CN106752141A - Waterborne conductive anticorrosive paint - Google Patents
Waterborne conductive anticorrosive paint Download PDFInfo
- Publication number
- CN106752141A CN106752141A CN201611154411.1A CN201611154411A CN106752141A CN 106752141 A CN106752141 A CN 106752141A CN 201611154411 A CN201611154411 A CN 201611154411A CN 106752141 A CN106752141 A CN 106752141A
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- natural minerals
- waterborne
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- 239000003973 paint Substances 0.000 title claims abstract description 37
- 239000000463 material Substances 0.000 claims abstract description 77
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 65
- 239000000853 adhesive Substances 0.000 claims abstract description 60
- 230000001070 adhesive effect Effects 0.000 claims abstract description 60
- 238000000576 coating method Methods 0.000 claims abstract description 60
- 239000011248 coating agent Substances 0.000 claims abstract description 59
- 239000004020 conductor Substances 0.000 claims abstract description 59
- 239000004568 cement Substances 0.000 claims abstract description 54
- 239000008187 granular material Substances 0.000 claims abstract description 54
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 54
- 239000011707 mineral Substances 0.000 claims abstract description 54
- 229920002521 macromolecule Polymers 0.000 claims abstract description 53
- 239000003822 epoxy resin Substances 0.000 claims abstract description 45
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000007787 solid Substances 0.000 claims abstract description 32
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000000470 constituent Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052755 nonmetal Inorganic materials 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000013528 metallic particle Substances 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 229920006335 epoxy glue Polymers 0.000 claims description 4
- 239000004833 fish glue Substances 0.000 claims description 4
- 235000013312 flour Nutrition 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 230000003628 erosive effect Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000006072 paste Substances 0.000 claims description 2
- 239000004836 Glue Stick Substances 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- ORVGYTXFUWTWDM-UHFFFAOYSA-N silicic acid;sodium Chemical compound [Na].O[Si](O)(O)O ORVGYTXFUWTWDM-UHFFFAOYSA-N 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 24
- 230000008901 benefit Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 8
- 230000007797 corrosion Effects 0.000 abstract description 6
- 239000004115 Sodium Silicate Substances 0.000 description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 10
- 229910052911 sodium silicate Inorganic materials 0.000 description 10
- 230000002421 anti-septic effect Effects 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000019795 sodium metasilicate Nutrition 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 244000274847 Betula papyrifera Species 0.000 description 2
- 235000009113 Betula papyrifera Nutrition 0.000 description 2
- 235000009109 Betula pendula Nutrition 0.000 description 2
- 235000010928 Betula populifolia Nutrition 0.000 description 2
- 235000002992 Betula pubescens Nutrition 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011231 conductive filler Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 235000015927 pasta Nutrition 0.000 description 2
- 229920005596 polymer binder Polymers 0.000 description 2
- 239000002491 polymer binding agent Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 244000226021 Anacardium occidentale Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 235000020226 cashew nut Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of waterborne conductive anticorrosive paint, belongs to coating products field.The coating includes liquid component and solid constituent；The liquid component and solid constituent separate storage, mix when using the coating；The liquid component includes the raw material of following weight portion：1 15 parts of waterborne curing agents, 0 15 parts of liquid-state epoxy resins, 1 15 parts of natural minerals water-base cements, 1 15 parts of macromolecule adhesives；The solid constituent is 85 90 parts of conductor material granules.Coating products provided by the present invention except conductive energy, Corrosion Protection is double outstanding the characteristics of in addition to, also have the advantages that it is dry soon, adhesive force is strong, pliability is good, anti-corrosion treatment, easy to use, simple, the with low cost, excellent effect of making are carried out to metal using coating of the invention.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of waterborne conductive anticorrosive paint.
