CN106700741B - A kind of easy-to-clean temporary marking automatic spray paint and preparation method thereof - Google Patents
A kind of easy-to-clean temporary marking automatic spray paint and preparation method thereof Download PDFInfo
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- 239000003973 paint Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000007921 spray Substances 0.000 title claims abstract description 11
- 230000003670 easy-to-clean Effects 0.000 title claims abstract description 9
- 238000000576 coating method Methods 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 42
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 21
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 15
- 239000004925 Acrylic resin Substances 0.000 claims description 15
- 229920000178 Acrylic resin Polymers 0.000 claims description 15
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 15
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 15
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 12
- 239000002270 dispersing agent Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 5
- 238000009924 canning Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- -1 calcium carbonate Methylal Chemical compound 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- 238000007592 spray painting technique Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000004568 cement Substances 0.000 abstract description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 22
- 238000011049 filling Methods 0.000 description 19
- 239000000047 product Substances 0.000 description 15
- 239000011265 semifinished product Substances 0.000 description 15
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 14
- 238000005507 spraying Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 9
- 239000012452 mother liquor Substances 0.000 description 8
- 239000000443 aerosol Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 238000004806 packaging method and process Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000005028 tinplate Substances 0.000 description 6
- 238000010276 construction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010413 mother solution Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000017274 Diospyros sandwicensis Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282838 Lama Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- GZVBAOSNKYQKIT-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC.COCOC GZVBAOSNKYQKIT-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses an easy-to-clean temporary marking automatic spray paint and a preparation method thereof. The dried paint film has the function of dissolving in water, has the advantages of easy cleaning, no damage to the original surface and the like which are not possessed by other products, and has excellent adhesive force and good smoothness and wear resistance on dry smooth cement or other surfaces.
Description
[ technical field ] A method for producing a semiconductor device
The invention relates to an easy-to-clean automatic paint spraying device for temporary marking and a preparation method thereof.
[ background of the invention ]
At present, the marking of modern enterprise production workshops, large-scale warehouse warehouses, large-scale exhibition site booths and indoor and outdoor temporary parking spaces tends to adopt paint which has no special requirements on construction machinery, high construction efficiency, rapid drying and all the effects of mechanical construction or manual coating. In addition, various spray paints can be used for surfaces needing to be marked in small places, such as laboratories, corridor passages, ticket queuing ground, school playgrounds and the like. In the existing spraying technology, the spraying paint is developed to achieve the purposes of simple operation, relatively low cost, easy cleaning and wiping, no damage to the original coating surface, and the characteristics of the used object are comprehensively considered according to the use requirement.
[ summary of the invention ]
The invention aims to overcome the defects of strong adhesion and difficult cleaning of the existing paint, and provides the easily cleaned temporary marking automatic spray paint which is simple in construction, good in adhesive force and smoothness, soluble in water and suitable for cement or other coating surfaces.
The invention also aims to provide a preparation method of the spray paint.
The invention is realized by the following technical scheme:
the easy-to-clean automatic paint spraying device for the temporary marking is characterized by comprising the following components in parts by weight:
the component A comprises: coating material
And B component: DME, wherein the weight ratio of the amount of DME to the coating is 0.52-0.56: 1.
the styrene butadiene rubber, the modified rosin resin and the modified acrylic resin are used as compound film forming substances, and the modification of the acrylic resin and the rosin resin ensures that a dried paint film has a good water dissolving function, and has the advantages of easiness in cleaning, no damage to the original surface and the like which are not possessed by other products. On one hand, the paint film has excellent adhesive force on dry and smooth cement or other surfaces, but the drawn paint surface can be dissolved and cleaned by clear water when not needed, and the original surface is recovered; on the other hand, the paint film has good smoothness and wear resistance.
The toner has good brightness, has a decoration function and also has a warning function.
DMC (dimethyl carbonate) is used as solvent, a colorless transparent, slightly odorous, slightly sweet liquid, non-toxic, environmental friendly, and widely used organic solvent. Has the characteristics of safe and convenient use, little pollution, easy transportation and the like in production.
