CN106753719B - 聚醚型全合成压缩机油组合物及其制备方法 - Google Patents
聚醚型全合成压缩机油组合物及其制备方法 Download PDFInfo
- Publication number
- CN106753719B CN106753719B CN201611208042.XA CN201611208042A CN106753719B CN 106753719 B CN106753719 B CN 106753719B CN 201611208042 A CN201611208042 A CN 201611208042A CN 106753719 B CN106753719 B CN 106753719B
- Authority
- CN
- China
- Prior art keywords
- polyethers
- polyether
- type
- oil composition
- fully synthetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010725 compressor oil Substances 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229920000570 polyether Polymers 0.000 claims abstract description 31
- -1 alkyl phenanthrene Chemical compound 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000008301 phosphite esters Chemical class 0.000 claims description 4
- 150000004867 thiadiazoles Chemical class 0.000 claims description 4
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 abstract description 19
- 230000003078 antioxidant effect Effects 0.000 abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 11
- 239000007866 anti-wear additive Substances 0.000 abstract description 11
- 239000013556 antirust agent Substances 0.000 abstract description 11
- 229930195733 hydrocarbon Natural products 0.000 abstract description 11
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 7
- 239000003995 emulsifying agent Substances 0.000 abstract description 7
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 7
- 238000007254 oxidation reaction Methods 0.000 abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 abstract description 7
- 239000011593 sulfur Substances 0.000 abstract description 7
- 230000007062 hydrolysis Effects 0.000 abstract description 6
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 239000010802 sludge Substances 0.000 abstract description 5
- 239000002270 dispersing agent Substances 0.000 abstract description 4
- 238000005461 lubrication Methods 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 10
- 239000000654 additive Substances 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 239000002530 phenolic antioxidant Substances 0.000 description 7
- 239000010452 phosphate Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- 239000010721 machine oil Substances 0.000 description 4
