CN106753932A - Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application - Google Patents
Degerming cleaning effervescent tablet of clothing biology enzyme and its preparation method and application Download PDFInfo
- Publication number
- CN106753932A CN106753932A CN201611134781.9A CN201611134781A CN106753932A CN 106753932 A CN106753932 A CN 106753932A CN 201611134781 A CN201611134781 A CN 201611134781A CN 106753932 A CN106753932 A CN 106753932A
- Authority
- CN
- China
- Prior art keywords
- clothing
- effervescent tablet
- sodium
- biology enzyme
- enzyme
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 102000004190 Enzymes Human genes 0.000 title claims abstract description 82
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 82
- 239000007938 effervescent tablet Substances 0.000 title claims abstract description 54
- 238000004140 cleaning Methods 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 238000009472 formulation Methods 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 230000002378 acidificating effect Effects 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000007844 bleaching agent Substances 0.000 claims abstract description 7
- 239000007884 disintegrant Substances 0.000 claims abstract description 7
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 229940088598 enzyme Drugs 0.000 claims description 74
- 239000002245 particle Substances 0.000 claims description 33
- 238000005469 granulation Methods 0.000 claims description 15
- 230000003179 granulation Effects 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 108091005804 Peptidases Proteins 0.000 claims description 13
- 239000004365 Protease Substances 0.000 claims description 13
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 235000019419 proteases Nutrition 0.000 claims description 12
- 102000004882 Lipase Human genes 0.000 claims description 11
- 108090001060 Lipase Proteins 0.000 claims description 11
- 239000004367 Lipase Substances 0.000 claims description 11
- 235000019421 lipase Nutrition 0.000 claims description 11
- 239000000344 soap Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 108010014251 Muramidase Proteins 0.000 claims description 9
- 102000016943 Muramidase Human genes 0.000 claims description 9
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims description 9
- 239000004325 lysozyme Substances 0.000 claims description 9
- 229960000274 lysozyme Drugs 0.000 claims description 9
- 235000010335 lysozyme Nutrition 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000004382 Amylase Substances 0.000 claims description 7
- 108010065511 Amylases Proteins 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 229940106157 cellulase Drugs 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 108010002430 hemicellulase Proteins 0.000 claims description 6
- 229940059442 hemicellulase Drugs 0.000 claims description 6
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 claims description 6
- 239000003826 tablet Substances 0.000 claims description 6
- 102000016938 Catalase Human genes 0.000 claims description 5
- 108010053835 Catalase Proteins 0.000 claims description 5
- 229940105657 catalase Drugs 0.000 claims description 5
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 5
- 229930182490 saponin Natural products 0.000 claims description 5
- 150000007949 saponins Chemical class 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 4
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- -1 olefin sulfonate Chemical class 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 229940045872 sodium percarbonate Drugs 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 claims description 3
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000002791 soaking Methods 0.000 claims 1
- 229940080313 sodium starch Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 238000005406 washing Methods 0.000 description 21
- 239000003599 detergent Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229960001367 tartaric acid Drugs 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241000060350 Citronella moorei Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 description 1
- 239000008118 PEG 6000 Substances 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 1
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229940048879 dl tartaric acid Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000007908 dry granulation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229940095696 soap product Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
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- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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Abstract
The invention discloses a kind of degerming cleaning effervescent tablet of clothing biology enzyme, by weight, the degerming cleaning effervescent tablet of clothing biology enzyme is made up of following component：Basic effervescent agent 20% ~ 55%, surfactant 15%~40%, acidic effervescent agent 10%~30%, adhesive 2%~10%, complex enzyme formulation 1%~5%, bleaching agent 0.5%~3%, disintegrant 0.5%~5%, enzyme stabilizers 0.5%~2.5%.The cleaning performance of the degerming cleaning effervescent tablet of clothing biology enzyme of the invention is good, and the effervesce time is fast, sensorial effects heat-flash；For cleaning during clothing, each component synergy in the degerming cleaning effervescent tablet of clothing biology enzyme, particularly enzyme preparation and surfactant and the synergy of various auxiliary agents, can quickly remove the various stains in clothing, surfactant noresidue after cleaning, it is healthy and safe.