Methylal: the methylal (dimethoxymethane) which is a new solvent popularized and used by the national general office for environmental protection has excellent physicochemical properties, namely good solubility, low boiling point and good water solubility, can be widely applied to products such as cosmetics, medicines, household products, industrial automobile products, insecticide leather polishing agents, detergents, rubber industry, paints, printing ink and the like, and can replace F11 and F13 and chlorine-containing solvents as the methylal has good oil stain removing capability and play performance, so that the methylal can replace Freon, the emission of Volatile Organic Compounds (VOCs) is reduced, and the pollution to the atmosphere is reduced. The methylal is used as a solvent to be matched with DMC and is used as a diluent in the invention, so that the whole mixed material is more uniform in a flowable system state, and the sprayed coating is finer and more uniform.
The light calcium carbonate is white or off-white, fine and non-gritty powder. Has excellent physical and chemical properties such as lubricity, anti-sticking property, flow aid, high melting point, chemical inactiveness, good covering power, softness, uniform density, smooth surface and the like, and can be used as a good filler in a coating film.
The dispersant is a surfactant which has two opposite properties of lipophilicity and hydrophilcity in a molecule. Can uniformly disperse solid particles of inorganic and organic pigments which are difficult to dissolve in liquid, and can prevent the solid particles from settling and coagulating to form a stable and uniform mixed system.
The DME (dimethyl ether) is used as the whole spray paint propellant, is colorless gas with slight ether fragrance at normal temperature and normal pressure, has inertia at normal temperature, is not easy to oxidize automatically, and has no corrosiveness and carcinogenicity. And the dual functions of the solvent and the propellant are realized in the formula, so that the propellant and the coating can be uniformly and continuously sprayed out when the content is sprayed out, and the coating is fully atomized when the propellant is liquefied.
The technical indexes of the components of the invention are as follows:
1. DMC (dimethyl carbonate)
Appearance: colorless, transparent, slightly odorous and slightly sweet liquid
Boiling point: 90.1 ℃ C, relative density (d)25)：1.069g/cm3；
2. Modified acrylic resin
The commodity model is as follows: 8532, commercial source: lama practice Co Ltd
The appearance is colorless transparent viscous liquid, and the acid value (mgKOH/g) is 4.0-6.0
Viscosity (mPas) is 5000-;
3. styrene butadiene rubber
Mooney viscosity ML1+4@100 ℃ of 30-45 and tensile strength of more than or equal to 22MPa
The volatile content is less than or equal to 1.2 percent, and the ash content is less than or equal to 1.0 percent;
4. modified rosin resin (product type: 138, product source: Yueyang chemical plant)
Appearance light brown solid, melting point: more than or equal to 110 ℃;
5. methylal
Appearance: colorless transparent liquid
Boiling point: 42.3 ℃ relative density (d)25)：0.8593g/cm3。
6. Light calcium carbonate
Appearance: white or off-white, fine, non-gritty, powdery solid
Hardness (mohs): 1, particle size: 800 meshes;
7. toner powder
Weather resistance 1/25: 5, light resistance 1/25: 8, heat resistance: 80 deg.C
8. Dispersing agent
Appearance: colorless transparent liquid, non-volatile: greater than or equal to 95%, flash point: higher than 100 DEG C
The preparation method of the easy-to-clean temporary scribing automatic spray paint is characterized by comprising the following steps of:
a. putting butadiene styrene rubber, modified rosin resin, modified acrylic resin and 2/3-4/5 DMC into a reaction kettle, stirring and dissolving uniformly, adding a dispersing agent, light calcium carbonate and toner, dispersing at a high speed until the fineness is less than or equal to 45 mu m, adjusting the rotating speed to a low speed, adding methylal and the rest DMC under stirring, and stirring uniformly until the viscosity is 10-20S to obtain a coating semi-finished product;
b. filtering the semi-finished paint product to remove impurities and large particles, canning, sealing, and filling DME.
Wherein, the increase of the light calcium carbonate can increase the viscosity of the paint semi-finished product, and the increase of the methylal and the DMC can decrease the viscosity of the paint semi-finished product; the viscosity of the paint base was measured at 25 ℃ in 4 cups.
The rotating speed of the high-speed dispersion in the invention is 1250-1500 rpm.
The rotation speed of the low-speed dispersion in the invention is 150-250 r/min.
