CN106731923B - Chemical fertilizer slurry agitation emulsifier unit - Google Patents
Chemical fertilizer slurry agitation emulsifier unit Download PDFInfo
- Publication number
- CN106731923B CN106731923B CN201611212653.1A CN201611212653A CN106731923B CN 106731923 B CN106731923 B CN 106731923B CN 201611212653 A CN201611212653 A CN 201611212653A CN 106731923 B CN106731923 B CN 106731923B
- Authority
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- Prior art keywords
- outer cylinder
- piston
- stirring blade
- partition
- chemical fertilizer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002002 slurry Substances 0.000 title claims abstract description 38
- 239000003337 fertilizer Substances 0.000 title claims abstract description 20
- 239000000126 substance Substances 0.000 title claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 16
- 238000013019 agitation Methods 0.000 title claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 74
- 238000005192 partition Methods 0.000 claims abstract description 21
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000007789 sealing Methods 0.000 claims abstract description 11
- 239000007921 spray Substances 0.000 claims description 31
- 238000004945 emulsification Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- -1 emulsifies Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/41—Emulsifying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/43—Mixing liquids with liquids; Emulsifying using driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/51—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle in which the mixture is circulated through a set of tubes, e.g. with gradual introduction of a component into the circulating flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/50—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
- B01F25/52—Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle with a rotary stirrer in the recirculation tube
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/80—Mixing plants; Combinations of mixers
- B01F33/82—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/717—Feed mechanisms characterised by the means for feeding the components to the mixer
- B01F35/7174—Feed mechanisms characterised by the means for feeding the components to the mixer using pistons, plungers or syringes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/71—Feed mechanisms
- B01F35/717—Feed mechanisms characterised by the means for feeding the components to the mixer
- B01F35/7179—Feed mechanisms characterised by the means for feeding the components to the mixer using sprayers, nozzles or jets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F2101/00—Mixing characterised by the nature of the mixed materials or by the application field
- B01F2101/32—Mixing fertiliser ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
Abstract
This patent discloses a kind of chemical fertilizer slurry agitation emulsifier units, are related to fertilizer production equipment；Chemical fertilizer slurry agitation emulsifier unit includes pedestal, emulsion tube and agitating device, emulsion tube is fixed on pedestal, emulsion tube includes outer cylinder and inner cylinder, the middle part of outer cylinder is equipped with partition, inner cylinder is arranged in outer barrel and is fixed by partition and outer cylinder, the top of outer cylinder is equipped with sealing cover, and the lower end of outer cylinder is equipped with outlet valve；Agitating device includes driving motor, stirring blade and piston, and driving motor is mounted on pedestal, and the lower part of outer cylinder is arranged in stirring blade, and stirring blade and outer cylinder are rotatablely connected, and stirring blade is connect with driving motor.Piston is slidably connected in inner cylinder, and the lower end of piston is equipped with cylindrical cam, and the shaft of stirring blade is equipped with the linkage block cooperated with cylindrical cam；Partition is equipped with the first check valve, and piston is equipped with second one-way valve, and the opening direction of the first check valve and second one-way valve is opposite；The device mixing effect is good, can quick emulsification slurry.
Description
Technical field
The present invention relates to fertilizer production equipments, and in particular to a kind of chemical fertilizer slurry agitation emulsifier unit.
Background technique
During chemical fertilizer production, whether uniformly mixed slurry is the key factor for influencing product appearance and granulating, but by
In the complicated component of compound fertilizer, raw material are more, need to mix the liquid of a variety of different specific weights and fully emulsified, just can be carried out
Next step production process, but in emulsion process, the emulsifier structure of existing chemical fertilizer production is simple, high production efficiency, but big
Most emulsifiers are the work for using auger, can only stir material in sustained height plane, it is vertical to be unable to drive material
Movement, when the specific gravity of different material difference is larger, it is uneven to will cause emulsification, and emulsifying effectiveness is poor, inefficiency, influences chemical fertilizer
Total quality.
Summary of the invention
It, can only be to solve existing blender the purpose of the present invention is to provide a kind of chemical fertilizer slurry agitation emulsifier unit
The technical issues of sustained height plane stirs material, is unable to drive material vertical movement.
