CN106719734A - A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam - Google Patents
A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam Download PDFInfo
- Publication number
- CN106719734A CN106719734A CN201710083270.7A CN201710083270A CN106719734A CN 106719734 A CN106719734 A CN 106719734A CN 201710083270 A CN201710083270 A CN 201710083270A CN 106719734 A CN106719734 A CN 106719734A
- Authority
- CN
- China
- Prior art keywords
- penoxsuam
- humulone
- herbicide
- preventive effect
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 26
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 title claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000005864 Sulphur Substances 0.000 title claims abstract description 12
- 150000002240 furans Chemical class 0.000 title claims abstract description 12
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 title claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 54
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- BXIGJZDQFDFASM-UHFFFAOYSA-N cyclopyrimorate Chemical compound N=1N=C(Cl)C=C(OC(=O)N2CCOCC2)C=1OC=1C(C)=CC=CC=1C1CC1 BXIGJZDQFDFASM-UHFFFAOYSA-N 0.000 claims abstract description 7
- ACDZDIIWZVQMIX-UHFFFAOYSA-N fenoxasulfone Chemical compound C1=C(Cl)C(OCC)=CC(Cl)=C1CS(=O)(=O)C1=NOC(C)(C)C1 ACDZDIIWZVQMIX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003090 pesticide formulation Substances 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 11
- 230000000361 pesticidal effect Effects 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 33
- 239000004009 herbicide Substances 0.000 description 27
- 230000003449 preventive effect Effects 0.000 description 27
- 230000000694 effects Effects 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- 239000003814 drug Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 241001272567 Hominoidea Species 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000003337 fertilizer Substances 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000004562 water dispersible granule Substances 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- UFAPVJDEYHLLBG-UHFFFAOYSA-N 2-{2-chloro-4-(methylsulfonyl)-3-[(tetrahydrofuran-2-ylmethoxy)methyl]benzoyl}cyclohexane-1,3-dione Chemical compound ClC1=C(COCC2OCCC2)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O UFAPVJDEYHLLBG-UHFFFAOYSA-N 0.000 description 2
- 241000234653 Cyperus Species 0.000 description 2
- 244000058871 Echinochloa crus-galli Species 0.000 description 2
- 241000801118 Lepidium Species 0.000 description 2
- 241000169076 Monochoria korsakowii Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 244000292697 Polygonum aviculare Species 0.000 description 2
- 235000006386 Polygonum aviculare Nutrition 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- -1 penoxsulam amine Chemical class 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- ZWDFMOMBVDVEHE-UHFFFAOYSA-N 1,2-dicyclohexylethane-1,2-dione Chemical compound C1CCCCC1C(=O)C(=O)C1CCCCC1 ZWDFMOMBVDVEHE-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 241001290610 Abildgaardia Species 0.000 description 1
- 244000233890 Alisma plantago Species 0.000 description 1
- 235000017300 Alisma plantago Nutrition 0.000 description 1
- 241000143476 Bidens Species 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 241000202296 Delphinium Species 0.000 description 1
- 102000016680 Dioxygenases Human genes 0.000 description 1
- 108010028143 Dioxygenases Proteins 0.000 description 1
- 241000192043 Echinochloa Species 0.000 description 1
- 244000286838 Eclipta prostrata Species 0.000 description 1
- 241000202829 Eleocharis Species 0.000 description 1
- 241001290564 Fimbristylis Species 0.000 description 1
- 241000959048 Gratiola Species 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000721671 Ludwigia Species 0.000 description 1
- 241000169139 Monochoria Species 0.000 description 1
- 235000003990 Monochoria hastata Nutrition 0.000 description 1
- 241000212324 Oenanthe <angiosperm> Species 0.000 description 1
- 241000209117 Panicum Species 0.000 description 1
- 235000006443 Panicum miliaceum subsp. miliaceum Nutrition 0.000 description 1
- 235000009037 Panicum miliaceum subsp. ruderale Nutrition 0.000 description 1
- 239000005592 Penoxsulam Substances 0.000 description 1
- 241000722195 Potamogeton Species 0.000 description 1
- 241000218206 Ranunculus Species 0.000 description 1
- 240000009132 Sagittaria sagittifolia Species 0.000 description 1
- 241000202758 Scirpus Species 0.000 description 1
- 235000005775 Setaria Nutrition 0.000 description 1
- 241000232088 Setaria <nematode> Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 244000273618 Sphenoclea zeylanica Species 0.000 description 1
- 235000017967 Sphenoclea zeylanica Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- 241000255632 Tabanus atratus Species 0.000 description 1