Description
Technical field
The invention belongs to detergent technical field, more particularly to a kind of degerming cleaning effervescent tablet and its system of clothing biology enzyme
Preparation Method and application.
Background technology
At present, the articles for washing source of goods of in the market is extremely abundant, comes in every shape, the washing class product that function is variant is
It is a feast for the eyes.Global laundry detergent market is increased with annual 4% speed, and washing powder, liquid detergent market are tended towards stability, and laundry sheet
Rapid development, is to develop most potential product type in clothing articles for washing.For various household washing articles for use, in life often
Laundry detergents mainly have three kinds of washing powder, liquid detergent and laundry soap.Washing powder easily makes moist after opening bag, lumps and influence its matter
Amount, and consumption is uncontrollable during taking.Liquid detergent is usually bottled, and measuring cup is needed when taking, and takes in addition
Liquid detergent spilling is easily caused in journey, further, liquid detergent more than 70% is water, it has not been convenient to packed and transported, logistics space is taken.
Laundry soap meeting residual moisture during washing by rubbing with the hands, after soap box is put into, moisture is retained for a long time can soften laundry soap, cause wave
Take；Solid soap blank is blocks of solid, packaging, transport and the low cost for storing, but dissolution velocity is slow in water due to it, therefore is difficult
For machine-washing, and soap product is high to washing water quality requirement, and, intolerant to the washing of hard water, the northern area of China water hardness is all for soaps
Than larger.
With the development of science and technology washing effervescent tablet enters the life of people, washing effervescent tablet is after washing powder, laundry
The new and high technology cleaning product of another different shape after liquid, laundry sheet.Washing effervescent tablet has easy to use, consumption essence
Really, aesthetic in appearance, effervesce sensorial effects are strong during washing, the features such as clean result is good, more and more welcomed by the people.Washing
Effervescent tablet requires quickly disintegrated performance and the short time in water in water in addition to the basic demand of washing force to be met, also
Dissolving is complete, that is, wash effervescent tablet should have strong hardness again can fater disintegration, this is the main feature for washing effervescent tablet, is also
Technological difficulties.At present, washing in the market does not occur the Betengent product that clothing biology enzyme washs effervescent tablet also.
The content of the invention
It is convenient for carrying the present invention solves the technical problem of one kind is provided, the strong Multifunctional clothes of instant and washability
Thing biology enzyme wash effervescent tablet, have the advantages that it is degerming, do not hurt hands, safe and efficient, environmental protection.
In order to solve the above technical problems, one aspect of the present invention is：There is provided a kind of clothing biology enzyme degerming
Cleaning effervescent tablet, by weight, the degerming cleaning effervescent tablet of clothing biology enzyme is made up of following component：
Basic effervescent agent 20% ~ 55%；
Surfactant 15%~40%；
Acidic effervescent agent 10%~30%；
Adhesive 2%~10%；
Complex enzyme formulation 1%~5%；
Bleaching agent 0.5%~3%；
Disintegrant 0.5%~5%；
Enzyme stabilizers 0.5%~2.5%.
Preferably, the basic effervescent agent be sodium carbonate, sodium acid carbonate in one or two.
Preferably, the surfactant is sodium n-alkylbenzenesulfonate, laruyl alcohol sodium sulfovinate, fatty acid methyl ester sulfonic acid
One or more in sodium, α-sodium olefin sulfonate, laureth sodium sulfovinate, natural soap powder, Tea Saponin.The surface
Activating agent source is healthy and safe, with effects such as cleaning, emulsification, infiltration, foamings, and enzyme preparation can be helped quickly to reach spot
Surface, promote enzyme preparation decompose spot, while, moreover it is possible to by enzyme preparation decompose spot after produce product quickly remove.
Preferably, the acidic effervescent agent be citric acid, tartaric acid in one or two.
Preferably, described adhesive is dextrin, polyethylene glycol, hydroxyethyl cellulose, polyvinylpyrrolidone, methylol fibre
One or more in the plain sodium of dimension.
It is further preferred that the molecular weight of the polyethylene glycol is 6000 ~ 10000.