Background technology
Metal material can occur spontaneous corrosion process in use, and metal material and its product have nearly 1/ every year in the world
3 loss, so anticorrosive paint has important application.And in special dimensions such as some electric power transports, on the one hand require metal material
Material has outside Anticorrosive Character, while also needing to keep the conductive characteristic of material.Conductive anti-corrosion coating is that recent decades grow up,
Various material surfaces can be covered in, it is possessed the function new material such as conduction, anti-corrosion.The common conductive anti-corrosion coating in this area
Have：Application for a patent for invention 201410024171.8 provide a kind of corrosion-resistant conductive coating, it include according to mass fraction meter as
Lower raw material：Polyurethane resin 5-10 parts, epoxy resin 25-30 parts, acrylic resin 4-6 parts, graphite powder 20-25 parts, silicon powder
8-12 parts, polyvinylpyrrolidone 10-12 parts, sodium acid carbonate 5-10 parts, n-butanol 25-28 parts, isopropanol 10-14 parts, water 48-
50 parts.Application for a patent for invention 201410346045.4 then discloses a kind of nano anti-corrosion conductive coating, is characterized in, by weight
Meter includes：5-20 parts of nano-carbon powder filler, epoxy resin-base 10-50 parts, nano magnetic iron oxide 10-20 parts, inert diluents
Agent 10-40 parts, curing agent 10-50 parts, silane coupler 1-5 parts.The conduction that application for a patent for invention 201510948036.7 is provided
Anticorrosive paint, including following percetage by weight composition：Matrix resin 15-18%, diluent 30-50%, curing agent 8-10%,
Auxiliary agent 0.1-0.2%, conductive filler 3-5%；Wherein, described matrix resin is the mixed of epoxy resin KD-175 and acrylic resin
Compound, the diluent is the mixture of dimethylbenzene, n-butanol and polyethylene glycol, and the curing agent is cashew nut modified polyamide
750, the auxiliary agent is dodecyl sodium sulfate, and the conductive filler is CNT and polyaniline mixture.
In electric lightening protection engineering field, common grounding body typically uses Hot-dip zinc-coated flat steel sheet, round steel or angle steel.Zinc-plating material with
And the antiseptic property of the above-mentioned conventional corrosion-resistant conductive coating in this area is in the application on ground, its anti-corrosion, anti-corrosion its effect is good
's.But then hardly possible has good antisepsis in the environment of underground humidity, even water ooze bubble.
Therefore, this area exploitation one kind of still needing still can keep good antiseptic property in, immersion environment moist in underground
Coating material.
The content of the invention
Above-mentioned not enough and demand based on this area, i.e. still lacking one kind can still can in, immersion environment moist in underground
The coating products of good antiseptic property are kept, the present invention provides a kind of conductive anti-corrosion coating, can be anti-as the ideal of grounded metal
Rotten electrically-conducting paint, in can be widely applied to various soil environments.
Technical scheme is as follows：
A kind of waterborne conductive anticorrosive paint, it is characterised in that including liquid component and solid constituent；The liquid component and
Solid constituent separates storage, mixes when using the coating；
The liquid component includes the raw material of following weight portion：1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin,
1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule adhesive；
The solid constituent is 85-90 parts of conductor material granule.
