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CN106693530B - An anti-fog and haze window net - Google Patents

An anti-fog and haze window net Download PDF

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Publication number
CN106693530B
CN106693530B CN201611170753.2A CN201611170753A CN106693530B CN 106693530 B CN106693530 B CN 106693530B CN 201611170753 A CN201611170753 A CN 201611170753A CN 106693530 B CN106693530 B CN 106693530B
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parts
window net
net
dedusting
haze
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CN106693530A (en
Inventor
任立超
任立岳
巩玉兵
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SHANDONG JINGUAN NET CO Ltd
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SHANDONG JINGUAN NET CO Ltd
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Priority to CN201611170753.2A priority Critical patent/CN106693530B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • B01D46/12Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces in multiple arrangements
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0002Casings; Housings; Frame constructions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0032Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions using electrostatic forces to remove particles, e.g. electret filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0036Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/52Devices affording protection against insects, e.g. fly screens; Mesh windows for other purposes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Structural Engineering (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Insects & Arthropods (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to window net field more particularly to a kind of haze window nets.Haze window net provided by the invention, the clearing window net of dedusting window net and internal layer including outer layer, dust in the dedusting window net main filtration air of outer layer, the clearing window net of internal layer primarily serves absorption and crosses the effect of the harmful chemicals gas in bacterium and vehicle exhaust in air filtering, make haze window net provided by the invention that not only there is dedusting function, but also has the function of filter bacteria and harmful chemicals gas.Haze window net provided by the invention can effectively control and improve thick weather high and medium indoor air quality, absorb the harmful bacteria in air, microorganism and dust to greatest extent.Very big effect is played to the health for protecting indoor occupant.To in following urban construction, safeguards that the health of all city dwellers there will be great meaning, can also play the role of to the improvement of future city living environment critical.

Description

A kind of haze window net
Technical field
The present invention relates to window net field more particularly to a kind of haze window nets.
Background technique
In recent years, it with the continuous development in industrialization city, development of real estate, a large amount of discharges of vehicle exhaust etc., causes Haze weather invades the whole nation on a large scale, and air quality is continuous worsening, brings and seriously threatens to people's physical and mental health, and resident living Indoors, it is often necessary to which windowing is divulged information, and the dust and harmful chemicals gas in air will enter the room therewith, not only to indoor Cleaning impacts, and directly jeopardizes the physical and mental health of numerous residents.The air how to be entered the room by the purification of window net, The topic paid special attention at us.
Although disclosing the screen window with dedusting function in the prior art, most dirt exclusion capabilities are insufficient, moreover, existing skill Dust-proof screen window in art can only generally cross the bulky grain pollutant in air filtering, to the bacterium in air, having in vehicle exhaust Evil chemical gas can not play effective catharsis, and therefore, further developing one kind on the basis of existing technology can The dust in air filtering is effectively crossed, and the bacterium in air, the harmful chemicals gas in vehicle exhaust can be played effective net The window net of change effect, has great importance.
Summary of the invention
To overcome the above technical problem, the present invention provides a kind of haze window nets.
To achieve the above object, the present invention adopts the following technical scheme:
A kind of haze window net, the clearing window net of dedusting window net and internal layer including outer layer, the dedusting window net and purification Window net is fixed by frame, and the dedusting window net and clearing window net are detachable, and the dedusting window net includes the first dedusting window of outer layer Second dedusting window net of net and internal layer, the first dedusting window net surface are attached with polytetrafluoroethylene (PTFE) positive polarity electret coating, The second dedusting window net surface is attached with perfluoroethylene-propylene negative polarity electret coating, the mesh of the first dedusting window net For 40~45 mesh, the mesh of the second dedusting window net is 30~35 mesh;
The clearing window net includes substrate, is attached to substrate surface and/or infiltrates through the scavenging material inside substrate, described Substrate includes the following parts by weight: 10~12 parts of graphene, PET20~25 part, 25~30 parts of ultra-high molecular weight polyethylene, 30~35 parts of porous basalt fiber, 25~30 parts of carbon fiber;The scavenging material includes the following parts by weight: intending thin water 20~23 parts of aluminium stone, 25~28 parts of integral honeycomb active carbon powder, sour 15~20 parts of modification infusorial earth, hydroxylamine chloride 5~8 Part, 8~10 parts of hexamethylenetetramine, 6~8 parts of cobaltosic oxide, 10~12 parts of humic acid, 10~15 parts of nano-titanium dioxide, Sterilize 15~20 parts of expelling parasite particle packet;