- 244000010375 Talinum crassifolium Species 0.000 description 1
- 235000015055 Talinum crassifolium Nutrition 0.000 description 1
- 241000719329 Trentepohlia Species 0.000 description 1
- 241001573053 Vandellia Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- QBGLSLJCCRQTCW-UHFFFAOYSA-L disodium;4-octoxy-4-oxo-3-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCOC(=O)C(S([O-])(=O)=O)CC([O-])=O QBGLSLJCCRQTCW-UHFFFAOYSA-L 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 244000037671 genetically modified crops Species 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- RNQBLUNNAYFBIW-NPULLEENSA-M hexadecyl(trimethyl)azanium (2S)-2-(6-methoxynaphthalen-2-yl)propanoate Chemical compound COc1ccc2cc(ccc2c1)[C@H](C)C([O-])=O.CCCCCCCCCCCCCCCC[N+](C)(C)C RNQBLUNNAYFBIW-NPULLEENSA-M 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of humulone of sulphur containing furans and the synergistic herbicidal compositions of penoxsuam, it is characterized in that including active components A and B, wherein, A is furans sulphur humulone and penoxsuam, B is one or more combinations in fenoxasulfone, cyclopyrimorate, also include the auxiliary agent that can be used in Pesticide formulation, be made conventional pesticidal preparations, and be applied to prevent and treat unwanted plant.
Description
Technical field
The invention belongs to pesticides application technical field, it is related to a kind of composition pesticide, specifically a kind of sulphur containing furans
The Herbicidal combinations of humulone and penoxsuam, are applied to prevent and kill off unwanted plant.
Background technology
In agricultural production process, it is not necessary to plant (weeds) there is serious, the target crop such as damage to crops, forest life
It is long, and influence undesirable vegetation plot (such as bare place, railway, highway, forest fire protection road, industrial sites, threshing ground) is just
Often use.Herbicide is to prevent and kill off the most economic, the quick and effective method for not needing plant.
Single herbicide is composed limited using easily developing immunity to drugs or prevent and treat, can not solve well in produce reality not
Need the harm of plant.Mixture herbicide has can expand preventing and treating spectrum, enhancing preventive effect, delay the advantages such as herbicide resistance, in life
Producing turns into most popular application form in putting into practice.Especially have between the herbicide of synergy, each active principle of herbicide
Interact, make combination aging fruit better than the theoretical summation of exclusive use effect, thus the work(of thing half can be played when actually used
Effect again, is more welcome by user.
Furans sulphur humulone (tefuryltrione) is the cyclohexyl diketone herbicide of Beyer Co., Ltd's exploitation.Belong to p- hydroxyl third
Ketone acid dioxygenase (HPPD) inhibitor.It is mainly used in paddy rice, corn field, before seedling after seedling is used, and is prevented and kill off annual and perennial
Broad leaved weed, nutgrass flatsedge and part grassy weed, the Weed-control effect to sulfonylurea herbicide tool resistance are notable.CAS accession number
It is 473278-76-1.Its structural formula See Figure：
Penoxsuam, fenoxasulfone, cyclopyrimorate are the broad spectrum activities developed by transnational agricultural chemicals enterprise
Herbicide.
The present invention is studied by substantial amounts of formulation screening test and found, when furans sulphur humulone and penoxsulam amine composition with
When one or more medicaments in fenoxasulfone, cyclopyrimorate are combined, show astonishing
Herbicidal effect, that is, show good synergy, actual herbicidal effect is substantially better than the theoretical summation of exclusive use, in life
There is application prospect widely on product.
The content of the invention
The present invention relates to synergistic herbicidal compositions, including active components A and B, described active components A is furans sulphur humulone
And penoxsuam, described active component B is one or more in fenoxasulfone, cyclopyrimorate
Combination.Additionally, also including the auxiliary agent that can be used in Pesticide formulation.
The composition can be especially good effect be used to prevent and treat weeds in various useful crops, the useful crop
Including but not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domesticating and cultivating it is wild
Plant etc., is particularly well-suited to prevent and kill off the weeds in rice terrace, or for bare place, railway, highway, forest fire protection road, industrial field
Weeds in the undesirable vegetation growth plot such as ground, threshing ground.
