CN106747827A - A kind of organic flower fertilizer rich in amino acid - Google Patents
A kind of organic flower fertilizer rich in amino acid Download PDFInfo
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- CN106747827A CN106747827A CN201710043608.6A CN201710043608A CN106747827A CN 106747827 A CN106747827 A CN 106747827A CN 201710043608 A CN201710043608 A CN 201710043608A CN 106747827 A CN106747827 A CN 106747827A
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- amino acid
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
The invention belongs to agriculture fertilizers for potted flowers technical field, and in particular to a kind of organic flower fertilizer rich in amino acid, and its preparation method is further disclosed.Organic flower fertilizer rich in amino acid of the present invention, it is Organic Ingredients by soya-bean cake, hawthorn, sweet potato starch waste residue, urea, addition potassium sulfate and ammonium phosphate are inorganic constituents, digested under papain and cellulase effect, contribute to the enzymolysis of amino acid during enzymatic hydrolysis and fermentation and effective dissolution by way of adding amino acid ion liquid, the amino acid content of gained fertilizers for potted flowers can be effectively improved.The nutrition content of organic flower fertilizer of the present invention is higher, and especially plantation of the high content of amino acid to flowers has fabulous facilitation.
Description
Technical field
The invention belongs to agriculture fertilizers for potted flowers technical field, and in particular to a kind of organic flower fertilizer rich in amino acid, and further
Open its preparation method.
Background technology
Fertilizers for potted flowers is the source of flowers nutriment, nutrition unit necessary to provide one or more plants for the growth of flowers
Element, some fertilizers for potted flowers or and can improve soil property, level of increasing soil fertility, the nutriment of fertilizers for potted flowers and the reasonable of fertilising with
It is no, the growth and development of flowers is directly influenced, it is related to the yield and quality of flowers.Therefore, fertile application process GPRS is fitted
When, it is appropriate, while going back GPRS season and time.
Growth and development of plants need element ratio it is more, main component be nitrogen, phosphorus, potassium " three elements ", next to that calcium, iron,
The elements such as sulphur, magnesium, boron, manganese, copper, zinc, cobalt, carbon, hydrogen, oxygen, carbon therein, hydrogen, oxygen can be obtained from water and air, remaining
Element then needs to be absorbed from soil.Nitrogen, phosphorus, potassium, merely by compost supply be inadequate, accordingly, it would be desirable to by apply fertilizer come
Supplement.
The existing fertilizers for potted flowers for using mainly includes machine fertilizer and inorganic fertilizer.Organic fertilizer mainly has night soil, animal dung and various
Grouts, such as soya-bean cake, sesame paste slag, cottonseed cake etc., they contain abundant nitrogen, phosphorus, potassium and trace element；Wherein, nitrogenous fertilizer has rush
Enter flowers effect with luxuriant foliage, phosphate fertilizer is mainly derived from bone meal, play the role of to promote that pattern is bright-coloured, fruit mast, and potash fertilizer is
Fertilizer based on plant ash, plays the role of to promote flowers limb and root system healthy and strong.Application of organic fertilizers must be raw by fermentation
It is fertile easily to damage flower root system.The fertilizer nutrient content of inorganic fertilizer is high, element is single, fertilizer efficiency is fast, sanitation and hygiene, using convenient,
But long-term use chemical fertilizer easily causes soil hardening, administration is preferably mixed with organic fertilizer, effect is more preferable；Inorganic fertilizer is generally divided into nitrogen
Fertile (such as urea, ammonium carbonate, ammonium hydrogen carbonate, ammoniacal liquor, ammonium chloride, calcium nitrate etc.), phosphate fertilizer (such as calcium superphosphate, calcium and magnesium phosphorus, many
As base manure additive, fertilizer efficiency is slow, and potassium dihydrogen phosphate, ammonium phosphate are high concentration quick-acting fertilizer, and nitrogenous and potash fertilizer can be used as
Topdress) and potash fertilizer (mainly have potassium chloride, potassium sulfate, potassium dihydrogen phosphate, potassium nitrate etc., be quick action fertilizer, can topdress and apply
With).