The clearing window net is prepared by following methods:
(1) preparation of substrate: accurately weighing required raw material according to recipe requirements, raw material be uniformly mixed, and then will mix Raw material afterwards heats 45~70 minutes under the conditions of 280~300 DEG C, extends 3~4 times, is made into the net of 25~35 mesh meshes, will The net arrived carries out fulling milling processing under the conditions of 200 DEG C using molding machine to get the substrate is arrived;
(2) preparation of scavenging material: required raw material is accurately weighed according to recipe requirements, raw material is added sequentially to water and silicon In the solution of sour sodium, be put into high-speed stirred kettle and be stirred, wherein mixing speed be 3000 revs/min, mixing time 2 hours, Mixed solution is obtained, mixed solution is then subjected to ultrasonic disperse processing, ultrasonic disperse frequency is 30kHz, bath temperature 35 DEG C, ultrasonic time is 40 minutes, and the mixed solution after ultrasonic treatment is stood 6 hours to get the scavenging material is arrived;
(3) adhesive is added into scavenging material obtained by step (2), stirs evenly, then soak substrate obtained by step (1) Enter and wherein impregnate 20h, so that scavenging material is attached to substrate surface, arrive the air after drying under the conditions of 150~180 DEG C Purifying net;
The sterilization expelling parasite particle packet is made by following methods:
20 parts of water are added in reaction vessel, 5 parts of mite suppressors, 8 parts of antibacterial agents and 7 parts of expelling parasites are sequentially added under stirring condition Agent, 30~50min of stirring is uniformly mixed under the conditions of room temperature, mixing speed are 200~250 revs/min, and it is spare to obtain solution A;By 8 Part beta-cyclodextrin is mixed with 15 parts of water, 65 DEG C, mixing speed stir 50min under the conditions of being 200 revs/min, make its heating for dissolving, obtain To solution B;Under the conditions of low whipping speed is 250 revs/min, temperature is 65 DEG C, solution A is added dropwise in solution B, is then stirred It is cooling after 50min, coat beta-cyclodextrin by pest repellant to get the sterilization expelling parasite particle packet is arrived.
Preferably, the mite suppressor is the mixed of the Ergol that weight ratio is 1:1.5 and diethyl phthalate Close object;The antibacterial agent is the mixture of the fennel oil that weight ratio is 1:2 and tea oil;The pest repellant is that weight ratio is 1: 1.2 fluorine chlorine ether pyrethroids and the mixture of ES Esbiothrin.
Preferably, the acid modification infusorial earth is made by following methods:
The diatomite of 10 parts by weight is added in the nitric acid solution that 20 parts of mass fractions are 30%, is put into high-speed stirred kettle In be stirred, wherein mixing speed be 2000~2500 revs/min, mixing time 1.5~2 hours, obtain mixed solution, then Mixed solution is placed into microwave generator, carries out ultrasonic disperse processing, ultrasonic disperse frequency is 25kHz, and bath temperature is 35 DEG C, ultrasonic time is 40~60min, the mixed solution after ultrasonic treatment is filtered, washing, is dried under the conditions of 180~200 DEG C It does to get the sour modification infusorial earth is arrived.
Preferably, the humic acid is by raw material: peat and lignite carry out oxidized activating processing with ozone, and alkalize and mention It is obtained after pure, the wherein content of organic matter >=87%, humic acid >=75%.
Preferably, the adhesive be weight ratio be 1:1.5:2 silica solution, self-crosslinking acrylic ester adhesive, water The mixture of property polyurethane binder.
Preferably, the water conservancy diversion direction of the mesh of the first dedusting window net and the second dedusting window net is wave-shaped.
Preferably, the diameter of the porous basalt fiber is 150~200 μm, length is 0.1mm~1mm, hole Rate is 70%~80%, and hole diameter is 50~60nm.
Preferably, the molecular weight of the ultra-high molecular weight polyethylene is 150~2,000,000.
Preferably, the average grain diameter of the nano-titanium dioxide is 10~15nm.
The beneficial effects of the present invention are:
(1) haze window net provided by the invention, the clearing window net of dedusting window net and internal layer including outer layer, outer layer remove Dust in dirt window net main filtration air, the clearing window net of internal layer primarily serve absorption and cross the bacterium in air filtering and nocuousness The effect of chemical gas makes haze window net provided by the invention not only have dedusting function, but also has filter bacteria and harmful Learn the function of gas.The dedusting window net and clearing window net are fixed by frame, and the dedusting window net and clearing window net are detachable, can Easily to be unpicked and washed, has and replace convenient effect.Haze window net provided by the invention effectively can control and change Indoor air quality in kind thick weather absorbs harmful bacteria, microorganism and dust in air to greatest extent.To protection room The health of interior occupant plays very big effect.It is strong to the body in following urban construction, safeguarding all city dwellers Health will have great meaning, can also play the role of to the improvement of future city living environment critical.
