CN106752741A - Ultraviolet light polymerization alkali-resistant coating composition - Google Patents
Ultraviolet light polymerization alkali-resistant coating composition Download PDFInfo
- Publication number
- CN106752741A CN106752741A CN201611117857.7A CN201611117857A CN106752741A CN 106752741 A CN106752741 A CN 106752741A CN 201611117857 A CN201611117857 A CN 201611117857A CN 106752741 A CN106752741 A CN 106752741A
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- Prior art keywords
- ultraviolet light
- coating composition
- resistant coating
- polyamine
- light polymerization
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of ultraviolet light polymerization alkali-resistant coating composition, including the following component counted by weight：35~80 parts of epoxy acrylate；15~50 parts of urethane acrylate；5~15 parts of photo-curing monomer；1~5 part of light trigger；0.01~0.05 part of auxiliary agent；Also including weight is other component weights 2~4 times of solvent.The present invention has following beneficial effect：The present invention is particularly well-suited to the anticorrosive paint of aluminium material surface because that using epoxy acrylate collocation urethane acrylate and high-ranking official's photo-curing monomer with excellent chemical moral character, can be made the good ultraviolet-curing paint of alkali resistance.
Description
Technical field
The present invention relates to a kind of ultraviolet light polymerization alkali-resistant coating composition, belong to photocureable coating technical field.
Background technology
Because ultraviolet light photocureable coating has " 5E " feature：Environment-friendly (Environmental friendly), warp
Ji (Economical), efficiently (Efficient), energy-conservation (Energy saving) and wide adaptability (Enabling).At present
Through being widely used in protection and the decorative paint on the surfaces such as plastics, metal, glass, timber, paper, it is specific as some be used for mobile phone,
The surface of the surface stiffened coating, automobile industry plastics and metal parts of the industry plastic basis material such as computer, TV, household electrical appliances is protected
Shield coating, printing ink of circuit board, metal insulated paint, optical fiber coatings, beverage tank coating, top grade are packed (plastic basis material and paper base material)
Very rapidly development is suffered from coating, high-grade nail polish, medicine equipment and automobile industry.It is hard well in order to assign coating
Degree, wear-resisting, scratch resistance and adhesive force, so matrix resin uses urethane acrylate mostly in photocureable coating, particularly gather
Ester type urethane acrylate.But because the hydrolytic resistance particularly alkali resistance of ester bond and amino-formate bond is poor, therefore,
Some need the necks such as alkali resistance requirement field high, such as metal, home appliance panel, the air conditioner vane manufacture especially with aluminium base
Domain does not often reach requirement.
Chinese patent CN102850899 discloses a kind of photocuring alkali resistance coating, and the coating is high poly- using a kind of solid
Thing improves alkali resistance.But the embodiment according to the patent can be seen that solid superpolymer is some thermoplastic polymers,
Photo curable double bond is not carried, therefore these solid superpolymers are the addition coating system in the form of physical blending,
Because without the double bond that can carry out photopolymerization, cross-linked network will not be formed after photocuring with other light-cured resins and monomer
Network, therefore the crosslink density of final coating can be reduced, as a result the hardness of coating, wear-resisting and adhesive force can decline accordingly.
Chinese patent CN102146253 discloses a kind of uv radiation curing anti-corrosive organic coatings and preparation method, should
Coating is using cationic prepolymer polymers and the freedom of bisphenol A epoxy acrylate with the good epoxy resin structural of chemical-resistant
Base oligomer reaches the effect of the alkali corrosion of resistance to 20-40% as matrix resin.But the coating except need it is conventional from
By base light trigger, in addition it is also necessary to use cation light initiator, and cation light initiator price general charged is all costly, so
The cost of the coating can be very high, is difficult to be applied in general industry.
The content of the invention
The present invention shortcoming poor to solve traditional ultraviolet-curing paint alkali resistance, the invention provides a kind of ultraviolet light
Solidification alkali-resistant coating composition, by good by introducing alkali resistance many official's bisphenol A epoxy acrylates in coating, and
High-ranking official's urethane acrylate and high-ranking official's monomer component are equipped with, the coating with cross-linked network high is obtained after photocuring, its tool
There is very excellent alkali resistance.It is particularly well-suited to the surface anticorrosion coating of aluminium.
The purpose of the present invention is achieved through the following technical solutions：
The invention provides a kind of ultraviolet light polymerization alkali-resistant coating composition, including count by weight such as the following group
Point：
Preferably, the composition also includes solvent, and the weight of the solvent is 2~4 times of other components gross weight.