Compared with the prior art, the invention has the following advantages:
the dried paint film has the function of dissolving in water, and has the advantages of easy cleaning, no damage to the original surface and the like which are not possessed by other products. On one hand, the paint film has excellent adhesive force on dry and smooth cement or other surfaces, but the drawn paint surface can be dissolved and cleaned by clear water when not needed, and the original surface is recovered; on the other hand, the paint film has good smoothness and wear resistance.
The environment-friendly easy-cleaning coating is prepared by taking modified acrylic resin and modified rosin resin as main film formers and nontoxic dimethyl carbonate as a blending solvent and adding various fillers and auxiliaries, can quickly form a film at normal temperature, can be used for the requirements of fixed position marking of storehouses in production workshops, temporary marking of large exhibition sites and booths, temporary marking of indoor temporary parking sites and other temporary marking, has a proper adhesion effect on the surface of the coating, and has good brightness. At the same time, when these scribes are not needed, the scribes can be cleaned using clean water.
The invention has the advantages of simple construction process, obvious comprehensive benefit and the like. The marking device can be used for marking off the temporary parking spaces in production workshops, large storage storehouses, large exhibition places, booths and rooms, and can also be used on surfaces needing marking off, such as laboratories, corridor passages, ticket selling queuing ground, school gymnasiums and the like.
[ detailed description ] embodiments
The present invention will be described in further detail with reference to specific examples below:
example 1:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 50kg of modified acrylic resin, 50kg of styrene-butadiene rubber, 45kg of modified rosin resin and DMC250kg are put into a reaction kettle, stirred at the stirring speed of 250-; adding 45kg of dispersing agent, 150kg of light calcium carbonate and 45kg of toner into the coating mother liquor, stirring at the rotating speed of 1250 revolutions per minute for high-speed dispersion for 40-60min until the fineness is less than or equal to 45 mu m, then adjusting the rotating speed to 150 revolutions per minute and 250 revolutions per minute, adding 265kg of methylal and the balance DMC100kg into a reaction kettle, uniformly stirring for 15-25min, and preparing a semi-finished coating, wherein the viscosity is detected at a central control value of 10-20S;
filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the gas-liquid weight ratio of 0.52-0.56, and a finished product is obtained.
Example 2:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 50kg of modified acrylic resin, 50kg of styrene-butadiene rubber, 43kg of modified rosin resin and 280kg of DMC280kg are put into a reaction kettle, stirred and dissolved uniformly at the stirring speed of 250-350 revolutions per minute to obtain coating mother liquor, 45kg of dispersant, 150kg of light calcium carbonate and 47kg of toner are added into the coating mother liquor, the mixture is stirred and dispersed at high speed for 40-60min at the rotating speed of 1500-1500 revolutions per minute until the fineness is less than or equal to 45 mu m, then the rotating speed is adjusted to 150-250 revolutions per minute, 265kg of methylal and 70kg of the rest of DMC are put into the reaction kettle, the mixture is stirred uniformly for 15-25min to obtain a semi-finished coating, and the viscosity is detected to be 10-20S.
Filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the gas-liquid weight ratio of 0.52-0.56, and a finished product is obtained.
Example 3:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 40kg of modified acrylic resin, 40kg of styrene-butadiene rubber, 45kg of modified rosin resin and 200kg of DMC are put into a reaction kettle, the stirring speed is 250-350 r/min, the mixture is stirred and dissolved evenly to obtain coating mother liquor, 35kg of dispersant, 240kg of light calcium carbonate and 35kg of toner are added into the coating mother liquor, the dispersant, the light calcium carbonate and the toner are dispersed at high speed for 60-80min through stirring at 1300 r/min until the fineness is less than or equal to 45 mu m, then the rotation speed is adjusted to 150 r/min, 250 r/min, the methylal 285kg and the balance of DMC80kg are put into the reaction kettle, the mixture is stirred evenly for 15-25min, and a semi-finished coating is prepared, and the viscosity is detected at the central control of 10.
Filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the gas-liquid weight ratio of 0.52-0.56, and a finished product is obtained.