In addition, current flower planting is also commonly used a kind of amino acid fertilizer.As its name suggests, amino acids fertilizer is
For the material that can provide various amino acids nutriments is referred to as.In the market amino acid fertilizer is generally amino acid and trace element
Deng the compound amino acid fertilizer of compound (complexing).Amino-acid compound fertilizer is under given conditions, by sufficient H2O-
HAS reactions are formed, 18 required for rich in plant growth kind amino acid.Amino Acid Chelated Mineral Fertilizer is used for crops, with obvious
Improve yield, improving quality, reduce residues of pesticides, the effect of preserving the ecological environment etc..Result of study on other crops shows,
15%-35% is reached using the general amount of increase in production of amino-acid compound fertilizer, quality of agricultural product can be improved, improved crop vivo acid and contain
Amount, increases fruit, western muskmelon pol 1-2 degree, and increases crop and fruit degree of staining, improves commodity value.Further, since amino acid
Micro- fertile production technology is updated, and raw material sources are wide (mainly hair, cotton dregs etc.), and production cost is more and more lower, so as to be honest and clean
Valency obtains amino-acid chelate and provides and ensures.Therefore, Amino Acid Chelated Mineral Fertilizer plays more and more important in agricultural production
Role, plays more and more important effect.
The content of the invention
Therefore, the technical problems to be solved by the invention are to provide a kind of organic chemical fertilizer rich in amino acid, one is gone forward side by side
The open its preparation method of step.
In order to solve the above technical problems, a kind of organic flower fertilizer rich in amino acid of the present invention, the organic flower fertilizer
Preparing raw material include：Soya-bean cake 30-50 weight portions, hawthorn 30-50 weight portions, sweet potato starch waste residue 20-50 weight portions, pawpaw egg
White enzyme 3-5 weight portions, cellulase 2-8 weight portions, amino acid ion liquid 8-12 weight portions, urea 5-15 weight portions, sulfuric acid
Potassium 3-8 weight portions, ammonium phosphate 2-4 weight portions.
Preferably, the preparing raw material of the organic flower fertilizer includes：The weight portion of soya-bean cake 40, the weight portion of hawthorn 40, sweet potato starch
The weight portion of waste residue 35, the weight portion of papain 4, the weight portion of cellulase 6, the weight portion of amino acid ion liquid 10, urea 10
Weight portion, the weight portion of potassium sulfate 5, the weight portion of ammonium phosphate 3.
The amino acid ion liquid include L-PROLINE ionic liquid, L-phenylalanine ionic liquid or ALANINE from
At least one in sub- liquid.
The structure of the L-PROLINE ionic liquid, L-phenylalanine ionic liquid or ALANINE ionic liquid is respectively such as
Under：
The invention also discloses a kind of method for preparing the described organic flower fertilizer rich in amino acid, comprise the following steps：
(1) a selected amount of hawthorn stoning, slurrying are taken, and adds a selected amount of soya-bean cake, sweet potato starch waste residue, mixed
It is even；
(2) a selected amount of papain, cellulase and amino acid ion liquid are taken, are added into said mixture,
Pile-fermentation 48-72h；
(3) to adding a selected amount of urea, potassium sulfate and ammonium phosphate to mix in above-mentioned fermentation reaction thing, crushing obtains final product required
Organic flower fertilizer.
In the step (2), the fermentation temperature of the pile-fermentation step is 30-60 DEG C.
In the step (2), also including carrying out turning to the fermentate the step of, to keep its fermentation temperature.
More excellent, in the step (2), the pile-fermentation step is specifically included：Take a selected amount of papain, fibre
The plain enzyme of dimension is added into the mixture, in 50-60 DEG C of pile-fermentation 36-48h, is subsequently added a selected amount of amino acid ionic liquid
Body, turns over even after 30-40 DEG C of continuation pile-fermentation 12-24h.
In the step (3), after being additionally included in fermentation ends, fermentate is sprayed with acid solution, fermentation heap thing pH is into for regulation
The step of property.
In the step (3), it is additionally included in before crushing by fermentation heap thing low temperature drying or the step of dry naturally.
The invention also discloses the organic flower fertilizer rich in amino acid prepared by described method.
