CN106731240A - A kind of ceramic base effluent filter - Google Patents
A kind of ceramic base effluent filter Download PDFInfo
- Publication number
- CN106731240A CN106731240A CN201710069383.1A CN201710069383A CN106731240A CN 106731240 A CN106731240 A CN 106731240A CN 201710069383 A CN201710069383 A CN 201710069383A CN 106731240 A CN106731240 A CN 106731240A
- Authority
- CN
- China
- Prior art keywords
- parts
- layer
- filter
- ceramic base
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 27
- 238000001914 filtration Methods 0.000 claims abstract description 51
- 239000002994 raw material Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002351 wastewater Substances 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 11
- 238000005245 sintering Methods 0.000 claims abstract description 11
- 239000003365 glass fiber Substances 0.000 claims abstract description 6
- 239000010455 vermiculite Substances 0.000 claims abstract description 6
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 6
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 6
- 239000010453 quartz Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 34
- 239000011148 porous material Substances 0.000 claims description 33
- 239000004094 surface-active agent Substances 0.000 claims description 24
- 239000011230 binding agent Substances 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- -1 graphite alkene Chemical class 0.000 claims description 10
- 238000007731 hot pressing Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 9
- 238000000746 purification Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 235000010981 methylcellulose Nutrition 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 235000010233 benzoic acid Nutrition 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims 2
- 239000012535 impurity Substances 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 8
- 238000003795 desorption Methods 0.000 abstract description 5
- 239000005995 Aluminium silicate Substances 0.000 abstract 2
- 235000012211 aluminium silicate Nutrition 0.000 abstract 2
- 238000010030 laminating Methods 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- LCDFWRDNEPDQBV-UHFFFAOYSA-N formaldehyde;phenol;urea Chemical compound O=C.NC(N)=O.OC1=CC=CC=C1 LCDFWRDNEPDQBV-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2068—Other inorganic materials, e.g. ceramics
- B01D39/2093—Ceramic foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
- B01D2239/10—Filtering material manufacturing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filtering Materials (AREA)
Abstract
一种陶瓷基废水过滤器，由过滤层和脱滤层叠合后高温烧结而成，所述过滤层为朝向未过滤的废水方向的一层，所述脱滤层为朝向已过滤的净水方向的一层；所述过滤层由以下重量份数的原料组成：活性氧化铝：30～40份；煅烧高岭土：20～30份；锐钛矿型二氧化钛：20～35份；玻璃纤维：5～8份；蛭石：1～3份；所述脱滤层由以下重量份数的原料组成：普通氧化铝：40～50份；普通高岭土：20～30份；金红石型二氧化钛：10～15份；石英：5～10份；预处理后的石墨烯：3～5份。本发明制备得到的陶瓷过滤器具有双层构造，既容易正向吸附废水杂质，也容易反洗脱附，且脱附压力小，脱附效果好，大大提高了过滤水的效率。A ceramic-based wastewater filter, which is formed by laminating a filter layer and a defiltration layer and sintering at high temperature, the filter layer is a layer facing the direction of unfiltered wastewater, and the defiltration layer is a layer facing the direction of filtered clean water The filter layer is composed of the following raw materials in parts by weight: activated alumina: 30-40 parts; calcined kaolin: 20-30 parts; anatase titanium dioxide: 20-35 parts; glass fiber: 5-35 parts 8 parts; vermiculite: 1-3 parts; the defiltration layer is composed of the following raw materials in parts by weight: ordinary alumina: 40-50 parts; ordinary kaolin: 20-30 parts; rutile titanium dioxide: 10-15 parts ; Quartz: 5-10 parts; Graphene after pretreatment: 3-5 parts. The ceramic filter prepared by the present invention has a double-layer structure, is easy to positively adsorb impurities in waste water, and is also easy to backwash and desorb. The desorption pressure is small, the desorption effect is good, and the efficiency of filtering water is greatly improved.
Description
Technical field
The present invention relates to water-treatment technology field, more particularly, to a kind of ceramic base effluent filter.
Background technology
Ceramic filter is the filtering material commonly used in water process.General running is：Allow under pressure useless
Water is filtrated to get water purification by filter；After operation a period of time, be by backwash come polishing filter.Backwash is exactly right
Filter applies the pressure in opposite direction come with waste water, allows water purification back through filter, and will build up in the filter is miscellaneous
Matter is rinsed out.
