fuse frame material according to claim 3 complicated pluralism copper alloy material preparation method for material, its feature exists
In：Finish rolling is carried out to the band after on-line solution is processed, working modulus is 20~40%.
11. blaster fuse frame materials according to claim 3 complicated pluralism copper alloy material preparation method for material, its feature exists
In：To carrying out low temperature tension Annealing by the band after finish rolling, for 350/380/360 DEG C, speed control is in 15- for low temperature of moving back
25m/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611036950.5A CN106756202A (en) | 2016-11-23 | 2016-11-23 | A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611036950.5A CN106756202A (en) | 2016-11-23 | 2016-11-23 | A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106756202A true CN106756202A (en) | 2017-05-31 |
Family
ID=58971398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611036950.5A Pending CN106756202A (en) | 2016-11-23 | 2016-11-23 | A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106756202A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107447121A (en) * | 2017-06-22 | 2017-12-08 | 安徽晋源铜业有限公司 | A kind of preparation method for significantly improving lead frame Cu alloy material surface defect |
| CN110042272A (en) * | 2019-05-28 | 2019-07-23 | 中南大学 | Highly conductive high-strength CuFeNb series elastic copper alloy of one kind and preparation method thereof |
| CN111020283A (en) * | 2019-12-06 | 2020-04-17 | 宁波金田铜业(集团)股份有限公司 | Copper alloy strip for plug-in and preparation method thereof |
| CN112080658A (en) * | 2020-08-28 | 2020-12-15 | 西安斯瑞先进铜合金科技有限公司 | Preparation method of copper-iron alloy plate strip |
| CN112170484A (en) * | 2020-08-26 | 2021-01-05 | 宁波兴业鑫泰新型电子材料有限公司 | Preparation method of copper-magnesium alloy strip for automobile relay |
| CN113828961A (en) * | 2021-10-20 | 2021-12-24 | 宁波兴业盛泰集团有限公司 | Lead-free copper alloy solder and preparation method thereof |
| CN114346600A (en) * | 2021-12-24 | 2022-04-15 | 安徽鑫科铜业有限公司 | Production process of lead frame copper strip for high-end manufacturing industry |
| CN114606409A (en) * | 2022-03-31 | 2022-06-10 | 江苏恒盈电子科技有限公司 | Heat-resistant semiconductor lead frame for signal amplifier and preparation method thereof |
| CN114717445A (en) * | 2022-05-10 | 2022-07-08 | 宁波金田铜业(集团)股份有限公司 | Copper alloy and preparation method thereof |
| CN115537692A (en) * | 2022-10-13 | 2022-12-30 | 安徽绿能技术研究院有限公司 | Method for improving internal stress uniformity of copper alloy strip |
| CN115572857A (en) * | 2022-10-20 | 2023-01-06 | 菏泽广源铜带有限公司 | High-performance high-copper alloy and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005048262A (en) * | 2003-07-31 | 2005-02-24 | Nikko Metal Manufacturing Co Ltd | Cu-Ni-Si BASED ALLOY HAVING EXCELLENT FATIGUE PROPERTY |
| JP2009007666A (en) * | 2007-05-31 | 2009-01-15 | Furukawa Electric Co Ltd:The | Copper alloy for electrical and electronic equipment |
| CN101646791A (en) * | 2007-03-30 | 2010-02-10 | 日矿金属株式会社 | Cu-Ni-Si-Co-based copper alloy for electronic material, and method for production thereof |
| CN102925746A (en) * | 2012-11-29 | 2013-02-13 | 宁波兴业鑫泰新型电子材料有限公司 | High-performance Cu-Ni-Si system copper alloy, and preparation method and processing method thereof |
| CN103088229A (en) * | 2012-11-06 | 2013-05-08 | 北京有色金属研究总院 | Low-cost copper alloy for socket connectors and processing method thereof |
-
2016
- 2016-11-23 CN CN201611036950.5A patent/CN106756202A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005048262A (en) * | 2003-07-31 | 2005-02-24 | Nikko Metal Manufacturing Co Ltd | Cu-Ni-Si BASED ALLOY HAVING EXCELLENT FATIGUE PROPERTY |
| CN101646791A (en) * | 2007-03-30 | 2010-02-10 | 日矿金属株式会社 | Cu-Ni-Si-Co-based copper alloy for electronic material, and method for production thereof |
| JP2009007666A (en) * | 2007-05-31 | 2009-01-15 | Furukawa Electric Co Ltd:The | Copper alloy for electrical and electronic equipment |
| CN103088229A (en) * | 2012-11-06 | 2013-05-08 | 北京有色金属研究总院 | Low-cost copper alloy for socket connectors and processing method thereof |
| CN102925746A (en) * | 2012-11-29 | 2013-02-13 | 宁波兴业鑫泰新型电子材料有限公司 | High-performance Cu-Ni-Si system copper alloy, and preparation method and processing method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107447121A (en) * | 2017-06-22 | 2017-12-08 | 安徽晋源铜业有限公司 | A kind of preparation method for significantly improving lead frame Cu alloy material surface defect |
| CN107447121B (en) * | 2017-06-22 | 2019-04-30 | 安徽晋源铜业有限公司 | A kind of preparation method significantly improving lead frame Cu alloy material surface defect |