In order to achieve the above objectives, base case of the invention is as follows:
Chemical fertilizer slurry agitation emulsifier unit includes pedestal, emulsion tube and agitating device, and the emulsion tube is fixed on pedestal,
Emulsion tube includes outer cylinder and inner cylinder, and the middle part of outer cylinder is equipped with partition, and partition top is spray chamber, and the lower partition is stir chamber, interior
Cylinder is arranged in outer barrel and is fixed by partition and outer cylinder, and the upper end of inner cylinder is connected to spray chamber, and inner cylinder lower end is connected to stir chamber,
The top of outer cylinder is equipped with openable sealing cover, and the lower end of outer cylinder is equipped with outlet valve；The agitating device includes driving motor, stirs
Blade and piston are mixed, the driving motor is mounted on pedestal, and stirring blade is arranged in the lower part of outer cylinder, and stirring blade and outer
Cylinder rotation connection, stirring blade are connect with driving motor；The piston is slidably connected in inner cylinder, and piston can be in inner cylinder up and down
Sliding, the lower end of piston are equipped with cylindrical cam, and the shaft of stirring blade is equipped with the linkage block cooperated with cylindrical cam；It is described every
Plate is equipped with the first check valve, and the piston is equipped with second one-way valve, the opening direction of the first check valve and second one-way valve
On the contrary.
After opening sealing cover is packed into appropriate slurry into emulsion tube, lock sealing lid closes emulsion tube.Starting driving electricity
Machine is stirred slurry, emulsifies, concrete principle are as follows: driving motor drive stirring blade rotation, to the slurry in stir chamber into
Row stirring；Since the linkage block and cylindrical cam of the shaft upper end of stirring blade cooperate, stirring blade is rotated one week, piston
It will move up and down primary.Due to being enclosure space in emulsion tube, and partition separates emulsion tube for spray chamber and stir chamber, works as work
When plug is run up, the pressure of spray chamber increases, then the first check valve conducting on partition, so that the slurry in spray chamber passes through
First check valve is sprayed to stir chamber；When piston is run down, the pressure of stir chamber increases, then the second one-way valve on piston
Conducting, so that the slurry in stir chamber is sprayed by two way valve to spray chamber.By sliding up and down for piston, so that spray chamber
It is constantly exchanged with the slurry in stir chamber, while slurry is by nebulizing dispersion when the first check valve and second one-way valve injection
Droplet, to be conducive to the mixing of different liquids, then the emulsification for cooperating the stirring of stirring blade that can then accelerate slurry.
The beneficial effect that this programme generates is:
(1) while stirring blade stirring slurry, piston can be such that stir chamber and the pressures cycle of spray chamber changes, thus
The size circulations in stir chamber and spray chamber are flowed, can be flowed in the vertical space of emulsion tube in slurry, so that stirring
Efficiency enhancing.
(2) when entering spray chamber from stir chamber due to slurry, or entering stir chamber from spray chamber, pressure increase can make to starch
Material is in spurting, thus by slurry atomization at droplet, therefore be conducive to the emulsification of slurry.
(3) piston can make have biggish pressure change in stir chamber and spray chamber during moving up and down, because
Slurry in this stir chamber and spray chamber can quickly complete exchange.
Preferred embodiment one: advanced optimizing as to base case, and the outer cylinder is externally provided with communicating pipe, and the one of communicating pipe
End is connected to spray chamber, communicating pipe the other end be connected to stir chamber, communicating pipe is equipped with communicating valve.After opening communicating valve, connection
Spray chamber is connected to by pipe with stir chamber, to be conducive to feed；In addition communicating pipe and communicating valve are arranged on the outside of outer cylinder, favorably
It is operated in communicating valve.
Preferred embodiment two: advanced optimizing as to base case, and the upper end of the shaft of the stirring blade is equipped with set
Cylinder, bush outer sleeve is on cylindrical cam, and sleeve and cylindrical cam are rotatablely connected, and linkage block is fixed on sleeve lining.Setting set
Cylinder cooperates with cylindrical cam, cylindrical cam stress can be made more stable, and reduce radial force suffered by cylindrical cam, prevent piston
There is clamping stagnation.
Preferred embodiment three: advanced optimizing as to base case, and the sealing cover is hinged on outer cylinder, so that emulsification
The opening and closing more convenient operation of cylinder improves safety in addition it can prevent sealing cover from falling.
Preferred embodiment four: advanced optimizing as to base case, and disturbance blade is equipped in the spray chamber, disturbs leaf
Piece is rotatably connected in outer cylinder, the screw rod that the upper end of piston is equipped with, and disturbance blade and screw flight cooperate, when piston moves up and down
When, screw rod rotates driving disturbance blade.The work that there can be auxiliary to stir in the slurry in spray chamber after disturbance blade is set
With, and the linkage structure of stirring blade, piston and disturbance blade three is simple, saves installation space.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of chemical fertilizer slurry agitation emulsifier unit embodiment of the present invention.
Specific embodiment
Below by specific embodiment, the present invention is described in further detail:
Appended drawing reference in Figure of description includes: outer cylinder 11, inner cylinder 12, partition 13, communicating pipe 14, communicating valve 15, stirs
Mix chamber 16, spray chamber 17, sealing cover 18, driving motor 21, stirring blade 22, piston 23, disturbance blade 24, cylindrical cam 25,
Linkage block 26, screw rod 27, the first check valve 28, second one-way valve 29.