Ceramic filter typically makes loose structure, so can more adsorb the impurity in waste water.But porous knot
The ceramics of structure are easier in adsorbing contaminant, more difficult when backwash is desorbed, and are not only because a large amount of holes and are difficult to entirely
Portion is uniformly subject to buffer brake to impact is desorbed impurity, but also because there is substantial amounts of work the hole inside of porous ceramics in itself
Property surface group, after being combined by hydrogen bond or Van der Waals force with impurity be difficult disengage.Want to disengage hole surface and impurity it
Between adhesion, it is necessary to increase buffer brake, the excessive easily direct internal structure of destruction porous ceramics of pressure makes its cracking collapse
Collapse, it is impossible to be continuing with.
The content of the invention
In view of the above-mentioned problems existing in the prior art, the applicant provides a kind of ceramic base effluent filter.The present invention
The ceramic filter for preparing has double-layer structural, both easily positive to adsorb waste water impurity, also easy backwash desorption, and desorption
Pressure is small, and desorption effect is good, substantially increases the efficiency of filter water.
Technical scheme is as follows：
A kind of ceramic base effluent filter, high temperature sintering is formed after being overlapped by filter layer and de- filtering layer, and the filter layer is
Towards one layer of unfiltered waste water direction, the de- filtering layer is a layer towards filtered water purification direction；
The filter layer is made up of the raw material of following parts by weight：
Activated alumina：30~40 parts；Calcined kaolin：20~30 parts；Anatase titanium dioxide：20~35 parts；Glass
Glass fiber：5~8 parts；Vermiculite：1~3 part；Each raw material average grain diameter of the filter layer is 300~500 microns；
The de- filtering layer is made up of the raw material of following parts by weight：
Common aluminum oxide：40~50 parts；Common kaolin：20~30 parts；Rutile titanium dioxide：10~15 parts；Stone
English：5~10 parts；Pretreated Graphene：3~5 parts；Each raw material average grain diameter of the de- filtering layer is 200~300 microns；
The method of the pretreating graphite alkene is：It is the ethoxy perhydro-s-triazine and graphite of Graphene 3~5% by quality
Alkene adds the acetone soln that concentration is 1~2wt% together, and ultrasonic disperse 40~60 minutes, then dry in the case of stirring
Into powder.
It is first each compressing after the filter layer and the respective raw material of de- filtering layer are well mixed respectively, then it is superimposed on one
Rise by hot binding together；Calcined with reference to after.
The pressure of the hot pressing is 3~5Mpa, and temperature is 120~150 DEG C, and hot pressing time is 3~5 minutes.
When the filter layer and the respective raw material of de- filtering layer mix respectively, surfactant, binding agent, pore creating material are added
And deionized water.
The surfactant is oleic acid, stearic acid, one kind of odium stearate.
The binding agent is methylcellulose or hydroxypropyl methyl cellulose.
The pore creating material is carbon dust, benzoic acid, phenolic resin ball or other conventional pore creating materials, and the particle diameter of the pore creating material is
10~20 microns.
With filter layer and the respective raw material weight of de- filtering layer and be an entirety, the surfactant is respectively the two
The 1~2.5% of total quality, binding agent is respectively the 4~6% of the two total qualities, and pore creating material is respectively the two entirety
The 10~25% of quality；Deionized water is respectively the 30~35% of the two total qualities.
The sintering temperature is 1250~1280 DEG C, and soaking time is 3~5 hours.
The present invention is beneficial to be had technical effect that：
Filter layer of the invention is the porous ceramic structure of conventional easy adsorbing contaminant, and de- filtering layer be then with filtering
Layer is kept on the basis of basically identical chemical composition, has carried out drop activity treatment.First feature of de- filtering layer is micropore chi
It is very little smaller than filter layer, can further prevent smaller size of impurity by filter, improve water purification ability.
Second feature is that activity is low, even if there is impurity to enter the micropore of de- filtering layer, cannot also produce hydrogen bond or model moral
The combination of Hua Li；Pretreated Graphene is particularly with the addition of, its activity, the impurity in backwash process is greatly reduced
Can be desorbed under the effect of small pressure, be backwashed water and be flushed in the micropore of filter layer；Swiftly flowing impurity impact filtration layer
Micropore, serves the effect that physics washes away, and the pressure with backwash water combines, and absorption is acted in mistake equivalent to two parts of strength
Impurity in the micropore of filtering layer, makes them faster, more thoroughly be backwashed away.