Organic flower fertilizer rich in amino acid of the present invention, is organic by soya-bean cake, hawthorn, sweet potato starch waste residue, urea
Raw material, addition potassium sulfate and ammonium phosphate be inorganic constituents, papain and cellulase effect under digest, pass through
The mode of addition amino acid ion liquid contributes to the enzymolysis of the amino acid during enzymatic hydrolysis and fermentation and effective dissolution, can effectively carry
The amino acid content of gained fertilizers for potted flowers high.The nutrition content of organic flower fertilizer of the present invention is higher, especially the height of amino acid
Plantation of the content to flowers has fabulous facilitation.
Organic flower fertilizer rich in amino acid of the present invention, not only can effectively utilize sweet potato starch waste residue, while make use of
Haw taste raw material, for high yield hawthorn plantation area, with fabulous economic worth.
Specific embodiment
Heretofore described amino acid ion liquid selects L-PROLINE ionic liquid, L-phenylalanine ionic liquid or L-
At least one in alanine ionic liquid, the L-PROLINE ionic liquid, L-phenylalanine ionic liquid or ALANINE
Ionic liquid is obtained according to method in the prior art.Such as the brave Master's thesis of Nankai University's Xiao's generation《Amino acid ionic liquid
The synthesis application of body》In described method synthesized.
Research shows, fine containing protein, meals in sweet potato starch waste residue in existing conventional sweet potato starch processing technology
The multiple nutritional components such as dimension, pectin, Polyphenols, beta amylase and sugar, add sweet potato starch and give up in following embodiments of the invention
Slag is the waste residue of general sweet potato starch processing technology, in addition to moisture, also contains 40%-50% remaining starch, 20%-30% meals
Food fiber and 3-5% protein.
Embodiment 1
The preparing raw material of organic flower fertilizer described in the present embodiment includes：Soya-bean cake 30kg, hawthorn 50kg, sweet potato starch waste residue
20kg, papain 5kg, cellulase 2kg, ALANINE ionic liquid 12kg, urea 5kg, potassium sulfate 8kg, ammonium phosphate
2kg。
The preparation method of organic flower fertilizer described in the present embodiment comprises the following steps：
(1) a selected amount of hawthorn stoning, slurrying are taken, and adds a selected amount of soya-bean cake, sweet potato starch waste residue, mixed
It is even；
(2) a selected amount of papain, cellulase and amino acid ion liquid are taken, are added into said mixture,
30 DEG C of temperature of control carries out pile-fermentation, and period carries out turning to the fermentate, to keep 30 DEG C of its fermentation temperature, pile fermentation hair
Ferment 72h；
(3) to after fermentation ends, fermentate is sprayed with acid solution, fermentation heap thing pH is to neutrality for regulation, then to above-mentioned fermentation
Add a selected amount of urea, potassium sulfate and ammonium phosphate to mix in reactant, and the fermentation heap thing is dried naturally, crushing is obtained final product
Required organic flower fertilizer.
Embodiment 2
The preparing raw material of organic flower fertilizer described in the present embodiment includes：Soya-bean cake 50kg, hawthorn 30kg, sweet potato starch waste residue
50kg, papain 3kg, cellulase 8kg, ALANINE ionic liquid 8kg, urea 15kg, potassium sulfate 3kg, ammonium phosphate
4kg。
The preparation method of organic flower fertilizer described in the present embodiment comprises the following steps：
(1) a selected amount of hawthorn stoning, slurrying are taken, and adds a selected amount of soya-bean cake, sweet potato starch waste residue, mixed
It is even；
(2) a selected amount of papain, cellulase and amino acid ion liquid are taken, are added into said mixture,
Control temperature 60 C carries out pile-fermentation, and period carries out turning to the fermentate, to keep 60 DEG C of its fermentation temperature, pile fermentation hair
Ferment 48h；
(3) to after fermentation ends, fermentate is sprayed with acid solution, fermentation heap thing pH is to neutrality for regulation, then to above-mentioned fermentation
Add a selected amount of urea, potassium sulfate and ammonium phosphate to mix in reactant, and the fermentation heap thing is dried naturally, crushing is obtained final product
Required organic flower fertilizer.