Preferably, the complex enzyme formulation is lipase, protease, cellulase, amylase, hemicellulase, peroxide
Change two or more in hydrogen enzyme, lysozyme.Complex enzyme formulation is the principle active component of laundry effervescent tablet, with decontamination
And sterilization, biocidal efficacies.Specifically, lipase decomposes the grease type spot on clothing；Protide on proteases for decomposing clothing
Dirt, protease also has sterilizing function；Cellulase, amylase and hemicellulase decompose the carbohydrate spot on clothing；Cross
Hydrogen oxide enzyme and lysozyme have sterilization, bactericidal action.
Preferably, the bleaching agent be sodium hypochlorite, sodium dithionite, SODIUM PERCARBONATE, sodium perborate in one kind or
It is two or more.
Preferably, the disintegrant be sodium carboxymethyl starch, PVPP, sodium chloride in one or more.
Preferably, the enzyme stabilizers be borax, potassium sorbate, sorbierite in one or two.
In order to solve the above technical problems, another technical solution used in the present invention is：There is provided a kind of clothing biological
The preparation method of the degerming cleaning effervescent tablet of enzyme, comprises the following steps：
（1）During adhesive is dissolved in into absolute ethyl alcohol or acetone, 5% solution is made, obtains solution A；
（2）Dried being placed in baking oven after the sprinkling granulation of basic effervescent agent solution A, obtain A particles；
（3）Dried being placed in baking oven after the sprinkling granulation of acidic effervescent agent solution A, obtain B particles；
（4）Surfactant is granulated and dried, C particles are obtained；
（5）A particles, B particles, C particles, complex enzyme formulation, bleaching agent, disintegrant, enzyme stabilizers are mixed, is stirred,
Grain carries out compressing tablet after crossing 20 mesh sieves, and the degerming cleaning effervescent tablet of clothing biology enzyme is obtained.
Above-mentioned steps（2）、（3）, preferably use sponging granulator and granulated.Above-mentioned steps（4）, preferably taken out through granulation
Mechanism grain is simultaneously dried.
The preparation method of the degerming cleaning effervescent tablet of clothing biology enzyme, is that the effervesce chip technology in prepared by tablet is introduced
The preparation of laundry effervescent tablet.
In order to solve the above technical problems, the present invention also provides the application of the degerming cleaning effervescent tablet of the clothing biology enzyme, 2
1 effervescent tablet is added in~5 liters of water, appropriate laundry item is put into after effervesce is finished, routinely journey after immersion 5~10 minutes
Sequence is washed, and is finally rinsed well with clear water.
The beneficial effects of the invention are as follows：For lacking in the use of existing washing powder, liquid detergent and laundry soap, transport, storage
Fall into and in the market lacks the situation that clothing biology enzyme washs effervescent tablet, the degerming cleaning effervescent tablet of clothing biology enzyme of the invention
Cleaning performance is good, and the effervesce time is fast, sensorial effects heat-flash；For cleaning during clothing, in the degerming cleaning effervescent tablet of clothing biology enzyme
Each component synergy, the particularly synergy of enzyme preparation and surfactant and various auxiliary agents can quickly remove clothing
The microorganisms such as various stains and bacterium in thing, surfactant noresidue after cleaning is healthy and safe.
Additionally, the present invention has following remarkable advantage：
1st, using tartaric acid as acidic effervescent agent, contrast commonly used acid effervesce in medicine and health products technology of preparing
Agent, one is smaller hygroscopicity；Two is acidity strong compared with citric acid；Three is good effervesce great efforts, foaming effect, gives birth to clothing of the present invention
Product can be easier to disintegration to the degerming cleaning effervescent tablet of thing enzyme in use, and dissolution velocity is fast.
2nd, preparation method uses compressing dry granulation, it is to avoid bring moisture into, while using granulation film-coating technique, it is to avoid product tide
Solution, it is easy to long-term storage and use.
