CN106750675A - A kind of anti-aging cable material of waterproof and oilproof heatproof and preparation method thereof - Google Patents
A kind of anti-aging cable material of waterproof and oilproof heatproof and preparation method thereof Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 33
- 230000003712 anti-aging effect Effects 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 33
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical class O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000010455 vermiculite Substances 0.000 claims abstract description 20
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 20
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 19
- 235000021323 fish oil Nutrition 0.000 claims abstract description 14
- 239000003063 flame retardant Substances 0.000 claims abstract description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000005864 Sulphur Substances 0.000 claims abstract description 13
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004014 plasticizer Substances 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000006229 carbon black Substances 0.000 claims abstract description 11
- 239000011651 chromium Substances 0.000 claims abstract description 11
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 11
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 11
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 229920002545 silicone oil Polymers 0.000 claims abstract description 11
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 38
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- 239000007822 coupling agent Substances 0.000 claims description 8
- 235000011056 potassium acetate Nutrition 0.000 claims description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 238000007670 refining Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000000395 magnesium oxide Substances 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims 2
- 241000545744 Hirudinea Species 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 abstract description 2
- 235000019198 oils Nutrition 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000005611 electricity Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910003978 SiClx Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- HRHBQGBPZWNGHV-UHFFFAOYSA-N azane;bromomethane Chemical compound N.BrC HRHBQGBPZWNGHV-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of anti-aging cable material of waterproof and oilproof heatproof, it is made up of according to weight portion following raw material：Butadiene-styrene rubber, fluorubber, LLDPE, fluorocarbon resin, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre, vermiculite, triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxide powder, sulphur, stabilizer, plasticizer, fire retardant and fish oil.The present invention also disclosed the preparation method of the cable material.Raw material sources of the present invention are extensive, preparation process is simple, low production cost, it is adaptable to large-scale industrial production；Butadiene-styrene rubber, fluorubber and fluorocarbon resin are used cooperatively in the present invention, compatibility is good, and using sulphur is as vulcanizing agent and coordinates modified kaolin, fish oil, stabilizer, plasticizer and fire retardant to use, the heat-resisting, wear-resisting of cable material, oil resistant, tear-proof and compression excellent performance is obtained, long service life, it is applied widely.
Description
Technical field
The present invention relates to a kind of cable material, specifically a kind of anti-aging cable material of waterproof and oilproof heatproof.
Background technology
With economic and society development, the continuous expansion of production, people are also more next for the requirement of living standard
It is higher, wherein, the demand to electric power is also increasing.Electric power is made up of links such as generating, transmission of electricity, power transformation, distribution and electricity consumptions
Power generation and consumption system.Electric wire is widely used as electric energy and information transfer body in every field.Electricity
Line cable mostly using plastics and rubber as insulation and sheath material, such polymeric material being heated, melt, decompose after,
Imflammable gas can be produced.During high temperature, these gases can be reacted and burn with oxygen, and substantial amounts of heat can be produced during burning, and
These heats can promote polymer further melt, decompose, sustained combustion, expand fire, so as to bring about great losses.China
The fire damage for only being caused by cable, annual up to tens yuans, people just investigated the good cable of fire resistance
Material.But the heat-resisting of existing flame retardant cable, service life and ageing resistace do not reach the expection of people also, this just turns into
People need the problem for solving.
The content of the invention
It is an object of the invention to provide a kind of anti-aging cable material of waterproof and oilproof heatproof, to solve above-mentioned background technology
The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme：
A kind of anti-aging cable material of waterproof and oilproof heatproof, is made up of following raw material according to weight portion：Butadiene-styrene rubber 30-42
Part, fluorubber 25-35 parts, LLDPE 2-6 parts, fluorocarbon resin 12-20 parts, containing hydrogen silicone oil 2-5 parts, modified kaolinite
Native 5-8 parts, carbon black 4-7 parts, APP 5-10 parts, glass fibre 1-5 parts, vermiculite 3-8 parts, triethanolamine 2-4 parts, nickel 1-3
Part, chromium 2-4 parts, calcium carbonate 3-7 parts, nano silicon 2-4 parts, ethylene glycol 4-8 parts, oxide powder 2-8 parts, sulphur 1-3
Part, stabilizer 2-6 parts, plasticizer 3-5 parts, fire retardant 2-6 parts and fish oil 2-7 parts.