3rd feature be it is substantially similar to the crystal structure of filter layer, with the unified with nature of filter layer and it is tight, will not
Because crystal formation suddenly change causes to produce clogging in two-layer junction.
Specific embodiment
With reference to embodiment, the present invention is specifically described.
Embodiment 1
A kind of ceramic base effluent filter, high temperature sintering is formed after being overlapped by filter layer and de- filtering layer, and the filter layer is
Towards one layer of unfiltered waste water direction, the de- filtering layer is a layer towards filtered water purification direction；
The filter layer is made up of the raw material of following parts by weight：Activated alumina：30 parts；Calcined kaolin：20 parts；It is sharp
Titanium ore type titanium dioxide：20 parts；Glass fibre：5 parts；Vermiculite：1 part；Each raw material average grain diameter of the filter layer is 300 micro-
Rice；
The de- filtering layer is made up of the raw material of following parts by weight：Common aluminum oxide：40 parts；Common kaolin：20 parts；Gold
Red stone-type titanium dioxide：10 parts；Quartz：5 parts；Pretreated Graphene：3 parts；Each raw material average grain diameter of the de- filtering layer
It is 200 microns；
The method of the pretreating graphite alkene is：It is the ethoxy perhydro-s-triazine and Graphene of Graphene 3% by quality
It is the acetone soln of 1wt% to add concentration together, and ultrasonic disperse 40 minutes, are then dried to powder in the case of stirring.
Specifically preparation method is：
(1) each raw material of filter layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is oleic acid, and the binding agent is methylcellulose, and the pore creating material is carbon dust, described to make
The particle diameter of hole agent is 10 microns；
With the raw material weight of filter layer and be an entirety, the surfactant is the 1% of this total quality, is bonded
Agent is the 4% of this total quality, and pore creating material is the 10% of this total quality；Deionized water is this total quality
30%.
(2) each raw material of de- filtering layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is oleic acid, and the binding agent is methylcellulose, and the pore creating material is carbon dust, described to make
The particle diameter of hole agent is 10 microns；
To take off the raw material weight of filtering layer and be an entirety, the surfactant is the 1.5% of this total quality, is glued
Knot agent is the 4.3% of this total quality, and pore creating material is the 12% of this total quality；Deionized water is this total quality
31.5%.
(3) it is filter layer and de- filtering layer is each compressing, then be superimposed together by hot binding together；Hot pressing
Pressure is 3Mpa, and temperature is 150 DEG C, and hot pressing time is 5 minutes.Calcined with reference to after.
(4) it is put into calcining furnace through hot binding filter layer together and de- filtering layer and is sintered, sintering temperature is 1250 DEG C,
Soaking time is 5 hours.
Embodiment 2
A kind of ceramic base effluent filter, high temperature sintering is formed after being overlapped by filter layer and de- filtering layer, and the filter layer is
Towards one layer of unfiltered waste water direction, the de- filtering layer is a layer towards filtered water purification direction；
The filter layer is made up of the raw material of following parts by weight：Activated alumina：35 parts；Calcined kaolin：25 parts；It is sharp
Titanium ore type titanium dioxide：30 parts；Glass fibre：6 parts；Vermiculite：2 parts；Each raw material average grain diameter of the filter layer is 400 micro-
Rice；
The de- filtering layer is made up of the raw material of following parts by weight：Common aluminum oxide：45 parts；Common kaolin：25 parts；Gold
Red stone-type titanium dioxide：12 parts；Quartz：8 parts；Pretreated Graphene：4 parts；Each raw material average grain diameter of the de- filtering layer
It is 250 microns；
The method of the pretreating graphite alkene is：It is the ethoxy perhydro-s-triazine and Graphene of Graphene 4% by quality
It is the acetone soln of 1.5wt% to add concentration together, and ultrasonic disperse 50 minutes, are then dried to powder in the case of stirring.
Specifically preparation method is：
(1) each raw material of filter layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is stearic acid, and the binding agent is hydroxypropyl methyl cellulose, and the pore creating material is benzene first
Acid, the particle diameter of the pore creating material is 12 microns；
With the raw material weight of filter layer and be an entirety, the surfactant is the 1.5% of this total quality, is glued
Knot agent is the 5% of this total quality, and pore creating material is the 18% of this total quality；Deionized water is this total quality
33%.
