CN106727050A - A kind of massage cream of Adsorption of Heavy Metals - Google Patents
A kind of massage cream of Adsorption of Heavy Metals Download PDFInfo
- Publication number
- CN106727050A CN106727050A CN201710098184.3A CN201710098184A CN106727050A CN 106727050 A CN106727050 A CN 106727050A CN 201710098184 A CN201710098184 A CN 201710098184A CN 106727050 A CN106727050 A CN 106727050A
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- Prior art keywords
- adsorption
- heavy metals
- massage cream
- skin
- nmf
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- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
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Abstract
The present invention relates to a kind of massage cream of Adsorption of Heavy Metals, mainly including following mass percent component：Ag/ graphene composite materials：0.5 4%, be modified orange peel biological adsorption agent：1 10%, NMF：7.1 21.5%, natural plant grease：1.1 4.5%, emollients：2 4%, animal fat：0.5 3%, emulsifying agent：1.1 5%, thickener：0.1 0.5%.The Ag/ graphene composite materials and modified orange peel biological adsorption agent that the present invention contains can adsorb skin surface dirt and heavy metal ion, promote skin blood circulation and metabolism, NMF and plant extracts is promoted to be permeated in skin, dirt and toxin to fine hair hole do deep layer cleaning, absorption excess oil and aging cutin, prevent the aging of skin and relax, long-term use can slow down because of symptoms such as the spots allergic, long that heavy metal poisoning causes.
Description
Technical field
The present invention relates to cosmetic field, a kind of massage cream of Adsorption of Heavy Metals is specifically related to.
Background technology
China State of Air pollution is extremely serious.If the dust suspended material carried in air pollution does not note clearly
It is clean, pore may be slowly collected in, cause clogging of pores and acne to occur.After atmosphere pollution, printing opacity degree meeting in air
Reduce, the ultraviolet of Near Ground is weakened, and various viruses in near-earth air, bacterium and fungi become to be not easy to be killed by ultraviolet
Extremely, various viruses are easily caused, bacterium, fungi reaches skin with the dust granules of air, and adheres to skin surface, causes
The infection of skin.Substantial amounts of experimental result and epidemiologic data confirm that PM2.5 toxicity in every respect is better than PM10.
Heavy metal element Pb, Zn, Cr, Ti, Cu, V, As and Mn etc. produce harm to health in grain thing.There is research to think about
75%~90% heavy metal distribution is in PM10, and particle is smaller, and content of beary metal is higher.
Nickel poisoning is mainly the dust of suction nickel and its esters, causes respiratory system irritation and skin lesion.It is chronic
Poisoning is that chronic skin contact has allergic dermatitis.
In chromium production of articles environment, workman is not in place due to safeguard procedures, easily causes the slow poisoning of chromium, shows as
Skin ulcer, can cause to fester and formed chrome ulcer or nasal septum infringement and be difficult to cure when serious.
Media frequently report some because of the cosmetics of the whitening spot-removing using mercury content severe overweight, and in causing mercury
Poison.After testing, exceeded 60,000 times unexpectedly of some Mercury In Cosmetics contents.Through rough estimate, the mercury poisoning victim accepted for medical treatment in ward works as
In, can account for more than eighty per cant by ratio caused by cosmetics.
What T.S.Sreeprasad et al. was delivered《Reduced graphene oxide–metal/metal oxide
composites:Facile synthesis and application in waterpurification》Prepared in paper
Graphene-Ag composites are tested and show the Graphene-Ag composites in an absorption huge sum of money as the model of absorption pollutant Hg
Possesses excellent effect on category Hg.
What Feng Ning rivers et al. were delivered《The absorption of the modified orange peel biological adsorption agent heavy metal ion of saponification》In with biology
Material orange peel is raw material, through ethanol, naoh treatment, has obtained modified orange peel biological adsorption agent, uses it for ion
Cu2+、Pb2+、Cd2+、Zn2+And Ni2+Absorption.
Chinese patent application 105287248A, discloses a kind of graphene oxide facial mask and preparation method thereof.The invention is first
It is secondary that Graphene is applied in facial mask, and elaborate that Graphene kills acarid and deep layer removes the effect of acarid, but not
Further investigate the derivative effect of graphene composite material.