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 229920013639 polyalphaolefin Polymers 0.000 description 3
- 239000011833 salt mixture Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Natural products C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- WDNQRCVBPNOTNV-UHFFFAOYSA-N dinonylnaphthylsulfonic acid Chemical class C1=CC=C2C(S(O)(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 WDNQRCVBPNOTNV-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 125000003275 alpha amino acid group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
- C10M2209/1045—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明提供一种聚醚型全合成压缩机油组合物，包括按重量百分比计的以下组分：60%～85%的聚醚，5%～30%的烷基芳烃，0.5%～8%的抗氧剂，0.01%～1%的含硫或含磷极压抗磨剂，0.01%～1%的防锈剂，0.001%～0.5%的金属钝化剂，以及0.001%～0.1%的抗乳化剂。本发明还提供上述聚醚型全合成压缩机油组合物的制备方法。本发明聚醚型全合成压缩机油组合物具有优异的氧化安定性、热安定性，还具有优异的清净分散性、低积炭和油泥形成倾向，以及优秀的水解安定性和抗乳化性能，尤其适用于高温、高压的螺杆式空气压缩机的润滑。
Description
技术领域
本发明涉及工业用压缩机油技术领域，特别是涉及一种用于润滑螺杆式空气压缩机的聚醚型全合成压缩机油组合物。
背景技术
压缩机油一直以来被用于润滑压缩机轴承、密封转子、冷却压缩空气。由于空气压缩机一直处于高压、高温及有冷凝水存在的工况下，所以所需润滑油应具有优异的氧化安定性、热稳定性，低积炭和油泥形成倾向、良好的油水分离性以及优秀的防锈性能等。压缩机油的质量对压缩机使用可靠性及安全性有着很大的影响，并且好的油品能有效的减少换油周期，延长油品及设备的使用寿命。
目前市场上的压缩机油通常分为矿物型和合成型，矿物型压缩机油使用寿命短，即使采用优秀的添加剂配方，一般在4000小时以下需换油。合成型压缩机油通常以合成酯和聚α烯烃为主要基础油，与矿物型压缩机油相比，该类压缩机油的使用寿命能够延长3倍以上，具有节能、降低能耗等优点。但聚α烯烃的润滑性较差；酯类油虽具有一定的润滑性能，但水解安定性差，遇水易分解。在专利（US4302343）中显示，酯类压缩机油更适合用于往复式压缩机中，在螺杆式压缩机中其低温粘度较大，不利于低温启动。
发明内容
本发明的目的在于提供一种聚醚型全合成压缩机油组合物及其制备方法，该聚醚型全合成压缩机油组合物具有优异的氧化安定性、热安定性，还具有优异的清净分散性、低积炭和油泥形成倾向，以及优秀的水解安定性和抗乳化性能，尤其适用于高温、高压的螺杆式空气压缩机的润滑。
为实现上述目的，本发明提供一种聚醚型全合成压缩机油组合物，包括按重量百分比计的以下组分：60%～85%的聚醚，5%～30%的烷基芳烃，0.5%～8%的抗氧剂，0.01%～1%的含硫或含磷极压抗磨剂，0.01%～1%的防锈剂，0.001%～0.5%的金属钝化剂，以及0.001%～0.1%的抗乳化剂。
优选的，所述聚醚的结构为Z-(-(CHR1-CHR2-O)n-R3)m，其中，Z是含1-8个活性氢基团的起始剂，R1和R2为烷基基团，n值为10-20，R3为含1-30个C原子的烷基基团；所述聚醚的分子量为500-5000,40℃运动粘度为22-220cSt。
优选的，所述R1和R2选自CH3或CH2CH3。
优选的，所述烷基芳烃选自烷基苯、烷基萘、烷基蒽、烷基菲中的一种或几种；
所述烷基奈由含10-20个C原子的烷基中间体烷基化而得，所述烷基奈的40℃运动粘度为22-220cSt。
优选的，所述抗氧剂选自酚类抗氧剂、胺类抗氧剂、磷酸酯型抗氧剂中的一种或几种；
所述酚类抗氧剂选自2,6-二叔丁基对甲酚、2,6-二叔丁基酚、4,4'-亚甲基二(2,6-二叔丁基酚)、硫醚酚中的一种或几种；
所述胺类抗氧剂选自苯基-α-萘胺、二苯胺、烷基二苯胺中的一种或几种；
所述磷酸酯型抗氧剂为亚磷酸酯。
优选的，所述含硫或含磷极压抗磨剂选自硫代氨基甲酸酯、磷酸酯铵盐、三苯硫代磷酸酯、二硫化磷酸盐、磷酸壬基胺盐混合物中的一种或几种。
优选的，所述防锈剂选自氨基酸衍生物、有机酸、二壬基萘磺酸盐、磷酸壬基胺盐混合物中的一种或几种。