Embodiment is substantially as shown in Figure 1:
The chemical fertilizer slurry agitation emulsifier unit of the present embodiment includes pedestal, emulsion tube and agitating device；Emulsion tube is welded on
On pedestal, emulsion tube includes outer cylinder 11 and inner cylinder 12, and the middle part of outer cylinder 11 is equipped with partition 13, and 13 top of partition is spray chamber 17,
13 lower part of partition is stir chamber 16, and the setting of inner cylinder 12 is inside outer cylinder 11 and fixed by partition 13 and outer cylinder 11, and inner cylinder 12
It is coaxial with outer cylinder 11.The upper end of inner cylinder 12 is connected to spray chamber 17, and 12 lower end of inner cylinder is connected to stir chamber 16, and the top of outer cylinder 11 is equipped with
Openable sealing cover 18, sealing cover 18 are hinged on 11 upper end of outer cylinder, and the lower end of outer cylinder 11 is equipped with outlet valve, and opening outlet valve can
Paddle material is discharged.Fixed there are three communicating pipe 14 on 11 outer wall of outer cylinder, one end of communicating pipe 14 is connected to spray chamber 17, communicating pipe 14
The other end is connected to stir chamber 16, and communicating pipe 14 is equipped with communicating valve 15；After opening communicating valve 15, communicating pipe 14 is by spray chamber 17
It is connected to stir chamber 16, to be conducive to feed；In addition communicating pipe 14 and the setting of communicating valve 15 are conducive in 11 outside of outer cylinder
Communicating valve 15 is operated.
Agitating device includes that driving motor 21, stirring blade 22, piston 23 and disturbance blade 24, driving motor 21 are installed
On pedestal, stirring blade 22 is arranged in stir chamber 16, and stirring blade 22 and outer cylinder 11 are rotatablely connected, and stirring blade 22 with
Driving motor 21 connects, so that driving motor 21 can drive stirring blade 22 to rotate.Piston 23 is slidably connected in inner cylinder 12, living
Plug 23 can slide up and down in inner cylinder 12, and the lower end of piston 23 is equipped with cylindrical cam 25, and the periphery of cylindrical cam 25 is equipped with a ring
Connected in star, the upper end of 22 shaft of stirring blade are equipped with sleeve, bush outer sleeve on cylindrical cam 25, sleeve with 25 turns of cylindrical cam
Dynamic connection, sleeve lining are equipped with linkage block 26, and linkage block 26 is embedded in annular groove.Blade 24 is disturbed to be arranged in spraying canister
Interior, disturbance blade 24 and outer cylinder 11 are rotatablely connected, and the screw rod 27 that the upper end of piston 23 is equipped with, screw rod 27 is equipped with trapezoidal thread,
Disturbance blade 24 is threadedly engaged with screw rod 27, and the helix angle of trapezoidal thread is 50o, self-locking to prevent from being threadedly engaged；Disturbance
Blade 24 has the function of auxiliary stirring, and stirring blade 22, piston 23 and disturbance blade 24 3 to the slurry in spray chamber 17
The linkage of person.Partition 13 is equipped with the first check valve 28, and piston 23 is equipped with second one-way valve 29, the first check valve 28 and second
The opening direction of check valve 29 is opposite；Specifically: when piston 23 moves up, the first check valve 28 is opened；When piston 23 moves down,
Second one-way valve 29 is opened.
When driving motor 21 drives stirring blade 22 to rotate, then stirring blade 22 stirs the slurry in stir chamber 16
It mixes, the helical angle of stirring blade 22 is set as 30o in the present embodiment, can provide enough mixing powers.When stirring blade 22
Rotation one week, piston 23 will move up and down once.When piston 23 is run up, the pressure of spray chamber 17 increases, then partition 13
On the conducting of the first check valve 28, so that slurry in spray chamber 17 is sprayed by the first check valve 28 to stir chamber 16；Work as work
When plug 23 is run down, the pressure of stir chamber 16 increases, then the second one-way valve 29 on piston 23 is connected, thus in stir chamber 16
Slurry sprayed by two way valve to spray chamber 17.By sliding up and down for piston 23, generate slurry in the vertical direction
Flowing, the droplet that slurry nebulizes dispersion when being sprayed by the first check valve 28 and second one-way valve 29, so as to add
Fast slurry emulsification.When piston 23 moves up and down, disturbance blade 24 will also be rotated, and be stirred to the slurry in spray chamber 17；
Since disturbance blade 24 only plays auxiliary stirring action, the helical angle of disturbance blade 24 is not easy excessive, disturbs in the present embodiment
The helical angle of blade 24 is set as 8o.