(2) each raw material of de- filtering layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is one kind of odium stearate, and the binding agent is methylcellulose, and the pore creating material is phenol
Urea formaldehyde ball, the particle diameter of the pore creating material is 16 microns；
To take off the raw material weight of filtering layer and be an entirety, the surfactant is the 1.8% of this total quality, is glued
Knot agent is the 5% of this total quality, and pore creating material is the 20% of this total quality；Deionized water is this total quality
32%.
(3) it is filter layer and de- filtering layer is each compressing, then be superimposed together by hot binding together；Hot pressing
Pressure is 4Mpa, and temperature is 130 DEG C, and hot pressing time is 4 minutes.Calcined with reference to after.
(4) it is put into calcining furnace through hot binding filter layer together and de- filtering layer and is sintered, sintering temperature is 1260 DEG C,
Soaking time is 4 hours.
Embodiment 3
A kind of ceramic base effluent filter, high temperature sintering is formed after being overlapped by filter layer and de- filtering layer, and the filter layer is
Towards one layer of unfiltered waste water direction, the de- filtering layer is a layer towards filtered water purification direction；
The filter layer is made up of the raw material of following parts by weight：Activated alumina：40 parts；Calcined kaolin：30 parts；It is sharp
Titanium ore type titanium dioxide：35 parts；Glass fibre：8 parts；Vermiculite：3 parts；Each raw material average grain diameter of the filter layer is 500 micro-
Rice；
The de- filtering layer is made up of the raw material of following parts by weight：Common aluminum oxide：50 parts；Common kaolin：30 parts；Gold
Red stone-type titanium dioxide：5 parts；Quartz：10 parts；Pretreated Graphene：5 parts；Each raw material average grain diameter of the de- filtering layer
It is 300 microns；
The method of the pretreating graphite alkene is：It is the ethoxy perhydro-s-triazine and Graphene of Graphene 5% by quality
It is the acetone soln of 2wt% to add concentration together, and ultrasonic disperse 60 minutes, are then dried to powder in the case of stirring.
Specifically preparation method is：
(1) each raw material of filter layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is odium stearate, and the binding agent is hydroxypropyl methyl cellulose, and the pore creating material is carbon
Powder, the particle diameter of the pore creating material is 20 microns；
With the raw material weight of filter layer and be an entirety, the surfactant is the 2.5% of this total quality, is glued
Knot agent is the 6% of this total quality, and pore creating material is the 25% of this total quality；Deionized water is this total quality
35%.
(2) each raw material of de- filtering layer is mixed, is subsequently adding surfactant, binding agent, pore creating material and deionized water
It is well mixed；The surfactant is odium stearate, and the binding agent is hydroxypropyl methyl cellulose, and the pore creating material is carbon
Powder, the particle diameter of the pore creating material is 20 microns；
To take off the raw material weight of filtering layer and be an entirety, the surfactant is the 2.2% of this total quality, is glued
Knot agent is the 4.7% of this total quality, and pore creating material is the 22% of this total quality；Deionized water is this total quality
35%.
(3) it is filter layer and de- filtering layer is each compressing, then be superimposed together by hot binding together；Hot pressing
Pressure is 5Mpa, and temperature is 120 DEG C, and hot pressing time is 3 minutes.Calcined with reference to after.
(4) it is put into calcining furnace through hot binding filter layer together and de- filtering layer and is sintered, sintering temperature is 1280 DEG C,
Soaking time is 3 hours.
Test case 1：Performance test, the test result such as institute of table 1 are carried out to the ceramic wastewater filter that embodiment 2 is prepared
Show.
Table 1
| Filter layer | De- filtering layer | |
| Porosity (%) | 68 | 75 |
| Micro-pore diameter (micron) | 60~90 | 20~40 |
| Compression strength (MPa) | 4.52 | 4.69 |
Test case 2：The effluent filter that the present invention is prepared, can as wastewater treatment equipment in intermediate filter ring
Section.Flocculation treatment and coarse filtration first are carried out to waste water, impurity therein is changed into cotton-shaped, and wherein granularity will be more than 100 microns
Contaminant filter fall, be left particle diameter less than 100 microns of impurity, cascade filtration is then carried out using this filter.