优选的，所述金属钝化剂选自苯三唑衍生物、噻二唑衍生物、专有杂环衍生物中的一种或几种。
优选的，所述抗乳化剂为聚醚类高分子化合物。
本发明还提供上述聚醚型全合成压缩机油组合物的制备方法，包括如下步骤：按重量百分比计，将60%～85%的聚醚与5%～30%的烷基芳烃加入带搅拌器的调和釜内，加热至60-70℃，调和0.5～1小时至均匀；然后加入0.5%～8%的抗氧剂、0.01%～1%的含硫或含磷极压抗磨剂、0.01%～1%的防锈剂、0.001%～0.5%的金属钝化剂以及0.001%～0.1%的抗乳化剂，在60-70℃下调和2～4小时，至混合物均匀透明。
本发明的优点和有益效果在于：提供一种聚醚型全合成压缩机油组合物及其制备方法，该聚醚型全合成压缩机油组合物具有优异的氧化安定性、热安定性，还具有优异的清净分散性、低积炭和油泥形成倾向，以及优秀的水解安定性和抗乳化性能，尤其适用于高温、高压的螺杆式空气压缩机的润滑。
聚醚是由含活性氢基团的起始剂与环氧乙烷、环氧丙烷、环氧丁烷等开环均聚或共聚制得的聚合物，其性能与分子结构紧密相关。与矿物油和其他合成油相比，聚醚具有优秀的清净分散性能，在高温下不易生成油泥和胶状物质；并且基于其极性，聚醚能形成非常稳定的具有大吸附力和承载能力的润滑剂膜，具有较低的摩擦系数与较强的抗剪切能力，因此聚醚的润滑性优于矿油、聚α烯烃和双酯。同时，聚醚还具有高粘度指数、低倾点等优异的性能。
相对于酯类油，烷基芳烃除具有出众的热氧化安定性、优异的添加剂溶解性外，还表现出优异的水解稳定性，并且，烷基芳烃中不含极性基团，其极性大大小于酯类油和多数添加剂，因而对金属表面的竞争力小，使添加剂能更好的发挥其功效。本发明中加入烷基芳烃以增加聚醚的添加剂溶解性。
螺杆压缩机油失效的一个重要原因就是压缩机油被严重氧化引起粘度增大，这也是定期换油的重要因素，因此抗老化性能是螺杆式压缩机油非常重要的特征。为满足这一要求，需要在基础油中加入抗氧剂，同时还需加入抗磨剂、防锈剂、腐蚀抑制剂、金属钝化剂等添加剂，以满足螺杆式压缩机油的其他性能。
本发明采用聚醚型全合成基础油，同时添加烷基芳烃解决聚醚的添加剂溶解问题，避免采用水解安定性较差的酯类油；同时添加高性能的添加剂，所获得的聚醚型全合成压缩机油具有优秀的氧化安定性和热安定性、优异的清净分散性、低积炭和油泥形成倾向，以及优秀的水解安定性和抗乳化性能，即使在高温高压下依然具有很长的使用寿命。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
本发明提供一种聚醚型全合成压缩机油组合物，包括按重量百分比计的以下组分：60%～85%的聚醚，5%～30%的烷基芳烃，0.5%～8%的抗氧剂，0.01%～1%的含硫或含磷极压抗磨剂，0.01%～1%的防锈剂，0.001%～0.5%的金属钝化剂，以及0.001%～0.1%的抗乳化剂。
所述聚醚的结构为Z-(-(CHR1-CHR2-O)n-R3)m，其中，Z是含1-8个活性氢基团的起始剂，R1和R2为烷基基团，n值为10-20，R3为含1-30个C原子的烷基基团；所述聚醚的分子量为500-5000,40℃运动粘度为22-220cSt；所述R1和R2选自CH3或CH2CH3。
所述烷基芳烃选自烷基苯、烷基萘、烷基蒽、烷基菲中的一种或几种；所述烷基奈由含10-20个C原子的烷基中间体烷基化而得，所述烷基奈的40℃运动粘度为22-220cSt。
所述抗氧剂选自酚类抗氧剂、胺类抗氧剂、磷酸酯型抗氧剂中的一种或几种；所述酚类抗氧剂选自2,6-二叔丁基对甲酚、2,6-二叔丁基酚、4,4'-亚甲基二(2,6-二叔丁基酚)、硫醚酚中的一种或几种；所述胺类抗氧剂选自苯基-α-萘胺、二苯胺、烷基二苯胺中的一种或几种；所述磷酸酯型抗氧剂为亚磷酸酯。
所述含硫或含磷极压抗磨剂选自硫代氨基甲酸酯、磷酸酯铵盐、三苯硫代磷酸酯、二硫化磷酸盐、磷酸壬基胺盐混合物中的一种或几种。
所述防锈剂选自氨基酸衍生物、有机酸、二壬基萘磺酸盐、磷酸壬基胺盐混合物中的一种或几种。
所述金属钝化剂选自苯三唑衍生物、噻二唑衍生物、专有杂环衍生物中的一种或几种。
所述抗乳化剂为聚醚类高分子化合物。
本发明还提供上述聚醚型全合成压缩机油组合物的制备方法，包括如下步骤：按重量百分比计，将60%～85%的聚醚与5%～30%的烷基芳烃加入带搅拌器的调和釜内，加热至60-70℃，调和0.5～1小时至均匀；然后加入0.5%～8%的抗氧剂、0.01%～1%的含硫或含磷极压抗磨剂、0.01%～1%的防锈剂、0.001%～0.5%的金属钝化剂以及0.001%～0.1%的抗乳化剂，在60-70℃下调和2～4小时，至混合物均匀透明。
本发明具体实施的技术方案包括：
实施例1
一种聚醚型全合成压缩机油组合物，其各组分按重量百分比分配如下：
聚醚：63.44%、烷基奈：28%、胺类抗氧剂：6.0%、酚类抗氧剂：2.0%、抗磨剂：0.5%、有机酸防锈剂：0.02%、苯三唑衍生物：0.02%、聚醚类抗乳化剂：0.02%。实施例1所得聚醚型全合成压缩机油组合物的主要测试性能见表1。
实施例2
一种聚醚型全合成压缩机油组合物，其各组分按重量百分比分配如下：
聚醚：64.44%、烷基奈：28%、胺类抗氧剂：5.0%、酚类抗氧剂：2.0%、抗磨剂：0.5%、有机酸防锈剂：0.02%、苯三唑衍生物：0.02%、聚醚类抗乳化剂：0.02%。实施例2所得聚醚型全合成压缩机油组合物的主要测试性能见表1。