The instantiation that can be mentioned that is representative grassy weed and the broad-leaved of some available composition for preventing and controlling of the invention
Weeds, the example is not limited to specified genus kind.It should be noted that the invention is not limited in example in detail below, can be with
Other unwanted plants are extended in the same manner：
The broad leaved weed of following category：Monochoria, Sagittaria, Waterplantain, water leaf spp, Trentepohlia, Potamogeton, knotweed
Category, Han Lepidium, section section Lepidium, Vandellia, Bidens, sphenoclea, horsefly eye grass category, Eclipta prostrata category, delphinium category, gratiola
Category, ludwigia, Oenanthe, Ranunculus, damp chilly category；The grassy weed of following category：Echinochloa, Panicum, Poa L., arm
Shape grass category, knotgrass, setaria；The sedge weed of following category：Cyperus, Eleocharis, Scirpus, genus fimbristylis.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that and is achieved：
The present composition component A and B can be with arbitrary proportion mixtures, and a kind of usual active component content is higher than rest activity
Composition, preferably mixing ratio are 100：1 to 1：100 or 50：1 to 1：50.
The present composition can mix by by active component with the auxiliary agent that can be used in Pesticide formulation, with known
Method is prepared as conventional preparation, such as missible oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, granule
Deng.The active component of 0.1~95% weight, the preferably active component of 0.5~90% weight are typically contained in preparation.
The auxiliary agent that can be used in Pesticide formulation is included but is not limited to：Water, solvent, filler, various surfactants
(emulsifying agent, dispersant, wetting agent etc.), adhesive, film forming agent, colouring agent, antifreezing agent, thickener, suspending agent, disintegrant, disappear
Infusion, bleeding agent, synergist, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to improve to spy
Ordered goods tolerance, can be properly added safener；Or sometimes for crop growth is promoted, can add in mixture composition
Plus conventional agriculture fertilizer, it is made medicament-fertilizer mixture.These auxiliary agents are all to commonly use in pesticidal preparations or allow the composition for using, and have no spy
Do not limit, one or more auxiliary agents may be selected and constitutes, specific composition and consumption are tested according to recipe requirements by simple
It is determined that.
The production technology of the various application forms of composition belongs to existing known technology, will not be repeated here.
The present composition can be used in a variety of ways, be such as watered spraying in a usual manner and used, or directly spread fertilizer over the fields or ditch
Apply, or mix pesticide-clay mixture and spread fertilizer over the fields, be can be used in early days in before weeds emerge or after emerging.Dosage can change in relative broad range,
And depending on the situation of soil, application method, crop, weeds species to be prevented and kill off and seedling age size, weather conditions at that time
And other factors.The present composition is generally applied with the consumption of 0.001~1.5kg mixture of active principles/hectare, more excellent
Selection of land, is applied with the consumption of 0.02~0.5kg mixture of active principles/hectare.
The present invention compared with prior art, has the following technical effect that：
1st, mixture composition has good synergy, and application effect is substantially better than single dose theoretical effect summation, that is, has
There is super superposition, dominant weed occurrence injury can be better controled over；
2nd, there is good complementarity in control of weeds spectrum between mixture composition active component, can very well expands preventing and treating
Spectrum, it is comprehensive effectively to control various weeds occurrence injuries；
3rd, mixture composition has good synergy, can reduce medicament usage amount, reduces use cost and environment is dirty
Dye, improves the security to crop.
Specific embodiment
Specific embodiment of the invention given below is, it is necessary to explanation is the invention is not limited in implementing in detail below
Example, all equivalents done on the basis of technical scheme each fall within protection scope of the present invention.
Embodiment 1：25% missible oil
Being formulated composition is：Active components A is 20%, and active component B is 5%, emulsifying agent APES 3%,
Emulsifying agent castor oil polyoxyethylene ether 4%, emulsifying agent calcium dodecyl benzene sulfonate 3%, solvent xylene complements to 100%.
Preparation method is：By in all materials input batching kettle, stirring and dissolving after chemical examination is qualified, is shifted to fully transparent
It is filling to storage tank.
Embodiment 2：34% suspending agent
Being formulated composition is：Active components A is 25%, and active component B is 9%, wetting agent sulfosuccinic acid monooctyl ester sodium salt
5%, dispersant lignosulfonates 4%, antifreeze glycol 5%, thickener xanthans 0.2%, water complements to 100%.