| CN110042272A (en) * | 2019-05-28 | 2019-07-23 | 中南大学 | Highly conductive high-strength CuFeNb series elastic copper alloy of one kind and preparation method thereof |
| CN111020283B (en) * | 2019-12-06 | 2021-07-20 | 宁波金田铜业(集团)股份有限公司 | Copper alloy strip for insert and preparation method thereof |
| CN111020283A (en) * | 2019-12-06 | 2020-04-17 | 宁波金田铜业(集团)股份有限公司 | Copper alloy strip for plug-in and preparation method thereof |
| CN112170484A (en) * | 2020-08-26 | 2021-01-05 | 宁波兴业鑫泰新型电子材料有限公司 | Preparation method of copper-magnesium alloy strip for automobile relay |
| CN112080658A (en) * | 2020-08-28 | 2020-12-15 | 西安斯瑞先进铜合金科技有限公司 | Preparation method of copper-iron alloy plate strip |
| CN113828961A (en) * | 2021-10-20 | 2021-12-24 | 宁波兴业盛泰集团有限公司 | Lead-free copper alloy solder and preparation method thereof |
| CN113828961B (en) * | 2021-10-20 | 2022-09-23 | 宁波兴业盛泰集团有限公司 | Lead-free copper alloy solder and preparation method thereof |
| CN114346600A (en) * | 2021-12-24 | 2022-04-15 | 安徽鑫科铜业有限公司 | Production process of lead frame copper strip for high-end manufacturing industry |
| CN114606409A (en) * | 2022-03-31 | 2022-06-10 | 江苏恒盈电子科技有限公司 | Heat-resistant semiconductor lead frame for signal amplifier and preparation method thereof |
| CN114717445A (en) * | 2022-05-10 | 2022-07-08 | 宁波金田铜业(集团)股份有限公司 | Copper alloy and preparation method thereof |
| CN115537692A (en) * | 2022-10-13 | 2022-12-30 | 安徽绿能技术研究院有限公司 | Method for improving internal stress uniformity of copper alloy strip |
| CN115572857A (en) * | 2022-10-20 | 2023-01-06 | 菏泽广源铜带有限公司 | High-performance high-copper alloy and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106756202A (en) | A kind of blaster fuse frame material complicated pluralism Cu alloy material and preparation method thereof | |
| CN109355525B (en) | Multi-scale multi-element high-strength high-conductivity copper chromium zirconium alloy material and preparation method thereof | |
| CN105177344B (en) | Cu-Fe alloy wire and preparing method thereof | |
| CN106282654B (en) | A kind of high resiliency low cost Sn-P-Cu alloy band and preparation method thereof | |
| CN105274386B (en) | High-performance complex multi-element phosphor bronze alloy material and preparation method thereof | |
| CN102808105B (en) | Method for preparing shape memory copper alloy | |
| CN108823466B (en) | Multi-element composite precipitation strengthening type high-strength high-conductivity copper alloy and preparation method thereof | |
| CN109609801A (en) | High property copper alloy and preparation method thereof | |
| CN106399748B (en) | A kind of cupro-nickel Si system alloy material used for lead frame and preparation method thereof | |
| CN108285988A (en) | Precipitation strength type copper alloy and its application | |
| CN103088229B (en) | Low-cost copper alloy for socket connectors and processing method thereof | |
| CN103388090A (en) | High-strength, high-conductivity and high-extensibility rare earth copper alloy and preparation method thereof | |
| CN105568039A (en) | High-strength high-conductivity copper-chromium-zirconium alloy and preparation method of plate/strip thereof | |
| CN105671356B (en) | A kind of copper alloy with high strength and high conductivity shielding material and preparation method thereof | |
| CN106636729A (en) | Polybasic copper alloy plate and strip for power battery connector and preparation method thereof | |
| CN104988350A (en) | High-ductility copper and iron alloy, preparation method thereof, and copper and iron alloy wire | |
| CN109930026B (en) | High-strength high-conductivity stress relaxation-resistant copper alloy lead frame material and preparation method thereof | |
| CN108193080A (en) | High intensity, highly conductive proof stress relaxation corson alloy material and preparation method thereof | |
| CN102912178A (en) | High-strength and high-conductivity rare-earth copper alloy and preparation method thereof | |
| CN102851527A (en) | Copper-silver-magnesium alloy contact wire and preparation method thereof | |
| CN111424224A (en) | Preparation method of high-strength high-toughness conductive copper alloy strip | |
| CN115652132B (en) | Copper alloy material and application and preparation method thereof | |
| CN104263992B (en) | Motor commutator Kufil material and preparation method thereof | |
| CN104404306B (en) | High-strength cube texture nickel base alloy baseband for coated conductors and preparation method thereof | |
| CN107400796A (en) | A kind of high-temperature-resistant high is without beryllium copper wire and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
| RJ01 | Rejection of invention patent application after publication |