The filter prepared using embodiment 2 carries out cascade filtration to coating wastewater and sanitary sewage, before and after filtering
Water index it is as shown in table 2.
Table 2
Claims (9)
1. a kind of ceramic base effluent filter, it is characterised in that high temperature sintering is formed after being overlapped by filter layer and de- filtering layer, described
Filter layer is a layer towards unfiltered waste water direction, and the de- filtering layer is a layer towards filtered water purification direction；
The filter layer is made up of the raw material of following parts by weight：
Activated alumina：30~40 parts；Calcined kaolin：20~30 parts；Anatase titanium dioxide：20~35 parts；Glass fibers
Dimension：5~8 parts；Vermiculite：1~3 part；Each raw material average grain diameter of the filter layer is 300~500 microns；
The de- filtering layer is made up of the raw material of following parts by weight：
Common aluminum oxide：40~50 parts；Common kaolin：20~30 parts；Rutile titanium dioxide：10~15 parts；Quartz：5
~10 parts；Pretreated Graphene：3~5 parts；Each raw material average grain diameter of the de- filtering layer is 200~300 microns；
The method of the pretreating graphite alkene is：It is the ethoxy perhydro-s-triazine and Graphene one of Graphene 3~5% by quality
The acetone soln for adding concentration to be 1~2wt% is acted, ultrasonic disperse 40~60 minutes, are then dried to powder in the case of stirring
End.
2. ceramic base effluent filter according to claim 1, it is characterised in that the filter layer and de- filtering layer are respective
It is first each compressing after raw material is well mixed respectively, then be superimposed together by hot binding together；Forged with reference to after
Burn.
3. ceramic base effluent filter according to claim 2, it is characterised in that the pressure of the hot pressing is 3~5Mpa,
Temperature is 120~150 DEG C, and hot pressing time is 3~5 minutes.
4. ceramic base effluent filter according to claim 2, it is characterised in that the filter layer and de- filtering layer are respective
When raw material mixes respectively, surfactant, binding agent, pore creating material and deionized water are added.
5. ceramic base effluent filter according to claim 4, it is characterised in that the surfactant is oleic acid, tristearin
Acid, one kind of odium stearate.
6. ceramic base effluent filter according to claim 4, it is characterised in that the binding agent be methylcellulose or
Hydroxypropyl methyl cellulose.
7. ceramic base effluent filter according to claim 4, it is characterised in that the pore creating material be carbon dust, benzoic acid,
Phenolic resin ball or other conventional pore creating materials, the particle diameter of the pore creating material is 10~20 microns.
8. ceramic base effluent filter according to claim 4, it is characterised in that with filter layer and the respective original of de- filtering layer
Material weight and be an entirety, the surfactant is respectively the 1~2.5% of the two total qualities, and binding agent is respectively
The 4~6% of the two total qualities, pore creating material is respectively the 10~25% of the two total qualities；Deionized water is respectively this
Two the 30~35% of total quality.
9. the ceramic base effluent filter according to any one of claim 1~8, it is characterised in that the sintering temperature is
1250~1280 DEG C, soaking time is 3~5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710069383.1A CN106731240B (en) | 2017-02-08 | 2017-02-08 | A kind of ceramic base effluent filter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710069383.1A CN106731240B (en) | 2017-02-08 | 2017-02-08 | A kind of ceramic base effluent filter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106731240A true CN106731240A (en) | 2017-05-31 |
| CN106731240B CN106731240B (en) | 2018-09-11 |
Family
ID=58955389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710069383.1A Active CN106731240B (en) | 2017-02-08 | 2017-02-08 | A kind of ceramic base effluent filter |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106731240B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109224629A (en) * | 2018-09-17 | 2019-01-18 | 江苏光天耐材科技有限公司 | A kind of filter of dry process and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1155723A2 (en) * | 2000-05-18 | 2001-11-21 | Fleetguard, Inc. | High temperature ceramic filter |
| CN101288815A (en) * | 2007-04-16 | 2008-10-22 | 黄瑞中 | High precision high flow rate micropore ceramic tube |
| CN202173845U (en) * | 2011-08-11 | 2012-03-28 | 王建伟 | Ceramic filter material for removing iron in steam condensate water at high temperature |
| CN102964124A (en) * | 2011-01-07 | 2013-03-13 | 宜兴市鑫帝豪高科陶瓷厂 | High-temperature gas-solid ceramic filter tube and preparation method |
-
2017
- 2017-02-08 CN CN201710069383.1A patent/CN106731240B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1155723A2 (en) * | 2000-05-18 | 2001-11-21 | Fleetguard, Inc. | High temperature ceramic filter |
| CN101288815A (en) * | 2007-04-16 | 2008-10-22 | 黄瑞中 | High precision high flow rate micropore ceramic tube |
| CN102964124A (en) * | 2011-01-07 | 2013-03-13 | 宜兴市鑫帝豪高科陶瓷厂 | High-temperature gas-solid ceramic filter tube and preparation method |
| CN202173845U (en) * | 2011-08-11 | 2012-03-28 | 王建伟 | Ceramic filter material for removing iron in steam condensate water at high temperature |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109224629A (en) * | 2018-09-17 | 2019-01-18 | 江苏光天耐材科技有限公司 | A kind of filter of dry process and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106731240B (en) | 2018-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2533309B2 (en) | High surface area and high compressive strength activated carbon-carbon composite | |
| CN108043243B (en) | Performance regulation and control method of carbon membrane for purifying oily wastewater | |
| CN106673698B (en) | A kind of ceramic particle for adsorbing waste water impurities | |
| CN106747431B (en) | Graphene-ceramic composite powder and preparation method thereof | |
| CN107008152B (en) | A kind of attapulgite-graphite-like carbon nitride composite ceramic microfiltration membrane with photocatalytic performance and preparation method and application thereof | |
| CN107324828B (en) | SiCf/SiC ceramic matrix composite filter tube and preparation method thereof | |
| CN107619296A (en) | A kind of preparation method of the full silicon carbide filter film of dish-style | |
| RU2010132870A (en) | FIRE-RESISTANT CONTAINING ZIRCONIUM AND CARBON DIOXIDE AND METHOD FOR ITS MANUFACTURE | |
| CN112028608B (en) | A kind of ceramic filter membrane prepared by using red mud and preparation method thereof | |
| CN107216134B (en) | High-temperature ceramic fiber membrane micro-filter tube | |
| CN103831085A (en) | A kind of wear-resisting adsorption good composite ceramic filter element and preparation method thereof | |
| CN103830967B (en) | A medical stone composite ceramic filter element rich in trace elements | |
| CN106478069A (en) | Bamboo charcoal bentonite composite ceramic material and preparation method thereof | |
| CN108585883A (en) | Micro-filtration ceramic membrane and preparation method thereof | |
| CN100515536C (en) | A kind of preparation technology of lipophilic porous ceramic filter material | |
| CN101328060A (en) | A preparation method of diatomite-based multifunctional microporous ceramics | |
| CN106731240A (en) | A kind of ceramic base effluent filter | |
| CN108479420A (en) | Microfiltration ceramic membrane and preparation method thereof | |
| WO2022142168A1 (en) | Low-melting-point porous ceramic material and preparation method therefor | |
| CN101204637B (en) | Porous ceramics Screen plate resisting low concentration hydrofluoric acid and preparation method thereof | |
| CN103830965A (en) | Palm fiber toughened composite ceramic filter element and preparation method thereof | |
| CN106495733A (en) | Bamboo charcoal composite diatomite ceramic material and preparation method thereof | |
| CN101530701A (en) | Preparation method for silicon carbide candled filter | |
| CN111841485B (en) | A kind of preparation method of carbonized modified red clay ceramsite adsorbent and its regeneration method and application | |
| CN115215672A (en) | Preparation method of mullite whisker-based ceramic fiber membrane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220610 Address after: 230000 Woye Garden Commercial Building B-1017, 81 Ganquan Road, Shushan District, Hefei City, Anhui Province Patentee after: HEFEI JINGLONG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Address before: 214206 No. 99, Jingyi South Road, Wuxi City, Jiangsu Province Patentee before: WUXI INSTITUTE OF ARTS AND TECHNOLOGY |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221230 Address after: 163000 Guangming South Street 23-2, Guangming Industrial Park, Longfeng District, Daqing City, Heilongjiang Province Patentee after: DAQING HUAYU PETROLEUM MACHINERY MANUFACTURING Co.,Ltd. Address before: 230000 Woye Garden Commercial Building B-1017, 81 Ganquan Road, Shushan District, Hefei City, Anhui Province Patentee before: HEFEI JINGLONG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right |