The waterborne conductive anticorrosive paint includes the raw material of following weight portion：
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 1 part of macromolecule adhesive, 85 parts of conductor material granules；
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of macromolecule adhesives, 90 parts of conductor material granules；
1 part of waterborne curing agent, 15 parts of natural minerals water-base cements, 1 part of macromolecule adhesive, 90 parts of conductor material granules；
7 parts of waterborne curing agents, 8 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 88 parts of conductor material granules；
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 1 part of macromolecule adhesive, 85 parts
Conductor material granule；
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives,
90 parts of conductor material granules；
15 parts of waterborne curing agents, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 85
Part conductor material granule；
3 parts of waterborne curing agents, 6 parts of liquid-state epoxy resins, 2 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 87 parts
Conductor material granule；
7 parts of waterborne curing agents, 4 parts of liquid-state epoxy resins, 11 parts of natural minerals water-base cements, 8 parts of macromolecule adhesives, 89 parts
Conductor material granule；
14 parts of waterborne curing agents, 8 parts of liquid-state epoxy resins, 4 parts of natural minerals water-base cements, 12 parts of macromolecule adhesives, 86
Part conductor material granule；
5 parts of waterborne curing agents, 12 parts of liquid-state epoxy resins, 8 parts of natural minerals water-base cements, 2 parts of macromolecule adhesives, 88 parts
Conductor material granule；
9 parts of waterborne curing agents, 3 parts of liquid-state epoxy resins, 14 parts of natural minerals water-base cements, 4 parts of macromolecule adhesives, 85 parts
Conductor material granule；
2 parts of waterborne curing agents, 7 parts of liquid-state epoxy resins, 12 parts of natural minerals water-base cements, 5 parts of macromolecule adhesives, 85 parts
Conductor material granule；
13 parts of waterborne curing agents, 10 parts of liquid-state epoxy resins, 5 parts of natural minerals water-base cements, 14 parts of macromolecule adhesives, 87
Part conductor material granule；
8 parts of waterborne curing agents, 9 parts of liquid-state epoxy resins, 10 parts of natural minerals water-base cements, 7 parts of macromolecule adhesives, 89 parts
Conductor material granule；
11 parts of waterborne curing agents, 13 parts of liquid-state epoxy resins, 3 parts of natural minerals water-base cements, 6 parts of macromolecule adhesives, 90
Part conductor material granule；
10 parts of waterborne curing agents, 11 parts of liquid-state epoxy resins, 6 parts of natural minerals water-base cements, 3 parts of macromolecule adhesives, 86
Part conductor material granule；Or
6 parts of waterborne curing agents, 5 parts of liquid-state epoxy resins, 9 parts of natural minerals water-base cements, 13 parts of macromolecule adhesives, 88 parts
Conductor material granule.
The waterborne curing agent is selected from：Closed isocyanate crosslinker, or, modified amine epoxy curing agent.
The natural minerals water-base cement refers to sodium metasilicate.
The macromolecule adhesive is selected from：Paste, fish glue or epoxy glue.
The conductor material granule is selected from nonmetal conductor material particle or metallic particles；
The nonmetal conductor material particle is selected from：The group being made up of graphite powder, bentonite, silica flour and carbon dust；
The metallic particles include copper powder, glass putty, and/or, stainless steel powder.
A kind of preparation method of waterborne conductive anticorrosive paint, it is characterised in that including：Prepare liquid component：The liquid
Component includes the raw material of following weight parts：1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural ore deposit
Thing water-base cement, 1-15 part of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule；
The liquid component and solid constituent separate storage.
The application method of the waterborne conductive anticorrosive paint, it is characterised in that mix the liquid component and solid constituent
Close, the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh.
A kind of method for preventing metal erosion, it is characterised in that use the waterborne conductive anticorrosive paint, and/or it is described
The coating that preparation method is prepared, after the liquid component and solid constituent are mixed, coats or brushes to the metal
Surface；Or,
Using the application method, the coating is coated or brushed to the metallic surface；Or,
By 1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals water-base cement, 1-15 parts of high score
Sub- adhesive, 85-90 part of conductor material granule, after mixing, coats or brushes to the metallic surface.
Application of the waterborne conductive anticorrosive paint in terms of earthing material is processed.
The present invention provides a kind of waterborne conductive anticorrosive paint, including following raw material：1-15 parts of waterborne curing agent, 0-
15 parts of liquid-state epoxy resins, 1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule adhesive, 85-90 parts of conductor material granules.
In above-mentioned raw materials, waterborne curing agent, liquid-state epoxy resin, natural minerals water-base cement, macromolecule adhesive belong to the coating
Liquid portion, and conductor material granule is the solid portion of the coating, two parts are in the mistake for being stored as coating products, transport
Cheng Zhong, is to separate storage；Only when using coating products of the invention, just two parts are mixed and/or ground.