(2) a kind of haze window net of the present invention, the dedusting window net of outer layer use the window net of positive and negative two layers of electret, point It Li Yong not Electrostatic Absorption (screen window and particulate matter respectively the band charges of different polarity) or electrostatic repulsion (screen window and particulate matter band like electricity respectively Lotus) processing charged particle, uncharged neutrophil granule object can first be adsorbed the polarization of neutrophil granule object again, or work as air circulation When, electret will be charged by friction the neutrophil granule object in absorption air, play better air cleaning, a dust-proof effect. The mesh of first dedusting window net is greater than the second dedusting window net, when air passes through window net, first stops larger by the first dedusting window net Grain object, then smaller particle object is adsorbed by the second dedusting window net, layered filtration may be implemented, improve filter effect.Two layers of dedusting Window net is respectively adopted polytetrafluoroethylene (PTFE) and perfluoroethylene-propylene electret coating, and staying of lasting a long time can be made in both materials Electret material increases its service life.
(3) it joined integral honeycomb active carbon powder in its scavenging material of air-purifying net provided by the invention, make institute Preferable purification absorption can be carried out to the contaminant particle in air by stating scavenging material, can preferably adsorb in air Grain, especially PM2.5 particle;And hydroxylamine chloride, hexamethylenetetramine, cobaltosic oxide, humic acid, nano-titanium dioxide plus Enter, the scavenging material can play good absorption to contaminant gases such as formaldehyde in air, acetaldehyde, acetic acid and ammonias and eliminate Effect plays preferable absorption to the heavy metal in air simultaneously;It joined mite suppressor, antibacterial agent and pest repellant, make this The material for air purification of invention plays killing effect to the bacterium in air, has stronger suppression mite antibacterial ability, and can Mosquito expelling, and act on and stablizing, is applied widely, the activity of acarid and bacterium can be effectively suppressed, effectively killing acarid, from Fundamentally solve the harm that dust mite is brought.The pest repellant is the fluorine chlorine ether pyrethroids that weight ratio is 1:1.2 and ES biology The mixture of pyrethroids, using the smallest pyrethroids class pest repellant of toxicity, more safety and environmental protection.Air-purifying net provided by the invention its Sour modification infusorial earth is used in scavenging material, and diatomite is modified processing with microwave acid processing technique, increases diatom Specific surface area, the micropore quantity of micro scale and the most probable radius of soil, also make the aperture increases of diatomite micropore, to make silicon Diatomaceous earth greatly increases the purification efficiency of air, material for air purification obtained also have higher purification efficiency, it is longer after Continuous clean-up effect and bigger adsorbance.
(4) a kind of haze window net of the present invention, joined in its scavenging material of the clearing window net of internal layer raw material mite suppressor and Antibacterial agent makes material for air purification of the invention have stronger suppression mite antibacterial ability, and acts on and stablizing, is applied widely It is general, the activity of acarid and bacterium can be effectively suppressed, effectively killing acarid, fundamentally solves the harm that dust mite is brought. The scavenging material can carry out preferable purification absorption to the contaminant particle in air, while by using integral honeycomb Active carbon powder can preferably adsorb the particle in air, especially PM2.5 particle;And it can be to formaldehyde in air, second The contaminant gases such as aldehyde, acetic acid and ammonia play the role of good absorption elimination, killing effect are played to the bacterium in air, is same When preferable absorption is played to the heavy metal in air.
(5) sterilization expelling parasite particle packet is used in its scavenging material of air-purifying net provided by the invention, by mite suppressor, is resisted Microbial inoculum and pest repellant are coated to form particle packet with beta-cyclodextrin, to realize the effect of sustained release, are prolonged its service life.
Specific embodiment
Below with reference to embodiment, technical solution of the present invention is further elaborated with.
Embodiment 1
A kind of haze window net, the clearing window net of dedusting window net and internal layer including outer layer, the dedusting window net and purification Window net is fixed by frame, and the dedusting window net and clearing window net are detachable, and the dedusting window net includes the first dedusting window of outer layer Second dedusting window net of net and internal layer, the first dedusting window net surface are attached with polytetrafluoroethylene (PTFE) positive polarity electret coating, The second dedusting window net surface is attached with perfluoroethylene-propylene negative polarity electret coating, the mesh of the first dedusting window net For 40 mesh, the mesh of the second dedusting window net is 30 mesh;
The clearing window net includes substrate, is attached to substrate surface and/or infiltrates through the scavenging material inside substrate, described Substrate includes the following parts by weight: 10 parts of graphene, PET20 parts, 25 parts of ultra-high molecular weight polyethylene, porous basalt fibre 30 parts, 25 parts of carbon fiber of dimension;The scavenging material includes the following parts by weight: 20 parts of boehmite, integral honeycomb 25 parts of active carbon powder, sour 15 parts of modification infusorial earth, 5 parts of hydroxylamine chloride, 8 parts of hexamethylenetetramine, 6 parts of cobaltosic oxide, corruption Grow 15 parts 10 parts of acid, 10 parts of nano-titanium dioxide, sterilization of expelling parasite particle packet.