What has been described above is only an embodiment of the present invention, and the common sense such as well known specific structure and characteristic are not made herein in scheme
Excessive description.It, without departing from the structure of the invention, can be with it should be pointed out that for those skilled in the art
Several modifications and improvements are made, these also should be considered as protection scope of the present invention, these all will not influence what the present invention was implemented
Effect and patent practicability.The scope of protection required by this application should be based on the content of the claims, in specification
The records such as specific embodiment can be used for explaining the content of claim.
Claims (5)
1. a kind of chemical fertilizer slurry agitation emulsifier unit, including pedestal, emulsion tube and agitating device, the emulsion tube are fixed on pedestal
On, emulsion tube includes outer cylinder and inner cylinder, and the middle part of outer cylinder is equipped with partition, and partition top is spray chamber, and the lower partition is stir chamber,
Inner cylinder is arranged in outer barrel and is fixed by partition and outer cylinder, and the upper end of inner cylinder is connected to spray chamber, the connection stirring of inner cylinder lower end
Chamber, which is characterized in that the top of outer cylinder is equipped with openable sealing cover, and the lower end of outer cylinder is equipped with outlet valve；The agitating device
Including driving motor, stirring blade and piston, the driving motor is mounted on pedestal, and stirring blade is arranged under outer cylinder
Portion, and stirring blade and outer cylinder are rotatablely connected, stirring blade is connect with driving motor；The piston is slidably connected in inner cylinder,
Piston can slide up and down in inner cylinder, and the lower end of piston is equipped with cylindrical cam, and the shaft of stirring blade is equipped with and cylindrical cam
The linkage block of cooperation；The partition is equipped with the first check valve, and the piston is equipped with second one-way valve, the first check valve and the
The opening direction of two check valves is opposite.
2. chemical fertilizer slurry agitation emulsifier unit according to claim 1, which is characterized in that the outer cylinder is externally provided with connection
Pipe, one end of communicating pipe is connected to spray chamber, communicating pipe the other end be connected to stir chamber, communicating pipe is equipped with communicating valve.
3. chemical fertilizer slurry agitation emulsifier unit according to claim 1, which is characterized in that the shaft of the stirring blade
Upper end is equipped with sleeve, and bush outer sleeve is on cylindrical cam, and sleeve and cylindrical cam are rotatablely connected, and linkage block is fixed on sleeve lining
On.
4. chemical fertilizer slurry agitation emulsifier unit according to claim 1, which is characterized in that the sealing cover is hinged on outer cylinder
On.
5. chemical fertilizer slurry agitation emulsifier unit according to claim 1, which is characterized in that be equipped with disturbance in the spray chamber
Blade, disturbance blade are rotatably connected in outer cylinder, and the screw rod that the upper end of piston is equipped with, disturbance blade and screw flight cooperate, when
When piston moves up and down, screw rod rotates driving disturbance blade.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611212653.1A CN106731923B (en) | 2016-12-25 | 2016-12-25 | Chemical fertilizer slurry agitation emulsifier unit |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611212653.1A CN106731923B (en) | 2016-12-25 | 2016-12-25 | Chemical fertilizer slurry agitation emulsifier unit |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106731923A CN106731923A (en) | 2017-05-31 |
| CN106731923B true CN106731923B (en) | 2019-02-12 |
Family
ID=58919706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611212653.1A Expired - Fee Related CN106731923B (en) | 2016-12-25 | 2016-12-25 | Chemical fertilizer slurry agitation emulsifier unit |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106731923B (en) |
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| CN1117892A (en) * | 1994-04-18 | 1996-03-06 | 普拉塞尔技术有限公司 | Variable liquid level eductor/impeller gas-liquid mixing apparatus and process |
| RU2154520C2 (en) * | 1995-06-23 | 2000-08-20 | Малое внедренческое предприятие "Камус" | Mixer |
| CN103861507A (en) * | 2014-04-06 | 2014-06-18 | 山东天山丰耘生态肥业有限公司 | Emulgator for producing nitro-sulfenyl slow-release fertilizer |
-
2016
- 2016-12-25 CN CN201611212653.1A patent/CN106731923B/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1117892A (en) * | 1994-04-18 | 1996-03-06 | 普拉塞尔技术有限公司 | Variable liquid level eductor/impeller gas-liquid mixing apparatus and process |
| RU2154520C2 (en) * | 1995-06-23 | 2000-08-20 | Малое внедренческое предприятие "Камус" | Mixer |
| CN103861507A (en) * | 2014-04-06 | 2014-06-18 | 山东天山丰耘生态肥业有限公司 | Emulgator for producing nitro-sulfenyl slow-release fertilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106731923A (en) | 2017-05-31 |
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