In the waterborne conductive anticorrosive paint that any embodiment of the present invention is provided, the content of each raw material components can take above-mentioned institute
Any value in the range of columns value, specifically, the components by weight percent of waterborne curing agent can be 1,2,3 ..., 7,8,9,
10th ..., 13,14,15 parts；The components by weight percent of liquid-state epoxy resin can be 0,1,2,3 ..., 7,8,9,10 ..., 13,
14th, 15 parts；The components by weight percent of natural minerals water-base cement can with 1,2,3 ..., 7,8,9,10 ..., 13,14,15 parts；High score
The components by weight percent of sub- adhesive can be 1,2,3 ..., 7,8,9,10 ..., 13,14,15 parts；The weight of macromolecule adhesive
Amount component can be 85,86,87,88,89,90 parts；Each weight portion corresponding to any one group is each in above-mentioned these numerical points of selection
Raw material, the coating obtained by mixing can realize the aqueous quick-drying of coating of the present invention, conductive corrosion-resistant effect.
In some preferred embodiments of the invention, the waterborne curing agent is selected from：Closed isocyanate crosslinker,
Or, modified amine epoxy curing agent.Waterborne curing agent has the advantages that viscosity is low, of light color, solidfied material good toughness, low temperature
It is moist without white birch, color inhibition, it is complete without pasta, low-temperature setting.Impact resistance is good, is particularly well-suited to water paint, while can make
It is adhesion promoters and crosslinking agent, improves adhesive strength, water proofing property, wearability, scrub resistance, scratch resistance and resistance toization of coating
Learn moral character.
The Main Function of the liquid-state epoxy resin is auxiliary bonding, filling and solidifies.
In some specific embodiments, the natural minerals water-base cement is sodium metasilicate, preferably liquid sodium silicate, also may be used
Being the liquid form of sodium silicate solid.Liquid sodium silicate is colourless, slightly colored transparent or semitransparent viscous liquid.Solid
Sodium metasilicate is colourless, slightly colored transparent or semitransparent glass blocks.Can directly buy；The natural minerals water-base cement master
Be used to bonding, fill etc..
In other embodiments of the invention, the macromolecule adhesive is selected from：Paste, fish glue, or, epoxy glue.Institute
State macromolecule adhesive and refer to a class adhesive material based on macromolecular compound, also referred to as polymer binder or macromolecule glues
Knot agent, it has high intensity, high temperature resistant, high-durability, low toxicity and easy, with low cost etc. many benefits of technique.
In some specific embodiments of the invention, the conductor material granule is nonmetal conductor material particle or gold
Metal particles；
The nonmetal conductor material particle is selected from one or more in graphite powder, bentonite, silica flour and carbon dust；
The preferably not oxidizable metallic of the metallic particles, including copper powder, glass putty, and/or, stainless steel powder.
The Main Function that conductor material granule is added in waterborne conductive anticorrosive paint of the present invention is to ensure coating
The long-term conductive effect of product.The product that coating can as needed be coated is different, and products application environment is different, and selection addition is non-
Metal Conductor Particles or not oxidizable metallic increase its conductive capability.
Some other embodiment of the invention additionally provides a kind of preparation method of waterborne conductive anticorrosive paint, including：Will
Following weight parts raw material mixes：1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals are aqueous
Glue, 1-15 part of producing high-molecular rubber alloy, 85-90 parts of conductor material granule.
Preferably, the preparation method also includes, by the raw material mix obtained by mixture grind repeatedly, make lapping degree
Reach 50 mesh to 3000 mesh, the benefit of grinding is to make mixture uniform level higher, formed evenly, the more preferable coating of effect
Product.
The present invention is also claimed a kind of method for preventing metal erosion, it is characterised in that use the coating and/or institute
State the coating coating metal surface that preparation method is prepared.