The sterilization expelling parasite particle packet is made by following methods:
20 parts of water are added in reaction vessel, 5 parts of mite suppressors, 8 parts of antibacterial agents and 7 parts of expelling parasites are sequentially added under stirring condition Agent, stirring 50min is uniformly mixed under the conditions of room temperature, mixing speed are 200 revs/min, and it is spare to obtain solution A;By 8 parts of beta-cyclodextrins Mixed with 15 parts of water, 65 DEG C, mixing speed be 200 revs/min under the conditions of stir 50min, make its heating for dissolving, obtain solution B;? Under the conditions of mixing speed is 250 revs/min, temperature is 65 DEG C, solution A is added dropwise in solution B, it is then cold after stirring 50min But, beta-cyclodextrin is coated by pest repellant to get the sterilization expelling parasite particle packet is arrived;
The acid modification infusorial earth is made by following methods:
The diatomite of 10 parts by weight is added in the nitric acid solution that 20 parts of mass fractions are 30%, is put into high-speed stirred kettle In be stirred, wherein mixing speed be 2000 revs/min, mixing time 2 hours, mixed solution is obtained, then by mixed solution It is placed into microwave generator, carries out ultrasonic disperse processing, ultrasonic disperse frequency is 25kHz, and bath temperature is 35 DEG C, when ultrasonic Between be 40min, by mixed solution filtering, the washing after ultrasonic treatment, drying is to get to the sour modified silicon under the conditions of 180 DEG C Diatomaceous earth.
The mite suppressor is the mixture of the Ergol that weight ratio is 1:1.5 and diethyl phthalate;It is described Antibacterial agent is the mixture of the fennel oil that weight ratio is 1:2 and tea oil;The pest repellant is the fluorine chlorine ether that weight ratio is 1:1.2 The mixture of pyrethroids and ES Esbiothrin.
The humic acid is by raw material: peat and lignite carry out oxidized activating processing with ozone, and are made after purification of alkalizing , the wherein content of organic matter >=87%, humic acid >=75%.
The clearing window net is prepared by following methods:
(1) preparation of substrate: according to recipe requirements by required raw material: 10 parts of graphene, PET40 parts, super high molecular weight it is poly- 35 parts of ethylene, 35 parts of porous basalt fiber, 30 parts of carbon fiber be uniformly mixed, then by the raw material after mixing in 280 DEG C of conditions Lower heating 45 minutes, extends 5 times, is made into the net of 25 mesh meshes, and obtained net is contracted under the conditions of 200 DEG C using molding machine Suede handles to arrive the substrate;
(2) preparation of scavenging material: according to recipe requirements by required raw material: 20 parts of boehmite, resists 5 parts of mite suppressor 8 parts of microbial inoculum, 25 parts of integral honeycomb active carbon powder, 15 parts of diatomite, 5 parts of hydroxylamine chloride, 8 parts of hexamethylenetetramine, four oxygen Change 6 parts of three cobalt, 10 parts of humic acid, 10 parts of nano-titanium dioxide be added sequentially in the solution of water and sodium metasilicate, be put into high-speed stirring It mixes in kettle and is stirred, wherein mixing speed is 3000 revs/min, mixing time 2 hours, obtains mixed solution, then will mixing Solution carries out ultrasonic disperse processing, and ultrasonic disperse frequency is 30kHz, and bath temperature is 35 DEG C, and ultrasonic time is 40 minutes, will surpass Mixed solution after sonication stands 6 hours to get the scavenging material is arrived;
(3) adhesive is added into scavenging material obtained by step (2), stirs evenly, then soak substrate obtained by step (1) Enter and wherein impregnate 20h, scavenging material is made to be attached to substrate surface, arrives the clearing window net after drying.
The adhesive be weight ratio be 1:1.5:2 silica solution, self-crosslinking acrylic ester adhesive, aqueous polyurethane it is viscous The mixture of mixture.
The water conservancy diversion direction of the mesh of the first dedusting window net and the second dedusting window net is wave-shaped.
The diameter of the porous basalt fiber is 150~200 μm, and length is 0.1mm~1mm, porosity 70% ~80%, hole diameter is 50~60nm.
The molecular weight of the ultra-high molecular weight polyethylene is 150~2,000,000.
The average grain diameter of the nano-titanium dioxide is 10~15nm.