The content of the invention
It is an object of the invention to provide a kind of massage cream of Adsorption of Heavy Metals, from Ag/ graphene composite materials and change
Property orange peel biological adsorption agent absorption skin surface dirt and heavy metal ion, promote skin blood circulation and metabolism, promote
Enter NMF and plant extracts to be permeated in skin, the dirt and toxin to fine hair hole do deep layer cleaning, absorption excess oil
And aging cutin, preventing the aging of skin and relax, long-term use can slow down because of the spot allergic, long that heavy metal poisoning causes
Etc. symptom.
To achieve the above object, the present invention is adopted the following technical scheme that：
A kind of massage cream of Adsorption of Heavy Metals, including following mass percent component：Ag/ graphene composite materials：1-
4%th, be modified orange peel biological adsorption agent：1-10%, NMF：7.1-21.5%, natural plant grease：It is 1.1-4.5%, soft and moist
Agent：2-4%, animal fat：0.5-3%, emulsifying agent：1.1-5%, thickener：0.1-0.5%.
Preferably, in a preferred embodiment of the invention, a kind of massage cream of described Adsorption of Heavy Metals also includes
Following mass percent component：Ag/ graphene composite materials：2-3%, modified orange peel biological adsorption agent：3-7%, NMF：
10-18%, natural plant grease：2-3.5%, emollients：2.5-3.5%, animal fat：1-2.5%, emulsifying agent：2-4%,
Thickener：0.2-0.4%.
Preferably, in a preferred embodiment of the invention, the NMF is glycerine, butanediol and Sodium Hyaluronate
Mixture.Aqueous solution of sodium hyaluronate is a kind of non-Newtonian fluid, there is good viscoplasticity and rheology shape.Based on transparent
The special performance of matter acid sodium, it can be widely used in the middle of medicine, cosmetics and health food.
Preferably, in a preferred embodiment of the invention, the natural plant grease is Butyrospermum parkii fruit fat and Australia
The mixture of continent nut seed oil.Butyrospermum parkii fruit fat is abundant moisturizing agent, is easily absorbed；Rich in unrighted acid, can strengthen
The moisture-retaining capacity of skin, can be moistened to dryness and the impaired skin of cutin, relative to other plant oil, contain highest rate
Fatty accompaniment, particularly grows triterpene alcohol and vitamin E, vitamin A, allantoin of necessary nutrient etc., nutritious；
Be prevented from skin water loss, help healing of wound, increase skin defence capability and compliance, be rare skin care it is natural into
Point.Queensland nut seed oil is rich in mineral matter, protein, multiple unrighted acid；Be adapted to all skins, can reconcile it is aging or
Dry skin, makes skin emolliency, controls treatment trauma, can be used to help the skin for treating sunburn；Grease protection is formed containing skin
Nutrient essential to layer, it is most important that oiliness is gentle, does not stimulate skin；Moisturiser can be made, is made skin soft and is had work
Power, protection cell membrane and moist, moisturizing.
Preferably, in a preferred embodiment of the invention, the emollients are ethylhexyl palmitate.Palm
Sour Octyl Nitrite is widely used in skin care item and cosmetics, is excellent skin emollient, stable in properties, not oxidizable or generation
Peculiar smell.Skin can be made soft soft and without greasy sensation, good penetrability, and can as in lipstick, mascara pigment it is good
Solvent, is usually used in the formula of face cream, vanishing cream, hair oil, eye shadow, lipstick, mascara etc..
Preferably, in a preferred embodiment of the invention, the animal fat is saualane.Saualane is rare
Chemical stability is high, the splendid animal fat of use feeling, there is preferable compatibility to skin, will not cause allergy and stimulation, and
Other active components are permeated in skin during formula can be accelerated；With relatively low polarity and medium spreadability, and pure, nothing
Color, free from extraneous odour, may also suppress the growth of mould, assign that product is fabulous and the feel of noble quality, feel very abundant after, moisten without
It is greasy.