Preparation method is：By in active component and wetting agent, dispersant, antifreezing agent and water input stirred tank, it is sufficiently stirred for
Afterwards, material is pumped into sand mill and is fully ground, after the completion of grinding, be pumped into high-speed shearing machine, after adding thickener, entered
Row high speed shear, is obtained suspending agent after the completion of shearing.
Embodiment 3：58% water dispersible granules
Being formulated composition is：Active components A is 46%, and active component B is 12%, wetting agent APES formaldehyde
Condensate sulfate 3%, the phenethyl phenol polyoxyethylene ether phosphate 6% of dispersant three, disintegrant sodium carbonate 2%, adhesive carboxylic
Methylcellulose 0.8%, filler diatomite complements to 100%.
Preparation method is：After all materials are well mixed, crushed through airslide disintegrating mill, be well mixed again, then, plus
Enter a certain amount of water to mediate this mixture, extruder grain is sieved through drying, that is, obtain water dispersible granules.
Embodiment 4：18% aqueous emulsion
Being formulated composition is：Active components A is 10%, and active component B is 8%, solvent xylene 10%, emulsifying agent maleic
Diacid di-sec-octyl sodium sulfonate 5%, emulsifier sodium lauryl sulfate 4%, antifreezing agent propane diols 3%, water complements to 100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent forms oil after being sufficiently stirred for
Phase；Antifreezing agent is added to the water dissolving, water phase is formed；Water is mutually slowly added in oil phase, is sheared using high-speed shearing machine, you can
Obtain aqueous emulsion.
Embodiment 5：26% microemulsion
Being formulated composition is：Active components A is 18%, and active component B is 8%, solvent xylene 6%, solvent cyclohexanone
3%, emulsifying agent castor oil polyoxyethylene ether 9%, emulsifying agent alkylphenol-polyethenoxy phosphate 6%, antifreeze glycol 4%,
Water complements to 100%.
Preparation method is：After active components A and B solvents are fully dissolved, input emulsifying agent and antifreezing agent are well mixed,
Deionized water is eventually adding, high speed shear is carried out, you can microemulsion is obtained.
Embodiment 6：45% wettable powder
Being formulated composition is：Active components A is 30%, and active component B is 15%, wetting agent APES 5%,
Dispersant APES formaldehyde condensation product sulfonate 4%, filler white carbon supply to 100%.
Preparation method is：Active component and each auxiliary agent are well mixed, just smashing is carried out in the mechanical disintegrating machine of input, afterwards
Crushed through airslide disintegrating mill, remix uniform, i.e., prepared wettable powder.
Embodiment 7：7% granule
Being formulated composition is：Active components A is 4%, and active component B is 3%, wetting agent dialkyl succinylsuccinate sulfonate 0.6%,
Dispersant calcium lignosulfonate 1.0%, colouring agent Viride Nitens (peacock green) 0.3%, filler diatomite complements to 100%.
Preparation method is：After all materials are well mixed, a certain amount of water is added to mediate this mixture, extruding is made
Grain, sieves through drying, that is, obtain granule.
Application effect example：
1st, test method
Reference《NY/T 1155.3-2006 farm-chemical indoor determination test rule herbicide third portions：Determination of activity is tried
Test soil spray-on process》Carry out.
Experiment is carried out under being located at greenhouse experiment.Grassy weed and broad leaved weed respectively select a kind of representative weeds, grass
Section weeds choose barnyard grass, and broad leaved weed chooses Monochoria korsakowii, and from field, collection weed seed is standby.
Experiment soil is quantitatively filled at the 4/5 of basin alms bowl.By the barnyard grass of pretreatment, Monochoria korsakowii seed, uniformly point is sowed at diameter
It is the round plastic nutritive cube surface of 30cm, 30~40 is broadcast per basin, earthing 1.0cm, with the bottom infiltrating irrigation mode moisturizing of basin alms bowl, makes
Soil is moistened to saturation state completely.The liquid that will be prepared after sowing 24h carries out soil spraying.Move into controllable heliogreenhouse
Culture.Often treatment sets 4 repetitions, 5 basins is repeated every time, with without chemicals treatment as blank.