Embodiment 2
A kind of haze window net, the clearing window net of dedusting window net and internal layer including outer layer, the dedusting window net and purification Window net is fixed by frame, and the dedusting window net and clearing window net are detachable, and the dedusting window net includes the first dedusting window of outer layer Second dedusting window net of net and internal layer, the first dedusting window net surface are attached with polytetrafluoroethylene (PTFE) positive polarity electret coating, The second dedusting window net surface is attached with perfluoroethylene-propylene negative polarity electret coating, the mesh of the first dedusting window net For 45 mesh, the mesh of the second dedusting window net is 35 mesh;
The clearing window net includes substrate, is attached to substrate surface and/or infiltrates through the scavenging material inside substrate, described Substrate includes the following parts by weight: 12 parts of graphene, PET25 parts, 30 parts of ultra-high molecular weight polyethylene, porous basalt fibre 35 parts, 30 parts of carbon fiber of dimension;The scavenging material includes the following parts by weight: 23 parts of boehmite, integral honeycomb 28 parts of active carbon powder, sour 20 parts of modification infusorial earth, 8 parts of hydroxylamine chloride, 10 parts of hexamethylenetetramine, 8 parts of cobaltosic oxide, corruption Grow 20 parts 12 parts of acid, 15 parts of nano-titanium dioxide, sterilization of expelling parasite particle packet.
The sterilization expelling parasite particle packet is made by following methods:
20 parts of water are added in reaction vessel, 5 parts of mite suppressors, 8 parts of antibacterial agents and 7 parts of expelling parasites are sequentially added under stirring condition Agent, stirring 30min is uniformly mixed under the conditions of room temperature, mixing speed are 250 revs/min, and it is spare to obtain solution A;By 8 parts of beta-cyclodextrins Mixed with 15 parts of water, 65 DEG C, mixing speed be 200 revs/min under the conditions of stir 50min, make its heating for dissolving, obtain solution B;? Under the conditions of mixing speed is 250 revs/min, temperature is 65 DEG C, solution A is added dropwise in solution B, it is then cold after stirring 50min But, beta-cyclodextrin is coated by pest repellant to get the sterilization expelling parasite particle packet is arrived;
The acid modification infusorial earth is made by following methods:
The diatomite of 10 parts by weight is added in the nitric acid solution that 20 parts of mass fractions are 30%, is put into high-speed stirred kettle In be stirred, wherein mixing speed be 2500 revs/min, mixing time 1.5 hours, obtain mixed solution, then will mix molten Liquid is placed into microwave generator, carries out ultrasonic disperse processing, and ultrasonic disperse frequency is 25kHz, and bath temperature is 35 DEG C, ultrasound Time is 60min, the mixed solution after ultrasonic treatment is filtered, washing, and drying is modified under the conditions of 200 DEG C to get to the acid Diatomite.
The mite suppressor is the mixture of the Ergol that weight ratio is 1:1.5 and diethyl phthalate;It is described Antibacterial agent is the mixture of the fennel oil that weight ratio is 1:2 and tea oil;The pest repellant is the fluorine chlorine ether that weight ratio is 1:1.2 The mixture of pyrethroids and ES Esbiothrin.
The humic acid is by raw material: peat and lignite carry out oxidized activating processing with ozone, and are made after purification of alkalizing , the wherein content of organic matter >=87%, humic acid >=75%.
The clearing window net is prepared by following methods:
(1) preparation of substrate: according to recipe requirements by required raw material: 10 parts of graphene, PET40 parts, super high molecular weight it is poly- 35 parts of ethylene, 35 parts of porous basalt fiber, 30 parts of carbon fiber be uniformly mixed, then by the raw material after mixing in 280 DEG C of conditions Lower heating 45 minutes, extends 5 times, is made into the net of 25 mesh meshes, and obtained net is contracted under the conditions of 200 DEG C using molding machine Suede handles to arrive the substrate;
(2) preparation of scavenging material: according to recipe requirements by required raw material: 20 parts of boehmite, resists 5 parts of mite suppressor 8 parts of microbial inoculum, 25 parts of integral honeycomb active carbon powder, 15 parts of diatomite, 5 parts of hydroxylamine chloride, 8 parts of hexamethylenetetramine, four oxygen Change 6 parts of three cobalt, 10 parts of humic acid, 10 parts of nano-titanium dioxide be added sequentially in the solution of water and sodium metasilicate, be put into high-speed stirring It mixes in kettle and is stirred, wherein mixing speed is 3000 revs/min, mixing time 2 hours, obtains mixed solution, then will mixing Solution carries out ultrasonic disperse processing, and ultrasonic disperse frequency is 30kHz, and bath temperature is 35 DEG C, and ultrasonic time is 40 minutes, will surpass Mixed solution after sonication stands 6 hours to get the scavenging material is arrived;
(3) adhesive is added into scavenging material obtained by step (2), stirs evenly, then soak substrate obtained by step (1) Enter and wherein impregnate 20h, scavenging material is made to be attached to substrate surface, arrives the clearing window net after drying.