In the present invention, if epoxy acrylate is higher than 80 parts, or urethane acrylate is when being less than 15 parts, or light is solid
When changing monomer higher than 15 parts, gained film is too crisp after causing final photocuring, and base material adhesive force is declined.If propylene oxide
Acid esters is less than 35 parts, or urethane acrylate is higher than 50 parts, or photo-curing monomer is when being less than 5 parts, can cause final
Film temperature tolerance declines and alkali resistance declines.
If light trigger is higher than 5 parts, a large amount of free radicals can be produced under UV illumination, cause the final three-dimensional network of gained to be polymerized
Thing molecular weight is low, causes film more crisp, and adhesive force can be deteriorated, while can also improve coating cost.If light trigger is less than 1 part,
Can produce free radical insufficient under UV illumination, it is more to cause to remain resin and content of monomer without photopolymerization, cause final painting
Film surface drying is bad, tacky, can not use at all.If auxiliary agent, when the present invention refers to that polymerization inhibitor is less than 0.01 part, the storage of coating is steady
Qualitative difference；Can just make coating that photocuring is fully achieved, it is necessary to improve UV luminous intensities during higher than 0.05 part, common luminous intensity is deposited
In the danger that can not be fully cured.
When the amount of solvent is higher than 4 times of monomer and total resin weight, coating is too dilute, and coating thickness is too low, causes final film
Hardness it is too low, wear-resisting variation.If the amount of solvent is less than 2 times of monomer and total resin weight, dope viscosity is too big, is easily caused
Film levelling is bad, and coating thickness is too thick, also brings along the incomplete problem of solidification.
Preferably, the epoxy acrylate is modified bisphenol A epoxy acrylate, the modified bisphenol A epoxy propylene
Acid esters is obtained with double official's bisphenol A epoxy acrylates for polyamine through Michael addition reaction.
Preferably, the polyamine be aliphatic polyamine, alicyclic polyamine or aromatic polyamine in one kind or
Various mixing.
Preferably, the aliphatic polyamine is diethylenetriamine, triethylene tetramine, TEPA and pentaethylene hexamine
In one kind；The alicyclic polyamine is in 1,3- bis aminomethyls hexamethylene, 4,4'- diamino-dicyclohexyl methanes
Kind；The aromatic polyamine is the one kind in p dimethylamine and m-xylene diamine.
It is highly preferred that the polyamine is the one kind in triethylene tetramine, pentaethylene hexamine and m-xylene diamine.
Preferably, the Michael addition reaction specifically includes following steps：
At ambient temperature, by the ethyl acetate solution of polyamine, double official's bisphenol-A epoxy propylene were added drop-wise in 1 hour
In the ethyl acetate solution of acid esters, reaction 5 hours is then proceeded to, obtain many official's bisphenol A epoxy acrylates, i.e. modified bisphenol A
Epoxy acrylate；The degree of functionality of many official's bisphenol A epoxy acrylates is more than 2.
Preferably, active hydrogen and the mol ratio of double official's bisphenol A epoxy acrylates are 1 in the polyamine:1.Thus may be used
It is 1 to extrapolate polyamine (active hydrogen number=n) and double official's bisphenol A epoxy acrylate mol ratios：n.Such as triethylene tetramine
There are six active hydrogens, then triethylene tetramine and the mol ratio of double official's bisphenol A epoxy acrylates are 1:6.
Preferably, the urethane acrylate is high-ranking official polyurethane acrylic resin of the degree of functionality more than or equal to 3.
Preferably, the photo-curing monomer is high-ranking official monomer of the degree of functionality more than or equal to 3, specially trimethylolpropane tris
Acrylate, pentaerythritol triacrylate, three (2- ethoxys) isocyanuric acid triacrylates, the acid of pentaerythrite tetrapropylene
One or more in ester, dipentaerythritol acrylate.
Preferably, the light trigger is 1- hydroxycyclohexyl phenyl ketones, 2,4,6- trimethylbenzoy-diphenies
One or more the composition of phosphine oxide, 2- methyl isophthalic acids-(4- methyl mercaptos phenyl) -2- morpholine -1- acetone；The auxiliary agent
Including one or more in levelling agent, polymerization inhibitor.
It is highly preferred that the levelling agent is polyether-modified polysiloxanes, dimethyl silicone polymer, polyacrylate helping
One or two in agent；The polymerization inhibitor is hydroquinones, MEHQ, 2.6- BHTs, the tertiary fourths of 2-
One or more in base hydroquinones.
Preferably, the solvent is ethyl acetate, butyl acetate, isopropanol, n-butanol, acetone, butanone, ethylene glycol fourth
One or more in ether, propylene glycol monomethyl ether, propylene glycol methyl ether acetate.
It is highly preferred that mixture of the solvent for ethyl acetate, butyl acetate and isopropanol, the weight ratio of three is 2:
3:1。
Present invention also offers a kind of preparation method of ultraviolet light polymerization alkali-resistant coating composition, comprise the following steps：
By epoxy acrylate, urethane acrylate, photo-curing monomer and solvent mix after, add light trigger and
Auxiliary agent, is well mixed, that is, the ultraviolet light polymerization alkali-resistant coating composition is obtained.
Prior art is compared, and the present invention has following beneficial effect：
1st, there is most of hydroxyl the bisphenol A epoxide resin part (i.e. modified bisphenol A epoxy acrylate) that the present invention is used,
Its hydroxyl value is more than two common official's bisphenol A epoxide resins, therefore splendid to the adhesive force of metal surface.
2nd, because containing a large amount of phenyl ring, and due to forming high density cross-linked network high after photocuring, so the resistance to height of film
Temperature, more than 200 DEG C.
3rd, water boiling resistance excellent performance, more than 2 hours in boiling water.
4th, alkaline resistance properties is excellent, can stand 10%NaOH solution and corrode more than 24 hours.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that to the ordinary skill of this area
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment and comparative example
As shown in table 1, urethane acrylate is by following methods system to the formula of each embodiment and comparative example described in table 1
For what is obtained, wherein amount of solid content is 70%.
At ambient temperature, by the ethyl acetate solution of polyamine, double official's bisphenol-A epoxy propylene were added drop-wise in 1 hour
In the ethyl acetate solution of acid esters, reaction 5 hours is then proceeded to, obtain many official's bisphenol A epoxy acrylates.
Wherein, active hydrogen and double official's bisphenol A epoxy acrylate mol ratios are 1 in polyamine：1, it is possible to extrapolate
Polyamine (active hydrogen number=n) is 1 with double official's bisphenol A epoxy acrylate mol ratios：n.As triethylene tetramine has six vivaciously
Hydrogen, then triethylene tetramine and the mol ratio of double official's bisphenol A epoxy acrylates are 1:6.
It is CN104 (the double bond density=2.6mmol/ of Sartomer used herein of double official's bisphenol A epoxy acrylates
g)。
The compound method of each embodiment and comparative example coating composition is as follows：
Many official's bisphenol A epoxy acrylates, urethane acrylate, photo-curing monomer and solvent are accurately weighed, is mixed
After closing 30 minutes, light trigger and levelling agent, polymerization inhibitor are added, it is alkaline-resisting that mixing is obtained the ultraviolet light polymerization after 10 minutes
Property coating composition, keeps in dark place.
Using aluminium foil as base material, coating (30% contains admittedly) is put into 60 DEG C of baking ovens with No. 10 line rod coating on its surface
1min, solidifies by UV afterwards, and energy is 500mJ/cm2。
Performance detection
To embodiment 1~6 and obtained in comparative example 1~4, coating carries out performance detection respectively, determines the attachment of coating
Power, pencil hardness, wearability, temperature tolerance, water boiling resistance and alkali resistance.Concrete outcome is listed in Table 2 below.
Specific performance detection project and corresponding method are as follows：
First, adhesive force
Using cross-cut methods, specimen page adhesive force is tested with 3M Pressure sensitive adhesive tapes.
Appraisal procedure：5B- scribing edges are smooth, at the edge and intersection of line without peeling paint；
4B- has the peeling paint of small pieces in the intersection of line, and the gross area that comes off is less than 5%；
3B- line edge and intersection have the peeling paint of small pieces, and come off the gross area 5~15% it
Between；
2B- has a sheet of peeling paint at the edge and intersection of line, and come off the gross area 15~35% it
Between；
1B- has a sheet of peeling paint at the edge and intersection of line, and come off the gross area 35~65% it
Between；
0B- has sheet of peeling paint, and the gross area that comes off more than 65% at the edge and intersection of line.
2nd, pencil hardness
With reference to standard GB/T/T6739《Hardness of paint film pencil determination method》.
3rd, anti-wear performance
Using 0000# steel wool, 1000g power, one is designated as once back and forth, and the number of times for scratching occurs in recording surface.
Appraisal procedure：By after the friction of certain number of times, whether observation coating has scratch, is resistant to when recording without scratch
Most Rubbing numbers.
4th, heatproof test
Using heat-sealing instrument, aluminium foil specimen page there is into coating in face of folding, sealed at different temperatures, observation doubling specimen page is
It is no adhesion, the heat-resisting maximum temperature of record coating occur.
5th, water boiling resistance test
Boiled in boiling water 2 hours, observation coating whether there is and comes off.
6th, alkali resistance test
Dripped on coating with 10%NaOH solution, observe whether coating occurs turning white after 24 hours, the corrosion phenomenon such as foaming.
Table 1
* remarks：Mol ratio when polyamine is with CN104 Michael addition reactions.
Table 2
Embodiment 1~6 can be seen that with preferable alkaline resistance properties by the test result of table 2, at the same have hardness it is high,
More than more than 200 times, heatproof is higher than more than 200 degree to abrasion resistance.Comparative example 1 compared with Example 1, using unmodified two official
Bisphenol A epoxy acrylate adds coating system, although, as adhered to, hardness is wear-resisting, and temperature tolerance is preferable for other performances, but
Alkali resistance is bad, and blushing occurs in coating, because degree of functionality is low, crosslink density is low, and total alkali resistance group-bis-
Caused by the structure number of phenol A epoxy resin is relatively fewer.Comparative example 2 compared with Example 2, without introducing alkali resistance structure-bis-
Phenol A epoxy resin, and substituted with the urethane acrylate of ten officials, as a result the alkali resistance of film is very poor, foaming of turning white occurs
Phenomenon.Hardness and temperature tolerance it is slightly worse be caused by cross-linked network density is slightly lower.Comparative example 3 compared with Example 3, due to many officials
Epoxy acrylic ester content is low, so alkali resistance is slightly worse, coating slightly turns white.Heatproof is slightly lower.Comparative example 4 compared with Example 4,
Because photo-curing monomer addition used is high, volume contraction is big in Light Curing, therefore film is more crisp, to base material attachment compared with
Difference.Other abrasion resistance is relatively low, only 50 times.Because many official's epoxy acrylates are more, therefore film alkali resistance is preferable.
Concrete application approach of the present invention is a lot, and the above is only the preferred embodiment of the present invention.It should be pointed out that more than
Embodiment is merely to illustrate the present invention, and the protection domain being not intended to limit the invention.For the common skill of the art
For art personnel, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as this hair
Bright protection domain.
Claims (10)
1. a kind of ultraviolet light polymerization alkali-resistant coating composition, it is characterised in that including the following component counted by weight：
2. ultraviolet light polymerization alkali-resistant coating composition as claimed in claim 1, it is characterised in that the composition also includes
Solvent, the weight of the solvent is 2~4 times of other component weights.
3. ultraviolet light polymerization alkali-resistant coating composition as claimed in claim 1, it is characterised in that the epoxy acrylate
It is modified bisphenol A epoxy acrylate, the modified bisphenol A epoxy acrylate is polyamine and double official's bisphenol-A epoxy propylene
Acid esters is obtained through Michael addition reaction.
4. ultraviolet light polymerization alkali-resistant coating composition as claimed in claim 3, it is characterised in that the polyamine is fat
One or more in race's polyamine, alicyclic polyamine or aromatic polyamine of mixing.
5. ultraviolet light polymerization alkali-resistant coating composition as claimed in claim 4, it is characterised in that the aliphatic polyamine
It is the one kind in diethylenetriamine, triethylene tetramine, TEPA and pentaethylene hexamine；The alicyclic polyamine is 1,3-
One kind in bis aminomethyl hexamethylene, 4,4'- diamino-dicyclohexyl methanes；The aromatic polyamine is p dimethylamine
With the one kind in m-xylene diamine.
6. ultraviolet light polymerization alkali-resistant coating composition as claimed in claim 3, it is characterised in that the Michael's addition is anti-
Following steps should be specifically included：
At ambient temperature, by the ethyl acetate solution of polyamine, double official's bisphenol A epoxy acrylates were added drop-wise in 1 hour
Ethyl acetate solution in, then proceed to reaction 5 hours, obtain many official's bisphenol A epoxy acrylates, i.e. modified bisphenol A epoxy
Acrylate.
7. the ultraviolet light polymerization alkali-resistant coating composition as described in claim 3 or 6, it is characterised in that in the polyamine
Active hydrogen is 1 with the mol ratio of double official's bisphenol A epoxy acrylates:1.
8. the ultraviolet light polymerization alkali-resistant coating composition as described in right wants 1, it is characterised in that the urethane acrylate
High-ranking official's polyurethane acrylic resin for degree of functionality more than or equal to 3.
9. the ultraviolet light polymerization alkali-resistant coating composition as described in right wants 1, it is characterised in that the photo-curing monomer is official
High-ranking official monomer of the energy degree more than or equal to 3, specially trimethylolpropane trimethacrylate, pentaerythritol triacrylate, three (2-
Ethoxy) isocyanuric acid triacrylate, tetramethylol methane tetraacrylate, the one kind or several in dipentaerythritol acrylate
Kind.
10. the ultraviolet light polymerization alkali-resistant coating composition as described in right wants 1, it is characterised in that the light trigger is 1-
Hydroxycyclohexyl phenyl ketone, 2,4,6- trimethylbenzoy-diphenies phosphine oxide, 2- methyl isophthalic acids-(4- methyl mercaptos phenyl)-
One or more composition of 2- morpholine -1- acetone；The auxiliary agent includes the one kind or several in levelling agent, polymerization inhibitor
Kind.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110552209A (en) * | 2019-08-05 | 2019-12-10 | 浙江佳阳塑胶新材料有限公司 | alkali-resistant TPU artificial leather and manufacturing method thereof |
| CN110588195A (en) * | 2019-09-19 | 2019-12-20 | 东莞智源彩印有限公司 | Preparation process of printed matter with gravure fission effect |
| CN111094464A (en) * | 2017-09-26 | 2020-05-01 | 株式会社Kcc | Ultraviolet-curable coating composition |
| CN111364083A (en) * | 2020-04-15 | 2020-07-03 | 浙江龙纪汽车零部件股份有限公司 | Automobile luggage rack anodic oxidation process with high-corrosion-resistance protective film |
| CN111634131A (en) * | 2020-06-12 | 2020-09-08 | 东莞智源彩印有限公司 | A kind of preparation method of printed matter with gravure fission effect |
| CN112980238A (en) * | 2021-03-20 | 2021-06-18 | 中山市中益油墨涂料有限公司 | Environment-friendly chemical-resistant UV (ultraviolet) photocuring ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059697A (en) * | 2012-12-28 | 2013-04-24 | 上海乘鹰新材料有限公司 | Ultraviolet curing coating composition for metallic yarn protective layer |
-
2016
- 2016-12-07 CN CN201611117857.7A patent/CN106752741B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059697A (en) * | 2012-12-28 | 2013-04-24 | 上海乘鹰新材料有限公司 | Ultraviolet curing coating composition for metallic yarn protective layer |
Non-Patent Citations (1)
| Title |
|---|
| 吴建兵等: "《环氧丙烯酸酯的改性及其性能的研究进展》", 《精细与专用化学品》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111094464A (en) * | 2017-09-26 | 2020-05-01 | 株式会社Kcc | Ultraviolet-curable coating composition |
| CN111094464B (en) * | 2017-09-26 | 2021-10-26 | 株式会社Kcc | Ultraviolet-curable coating composition |
| CN110552209A (en) * | 2019-08-05 | 2019-12-10 | 浙江佳阳塑胶新材料有限公司 | alkali-resistant TPU artificial leather and manufacturing method thereof |
| CN110588195A (en) * | 2019-09-19 | 2019-12-20 | 东莞智源彩印有限公司 | Preparation process of printed matter with gravure fission effect |
| CN111364083A (en) * | 2020-04-15 | 2020-07-03 | 浙江龙纪汽车零部件股份有限公司 | Automobile luggage rack anodic oxidation process with high-corrosion-resistance protective film |
| CN111634131A (en) * | 2020-06-12 | 2020-09-08 | 东莞智源彩印有限公司 | A kind of preparation method of printed matter with gravure fission effect |
| CN112980238A (en) * | 2021-03-20 | 2021-06-18 | 中山市中益油墨涂料有限公司 | Environment-friendly chemical-resistant UV (ultraviolet) photocuring ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106752741B (en) | 2019-03-08 |
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