As further scheme of the invention：Modified kaolin is well mixed for kaolin with potassium acetate, 3-5 points of vibration
Clock, grind 10-30 minute, standing 10-16 hours, then in 60-80 degrees Celsius freeze-day with constant temperature 20-28 hours, be cooled to room temperature
First material is obtained, then first material is ground 5-15 minutes, then washing 1-3 times, drying and grinding obtains second material,
Cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water are well mixed and 80-90 degrees Celsius is heated to, then
Add second material and be heated to 105-115 degrees Celsius, then suction filtration and be dried to obtain, kaolin, potassium acetate, cetyl three
The weight ratio of methyl bromide ammonium, coupling agent OL-AT1618 and water is 2-6：1-5：3-6：1-3：4-12.
As further scheme of the invention：Oxide powder uses magnesia, calcium oxide, sodium oxide molybdena and alumina powder
One or more mixture.
The anti-aging preparation method of the waterproof and oilproof heatproof, comprises the following steps that：
Step one, vermiculite is calcined 1-3 hours under 1000-1080 degrees Celsius, obtains the vermiculite that foams；
Step 2, is 100-110 by butadiene-styrene rubber, fluorubber, LLDPE and fluorocarbon resin feeding temperature
Degree Celsius reactor in mechanical agitation, stir 10-20 minutes, obtain the first mixture；
Step 3, then by the first mixture, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre and hair
In bubble vermiculite feeding banbury, refining temperature is 80-105 degrees Celsius, and mixing time is 5-15 minutes, obtains the second mixture；
Step 4, to addition triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxygen in the second mixture
Compound powder and fish oil, reaction is 30-60 minutes under 130-150 degrees Celsius, obtains the 3rd mixture；
Step 5, by sulphur, stabilizer, plasticizer and fire retardant add the 3rd mixture in and be well mixed, mix
Input double screw extruder is in 120-150 degrees Celsius of lower extruding pelletization after uniform, you can obtain finished product.
Compared with prior art, the beneficial effects of the invention are as follows：Extensively, preparation process is simple is raw for raw material sources of the present invention
Produce low cost, it is adaptable to large-scale industrial production；Butadiene-styrene rubber, fluorubber and fluorocarbon resin are used cooperatively in the present invention,
Compatibility is good, and using sulphur is as vulcanizing agent and coordinates modified kaolin, fish oil, stabilizer, plasticizer and fire retardant
Use, the heat-resisting, wear-resisting of cable material, oil resistant, tear-proof and compression excellent performance is obtained, long service life is applicable model
Enclose wide.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of anti-aging cable material of waterproof and oilproof heatproof, is made up of following raw material according to weight portion：30 parts of butadiene-styrene rubber,
25 parts of fluorubber, 2 parts of LLDPE, 12 parts of fluorocarbon resin, 2 parts of containing hydrogen silicone oil, 5 parts of modified kaolin, carbon black 4
Part, 5 parts of APP, 1 part of glass fibre, 3 parts of vermiculite, 2 parts of triethanolamine, 1 part of nickel, 2 parts of chromium, 3 parts of calcium carbonate, nano-silica
2 parts of SiClx, 4 parts of ethylene glycol, 2 parts of oxide powder, 1 part of sulphur, 2 parts of stabilizer, 3 parts of plasticizer, 2 parts of fire retardant and fish oil 2
Part.Modified kaolin is well mixed for kaolin with potassium acetate, vibrates 3 minutes, grinds 105 minutes, stands 12 hours, Ran Houyu
65 degrees Celsius of freeze-day with constant temperature 24 hours, are cooled to room temperature and obtain first material, first material then are ground into 8 minutes, then water
Wash 2 times, drying and grinding obtain second material, cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water are mixed equal
It is even and be heated to 83 degrees Celsius, it is subsequently added into second material and is heated to 108 degrees Celsius, then suction filtration and be dried to obtain, it is high
The weight ratio of ridge soil, potassium acetate, cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water is 3：2：3：1：6.