The present invention is also claimed application of the described conductive anti-corrosion coating in terms of earthing material is processed.
In the raw material that coating of the invention is used, the curing agent of use, adhesive are aqueous feature, so as to cause this
The there is provided coating of invention has the advantages that to do soon, and after tested, surface drying time is less than 1 hour, is parched under normal temperature environment
Time is between 4-6 hours.Additionally, the coating of the invention obtained using the raw material of above-mentioned formula, through salt tolerant, acid proof test,
Come off without foaming, nothing in 720 hours, nothing is got rusty；Detection is also carried out to its electric conductivity simultaneously, coating of the present invention is led
Electrostrictive coefficient is in 1.57 × 104Ω to 3.21 × 105Ω.To sum up illustrate, coating of the present invention is except conductive energy, anti-
Outside the characteristics of corrosive nature is double outstanding, also have the advantages that it is dry soon, adhesive force is strong, pliability is good, using coating of the invention
Anti-corrosion treatment, easy to use, simple, the with low cost, excellent effect of making are carried out to metal.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, but is not intended to limit model of the invention
Enclose.Unless otherwise specified, the operation for being used in following embodiments is conventional method, and the reagent for being used can be obtained with commercially available
.
Embodiment 1-18,1-18 conductive anti-corrosion coatings of the present invention and its performance
Embodiment 1-18 provides various Ju Ti Pei Fangs of the conductive anti-corrosion coating in the scope of the present invention, and they are total to
With the characteristics of be that antiseptic property and electric conductivity are double excellent.
In following Ju Ti Pei Fangs：Waterborne curing agent, liquid-state epoxy resin, natural minerals water-base cement, macromolecule adhesive category
In the liquid portion of coating products of the present invention, and conductor material granule is the solid portion of coating products of the present invention.It is of the invention
During transport, and/or storage, the liquid portion is to separate storage with solid portion to coating products；And using this
When the coating of invention carries out the application in terms of anti-corrosion of metal conduction, for example, it is necessary to by the liquid portion before brushing or coating
It is sufficiently mixed with solid portion and/or is ground.
Embodiment 19, the preparation method and application method of conductive anti-corrosion coating of the present invention
The present embodiment provides the preparation method of conductive anti-corrosion coating of the present invention, specifically includes following preparation process：
Prepare liquid component：The liquid component includes the raw material of following weight parts：1-15 parts of aqueous cyclammonium curing agent, 0-
15 parts of liquid-state epoxy resins, 1-15 parts of natural minerals water-base cement, 1-15 parts of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule；
The liquid component and solid constituent constitute coating products of the invention, but need to separate storage.
The present embodiment also provides the application method of conductive anti-corrosion coating of the present invention：Including, by the liquid component and
Solid constituent mixes, and the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh, and the benefit of grinding is to make to mix
Compound uniform level is higher, formed evenly, the more preferable coating products of effect.
In any of the above-described embodiment, the waterborne curing agent is selected from：Closed isocyanate crosslinker, or, modified amine
Based epoxy resin curing agent.Have the advantages that viscosity is low, of light color, solidfied material good toughness, low temperature and moisture without white birch, color inhibition,
It is complete without pasta, low-temperature setting.Impact resistance is good, is particularly well-suited to epoxy floor face and applies material.It is applied to aqueous acrylamide
The water paint such as acid and polyurethane, as adhesion promoters and crosslinking agent.Improve the adhesive strength of coating, water proofing property, wearability,
Scrub resistance, scratch resistance and chemical-resistant.
In certain embodiments, the natural minerals water-base cement is preferably the liquid of liquid sodium silicate or sodium silicate solid
Body form.Liquid sodium silicate is colourless, slightly colored transparent or semitransparent viscous liquid.Sodium silicate solid is colourless, slightly
The transparent or semitransparent glass blocks of color.Can directly buy；The natural minerals water-base cement is mainly used in bonding, fills
Deng.
In some specific embodiments, the macromolecule adhesive is selected from：Paste, fish glue, or, epoxy glue.The height
Molecule adhesive refers to the class adhesive material based on macromolecular compound, and also referred to as polymer binder or macromolecule is bonded
Agent, it has high intensity, high temperature resistant, high-durability, low toxicity and easy, with low cost etc. many benefits of technique.
In certain embodiments, the conductor material granule is selected from nonmetal conductor material particle or metallic particles；
Preferably, the nonmetal conductor material particle is selected from the group being made up of graphite powder, bentonite, silica flour and carbon dust；
The preferably not oxidizable metallic of the metallic particles, such as but not limited to copper powder, glass putty, and/or, no
Rust comminuted steel shot.
The Main Function that the conductor material granule is added in the coating that any of the above-described embodiment is provided is to ensure to apply
Expect the long-term conductive effect of product.The product that coating can as needed be coated is different, and products application environment is different, selection addition
Non-metal conductor particle or not oxidizable metallic increase its conductive capability.
In above-described embodiment, the waterborne conductive anticorrosive paint performance test methods are as follows：
The electric conductivity of waterborne conductive anticorrosive paint of the invention is according to GB/T1410-2006《Solid insulating material volume
Resistivity and surface resistivity test method》Measure, No. 1-15 painting is can be seen that from the numerical value on the column of electrical conductivity one in upper table
The electrical conductivity of material is in 1.57 × 104Ω to 3.21 × 105Ω, illustrates conductive anti-corrosion coating electric conductivity of the present invention
It is excellent.
The antiseptic property of waterborne conductive anticorrosive paint of the invention is according to GB/T9274-1988《Paint and varnish resistant to liquid
The measure of medium》Standard is measured, and in upper table, either salt tolerant or acidproof aspect, all possess good lasting corrosion resistance；
Simultaneously in terms of salt spray resistance, the performance of above-mentioned 1-15 coating is：More than 300 hours non-foaming non-corrosives.
Except with excellent electric conductivity and antiseptic property, waterborne conductive anticorrosive paint provided by the present invention also has
The advantage, surface drying such as simple are required in terms of technique for applying and construction technology：Less than 1 hour, 4-6 hours under normal temperature environment can be with
Parch.
The attachment force data of conductive anti-corrosion coating is according to GB/T9286-1998 through experimental tests in above-described embodiment
, adhesive force (drawing compartment away from 2mm) assay is 1 grade, and its adhesive force is excellent；
The pliability of waterborne conductive anticorrosive paint of the invention is according to GB/T 1731-93《Paint film flexibility determination method》
Measure, the pliability of paint film is represented with the minimum mandrel rod diameter for not causing paint film to destroy, measuring result is：1mm, illustrates the present invention
Coating flexibility it is good.
Claims (10)
1. a kind of waterborne conductive anticorrosive paint, it is characterised in that including liquid component and solid constituent；The liquid component and solid
Body component separates storage, mixes when using the coating；
The liquid component includes the raw material of following weight portion：1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15
Part natural minerals water-base cement, 1-15 parts of macromolecule adhesive；
The solid constituent is 85-90 parts of conductor material granule.
2. waterborne conductive anticorrosive paint according to claim 1, it is characterised in that the raw material including following weight portion：
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 1 part of macromolecule adhesive, 85 parts of conductor material granules；
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of macromolecule adhesives, 90 parts of conductor material granules；
1 part of waterborne curing agent, 15 parts of natural minerals water-base cements, 1 part of macromolecule adhesive, 90 parts of conductor material granules；
7 parts of waterborne curing agents, 8 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 88 parts of conductor material granules；
1 part of waterborne curing agent, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 1 part of macromolecule adhesive, 85 parts of conductors
Material granule；
15 parts of waterborne curing agents, 15 parts of natural minerals water-base cements, 15 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 90 parts
Conductor material granule；
15 parts of waterborne curing agents, 1 part of natural minerals water-base cement, 2 parts of liquid-state epoxy resins, 15 parts of macromolecule adhesives, 85 parts lead
Body material granule；
3 parts of waterborne curing agents, 6 parts of liquid-state epoxy resins, 2 parts of natural minerals water-base cements, 10 parts of macromolecule adhesives, 87 parts of conductors
Material granule；
7 parts of waterborne curing agents, 4 parts of liquid-state epoxy resins, 11 parts of natural minerals water-base cements, 8 parts of macromolecule adhesives, 89 parts of conductors
Material granule；
14 parts of waterborne curing agents, 8 parts of liquid-state epoxy resins, 4 parts of natural minerals water-base cements, 12 parts of macromolecule adhesives, 86 parts lead
Body material granule；
5 parts of waterborne curing agents, 12 parts of liquid-state epoxy resins, 8 parts of natural minerals water-base cements, 2 parts of macromolecule adhesives, 88 parts of conductors
Material granule；
9 parts of waterborne curing agents, 3 parts of liquid-state epoxy resins, 14 parts of natural minerals water-base cements, 4 parts of macromolecule adhesives, 85 parts of conductors
Material granule；
2 parts of waterborne curing agents, 7 parts of liquid-state epoxy resins, 12 parts of natural minerals water-base cements, 5 parts of macromolecule adhesives, 85 parts of conductors
Material granule；
13 parts of waterborne curing agents, 10 parts of liquid-state epoxy resins, 5 parts of natural minerals water-base cements, 14 parts of macromolecule adhesives, 87 parts lead
Body material granule；
8 parts of waterborne curing agents, 9 parts of liquid-state epoxy resins, 10 parts of natural minerals water-base cements, 7 parts of macromolecule adhesives, 89 parts of conductors
Material granule；
11 parts of waterborne curing agents, 13 parts of liquid-state epoxy resins, 3 parts of natural minerals water-base cements, 6 parts of macromolecule adhesives, 90 parts lead
Body material granule；
10 parts of waterborne curing agents, 11 parts of liquid-state epoxy resins, 6 parts of natural minerals water-base cements, 3 parts of macromolecule adhesives, 86 parts lead
Body material granule；Or
6 parts of waterborne curing agents, 5 parts of liquid-state epoxy resins, 9 parts of natural minerals water-base cements, 13 parts of macromolecule adhesives, 88 parts of conductors
Material granule.
3. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the waterborne curing agent is selected from：Envelope
Closed form isocyanate crosslinking, or, modified amine epoxy curing agent.
4. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that natural minerals water-base cement refers to silicic acid
Sodium.
5. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the macromolecule adhesive is selected from：
Paste, fish glue or epoxy glue.
6. waterborne conductive anticorrosive paint according to claim 1 and 2, it is characterised in that the conductor material granule is selected from
Nonmetal conductor material particle or metallic particles；
The nonmetal conductor material particle is selected from：The group being made up of graphite powder, bentonite, silica flour and carbon dust；
The metallic particles include copper powder, glass putty, and/or, stainless steel powder.
7. a kind of preparation method of waterborne conductive anticorrosive paint, it is characterised in that including：Prepare liquid component：The liquid group
Dividing includes the raw material of following weight parts：1-15 parts of aqueous cyclammonium curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals
Water-base cement, 1-15 part of producing high-molecular rubber alloy,
Solid constituent is prepared, the solid constituent refers to 85-90 parts of conductor material granule；
The liquid component and solid constituent separate storage.
8. the application method of any described coating of claim 1-6, it is characterised in that by the liquid component and solid constituent
Mixing, the mixture of gained grinds repeatedly, lapping degree is reached 50 mesh to 3000 mesh.
9. a kind of method for preventing metal erosion, it is characterised in that any described coating of usage right requirement 1-6, and/or power
Profit requires the coating that the preparation method described in 7 is prepared, and after the liquid component and solid constituent are mixed, coats or brushes
To the metallic surface；Or,
Using the application method described in claim 8, the coating is coated or brushed to the metallic surface；Or,
By 1-15 parts of waterborne curing agent, 0-15 parts of liquid-state epoxy resin, 1-15 parts of natural minerals water-base cement, 1-15 parts of macromolecule glue
Stick, 85-90 part of conductor material granule, after mixing, coats or brushes to the metallic surface.
10. application of the waterborne conductive anticorrosive paint described in claim 1- in terms of earthing material is processed.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611154411.1A CN106752141A (en) | 2016-12-14 | 2016-12-14 | Waterborne conductive anticorrosive paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611154411.1A CN106752141A (en) | 2016-12-14 | 2016-12-14 | Waterborne conductive anticorrosive paint |
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ID=58888715
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113402961A (en) * | 2021-06-10 | 2021-09-17 | 广州盛门新材料科技有限公司 | Protective coating for zinc-plated material and preparation method and application thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001051570A1 (en) * | 2000-01-14 | 2001-07-19 | Basf Coatings Ag | Coating that contains a colloidally dispersed metallic bismuth |
| US6479103B1 (en) * | 1997-11-05 | 2002-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Conductive organic coatings |
| CN101508870A (en) * | 2009-03-20 | 2009-08-19 | 武汉铁神化工有限公司 | Electrostatic conductive anticorrosion paint and method of preparing the same |
| CN102417781A (en) * | 2011-11-10 | 2012-04-18 | 武汉爱劳高科技有限责任公司 | Anticorrosion conductive coating for grounding and preparation process thereof |
| CN103409033A (en) * | 2013-06-09 | 2013-11-27 | 广东电网公司电力科学研究院 | Conductive anticorrosive coating and preparation method thereof |
| CN103756514A (en) * | 2014-01-17 | 2014-04-30 | 广州集泰化工有限公司 | Waterborne two-component light-color in-tank electrostatic conduction anticorrosive paint and preparation method thereof |
| CN105038446A (en) * | 2015-06-04 | 2015-11-11 | 上海电力学院 | Water-based anticorrosive conducting paint and preparation method thereof |
| CN105440879A (en) * | 2014-08-21 | 2016-03-30 | 中国石油天然气集团公司 | Electrostatic conductive coating |
-
2016
- 2016-12-14 CN CN201611154411.1A patent/CN106752141A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6479103B1 (en) * | 1997-11-05 | 2002-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Conductive organic coatings |
| WO2001051570A1 (en) * | 2000-01-14 | 2001-07-19 | Basf Coatings Ag | Coating that contains a colloidally dispersed metallic bismuth |
| CN101508870A (en) * | 2009-03-20 | 2009-08-19 | 武汉铁神化工有限公司 | Electrostatic conductive anticorrosion paint and method of preparing the same |
| CN102417781A (en) * | 2011-11-10 | 2012-04-18 | 武汉爱劳高科技有限责任公司 | Anticorrosion conductive coating for grounding and preparation process thereof |
| CN103409033A (en) * | 2013-06-09 | 2013-11-27 | 广东电网公司电力科学研究院 | Conductive anticorrosive coating and preparation method thereof |
| CN103756514A (en) * | 2014-01-17 | 2014-04-30 | 广州集泰化工有限公司 | Waterborne two-component light-color in-tank electrostatic conduction anticorrosive paint and preparation method thereof |
| CN105440879A (en) * | 2014-08-21 | 2016-03-30 | 中国石油天然气集团公司 | Electrostatic conductive coating |
| CN105038446A (en) * | 2015-06-04 | 2015-11-11 | 上海电力学院 | Water-based anticorrosive conducting paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113402961A (en) * | 2021-06-10 | 2021-09-17 | 广州盛门新材料科技有限公司 | Protective coating for zinc-plated material and preparation method and application thereof |
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Application publication date: 20170531 |