Embodiment 3
The preparing raw material of organic flower fertilizer described in the present embodiment includes：Soya-bean cake 40kg, hawthorn 40kg, sweet potato starch waste residue
35kg, papain 4kg, cellulase 6kg, L-PROLINE ionic liquid 10kg, urea 10kg, potassium sulfate 5kg, ammonium phosphate
3kg。
The preparation method of organic flower fertilizer described in the present embodiment comprises the following steps：
(1) a selected amount of hawthorn stoning, slurrying are taken, and adds a selected amount of soya-bean cake, sweet potato starch waste residue, mixed
It is even；
(2) a selected amount of papain, cellulase and amino acid ion liquid are taken, are added into said mixture,
Control temperature 45 C carries out pile-fermentation, and period carries out turning to the fermentate, to keep 45 DEG C of its fermentation temperature, pile fermentation hair
Ferment 60h；
(3) to after fermentation ends, fermentate is sprayed with acid solution, fermentation heap thing pH is to neutrality for regulation, then to above-mentioned fermentation
Add a selected amount of urea, potassium sulfate and ammonium phosphate to mix in reactant, and the fermentation heap thing is dried naturally, crushing is obtained final product
Required organic flower fertilizer.
Embodiment 4
With embodiment 1, it is differed only in the preparing raw material and method of organic flower fertilizer described in the present embodiment, the step
(2) in, the pile-fermentation step is specifically included：A selected amount of papain, cellulase is taken to add to the mixture
In, in 50 DEG C of pile-fermentation 48h, a selected amount of amino acid ion liquid is subsequently added, turn over even after 30 DEG C of continuation pile-fermentations
24h。
Embodiment 5
With embodiment 2, it is differed only in the preparing raw material and method of organic flower fertilizer described in the present embodiment, the step
(2) in, the pile-fermentation step is specifically included：A selected amount of papain, cellulase is taken to add to the mixture
In, in 60 DEG C of pile-fermentation 36h, a selected amount of amino acid ion liquid is subsequently added, turn over even after 40 DEG C of continuation pile-fermentations
12h。
Embodiment 6
With embodiment 3, it is differed only in the preparing raw material and method of organic flower fertilizer described in the present embodiment, the step
(2) in, the pile-fermentation step is specifically included：A selected amount of papain, cellulase is taken to add to the mixture
In, in 55 DEG C of pile-fermentation 42h, a selected amount of amino acid ion liquid is subsequently added, turn over even after 35 DEG C of continuation pile-fermentations
18h。
Comparative example 1-3
Respectively with embodiment 1-3, it is differed only in the preparing raw material and method of organic flower fertilizer described in comparative example 1-3,
Without corresponding amino acid ion liquid.
Experimental example
Nutrient content to gained organic flower fertilizer in above-described embodiment 1-6 and comparative example 1-3 is detected (%), while pressing
More solito implantation methods are control to apply flower the more Special rose fertilizer so that rose is planted as an example, and fertilizer is applied in identical
In the case of amount and crop cycle, as a result the effect of increasing production (%) of test gained fertilizers for potted flowers see the table below 1.
The performance test results (%) of the organic flower fertilizer of table 1
| Numbering | Total organic matter | Amino acid content | Water-soluble carbon | Organic N P and K | Volume increase |
| Embodiment 1 | 30.12 | 10.05 | 8.21 | 6.33 | 7.13 |
| Embodiment 2 | 31.38 | 10.37 | 8.39 | 6.45 | 7.18 |
| Embodiment 3 | 32.02 | 11.92 | 8.83 | 6.67 | 7.47 |
| Embodiment 4 | 32.01 | 16.19 | 8.75 | 6.92 | 10.09 |
| Embodiment 5 | 32.22 | 16.42 | 8.99 | 7.01 | 10.21 |
| Embodiment 6 | 33.75 | 17.08 | 9.44 | 7.22 | 10.35 |
| Comparative example 1 | 30.05 | 5.04 | 7.92 | 6.21 | 5.89 |
| Comparative example 2 | 30.88 | 5.27 | 7.99 | 6.26 | 5.02 |
| Comparative example 3 | 31.63 | 6.13 | 8.11 | 6.29 | 6.32 |
Knowable to upper table data, the organic flower fertilizer rich in amino acid of the present invention, in general organic or inorganic fertilizer
In the screening of raw material, the amino acid during enzymatic hydrolysis and fermentation is contributed to digest and molten by way of adding amino acid ion liquid
Go out, the amino acid content of gained fertilizers for potted flowers can be effectively improved.The nutrition content of organic flower fertilizer of the present invention is higher, especially
Plantation of the high content of amino acid to flowers has fabulous facilitation.