21d after chemicals treatment, using absolute value (number is surveyed) investigation method investigation records activity of weeding, weighs each treatment weeds ground
Upper part fresh weight, calculates actual preventive effect, and (be directed to ternary according to Gowing methods (being directed to binary mixture herbicide) or Colby methods
Mixture herbicide) evaluate synergy.Referring to COLBY, S.R.：" calculating collaboration and the Antagonistic reaction of combinations of herbicides ", Weeds
15, p.20~22,1967：
According to survey data, the actual preventive effect of each treatment is calculated by formula (1), unit is percentage (%), result of calculation
Retain 2 significant digits.
In formula：
E-actual preventive effect；
C-control weeds aerial part fresh weight；
T-treatment weeds aerial part fresh weight.
Gowing methods：Theoretical preventive effect (expected preventive effect) E of Mixed Pharmacy0(2) formula is calculated：
In formula：
Actual preventive effect when the consumption of X-herbicide 1 is P；
Actual preventive effect when the consumption of Y-herbicide 2 is Q；
Actual preventive effect after E-herbicide 1 is mixed according to the above ratio with herbicide 2；
E0The consumption of-herbicide 1 is the theoretical preventive effect when consumption of P+ herbicides 2 is Q, the i.e. expected preventive effect of mixture herbicide.
As E ＞ E0When, if that is, the actual preventive effect of Mixed Pharmacy exceedes the theoretical preventive effect (expected preventive effect) for being calculated, should
Combination just has super superposition, that is, act synergistically.
Colby methods：Theoretical preventive effect (expected preventive effect) E of Mixed Pharmacy0(3) formula is calculated：
In formula：
Actual preventive effect when the consumption of X-herbicide 1 is P；
Actual preventive effect when the consumption of Y-herbicide 2 is Q；
Actual preventive effect when the consumption of Z-herbicide 3 is R；
E0The consumption of-herbicide 1 is that the consumption of P+ herbicides 2 is the theoretical preventive effect when consumption of Q+ herbicides 3 is R, i.e. mixture is removed
The expected preventive effect of careless agent；
E-herbicide 1,2 and 3 presses actual preventive effect during different ratio mixture
As E ＞ E0When, if that is, the actual preventive effect of Mixed Pharmacy exceedes the theoretical preventive effect (expected preventive effect) for being calculated, should
Combination just has super superposition, that is, act synergistically.
2nd, result of the test
Result of the test refers to table 1~2, it is seen then that active components A (furans sulphur humulone and penoxsuam) with selected from activity into
After dividing the medicament mixture of B (fenoxasulfone, cyclopyrimorate), it is (expected anti-that actual preventive effect is all higher than theoretical preventive effect
Effect), illustrate that active components A has synergy with the medicament mixture in active component B.
The synergy effect of the furans sulphur humulone of table 1, penoxsuam and fenoxasulfone mixtures to weeds
The synergy effect of the furans sulphur humulone of table 2, penoxsuam and cyclopyrimorate mixtures to weeds
Claims (5)
1. a kind of herbicidal composition, it is characterised in that including active components A and B.
2. herbicidal composition as claimed in claim 1, it is characterised in that described active components A be furans sulphur humulone and
Penoxsuam.
3. herbicidal composition as claimed in claim 1, it is characterised in that described active component B is
One or more combinations in fenoxasulfone, cyclopyrimorate.
4. the herbicidal composition as described in claim 1,2 or 3, it is characterised in that in addition to active components A and B, also include
The auxiliary agent that can be used in Pesticide formulation.