3rd, under sheet solid conditions, the storage of the biology enzyme in the degerming cleaning effervescent tablet of clothing biology enzyme of the invention is steady
It is qualitative more stable than in the liquid state.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
Embodiment 1~3
It is formulated according to table 1, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 1~3 is prepared respectively, its preparation method is：First will
Polyvinylpyrrolidone, PEG-4000 are dissolved in absolute ethyl alcohol, are made 5% solution, obtain solution A；Sodium acid carbonate is passed through
It is placed in baking oven after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains A particles；By DL- wine
Stone acid is placed in baking oven by after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；
By granulating knockout machine after laureth sodium sulfovinate, natural soap powder, sodium n-alkylbenzenesulfonate, Tea Saponin are well mixed
Granulation drying, obtains C particles；By A particles, B particles, C particles, complex enzyme formulation, SODIUM PERCARBONATE, sodium carboxymethyl starch, sorbic acid
Potassium mixes, and stirs, and particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, inspection is closed
Lattice can be prepared by the degerming cleaning effervescent tablet of clothing biology enzyme of the present invention.In embodiment 1 complex enzyme formulation by lipase, protease and
Lysozyme is constituted, and complex enzyme formulation is made up of lipase and protease in embodiment 2, and complex enzyme formulation is by fat in embodiment 3
Enzyme, protease and amylase composition.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 1~3 of table 1
Embodiment 4~6
It is formulated according to table 2, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 4~6 is prepared respectively, its preparation method is：First will
PEG-8 000 is dissolved in absolute ethyl alcohol, is made 5% solution, obtains solution A；By sodium carbonate by sponging granulator solution A
It is placed in baking oven after sprinkling granulation, by anhydrous ethanol solvent volatile dry, obtains A particles；By DL- tartaric acid by sponging granulator
It is placed in baking oven after spraying granulation with solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；By laruyl alcohol sodium sulfovinate,
By granulating knockout machine granulation drying after methyl sodiosul foaliphatate, α-sodium olefin sulfonate, Tea Saponin are well mixed, C particles are obtained；
A particles, B particles, C particles, complex enzyme formulation, sodium hypochlorite, PVPP, dextrin, sorbierite are mixed, are stirred,
Particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, inspection is qualified to can be prepared by the present invention
The degerming cleaning effervescent tablet of clothing enzyme.Complex enzyme formulation is made up of lipase, protease, cellulase and lysozyme in embodiment 4,
Complex enzyme formulation is made up of lipase, protease, amylase, hemicellulase and catalase in embodiment 5, embodiment 6
Middle complex enzyme formulation is made up of lipase, protease, cellulase, amylase and lysozyme.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 4~6 of table 2
Embodiment 7~9
It is formulated according to table 3, the degerming cleaning effervescent tablet of clothing biology enzyme of embodiment 7~9 is prepared respectively, its preparation method is：First will
Polyvinylpyrrolidone, PEG-6000 0 are dissolved in absolute ethyl alcohol, are made 5% solution, obtain solution A；Sodium acid carbonate is passed through
It is placed in baking oven after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains A particles；By citric acid
It is placed in baking oven by after the sprinkling granulation of sponging granulator solution A, by anhydrous ethanol solvent volatile dry, obtains B particles；By the moon
Dried by granulating knockout machine granulation after laureth sodium sulfovinate, natural soap powder, α-sodium olefin sulfonate, Tea Saponin are well mixed
It is dry, obtain C particles；A particles, B particles, C particles, complex enzyme formulation, SODIUM PERCARBONATE, carboxyrnethyl starch sodium, borax are mixed, stirring is equal
Even, particle crosses 20 mesh sieves；Then compressing tablet is carried out, sample is extracted and is tested by quality standard, check qualified can be prepared by originally
The degerming cleaning effervescent tablet of invention clothing biology enzyme.Complex enzyme formulation is by lipase, protease, cellulase, starch in embodiment 7
Enzyme, hemicellulase, catalase and lysozyme composition, complex enzyme formulation is by lipase, protease, starch in embodiment 8
Enzyme, catalase and lysozyme composition, in embodiment 9 complex enzyme formulation by lipase, protease, cellulase, amylase,
Hemicellulase, catalase and lysozyme composition.