Obviously, above-described embodiment is only intended to clearly illustrate example, and not to the restriction of implementation method.It is right
For those of ordinary skill in the art, can also make on the basis of the above description other multi-forms change or
Change.There is no need and unable to be exhaustive to all of implementation method.And the obvious change thus extended out or
Among changing still in the protection domain of the invention.
Claims (10)
1. a kind of organic flower fertilizer rich in amino acid, it is characterised in that the preparing raw material of the organic flower fertilizer includes：Soya-bean cake 30-
50 weight portions, hawthorn 30-50 weight portions, sweet potato starch waste residue 20-50 weight portions, papain 3-5 weight portions, cellulase
2-8 weight portions, amino acid ion liquid 8-12 weight portions, urea 5-15 weight portions, potassium sulfate 3-8 weight portions, ammonium phosphate 2-4 weights
Amount part.
2. the organic flower fertilizer rich in amino acid according to claim 1, it is characterised in that the preparation of the organic flower fertilizer is former
Material includes：The weight portion of soya-bean cake 40, the weight portion of hawthorn 40, the weight portion of sweet potato starch waste residue 35, the weight portion of papain 4, fiber
The weight portion of plain enzyme 6, the weight portion of amino acid ion liquid 10, the weight portion of urea 10, the weight portion of potassium sulfate 5, the weight portion of ammonium phosphate 3.
3. the organic flower fertilizer rich in amino acid according to claim 1 and 2, it is characterised in that the amino acid ionic liquid
Body includes at least one in L-PROLINE ionic liquid, L-phenylalanine ionic liquid or ALANINE ionic liquid.
4. a kind of method for preparing the organic flower fertilizer rich in amino acid described in claim any one of 1-3, it is characterised in that bag
Include following steps：
(1) a selected amount of hawthorn stoning, slurrying are taken, and adds a selected amount of soya-bean cake, sweet potato starch waste residue, mixed；
(2) a selected amount of papain, cellulase and amino acid ion liquid are taken, is added into said mixture, pile fermentation
Fermentation 48-72h；
(3) to adding a selected amount of urea, potassium sulfate and ammonium phosphate to mix in above-mentioned fermentation reaction thing, crushing is organic needed for obtaining final product
Fertilizers for potted flowers.
5. the method for the organic flower fertilizer rich in amino acid described in preparation according to claim 4, it is characterised in that described
In step (2), the fermentation temperature of the pile-fermentation step is 30-60 DEG C.
6. the method for the organic flower fertilizer rich in amino acid described in preparation according to claim 5, it is characterised in that described
In step (2), also including carrying out turning to the fermentate the step of, to keep its fermentation temperature.
7. the method for the organic flower fertilizer rich in amino acid described in the preparation according to claim 5 or 6, it is characterised in that
In the step (2), the pile-fermentation step is specifically included：A selected amount of papain, cellulase is taken to add to institute
State in mixture, in 50-60 DEG C of pile-fermentation 36-48h, be subsequently added a selected amount of amino acid ion liquid, turn over even after 30-
40 DEG C are continued pile-fermentation 12-24h.
8. the method for the organic flower fertilizer rich in amino acid described in the preparation according to claim any one of 4-7, its feature
It is in the step (3), after being additionally included in fermentation ends, fermentate, regulation fermentation heap thing pH to neutrality to be sprayed with acid solution
Step.
9. the method for the organic flower fertilizer rich in amino acid described in preparation according to claim 8, it is characterised in that described
In step (3), it is additionally included in before crushing by fermentation heap thing low temperature drying or the step of dry naturally.
10. the organic flower fertilizer rich in amino acid that the method as described in claim any one of 4-9 is prepared.
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| CN109265201A (en) * | 2018-11-21 | 2019-01-25 | 山东农业大学 | Using animal wool lysate as the bio-feritlizer of effective component and preparation method and application |
| CN118324586A (en) * | 2024-04-15 | 2024-07-12 | 山东沃力生物科技集团有限公司 | Absorption-promoting amino acid fertilizer, preparation method and application |
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