Preferably, the adhesive be weight ratio be 1:1.5:2 silica solution, self-crosslinking acrylic ester adhesive, water The mixture of property polyurethane binder.The water conservancy diversion direction of the mesh of the first dedusting window net and the second dedusting window net is in wave Shape.The diameter of the porous basalt fiber be 150~200 μm, length be 0.1mm~1mm, porosity be 70%~ 80%, hole diameter is 50~60nm.The molecular weight of the ultra-high molecular weight polyethylene is 150~2,000,000.The nanometer two The average grain diameter of titanium oxide is 10~15nm.
Embodiment 3
A kind of haze window net, the clearing window net of dedusting window net and internal layer including outer layer, the dedusting window net include outer First dedusting window net of layer and the second dedusting window net of internal layer, the first dedusting window net surface are attached with polytetrafluoroethylene (PTFE) anode Property electret coating, the second dedusting window net surface are attached with perfluoroethylene-propylene negative polarity electret coating, and described first The mesh of dedusting window net is 40 mesh, and the mesh of the second dedusting window net is 35 mesh;
The clearing window net includes substrate, is attached to substrate surface and/or infiltrates through the scavenging material inside substrate, described Substrate includes the following parts by weight: 112 parts of graphene, PET24 parts, 28 parts of ultra-high molecular weight polyethylene, porous basalt 31 parts of fiber, 27 parts of carbon fiber;The scavenging material includes the following parts by weight: 21 parts of boehmite, monoblock type bee 27 parts of nest active carbon powder, sour 17 parts of modification infusorial earth, 7 parts of hydroxylamine chloride, 9 parts of hexamethylenetetramine, 7 parts of cobaltosic oxide, 19 parts 11 parts of humic acid, 14 parts of nano-titanium dioxide, sterilization of expelling parasite particle packet.
The sterilization expelling parasite particle packet is made by following methods:
20 parts of water are added in reaction vessel, 5 parts of mite suppressors, 8 parts of antibacterial agents and 7 parts of expelling parasites are sequentially added under stirring condition Agent, stirring 45min is uniformly mixed under the conditions of room temperature, mixing speed are 230 revs/min, and it is spare to obtain solution A;By 8 parts of beta-cyclodextrins Mixed with 15 parts of water, 65 DEG C, mixing speed be 200 revs/min under the conditions of stir 50min, make its heating for dissolving, obtain solution B;? Under the conditions of mixing speed is 250 revs/min, temperature is 65 DEG C, solution A is added dropwise in solution B, it is then cold after stirring 50min But, beta-cyclodextrin is coated by pest repellant to get the sterilization expelling parasite particle packet is arrived;
The acid modification infusorial earth is made by following methods:
The diatomite of 10 parts by weight is added in the nitric acid solution that 20 parts of mass fractions are 30%, is put into high-speed stirred kettle In be stirred, wherein mixing speed be 2300 revs/min, mixing time 2 hours, mixed solution is obtained, then by mixed solution It is placed into microwave generator, carries out ultrasonic disperse processing, ultrasonic disperse frequency is 25kHz, and bath temperature is 35 DEG C, when ultrasonic Between be 50min, by mixed solution filtering, the washing after ultrasonic treatment, drying is to get to the sour modified silicon under the conditions of 190 DEG C Diatomaceous earth.
The mite suppressor is the mixture of the Ergol that weight ratio is 1:1.5 and diethyl phthalate;It is described Antibacterial agent is the mixture of the fennel oil that weight ratio is 1:2 and tea oil;The pest repellant is the fluorine chlorine ether that weight ratio is 1:1.2 The mixture of pyrethroids and ES Esbiothrin.
Preferably, the humic acid is by raw material: peat and lignite carry out oxidized activating processing with ozone, and alkalize and mention It is obtained after pure, the wherein content of organic matter >=87%, humic acid >=75%.
The clearing window net is prepared by following methods:
(1) preparation of substrate: according to recipe requirements by required raw material: 10 parts of graphene, PET40 parts, super high molecular weight it is poly- 35 parts of ethylene, 35 parts of porous basalt fiber, 30 parts of carbon fiber be uniformly mixed, then by the raw material after mixing in 280 DEG C of conditions Lower heating 45 minutes, extends 5 times, is made into the net of 25 mesh meshes, and obtained net is contracted under the conditions of 200 DEG C using molding machine Suede handles to arrive the substrate;
(2) preparation of scavenging material: according to recipe requirements by required raw material: 20 parts of boehmite, resists 5 parts of mite suppressor 8 parts of microbial inoculum, 25 parts of integral honeycomb active carbon powder, 15 parts of diatomite, 5 parts of hydroxylamine chloride, 8 parts of hexamethylenetetramine, four oxygen Change 6 parts of three cobalt, 10 parts of humic acid, 10 parts of nano-titanium dioxide be added sequentially in the solution of water and sodium metasilicate, be put into high-speed stirring It mixes in kettle and is stirred, wherein mixing speed is 3000 revs/min, mixing time 2 hours, obtains mixed solution, then will mixing Solution carries out ultrasonic disperse processing, and ultrasonic disperse frequency is 30kHz, and bath temperature is 35 DEG C, and ultrasonic time is 40 minutes, will surpass Mixed solution after sonication stands 6 hours to get the scavenging material is arrived;
(3) adhesive is added into scavenging material obtained by step (2), stirs evenly, then soak substrate obtained by step (1) Enter and wherein impregnate 20h, scavenging material is made to be attached to substrate surface, arrives the clearing window net after drying.