Example 4:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 50kg of modified acrylic resin, 50kg of styrene-butadiene rubber, 50kg of modified rosin resin and 200kg DMC are put into a reaction kettle, stirred at the stirring speed of 250-350 r/min and uniformly dissolved to prepare a coating mother solution; adding 37.5kg of dispersing agent, 188kg of light calcium carbonate and 37.5kg of toner into the coating mother liquor, stirring at the rotating speed of 1250 revolutions per minute for high-speed dispersion for 40-60min until the fineness is less than or equal to 45 mu m, then adjusting the rotating speed to be 150 revolutions per minute and 250 revolutions per minute, adding 275kg of methylal and the balance of DMC112.5kg into a reaction kettle, uniformly stirring for 15-25min to prepare a semi-finished coating, wherein the viscosity is detected to be 10-20S by a central control method;
filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the weight ratio of 0.52-0.56, and a finished product is obtained.
Example 5:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 50kg of modified acrylic resin, 50kg of styrene-butadiene rubber, 50kg of modified rosin resin and 200kg DMC are put into a reaction kettle, stirred at the stirring speed of 250-350 r/min and uniformly dissolved to prepare a coating mother solution; adding 40kg of dispersing agent, 200kg of light calcium carbonate and 40kg of toner into the coating mother liquor, stirring at the rotating speed of 1250 revolutions per minute for high-speed dispersion for 40-60min until the fineness is less than or equal to 45 mu m, then adjusting the rotating speed to be 150 revolutions per minute and 250 revolutions per minute, adding 270kg of methylal and the balance of DMC100kg into a reaction kettle, uniformly stirring for 15-25min, and preparing a semi-finished coating, wherein the viscosity is detected at a central control of 10-20S;
filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the weight ratio of 0.52-0.56, and a finished product is obtained.
Example 6:
preparation of the coating (taking the preparation of 1000kg of coating as an example): 50kg of modified acrylic resin, 50kg of styrene-butadiene rubber, 50kg of modified rosin resin and 200kg DMC are put into a reaction kettle, stirred at the stirring speed of 250-350 r/min and uniformly dissolved to prepare a coating mother solution; adding 41.5kg of dispersing agent, 208kg of light calcium carbonate and 41.5kg of toner into the coating mother liquor, stirring at the rotating speed of 1250 revolutions per minute for high-speed dispersion for 40-60min until the fineness is less than or equal to 45 mu m, then adjusting the rotating speed to 150 revolutions per minute and 250 revolutions per minute, adding 267kg of methylal and the rest of DMC92kg into a reaction kettle, stirring uniformly for 15-25min, and preparing a semi-finished coating product, wherein the viscosity is detected by a central control method and is 10-20S;
filling by automatic spraying: filtering the paint semi-finished product by a 400-mesh filter screen to remove various impurities and large particles, filling 150g of the paint semi-finished product into a 400ml aerosol tinplate can by an automatic filling machine, putting mixed steel balls, and inserting a pneumatic valve for packaging; finally, DME is filled according to the weight ratio of 0.52-0.56, and a finished product is obtained.
The automatic spray paint meets the standard requirement of the packaging industry standard of the people's republic of China-aerosol paint (standard No. BB/T0047-2007). The test results are shown in table 1:
table 1:
the comparative test conditions of the easy-cleaning performance of the automatic spray paint of the invention are shown in Table 2:
table 2:
Claims (3)
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| CN108084822A (en) * | 2017-12-18 | 2018-05-29 | 肇庆欧迪斯实业有限公司 | The reflective aerosol paint of aqueous, environmental protective and the reflective aerosol paint device of aqueous, environmental protective |
| CN116694164A (en) * | 2023-07-06 | 2023-09-05 | 东易日盛智能家居科技(枣庄)有限公司 | A kind of aerosol paint and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1592771A (en) * | 2001-11-27 | 2005-03-09 | 奇乐·格梅灵有限公司及两合公司 | Use of a coating composition for producing a temporary protective coat on plastics surfaces |
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| FR2981085B1 (en) * | 2011-10-11 | 2015-06-26 | Gm Agri | PAINT, IN PARTICULAR FOR TEMPORARY ROAD MARKING, BASED ON BIODEGRADABLE POLYMERS |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1592771A (en) * | 2001-11-27 | 2005-03-09 | 奇乐·格梅灵有限公司及两合公司 | Use of a coating composition for producing a temporary protective coat on plastics surfaces |
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