The anti-aging preparation method of the waterproof and oilproof heatproof, comprises the following steps that：
Step one, vermiculite is calcined 1 hour under 1000 degrees Celsius, obtains the vermiculite that foams；
Step 2, is 100 Celsius by butadiene-styrene rubber, fluorubber, LLDPE and fluorocarbon resin feeding temperature
Mechanical agitation in the reactor of degree, stirs 15 minutes, obtains the first mixture；
Step 3, then by the first mixture, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre and hair
In bubble vermiculite feeding banbury, refining temperature is 85 degrees Celsius, and mixing time is 7 minutes, obtains the second mixture；
Step 4, to addition triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxygen in the second mixture
Compound powder and fish oil, reaction is 36 minutes under 134 degrees Celsius, obtains the 3rd mixture；
Step 5, by sulphur, stabilizer, plasticizer and fire retardant add the 3rd mixture in and be well mixed, mix
Input double screw extruder is in 130 degrees Celsius of lower extruding pelletizations after uniform, you can obtain finished product.
Embodiment 2
A kind of anti-aging cable material of waterproof and oilproof heatproof, is made up of following raw material according to weight portion：36 parts of butadiene-styrene rubber,
32 parts of fluorubber, 4 parts of LLDPE, 16 parts of fluorocarbon resin, 4 parts of containing hydrogen silicone oil, 7 parts of modified kaolin, carbon black 6
Part, 8 parts of APP, 3 parts of glass fibre, 6 parts of vermiculite, 3 parts of triethanolamine, 2 parts of nickel, 3 parts of chromium, 5 parts of calcium carbonate, nano-silica
3 parts of SiClx, 6 parts of ethylene glycol, 6 parts of oxide powder, 2 parts of sulphur, 4 parts of stabilizer, 5 parts of plasticizer, 4 parts of fire retardant and fish oil 6
Part.Oxide powder is using magnesia and the mixture of alumina powder.
The anti-aging preparation method of the waterproof and oilproof heatproof, comprises the following steps that：
Step one, vermiculite is calcined 2 hours under 1040 degrees Celsius, obtains the vermiculite that foams；
Step 2, is 105 Celsius by butadiene-styrene rubber, fluorubber, LLDPE and fluorocarbon resin feeding temperature
Mechanical agitation in the reactor of degree, stirs 18 minutes, obtains the first mixture；
Step 3, then by the first mixture, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre and hair
In bubble vermiculite feeding banbury, refining temperature is 96 degrees Celsius, and mixing time is 12 minutes, obtains the second mixture；
Step 4, to addition triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxygen in the second mixture
Compound powder and fish oil, reaction is 52 minutes under 144 degrees Celsius, obtains the 3rd mixture；
Step 5, by sulphur, stabilizer, plasticizer and fire retardant add the 3rd mixture in and be well mixed, mix
Input double screw extruder is in 140 degrees Celsius of lower extruding pelletizations after uniform, you can obtain finished product.
Embodiment 3
A kind of anti-aging cable material of waterproof and oilproof heatproof, is made up of following raw material according to weight portion：42 parts of butadiene-styrene rubber,
35 parts of fluorubber, 6 parts of LLDPE, 20 parts of fluorocarbon resin, 5 parts of containing hydrogen silicone oil, 8 parts of modified kaolin, carbon black 7
Part, 10 parts of APP, 5 parts of glass fibre, 8 parts of vermiculite, 4 parts of triethanolamine, 3 parts of nickel, 4 parts of chromium, part, nanometer two of calcium carbonate 7
4 parts of silica, 8 parts of ethylene glycol, 8 parts of oxide powder, 3 parts of sulphur, 6 parts of stabilizer, 5 parts of plasticizer, 6 parts of fire retardant and fish oil
7 parts.Modified kaolin is well mixed for kaolin with potassium acetate, vibrates 5 minutes, grinds 25 minutes, stands 15 hours, Ran Houyu
75 degrees Celsius of freeze-day with constant temperature 26 hours, are cooled to room temperature and obtain first material, first material then are ground into 15 minutes, then water
Wash 3 times, drying and grinding obtain second material, cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water are mixed equal
It is even and be heated to 88 degrees Celsius, it is subsequently added into second material and is heated to 115 degrees Celsius, then suction filtration and be dried to obtain, it is high
The weight ratio of ridge soil, potassium acetate, cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water is 5：4：4：2：9.Oxidation
Thing powder uses the mixture of magnesia, calcium oxide, sodium oxide molybdena and alumina powder.