Preferably, the adhesive be weight ratio be 1:1.5:2 silica solution, self-crosslinking acrylic ester adhesive, water The mixture of property polyurethane binder.The water conservancy diversion direction of the mesh of the first dedusting window net and the second dedusting window net is in wave Shape.The diameter of the porous basalt fiber be 150~200 μm, length be 0.1mm~1mm, porosity be 70%~ 80%, hole diameter is 50~60nm.The molecular weight of the ultra-high molecular weight polyethylene is 150~2,000,000.The nanometer two The average grain diameter of titanium oxide is 10~15nm.
The purifying property of 4 gained clearing window net of embodiment is tested
This experiment uses 4 groups of tests, and test 1~3 tests 4 using by clearing window net obtained in above-described embodiment 1~3 Using commercially available common purifying window net, respectively using four groups of air-purifying nets as window net, it is mounted on 20 layers or more civil construction objects On window.After window continuously opens 10 hours, room air matter is detected by " Indoor Air Quality standards " GB/T18883-2002 Amount.Testing result is as shown in table 1, table 2.
The performance test of 1. clearing window net of table
From table 1 it follows that clearing window net obtained by the embodiment of the present invention had not only had good dedusting function, but also have It imitates filter bacteria and adsorbs the function of harmful chemical gas, the clearing window net can be to pollutants such as formaldehyde in air, acetaldehyde Gas plays the role of good absorption elimination, can effectively control and improve indoor air quality in thick weather, to protection The health of indoor occupant plays very big effect, in following urban construction, safeguards the body of all city dwellers Health will have great meaning, can also play the role of to the improvement of future city living environment critical.
The antibacterial mite-removing performance test of 2. clearing window net of table
From Table 2, it can be seen that making clearing window net of the invention in air due to joined mite suppressor, antibacterial agent Bacterium plays killing effect, has stronger suppression mite antibacterial ability, and act on and stablizing, is applied widely, can be effectively suppressed The activity of acarid and bacterium, effectively killing acarid, fundamentally solve bacterium, the harm that dust mite is brought.
And joined pest repellant in clearing window net of the invention, make it have the effect of mosquito expelling, the pest repellant It is the mixture of fluorine chlorine ether pyrethroids and ES Esbiothrin that weight ratio is 1:1.2, using the smallest pyrethroids class pest repellant of toxicity, more Add safety and environmental protection.
The performance lasting test of antibacterial mite-removing of 5 gained clearing window net of embodiment
Using clearing window net obtained in above-described embodiment 1 as window net, it is mounted on the window of 20 layers or more civil construction objects On, window continuously opens, and detected it respectively every 30 days and sterilizes anthelminthic effect, testing result is as shown in table 3.
The performance lasting test of antibacterial mite-removing of 3. clearing window net of table
The antibacterial mite-removing consistency of performance performance that can be seen that clearing window net provided by the invention from the data in table 3 is good, This is because sterilization expelling parasite particle packet is used in its scavenging material, by mite suppressor, antibacterial agent and pest repellant beta-cyclodextrin packet It covers to form particle packet, to realize the effect of sustained release, prolong its service life.

Claims (9)

1. a kind of haze window net, it is characterised in that:
The clearing window net of dedusting window net and internal layer including outer layer, the dedusting window net include the first dedusting window net of outer layer and interior Second dedusting window net of layer, the first dedusting window net surface are attached with polytetrafluoroethylene (PTFE) positive polarity electret coating, and described the Two dedusting window net surfaces are attached with perfluoroethylene-propylene negative polarity electret coating, and the mesh of the first dedusting window net is 40~ 45 mesh, the mesh of the second dedusting window net are 30~35 mesh;
The clearing window net includes substrate, is attached to substrate surface and/or infiltrates through the scavenging material inside substrate, the substrate It includes the following parts by weight: 10~12 parts of graphene, PET20~25 part, 25~30 parts of ultra-high molecular weight polyethylene, porous 30~35 parts of basalt fibre, 25~30 parts of carbon fiber;The scavenging material includes the following parts by weight: boehmite 20~23 parts, 25~28 parts of integral honeycomb active carbon powder, sour 15~20 parts of modification infusorial earth, 5~8 parts of hydroxylamine chloride, six 8~10 parts of methine tetramine, 6~8 parts of cobaltosic oxide, 10~12 parts of humic acid, 10~15 parts of nano-titanium dioxide, sterilization are driven 15~20 parts of worm particle packet;
The clearing window net is prepared by following methods:
(1) preparation of substrate: accurately weighing required raw material according to recipe requirements, raw material be uniformly mixed, then will be after mixing Raw material heats 45~70 minutes under the conditions of 280~300 DEG C, extends 3~4 times, the net of 25~35 mesh meshes is made into, by what is obtained Net carries out fulling milling processing under the conditions of 200 DEG C using molding machine to get the substrate is arrived;
(2) preparation of scavenging material: required raw material is accurately weighed according to recipe requirements, raw material is added sequentially to water and sodium metasilicate Solution in, be put into high-speed stirred kettle and be stirred, wherein mixing speed be 3000 revs/min, mixing time 2 hours, obtain Then mixed solution is carried out ultrasonic disperse processing by mixed solution, ultrasonic disperse frequency is 30kHz, and bath temperature is 35 DEG C, is surpassed The sound time is 40 minutes, and the mixed solution after ultrasonic treatment is stood 6 hours to get the scavenging material is arrived;
(3) adhesive is added into scavenging material obtained by step (2), stirs evenly, substrate obtained by step (1) is then immersed it Middle immersion 20h makes scavenging material be attached to substrate surface, arrives the clearing window net after drying under the conditions of 150~180 DEG C;
The sterilization expelling parasite particle packet is made by following methods:
20 parts of water are added in reaction vessel, 5 parts of mite suppressors, 8 parts of antibacterial agents and 7 portions of pest repellants are sequentially added under stirring condition, 30~50min of stirring is uniformly mixed under the conditions of room temperature, mixing speed are 200~250 revs/min, and it is spare to obtain solution A;By 8 parts of β- Cyclodextrin is mixed with 15 parts of water, 65 DEG C, mixing speed be 200 revs/min under the conditions of stir 50min, make its heating for dissolving, obtain molten Liquid B;Under the conditions of low whipping speed is 250 revs/min, temperature is 65 DEG C, solution A is added dropwise in solution B, is then stirred It is cooling after 50min, coat beta-cyclodextrin by pest repellant to get the sterilization expelling parasite particle packet is arrived.
2. haze window net as described in claim 1, it is characterised in that: the mite suppressor is the benzene first that weight ratio is 1:1.5 The mixture of acid benzyl ester and diethyl phthalate;The antibacterial agent is the mixed of the fennel oil that weight ratio is 1:2 and tea oil Close object;The pest repellant is the mixture of the fluorine chlorine ether pyrethroids that weight ratio is 1:1.2 and ES Esbiothrin.
3. haze window net as described in claim 1, it is characterised in that: the acid modification infusorial earth is made by following methods:
By the diatomite of 10 parts by weight be added to 20 parts of mass fractions be 30% nitric acid solution in, be put into high-speed stirred kettle into Row stirring, wherein mixing speed is 2000~2500 revs/min, mixing time 1.5~2 hours, obtains mixed solution, then will mix It closes solution to be placed into microwave generator, carries out ultrasonic disperse processing, ultrasonic disperse frequency is 25kHz, and bath temperature is 35 DEG C, Ultrasonic time is 40~60min, by mixed solution filtering, the washing after ultrasonic treatment, under the conditions of 180~200 DEG C drying to get To the sour modification infusorial earth.
4. haze window net as described in claim 1, it is characterised in that: the humic acid is by raw material peat and lignite with smelly Oxygen carries out oxidized activating processing, and obtained after purification of alkalizing, wherein the content of organic matter >=87%, humic acid >=75%.
5. haze window net as described in claim 1, it is characterised in that: the adhesive is the silicon that weight ratio is 1:1.5:2 Colloidal sol, self-crosslinking acrylic ester adhesive, aqueous polyurethane adhesive mixture.
6. haze window net as described in claim 1, it is characterised in that: the first dedusting window net and the second dedusting window net The water conservancy diversion direction of mesh is wave-shaped.
7. haze window net as described in claim 1, it is characterised in that: the diameter of the porous basalt fiber is 150 ~200 μm, length is 0.1mm~1mm, and porosity is 70%~80%, and hole diameter is 50~60nm.
8. haze window net as described in claim 1, it is characterised in that: the molecular weight of the ultra-high molecular weight polyethylene is 150~2,000,000.
9. haze window net as described in claim 1, it is characterised in that: the average grain diameter of the nano-titanium dioxide is 10 ~15nm.
CN201611170753.2A 2016-12-16 2016-12-16 An anti-fog and haze window net Active CN106693530B (en)

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