实施例3
一种聚醚型全合成压缩机油组合物，其各组分按重量百分比分配如下：
聚醚：69.44%、烷基奈：25%、胺类抗氧剂：3.0%、酚类抗氧剂：2.0%、抗磨剂：0.5%、有机酸防锈剂：0.02%、苯三唑衍生物：0.02%、聚醚类抗乳化剂：0.02%。实施例3所得聚醚型全合成压缩机油组合物的主要测试性能见表1。
表1 各实施例性能测试数据
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (2)
1.聚醚型全合成压缩机油组合物，其特征在于，包括按重量百分比计的以下组分：60%～85%的聚醚，5%～30%的烷基菲，0.5%～8%的亚磷酸酯，0.01%～1%的硫代氨基甲酸酯，0.01%～1%的磷酸壬基胺盐，0.001%～0.5%的噻二唑衍生物，以及0.001%～0.1%的聚醚类高分子化合物；
所述聚醚的结构为Z-(-(CHR1-CHR2-O)n-R3)m，其中，Z是含1-8个活性氢基团的起始剂，R1和R2为选自CH3或CH2CH3，n值为10-20，R3为含1-30个C原子的烷基基团；所述聚醚的分子量为500-5000,40℃运动粘度为22-220cSt。
2.权利要求1所述聚醚型全合成压缩机油组合物的制备方法，其特征在于，包括如下步骤：按重量百分比计，将60%～85%的聚醚与5%～30%的烷基菲加入带搅拌器的调和釜内，加热至60-70℃，调和0.5～1小时至均匀；然后加入0.5%～8%的亚磷酸酯、0.01%～1%的硫代氨基甲酸酯、0.01%～1%的磷酸壬基胺盐、0.001%～0.5%的噻二唑衍生物以及0.001%～0.1%的聚醚类高分子化合物，在60-70℃下调和2～4小时，至混合物均匀透明。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611208042.XA CN106753719B (zh) | 2016-12-23 | 2016-12-23 | 聚醚型全合成压缩机油组合物及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611208042.XA CN106753719B (zh) | 2016-12-23 | 2016-12-23 | 聚醚型全合成压缩机油组合物及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106753719A CN106753719A (zh) | 2017-05-31 |
| CN106753719B true CN106753719B (zh) | 2019-10-11 |
Family
ID=58920271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611208042.XA Active CN106753719B (zh) | 2016-12-23 | 2016-12-23 | 聚醚型全合成压缩机油组合物及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106753719B (zh) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108690693A (zh) * | 2018-05-31 | 2018-10-23 | 烟台恒邦化工有限公司 | 一种高铁专用齿轮油及其制备方法 |
| CN108865358A (zh) * | 2018-07-20 | 2018-11-23 | 烟台恒邦化工有限公司 | 一种长寿命螺杆空气压缩机油及其制备方法 |
| CN109321336A (zh) * | 2018-10-30 | 2019-02-12 | 深圳市鸿庆泰石油添加剂有限公司 | 螺杆压缩机油及其制备方法 |
| CN109536257A (zh) * | 2018-12-13 | 2019-03-29 | 佛山市安德森科技有限公司 | 一种抗乳化变频空压机专用润滑油 |
| CN109536258A (zh) * | 2018-12-19 | 2019-03-29 | 上海森帝润滑技术有限公司 | 离心压缩机用全合成油 |
| CN110029004A (zh) * | 2019-04-08 | 2019-07-19 | 江苏龙蟠科技股份有限公司 | 一种电动空压机用润滑油组合物及其制备方法 |
| CN112940692A (zh) * | 2021-01-25 | 2021-06-11 | 广东石油化工学院 | 热管理系统液组合物 |
| CN119372006A (zh) * | 2023-07-25 | 2025-01-28 | 中国石油天然气股份有限公司 | 聚醚类高压天然气压缩机气缸油组合物 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101484560A (zh) * | 2006-07-06 | 2009-07-15 | 新日本石油株式会社 | 冷冻机油、压缩机油组合物、液压工作油组合物、金属加工油组合物、热处理油组合物、工作机械用润滑油组合物、润滑油组合物 |