The anti-aging preparation method of the waterproof and oilproof heatproof, comprises the following steps that：
Step one, vermiculite is calcined 3 hours under 1080 degrees Celsius, obtains the vermiculite that foams；
Step 2, is 110 Celsius by butadiene-styrene rubber, fluorubber, LLDPE and fluorocarbon resin feeding temperature
Mechanical agitation in the reactor of degree, stirs 20 minutes, obtains the first mixture；
Step 3, then by the first mixture, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre and hair
In bubble vermiculite feeding banbury, refining temperature is 105 degrees Celsius, and mixing time is 15 minutes, obtains the second mixture；
Step 4, to addition triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxygen in the second mixture
Compound powder and fish oil, reaction is 60 minutes under 150 degrees Celsius, obtains the 3rd mixture；
Step 5, by sulphur, stabilizer, plasticizer and fire retardant add the 3rd mixture in and be well mixed, mix
Input double screw extruder is in 150 degrees Celsius of lower extruding pelletizations after uniform, you can obtain finished product.
Comparative example
Except modified kaolin is not contained, remaining component and preparation method of comparative example 1 are same as Example 1.Except being free of
There is fish oil, remaining component and preparation method of comparative example 2 are same as Example 3.
Product, the product of comparative example 1-2 and existing shovel to embodiment 1-3 carry out performance test, and test result is shown in Table
1。
Table 1
The intensity of the product of embodiment 1-3, ageing-resistant performance and fire resistance are superior to comparative example 1- as can be seen from Table 1
2 product and existing product.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires to be limited rather than described above, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (4)
1. a kind of anti-aging cable material of waterproof and oilproof heatproof, it is characterised in that be made up of according to weight portion following raw material：Butylbenzene
Rubber 30-42 parts, fluorubber 25-35 parts, LLDPE 2-6 parts, fluorocarbon resin 12-20 parts, containing hydrogen silicone oil 2-5
Part, modified kaolin 5-8 parts, carbon black 4-7 parts, APP 5-10 parts, glass fibre 1-5 parts, vermiculite 3-8 parts, triethanolamine
2-4 parts, nickel 1-3 parts, chromium 2-4 parts, calcium carbonate 3-7 parts, nano silicon 2-4 parts, ethylene glycol 4-8 parts, oxide powder 2-8
Part, sulphur 1-3 parts, stabilizer 2-6 parts, plasticizer 3-5 parts, fire retardant 2-6 parts and fish oil 2-7 parts.
2. waterproof and oilproof heatproof according to claim 1 is anti-aging, it is characterised in that the modified kaolin is kaolin
It is well mixed with potassium acetate, is vibrated 3-5 minutes, ground 10-30 minutes, 10-16 hours is stood, then in 60-80 degrees Celsius of perseverance
Temperature is dried 20-28 hours, is cooled to room temperature and is obtained first material, then grinds first material 5-15 minutes, then washes 1-3
Secondary, drying and grinding obtain second material, and cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water are well mixed
And 80-90 degrees Celsius is heated to, second material is subsequently added into and is heated to 105-115 degrees Celsius, then suction filtration and dry
Arrive, the weight ratio of kaolin, potassium acetate, cetyl trimethylammonium bromide, coupling agent OL-AT1618 and water is 2-6：1-5：3-
6：1-3：4-12.
3. waterproof and oilproof heatproof according to claim 1 and 2 is anti-aging, it is characterised in that the oxide powder is used
One or more mixture of magnesia, calcium oxide, sodium oxide molybdena and alumina powder.
4. the anti-aging preparation method of a kind of waterproof and oilproof heatproof as described in claim 1-3 is any, it is characterised in that specific
Step is as follows：
Step one, vermiculite is calcined 1-3 hours under 1000-1080 degrees Celsius, obtains the vermiculite that foams；
Step 2, is that 100-110 is Celsius by butadiene-styrene rubber, fluorubber, LLDPE and fluorocarbon resin feeding temperature
Mechanical agitation in the reactor of degree, stirs 10-20 minutes, obtains the first mixture；
Step 3, then by the first mixture, containing hydrogen silicone oil, modified kaolin, carbon black, APP, glass fibre and foaming leech
In stone feeding banbury, refining temperature is 80-105 degrees Celsius, and mixing time is 5-15 minutes, obtains the second mixture；
Step 4, to addition triethanolamine, nickel, chromium, calcium carbonate, nano silicon, ethylene glycol, oxide in the second mixture
Powder and fish oil, reaction is 30-60 minutes under 130-150 degrees Celsius, obtains the 3rd mixture；
Step 5, by sulphur, stabilizer, plasticizer and fire retardant add the 3rd mixture in and be well mixed, be well mixed
Input double screw extruder is in 120-150 degrees Celsius of lower extruding pelletization afterwards, you can obtain finished product.
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| CN201611238595.XA CN106750675A (en) | 2016-12-28 | 2016-12-28 | A kind of anti-aging cable material of waterproof and oilproof heatproof and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151407A (en) * | 2017-06-23 | 2017-09-12 | 芜湖航天特种电缆厂股份有限公司 | Ageing-resistant composite cable insulating materials in field and preparation method thereof |
| CN107189289A (en) * | 2017-06-23 | 2017-09-22 | 芜湖航天特种电缆厂股份有限公司 | Ship anti-aging cable seal sheath and preparation method thereof |
| CN107325356A (en) * | 2017-09-06 | 2017-11-07 | 南通凤凰橡胶制品有限公司 | Fire-resistant rubber |
| CN107629273A (en) * | 2017-09-06 | 2018-01-26 | 南通凤凰橡胶制品有限公司 | fire-resistant rubber |
| GB2585635B (en) * | 2019-05-28 | 2022-03-23 | Kafrit Ind 1993 Ltd | Compositions and methods for use in the preparation of hydrophobic surfaces |
| CN118652542A (en) * | 2024-06-27 | 2024-09-17 | 会通特种材料科技有限公司 | A kind of instantaneous hydrophilic long carbon chain polyamide powder material and preparation method thereof |
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2016
- 2016-12-28 CN CN201611238595.XA patent/CN106750675A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107151407A (en) * | 2017-06-23 | 2017-09-12 | 芜湖航天特种电缆厂股份有限公司 | Ageing-resistant composite cable insulating materials in field and preparation method thereof |
| CN107189289A (en) * | 2017-06-23 | 2017-09-22 | 芜湖航天特种电缆厂股份有限公司 | Ship anti-aging cable seal sheath and preparation method thereof |
| CN107325356A (en) * | 2017-09-06 | 2017-11-07 | 南通凤凰橡胶制品有限公司 | Fire-resistant rubber |
| CN107629273A (en) * | 2017-09-06 | 2018-01-26 | 南通凤凰橡胶制品有限公司 | fire-resistant rubber |
| GB2585635B (en) * | 2019-05-28 | 2022-03-23 | Kafrit Ind 1993 Ltd | Compositions and methods for use in the preparation of hydrophobic surfaces |
| CN118652542A (en) * | 2024-06-27 | 2024-09-17 | 会通特种材料科技有限公司 | A kind of instantaneous hydrophilic long carbon chain polyamide powder material and preparation method thereof |
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