Preferably, in a preferred embodiment of the invention, the emulsifying agent be methyl sesquistearate and
The mixture of polyacrylamide/C13-14 isoparaffins/laureth -7.Glucate SS has excellent
Emulsification, dispersion, solubilising power, and the compatibility of skin is good.Polyacrylamide/C13-14 isoparaffins/laureth -7
With extremely strong gelling ability, remarkable emulsification function, outstanding stabilization, extremely simple application method；It is a kind of normal
The lower new material that can produce creams of temperature, thickening, gel, emulsification, stabilization and absorption that it plays the role of superior performance can breasts
Change various oil phases, the various formulas of thick stabilization have good intermiscibility, assign product brightness and salubrious smooth feel, be applicable
In all kinds of skin care item.
Preferably, in a preferred embodiment of the invention, the thickener is xanthans.Xanthans is passed through by carbohydrate
Xanthomonas campestris sends out liquor-saturated, many pools of extracellular microorganism of generation.Due to its macromolecular special construction and colloid property, and have many
Function is planted, national economy can be widely used in each as emulsifying agent, stabilizer, gelling thickener, size, film forming agent etc.
Field.
Since Graphene was found from 2004, due to its unique structure and performance, it has been set to rapidly become international green wood
Expect the focus of area research.Graphene is the carbon atom by monoatomic layer by sp2The two-dimensional atomic crystal that hydridization is formed.It is this
Special construction has contained the abundant and physical phenomenon of novelty, Graphene is shown many excellent properties.For example, Graphene
Intensity is highest in known materials, is more than 100 times of steel up to 130GPa；Its theoretical specific surface area is up to 2630m2/g。
The mechanism of sorbing material Adsorption of Heavy Metals ion typically has 3：Electrostatic interaction, ion exchange and complexing.When
When solution ph is relatively low, H in solution+Concentration is higher, and now surface of graphene oxide oxy radical is difficult to dissociate H+, at this moment stone
The absorption of black alkene composite heavy metal cation realizes that is, heavy metal cation exchanges oxidation stone mainly by ion exchange
The proton of institute's band in black alkene Surface oxygen-containing groups.Because the absorption of metal cation in ion exchange process will face the competing of proton
Strive, therefore the adsorbance is not often high；When solution ph is higher, OH in solution-Concentration is higher, now due to graphene oxide table
Proton in the oxy radical of face is neutralized and makes material surface negatively charged, and such as-COOH is changed into-COO-, at this moment can be drawn with electrostatic
Power Adsorption of Heavy Metals ion, while also complex compound can be formed with complex.At this moment adsorbance is often higher.
A kind of application method of the massage cream of Adsorption of Heavy Metals of the invention is：The uniform point minute of appropriate massage cream is taken in face
Portion, both hands carry out regular massage in the way of looping, and can also be aided with steam spray face 5-10 minutes, after massaging 20-30 minutes,
Cleaned with clear water.In massage, overexertion is careful not to, in order to avoid cause the uncomfortable easily phenomenon such as rubefaction, heating.
Beneficial effects of the present invention：Compared with prior art, a kind of massage cream of Adsorption of Heavy Metals of the invention has such as
Lower advantage：Ag/ graphene composite materials and modified orange peel biological adsorption agent are strengthened to skin surface dirt by scientific matching
With the absorption of heavy metal ion, promote skin blood circulation and metabolism, promote NMF and plant extracts in skin
Infiltration, dirt and toxin to fine hair hole do deep layer cleaning, absorption excess oil and aging cutin.Additionally, can also prevent skin
Aging and lax, long-term use can slow down because of symptoms such as the spots allergic, long that heavy metal poisoning causes.
Brief description of the drawings
Fig. 1 is the comparison diagram of embodiment 2 and massage cream sample adsorption Hg (II) of comparative example 1,2,3,4,5.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
The following component title occurred in text is INCI (Internation Nomenclaure Cosmetic
Ingredent, i.e. international cosmetic raw material name) institute to regulation title：Vinyldimethicone/methyl polysilicone
Alkane silsesquioxane cross-linked polymer, stearine/PEG-100 stearates, the different alkanes of polyacrylamide/C13-14
Hydrocarbon/laureth -7, propane diols/Bis(hydroxymethyl)imidazolidinyl urea/iodine propilolic alcohol butyl mephenesin Carbamate.
Embodiment 1~5
A kind of 5 specific embodiments of the massage cream of Adsorption of Heavy Metals of the present invention are listed in table 1.
Table 1
A kind of 5 specific comparative examples of the massage cream of Adsorption of Heavy Metals of the present invention are listed in table 2.
Table 2
By adding Hg (II) sample of embodiment 2 and comparative example 1,2,3,4,5 with conventional method detection, (concentration is 1mg/
L content), as a result as shown in figure.
From figure 1 it appears that embodiment 2 has the spy of obvious absorption Hg (II) compared to comparative example 1,2,3,4,5
Property, and effect is significant.Show Ag/ graphene composite materials and modified orange peel biological adsorption agent by scientific matching, it is right to strengthen
The absorption of skin surface dirt and heavy metal ion, the i.e. effect with Synergistic.
Evaluation test on probation
For the massage cream for preferably proving a kind of Adsorption of Heavy Metals provided by the present invention has excellent effect, choose real
Applying example 1,2,3,4,5 and comparative example 1,2,3,4,5 carries out further investigation on probation and evaluation test.Embodiment is as follows：Choosing
Take 50 special volunteers, the wherein people of male 25, the people of women 25.Evaluation test is carried out to embodiment and comparative example, each sample
Trial period is one month, and it is heavy metal poisoning rear face allergy, spot crowd long to try out object.Table 3 is test index and result.
Table 3
Result shows：
It is visible for heavy metal poisoning rear face allergy, spot crowd long, long-term use one kind of the present invention by table three
The massage cream of Adsorption of Heavy Metals, the effect for improving significantly and alleviating.And embodiment 2 have it is best be obviously improved it is gentle
The effect of solution.Result shows that Ag/ graphene composite materials and modified orange peel biological adsorption agent, by scientific matching, strengthen to skin
The absorption of skin surface contaminants and heavy metal ion, the i.e. effect with Synergistic.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art in the technical scope of present disclosure, the change or replacement that can be readily occurred in,
Should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims
Scope is defined.
Claims (8)
1. a kind of massage cream of Adsorption of Heavy Metals, it is characterised in that including following mass percent component：Ag/ Graphenes are combined
Material：1-4%, modified orange peel biological adsorption agent：1-10%, NMF：7.1-21.5%, natural plant grease：1.1-
4.5%th, emollients：2-4%, animal fat：0.5-3%, emulsifying agent：1.1-5%, thickener：0.1-0.5%.
2. the massage cream of a kind of Adsorption of Heavy Metals according to claim 1, it is characterised in that including following mass percent
Component：Ag/ graphene composite materials：2-3%, modified orange peel biological adsorption agent：3-7%, NMF：10-18%, natural plant
Thing grease：2-3.5%, emollients：2.5-3.5%, animal fat：1-2.5%, emulsifying agent：2-4%, thickener：0.2-
0.4%.
3. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the NMF be glycerine,
The mixture of butanediol and Sodium Hyaluronate.
4. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the natural plant grease is
The mixture of Butyrospermum parkii fruit fat and Queensland nut seed oil.
5. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the emollients are palmitic acid
Octyl Nitrite.
6. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the animal fat is spiny dogfish
Alkane.
7. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the emulsifying agent is methyl Portugal
The mixture of sugared sesquistearate and polyacrylamide/C13-14 isoparaffins/laureth -7.
8. the massage cream of a kind of Adsorption of Heavy Metals according to claim 2, it is characterised in that the thickener is xanthan
Glue.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107412078A (en) * | 2017-09-05 | 2017-12-01 | 广州聚注通用技术研究院有限公司 | A kind of facial mask for adsorbing heavy metal |
Citations (2)
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|---|---|---|---|---|
| CN103405379A (en) * | 2013-07-29 | 2013-11-27 | 广州丹奇日用化工厂有限公司 | Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product |
| CN105963211A (en) * | 2016-07-02 | 2016-09-28 | 广东万海细胞生物科技有限公司 | Deep nursing mask cream and preparation method thereof |
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| CN103405379A (en) * | 2013-07-29 | 2013-11-27 | 广州丹奇日用化工厂有限公司 | Cosmetic composition rich in amino acids and application of cosmetic composition in skin care product |
| CN105963211A (en) * | 2016-07-02 | 2016-09-28 | 广东万海细胞生物科技有限公司 | Deep nursing mask cream and preparation method thereof |
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| CN107412078A (en) * | 2017-09-05 | 2017-12-01 | 广州聚注通用技术研究院有限公司 | A kind of facial mask for adsorbing heavy metal |
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