5. the herbicidal composition as described in claim 1,2,3 or 4, it is characterised in that be applied to preventing and treating unwanted
Plant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710083270.7A CN106719734A (en) | 2017-02-16 | 2017-02-16 | A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710083270.7A CN106719734A (en) | 2017-02-16 | 2017-02-16 | A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106719734A true CN106719734A (en) | 2017-05-31 |
Family
ID=58958623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710083270.7A Pending CN106719734A (en) | 2017-02-16 | 2017-02-16 | A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106719734A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410313A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing cyhalofop-butyl |
| CN107410344A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing penoxsuam and orthosulfamuron |
| CN107410345A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing halosulfuronmethyl |
| CN107410320A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing pyribenzoxim |
| CN108576000A (en) * | 2018-06-05 | 2018-09-28 | 广东中迅农科股份有限公司 | Herbicidal combinations containing furans sulphur humulone and penoxsuam and sulfonylurea herbicide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005145958A (en) * | 2003-10-20 | 2005-06-09 | Kumiai Chem Ind Co Ltd | Herbicidal composition |
| JP2011006386A (en) * | 2009-05-29 | 2011-01-13 | Mitsui Chemicals Agro Inc | Herbicidal composition |
| JP2011190198A (en) * | 2010-03-12 | 2011-09-29 | Mitsui Chemicals Agro Inc | Mixed herbicidal composition |
-
2017
- 2017-02-16 CN CN201710083270.7A patent/CN106719734A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005145958A (en) * | 2003-10-20 | 2005-06-09 | Kumiai Chem Ind Co Ltd | Herbicidal composition |
| JP2011006386A (en) * | 2009-05-29 | 2011-01-13 | Mitsui Chemicals Agro Inc | Herbicidal composition |
| JP2011190198A (en) * | 2010-03-12 | 2011-09-29 | Mitsui Chemicals Agro Inc | Mixed herbicidal composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107410313A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing cyhalofop-butyl |
| CN107410344A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing penoxsuam and orthosulfamuron |
| CN107410345A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing halosulfuronmethyl |
| CN107410320A (en) * | 2017-06-09 | 2017-12-01 | 北京科发伟业农药技术中心 | A kind of Herbicidal combinations containing pyribenzoxim |
| CN108576000A (en) * | 2018-06-05 | 2018-09-28 | 广东中迅农科股份有限公司 | Herbicidal combinations containing furans sulphur humulone and penoxsuam and sulfonylurea herbicide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107372565A (en) | A kind of sulphur of ketone containing thiophene is grand and the Herbicidal combinations of pinoxaden | |
| CN106719734A (en) | A kind of Herbicidal combinations of the humulone of sulphur containing furans and penoxsuam | |
| CN106982845A (en) | A kind of Herbicidal combinations containing the Evil humulones of ring penta and three azole amides | |
| CN106993626A (en) | A kind of Herbicidal combinations of Han Huan Wu Evil humulones and furans sulphur humulone | |
| CN106719706A (en) | A kind of Herbicidal combinations of the humulone of sulphur containing furans and fenoxasulfone | |
| CN108013041A (en) | The Herbicidal combinations of flumetsulam containing benzene and ring sulphur ketone | |
| CN107455381A (en) | A kind of sulphur of ketone containing thiophene is grand and trifludimoxazin Herbicidal combinations | |
| CN106719679A (en) | A kind of Herbicidal combinations of containing chlorine fluorine pyridine ester | |
| CN107114384A (en) | A kind of Herbicidal combinations containing pyraclonil | |
| CN107279170A (en) | The Herbicidal combinations of flufenacet, flucarbazone and amicarbazone | |
| CN106857554A (en) | A kind of Herbicidal combinations of the humulone of sulphur containing furans | |
| CN106857574A (en) | A kind of Herbicidal combinations of containing chlorine fluorine pyridine ester and penoxsuam | |
| CN106577718A (en) | Weeding composition including furan sulcotrione and pyriftalid | |
| CN107410321A (en) | A kind of Herbicidal combinations containing fluorochloridone and pyrithiobac-sodium | |
| CN107156164A (en) | The Herbicidal combinations of flufenacet, flucarbazone and diflufenican | |
| CN107232221A (en) | A kind of grand and fluorine benzofenap the Herbicidal combinations of sulphur of ketone containing thiophene | |
| CN108013066A (en) | Herbicidal combinations containing pinoxaden and mesosulfuron | |
| CN106857619A (en) | A kind of Herbicidal combinations of containing chlorine fluorine pyridine ester and furans sulphur humulone | |
| CN107006506A (en) | A kind of Herbicidal combinations for containing three azole amides | |
| CN107114390A (en) | A kind of Herbicidal combinations containing oxadiargyl and AC322140 | |
| CN107114391A (en) | A kind of Herbicidal combinations containing penoxsuam and fenoxasulfone | |
| CN107079916A (en) | A kind of Herbicidal combinations containing penoxsuam | |
| CN107183045A (en) | A kind of Herbicidal combinations of Han Huan Wu Evil humulones | |
| CN106982848A (en) | A kind of Herbicidal combinations containing pyraclonil and three azole amides | |
| CN107258788A (en) | A kind of Herbicidal combinations containing cyhalofop-butyl and fenoxasulfone |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
| RJ01 | Rejection of invention patent application after publication |