The formula of the degerming cleaning effervescent tablet of clothing biology enzyme of the embodiment 7~9 of table 3
Embodiment 10
The decontamination in measure by standard GB/T/T 1314-2008 dress materials with detergent detergency and circulation scourability is surveyed
Method for testing carries out detergency ability test, the results are shown in Table 4.
The detergency ability test result of table 4
The requirement of detergency national standard parameter index is as follows：Any two kinds of dirts in tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03
Cloth is more than or equal to standard liquid detergent.The degerming cleaning effervescent tablet of clothing biology enzyme of the invention, there is higher as can be seen from Table 4
Scourability.
Those skilled in the art do not depart from essence of the invention and spirit, can have various deformation scheme to realize the present invention,
Preferably feasible embodiment of the invention is the foregoing is only, not thereby limits to interest field of the invention, it is all with this
The equivalent structure change that description of the invention is made, is both contained within interest field of the invention.
Claims (12)
1. the degerming cleaning effervescent tablet of a kind of clothing biology enzyme, it is characterised in that by weight, the degerming cleaning of clothing biology enzyme
Effervescent tablet is made up of following component：
Basic effervescent agent 20% ~ 55%；
Surfactant 15%~40%；
Acidic effervescent agent 10%~30%；
Adhesive 2%~10%；
Complex enzyme formulation 1%~5%；
Bleaching agent 0.5%~3%；
Disintegrant 0.5%~5%；
Enzyme stabilizers 0.5%~2.5%.
2. the biological degerming enzyme cleaning effervescent tablet of clothing according to claim 1, it is characterised in that the basic effervescent agent is
One or two in sodium carbonate, sodium acid carbonate.
3. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the surfactant is
Sodium n-alkylbenzenesulfonate, laruyl alcohol sodium sulfovinate, methyl sodiosul foaliphatate, α-sodium olefin sulfonate, laureth sulfuric acid
One or more in ester sodium, natural soap powder, Tea Saponin.
4. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the acidic effervescent agent is
One or two in citric acid, tartaric acid.
5. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that described adhesive is paste
One or more in essence, polyethylene glycol, hydroxyethyl cellulose, polyvinylpyrrolidone, sodium cellulose glycolate.
6. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 5, it is characterised in that the polyethylene glycol point
Son amount is 6000 ~ 10000.
7. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the complex enzyme formulation is
Two or more in lipase, protease, cellulase, amylase, hemicellulase, catalase, lysozyme.
8. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the bleaching agent is time chlorine
One or more in sour sodium, sodium dithionite, SODIUM PERCARBONATE, sodium perborate.
9. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the disintegrant is carboxylic first
One or more in base sodium starch, PVPP, sodium chloride.
10. the degerming cleaning effervescent tablet of clothing biology enzyme according to claim 1, it is characterised in that the enzyme stabilizers are
One or two in borax, potassium sorbate, sorbierite.
The preparation method of the degerming cleaning effervescent tablet of clothing biology enzyme described in 11. any one of claim 1 ~ 10, it is characterised in that
Comprise the following steps：
（1）During adhesive is dissolved in into absolute ethyl alcohol or acetone, 5% solution is made, obtains solution A；
（2）Dried being placed in baking oven after the sprinkling granulation of basic effervescent agent solution A, obtain A particles；
（3）Dried being placed in baking oven after the sprinkling granulation of acidic effervescent agent solution A, obtain B particles；
（4）Surfactant is granulated and dried, C particles are obtained；
（5）A particles, B particles, C particles, complex enzyme formulation, bleaching agent, disintegrant, enzyme stabilizers are mixed, is stirred,
Grain carries out compressing tablet after crossing 20 mesh sieves, and the degerming cleaning effervescent tablet of clothing biology enzyme is obtained.
The application of the degerming cleaning effervescent tablet of clothing biology enzyme described in 12. any one of claim 1 ~ 11, it is characterised in that 2
1 effervescent tablet is added in~5 liters of water, laundry item is put into after effervesce is finished, routinely program is washed after soaking 5~10 minutes
Wash, rinsed well with clear water.
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Application publication date: 20170531 |