| CN101955841A (zh) * | 2010-09-09 | 2011-01-26 | 中国石油化工股份有限公司 | 一种压缩多组份混合烃类气体的合成压缩机油 |
| CN102618360A (zh) * | 2011-01-27 | 2012-08-01 | 中国石油化工股份有限公司 | 压缩机油组合物 |
| CN105255567A (zh) * | 2015-11-16 | 2016-01-20 | 湖北海拓化工科技有限公司 | 一种冷冻机油组合物及其应用 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9593292B2 (en) * | 2013-03-13 | 2017-03-14 | The Lubrizol Corporation | Engine lubricants containing a polyether |
-
2016
- 2016-12-23 CN CN201611208042.XA patent/CN106753719B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101484560A (zh) * | 2006-07-06 | 2009-07-15 | 新日本石油株式会社 | 冷冻机油、压缩机油组合物、液压工作油组合物、金属加工油组合物、热处理油组合物、工作机械用润滑油组合物、润滑油组合物 |
| CN101955841A (zh) * | 2010-09-09 | 2011-01-26 | 中国石油化工股份有限公司 | 一种压缩多组份混合烃类气体的合成压缩机油 |
| CN102618360A (zh) * | 2011-01-27 | 2012-08-01 | 中国石油化工股份有限公司 | 压缩机油组合物 |
| CN105255567A (zh) * | 2015-11-16 | 2016-01-20 | 湖北海拓化工科技有限公司 | 一种冷冻机油组合物及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106753719A (zh) | 2017-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106753719B (zh) | 聚醚型全合成压缩机油组合物及其制备方法 | |
| CN106753720B (zh) | 半合成压缩机油组合物及其制备方法 | |
| CN102618360B (zh) | 压缩机油组合物 | |
| CN103981005A (zh) | 用于回转式螺杆空气压缩机的润滑油组合物及其制备方法 | |
| CN110846113A (zh) | 一种多元醇酯类空气压缩机油组合物及其制备方法 | |
| US9365797B2 (en) | Lubricant oil composition for transmissions | |
| TW200923071A (en) | Lubricating oil base oil and lubricating oil composition | |
| CN102337175B (zh) | 一种具有高极压性能的液压油组合物 | |
| TW201211234A (en) | Lubricant base oil and lubricant composition | |
| JP2011162652A (ja) | 潤滑油組成物 | |
| CN106701290B (zh) | 润滑脂组合物及其制备方法 | |
| CN104395274B (zh) | 烷基化二苯基醚化合物及含有该化合物的润滑油剂 | |
| CN103946354A (zh) | 高温油脂 | |
| CN116286149A (zh) | 一种全合成真空泵油组合物及其应用 | |
| JP2012087221A (ja) | グリース組成物 | |
| CN104507900B (zh) | 烷基化二苯基醚化合物及含有该化合物的润滑油剂 | |
| CN115386413B (zh) | 一种长寿命螺杆型空压机油复合剂及其制备方法 | |
| CN106147946A (zh) | 一种冷冻机油组合物及其应用 | |
| CN103031188A (zh) | 螺杆式氨压缩机油组合物 | |
| CN104927994B (zh) | 冷冻机油和制冷压缩机及系统 | |
| CN105238522A (zh) | 润滑油组合物及用途 | |
| CN109536258A (zh) | 离心压缩机用全合成油 | |
| CN100540639C (zh) | 螺杆式空气压缩机超冷剂 | |
| CN116904252A (zh) | 一种烃类气体压缩机润滑油及其制备方法和应用 | |
| CN103031186A (zh) | 提高含铜氨液的氨压缩机油抗氧化性的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |