CN106674804A - Light-weight high-toughness PVC foamed trough plate for display panel - Google Patents
Light-weight high-toughness PVC foamed trough plate for display panel Download PDFInfo
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- CN106674804A CN106674804A CN201611132636.7A CN201611132636A CN106674804A CN 106674804 A CN106674804 A CN 106674804A CN 201611132636 A CN201611132636 A CN 201611132636A CN 106674804 A CN106674804 A CN 106674804A
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- parts
- neutrality
- zeolite powder
- bombax cotton
- pretreatment
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Links
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 65
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000010457 zeolite Substances 0.000 claims abstract description 65
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 24
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011521 glass Substances 0.000 claims abstract description 14
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 13
- 239000004005 microsphere Substances 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 11
- 239000011280 coal tar Substances 0.000 claims abstract description 11
- 229920001155 polypropylene Polymers 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002250 absorbent Substances 0.000 claims abstract description 10
- 230000002745 absorbent Effects 0.000 claims abstract description 10
- 239000004088 foaming agent Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims abstract description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 9
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 9
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008117 stearic acid Substances 0.000 claims abstract description 9
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 9
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 8
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 244000146553 Ceiba pentandra Species 0.000 claims abstract description 3
- 235000003301 Ceiba pentandra Nutrition 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 claims abstract 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract 2
- 239000000843 powder Substances 0.000 claims description 65
- 241000219146 Gossypium Species 0.000 claims description 64
- 238000000034 method Methods 0.000 claims description 41
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 33
- 239000004800 polyvinyl chloride Substances 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 239000006260 foam Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 20
- 238000000926 separation method Methods 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 18
- 238000010792 warming Methods 0.000 claims description 16
- 239000004593 Epoxy Substances 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 229950000845 politef Drugs 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 239000003643 water by type Substances 0.000 claims description 9
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910000077 silane Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000007654 immersion Methods 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 239000004677 Nylon Substances 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 229940116364 hard fat Drugs 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000011806 microball Substances 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 229920001778 nylon Polymers 0.000 claims 1
- 229940058401 polytetrafluoroethylene Drugs 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 19
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 5
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- ILRSCQWREDREME-UHFFFAOYSA-N lauric acid amide propyl betaine Natural products CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 3
- 230000013011 mating Effects 0.000 description 3
- 235000019082 Osmanthus Nutrition 0.000 description 2
- 241000333181 Osmanthus Species 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 2
- QQGISFDJEJMKIL-JAIQZWGSSA-N (5z)-5-[[3-(hydroxymethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1CO QQGISFDJEJMKIL-JAIQZWGSSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- GCAIEATUVJFSMC-UHFFFAOYSA-N benzenetetracarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a light-weight high-toughness PVC foamed trough plate for a display panel. The trough plate comprises the following raw materials in parts by weight: 50-70 parts of PVC resin, 4-8 parts of polytetrafluoroethylene, 4-10 parts of polypropylene, 0.8-1.2 parts of dibenzoyl peroxide, 1.5-2.5 parts of 2-thiol benzimidazole, 0.3-0.9 part of pyromellitic dianhydride, 1.5-2.5 parts of coal tar, 0.4-1 part of dibutyl phthalate, 1.5-2.5 parts of stearic acid, 1-2 parts of triphenyl phosphate, 0.4-1 part of disproportionated rosin, 4-8 parts of ceramic microspheres, 4-8 parts of polyamide fibers, 3-7 parts of glass beads, 20-30 parts of zeolite power compound kapok fibers, 4-8 parts of a silane coupling agent KH550, 6-10 parts of white carbon black, 4-8 parts of magnesium hydroxide, 3-7 parts of a foaming agent, 1.5-2.5 parts of an ultraviolet absorbent and 1-2 parts of an anti-aging agent.
Description
Technical field
The present invention relates to PVC technical fields, more particularly to a kind of panel light weight high tenacity PVC foam frid.
Background technology
Panel is generally fixed to display on wall or display rack, for display or the article of sale.In prior art, exhibition
Plate is a big plate, and suspension groove is provided with panel, and article is suspended on suspension groove by suspender, due to PVC foam frid quality
It is light and pliability is good, it is widely used in panel, but the hardness of traditional PVC foam frid is relatively low, although there is higher-strength
PVC foam plate, but heavier mass, can not meet panel wall hanging requirement, and it easily drops, and how to make a kind of light weight, and resistance to
Good, the panel current technical issues that need to address of light weight high tenacity PVC foam frid cost of good toughness of mill property.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of panel light weight high tenacity PVC foam groove
Plate, light weight, and wearability are good, good toughness.
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
Fat 50-70 parts, politef 4-8 parts, polypropylene 4-10 parts, dibenzoyl peroxide 0.8-1.2 parts, 2- mercaptos benzene a pair of horses going side by side miaow
Azoles 1.5-2.5 parts, pyromellitic dianhydride 0.3-0.9 parts, coal tar 1.5-2.5 parts, dibutyl phthalate 0.4-1 parts, firmly
Fat acid 1.5-2.5 parts, triphenyl phosphate 1-2 parts, disproportionated rosin 0.4-1 parts, ceramic microsphere 4-8 parts, Fypro 4-8 parts,
Glass microballoon 3-7 parts, the compound bombax cotton 20-30 parts of zeolite powder, Silane coupling agent KH550 4-8 parts, white carbon 6-10 parts, hydrogen
Magnesium oxide 4-8 parts, foaming agent 3-7 parts, UV absorbent 1.5-2.5 part, age resistor 1-2 parts.
Preferably, polyvinyl chloride resin, politef, polypropylene, dibenzoyl peroxide, 2- mercapto benzimidazoles, equal benzene
The weight ratio of tetracarboxylic acid anhydride is 55-65：5-7：6-8：0.9-1.1：1.8-2.2：0.5-0.7.
Preferably, ceramic microsphere, Fypro, glass microballoon, zeolite powder compound bombax cotton, silane coupler
The weight ratio of KH550 is 5-7：5-7：4-6：22-28：5-7.
Preferably, its raw material includes by weight：Polyvinyl chloride resin 55-65 parts, politef 5-7 parts, polypropylene 6-8 parts,
Dibenzoyl peroxide 0.9-1.1 parts, 2- mercapto benzimidazole 1.8-2.2 parts, pyromellitic dianhydride 0.5-0.7 parts, coal tar
Oily 1.8-2.2 parts, dibutyl phthalate 0.6-0.8 parts, stearic acid 1.8-2.2 parts, triphenyl phosphate 1.2-1.8 parts, discrimination
Change Colophonium 0.6-0.8 parts, ceramic microsphere 5-7 parts, Fypro 5-7 parts, glass microballoon 4-6 parts, the compound kapok of zeolite powder is fine
Dimension 22-28 parts, Silane coupling agent KH550 5-7 parts, white carbon 7-9 parts, magnesium hydroxide 5-7 parts, foaming agent 4-6 parts, ultraviolet
Absorbent 1.8-2.2 parts, age resistor 1.2-1.8 parts.
Preferably, the compound bombax cotton of zeolite powder is prepared using following technique：Bombax cotton, salpeter solution are heated up and stirred
Mix, filter, wash to neutrality, add in isopropanol and soak, filter, wash to neutrality, add dehydrated alcohol, epoxychloropropane,
Heat up stirring, and washing is dried to obtain pretreatment bombax cotton；By dehydrated alcohol, γ-(oxygen of 2,3- epoxies third) propyl trimethoxy
Silane, zeolite powder heat up and stir, cooling, solid-liquid separation, wash to neutrality, add deionized water, lauroylamidopropyl betaine,
Supersound process, solid-liquid separation is washed to neutrality, is dried to obtain pretreatment zeolite powder；By pretreatment bombax cotton, pretreatment zeolite
Powder, deionized water mix homogeneously, nitrogen protection is lower to heat up, and supersound process is separated, and solidss are washed to neutrality, dry, pulverize
To the compound bombax cotton of zeolite powder.
Preferably, the compound bombax cotton of zeolite powder is prepared using following technique：By weight by 20-30 part bombax cottons,
70-90 parts concentration heats up for the salpeter solution of 2-2.4mol/L and stirs, and filters, and washs to neutrality, adds 20-30 part isopropyl alcohol leaching
Bubble, filters, and washs to neutrality, adds 35-55 part dehydrated alcohol, 25-45 part epoxychloropropane, and heat up stirring, washing, dry
To pretreatment bombax cotton；By weight by 45-65 part dehydrated alcohol, 4-8 part γ-(oxygen of 2,3- epoxies third) propyl trimethoxy
Silane, 14-22 parts zeolite powder heat up and stir, cooling, solid-liquid separation, wash to neutrality, add 55-85 part deionized waters, 2-6 parts
Lauroylamidopropyl betaine, supersound process, solid-liquid separation is washed to neutrality, is dried to obtain pretreatment zeolite powder；By weight
10-20 part pretreatment bombax cottons, 15-35 part pretreatment zeolite powders, 100-140 part deionized water mix homogeneously, nitrogen are protected
Shield is lower to heat up, and supersound process is separated, and solidss are washed to neutrality, dry, pulverize and obtains the compound bombax cotton of zeolite powder.
Preferably, the compound bombax cotton of zeolite powder is prepared using following technique：By weight by 20-30 part bombax cottons,
70-90 parts concentration is warming up to 62-70 DEG C of stirring 25-45min for the salpeter solution of 2-2.4mol/L, filters, and washs to neutrality, plus
Enter 20-30 parts isopropanol immersion 4-8h, filter, wash to neutrality, add 35-55 part dehydrated alcohol, 25-45 part epoxy chloropropionates
Alkane, is warming up to 70-80 DEG C of stirring 25-55min, and washing is dried to obtain pretreatment bombax cotton；By weight by 45-65 part nothings
Water-ethanol, 4-8 part γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane, 14-22 part zeolite powders are warming up to 70-80 DEG C of stirring
15-25min, cooling, solid-liquid separation is washed to neutrality, adds 55-85 part deionized waters, 2-6 part dodecanamide propyl Radix Betaes
Alkali, supersound process 30-40min, the frequency of supersound process is 20-25kHz, and solid-liquid separation is washed to neutrality, is dried to obtain pre- place
Reason zeolite powder；By weight by 10-20 part pretreatment bombax cottons, 15-35 part pretreatment zeolite powders, 100-140 part deionizations
Water mix homogeneously, under nitrogen protection 65-75 DEG C is warming up to, supersound process 10-16min, and the frequency of supersound process is 25-35kHz,
Separate, solidss are washed to neutrality, dry, pulverize and obtain the compound bombax cotton of zeolite powder.
The present invention is obtained using conventional fabrication process.
The present invention adopts polyvinyl chloride resin, polypropylene, politef as base material, with dibenzoyl peroxide, equal benzene tetramethyl
Anhydride, 2- mercapto benzimidazole mating reactions, not only wearability is good after solidification, and excellent in mechanical performance；It is multiple in zeolite powder
In closing the pretreatment bombax cotton of bombax cotton, cocamido propyl betaine is rolled into a ball and amido functionality containing alkyl functional, acyl
There is amido good activity can be combined with various groups, and bombax cotton through oxidation with epoxidation process after, can be with coconut palm
Oleamide CAB is acted on, and not only high mechanical strength, and adsorption capacity is big, and in pretreatment zeolite powder lauramide
CAB can effectively reduce storeroom interfacial tension, while the adjustment effect that bonds is good, with γ-(2,3- the third oxygen of epoxy) propyl group
Trimethoxy silane, zeolite powder mating reaction, high adsorption capacity, and emulsifying activity is good mixes point with pretreatment bombax cotton
Scattered property is fabulous, and under nitrogen protection after supersound process, mutual combination degree is high, excellent in mechanical performance, good toughness, weight
Gently；The compound bombax cotton of zeolite powder and Fypro, ceramic microsphere, glass microballoon mating reaction, and add appropriate silane idol
Connection agent KH550, storeroom can form height cross-linked network, make toughness of the present invention, wearability good, light weight, and tricresyl phosphate
Phenyl ester, dibutyl phthalate, stearic acid, disproportionated rosin, coal tar can effectively promote to be uniformly dispersed between said components, make this
Invention surface flatness is high, and wearability is good, and toughness is further enhanced.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
50 parts of fat, 8 parts of politef, 4 parts of polypropylene, 1.2 parts of dibenzoyl peroxide, 1.5 parts of 2- mercaptos benzimidazole, equal benzene
0.9 part of tetracarboxylic acid anhydride, 1.5 parts of coal tar, 1 part of dibutyl phthalate, 1.5 parts of stearic acid, 2 parts of triphenyl phosphate, disproportionation
0.4 part of Colophonium, 8 parts of ceramic microsphere, 4 parts of Fypro, 7 parts of glass microballoon, zeolite powder is combined 20 parts of bombax cotton, silane idol
8 parts of connection agent KH550,6 parts of white carbon, 8 parts of magnesium hydroxide, 3 parts of foaming agent, 2.5 parts of UV absorbent, 1 part of age resistor.
Embodiment 2
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
70 parts of fat, 4 parts of politef, 10 parts of polypropylene, 0.8 part of dibenzoyl peroxide, 2.5 parts of 2- mercaptos benzimidazole,
0.3 part of benzene tetracarboxylic acid acid anhydride, 2.5 parts of coal tar, 0.4 part of dibutyl phthalate, 2.5 parts of stearic acid, 1 part of triphenyl phosphate,
1 part of disproportionated rosin, 4 parts of ceramic microsphere, 8 parts of Fypro, 3 parts of glass microballoon, zeolite powder is combined 30 parts of bombax cotton, silane
Coupling agent KH5504 parts, 10 parts of white carbon, 4 parts of magnesium hydroxide, 7 parts of foaming agent, 1.5 parts of UV absorbent, 2 parts of age resistor.
The compound bombax cotton of zeolite powder is prepared using following technique：Bombax cotton, salpeter solution are heated up and are stirred, filtered,
Wash to neutrality, add in isopropanol and soak, filter, wash to neutrality, add dehydrated alcohol, epoxychloropropane, heat up stirring,
Washing, is dried to obtain pretreatment bombax cotton；By dehydrated alcohol, γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane, zeolite
Powder heats up stirring, and cooling, solid-liquid separation is washed to neutrality, adds deionized water, lauroylamidopropyl betaine, supersound process,
Solid-liquid separation, washs to neutrality, is dried to obtain pretreatment zeolite powder；By pretreatment bombax cotton, pretreatment zeolite powder, deionization
Water mix homogeneously, nitrogen protection is lower to heat up, and supersound process is separated, and solidss wash to neutrality, dry, pulverize and obtain zeolite powder
Compound bombax cotton.
Embodiment 3
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
65 parts of fat, 5 parts of politef, 8 parts of polypropylene, 0.9 part of dibenzoyl peroxide, 2.2 parts of 2- mercaptos benzimidazole, equal benzene
0.5 part of tetracarboxylic acid anhydride, 2.2 parts of coal tar, 0.6 part of dibutyl phthalate, 2.2 parts of stearic acid, 1.2 parts of triphenyl phosphate,
0.8 part of disproportionated rosin, 5 parts of ceramic microsphere, 7 parts of Fypro, 4 parts of glass microballoon, zeolite powder is combined 28 parts of bombax cotton, silicon
Alkane coupling agent KH5505 parts, 9 parts of white carbon, 5 parts of magnesium hydroxide, 6 parts of foaming agent, 1.8 parts of UV absorbent, age resistor 1.8
Part.
The compound bombax cotton of zeolite powder is prepared using following technique：It is by 25 parts of bombax cottons, 80 parts of concentration by weight
The salpeter solution of 2.2mol/L heats up and stirs, and filters, and washs to neutrality, adds 25 parts of isopropanols immersions, filters, and washs into
Property, 45 parts of dehydrated alcohol, 35 parts of epoxychloropropane are added, heat up stirring, washing, is dried to obtain pretreatment bombax cotton；By weight
55 parts of dehydrated alcohol, 6 parts of γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicanes, 18 parts of zeolite powders are heated up and are stirred by amount part, cold
But, solid-liquid separation, washs to neutrality, adds 70 parts of deionized waters, 4 parts of lauroylamidopropyl betaines, supersound process, solid-liquid point
From, wash to neutrality, it is dried to obtain pretreatment zeolite powder；By weight by 15 parts of pretreatment bombax cottons, 25 parts of pretreatment boilings
Stone powder, 120 parts of deionized water mix homogeneously, nitrogen protection is lower to heat up, and supersound process is separated, and solidss are washed to neutrality, is done
Dry, crushing obtains the compound bombax cotton of zeolite powder.
Embodiment 4
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
55 parts of fat, 7 parts of politef, 6 parts of polypropylene, 1.1 parts of dibenzoyl peroxide, 1.8 parts of 2- mercaptos benzimidazole, equal benzene
0.7 part of tetracarboxylic acid anhydride, 1.8 parts of coal tar, 0.8 part of dibutyl phthalate, 1.8 parts of stearic acid, 1.8 parts of triphenyl phosphate,
0.6 part of disproportionated rosin, 7 parts of ceramic microsphere, 5 parts of Fypro, 6 parts of glass microballoon, zeolite powder is combined 22 parts of bombax cotton, silicon
Alkane coupling agent KH5507 parts, 7 parts of white carbon, 7 parts of magnesium hydroxide, 4 parts of foaming agent, 2.2 parts of UV absorbent, age resistor 1.2
Part.
The compound bombax cotton of zeolite powder is prepared using following technique：It is by 20 parts of bombax cottons, 90 parts of concentration by weight
The salpeter solution of 2mol/L is warming up to 70 DEG C of stirring 25min, filters, and washs to neutrality, adds 30 parts of isopropanols to soak 4h, mistake
Filter, washs to neutrality, adds 55 parts of dehydrated alcohol, 25 parts of epoxychloropropane, is warming up to 80 DEG C of stirring 25min, washs, dry
To pretreatment bombax cotton；By weight by 65 parts of dehydrated alcohol, 4 parts of γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicanes,
22 parts of zeolite powders are warming up to 70 DEG C of stirring 25min, and cooling, solid-liquid separation is washed to neutrality, add 55 parts of deionized waters, 6 parts months
Osmanthus amido propyl betaine, supersound process 30min, the frequency of supersound process is 25kHz, and solid-liquid separation is washed to neutrality, is dried
Obtain pretreatment zeolite powder；By weight by 10 parts of pretreatment bombax cottons, 35 parts of pretreatment zeolite powders, 100 parts of deionized waters
Mix homogeneously, under nitrogen protection 75 DEG C are warming up to, supersound process 10min, and the frequency of supersound process is 35kHz, is separated, solidss
Wash to neutrality, dry, pulverize and obtain the compound bombax cotton of zeolite powder.
Embodiment 5
A kind of panel proposed by the present invention light weight high tenacity PVC foam frid, its raw material includes by weight：PVC trees
60 parts of fat, 6 parts of politef, 7 parts of polypropylene, 1 part of dibenzoyl peroxide, 2 parts of 2- mercaptos benzimidazole, equal benzene tetramethyl
0.6 part of anhydride, 2 parts of coal tar, 0.7 part of dibutyl phthalate, 2 parts of stearic acid, 1.5 parts of triphenyl phosphate, disproportionated rosin
0.7 part, 6 parts of ceramic microsphere, 6 parts of Fypro, 5 parts of glass microballoon, zeolite powder is combined 25 parts of bombax cotton, silane coupler
6 parts of KH550,8 parts of white carbon, 6 parts of magnesium hydroxide, 5 parts of foaming agent, 2 parts of UV absorbent, 1.5 parts of age resistor.
The compound bombax cotton of zeolite powder is prepared using following technique：It is by 30 parts of bombax cottons, 70 parts of concentration by weight
The salpeter solution of 2.4mol/L is warming up to 62 DEG C of stirring 45min, filters, and washs to neutrality, adds 20 parts of isopropanols to soak 8h, mistake
Filter, washs to neutrality, adds 35 parts of dehydrated alcohol, 45 parts of epoxychloropropane, is warming up to 70 DEG C of stirring 55min, washs, dry
To pretreatment bombax cotton；By weight by 45 parts of dehydrated alcohol, 8 parts of γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicanes,
14 parts of zeolite powders are warming up to 80 DEG C of stirring 15min, and cooling, solid-liquid separation is washed to neutrality, add 85 parts of deionized waters, 2 parts months
Osmanthus amido propyl betaine, supersound process 40min, the frequency of supersound process is 20kHz, and solid-liquid separation is washed to neutrality, is dried
Obtain pretreatment zeolite powder；By weight by 20 parts of pretreatment bombax cottons, 15 parts of pretreatment zeolite powders, 140 parts of deionized waters
Mix homogeneously, under nitrogen protection 65 DEG C are warming up to, supersound process 16min, and the frequency of supersound process is 25kHz, is separated, solidss
Wash to neutrality, dry, pulverize and obtain the compound bombax cotton of zeolite powder.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of panel light weight high tenacity PVC foam frid, it is characterised in that its raw material includes by weight：Polyvinyl chloride resin
50-70 parts, politef 4-8 parts, polypropylene 4-10 parts, dibenzoyl peroxide 0.8-1.2 parts, 2- mercapto benzimidazoles
1.5-2.5 parts, pyromellitic dianhydride 0.3-0.9 parts, coal tar 1.5-2.5 parts, dibutyl phthalate 0.4-1 parts, Hard Fat
Sour 1.5-2.5 parts, triphenyl phosphate 1-2 parts, disproportionated rosin 0.4-1 parts, ceramic microsphere 4-8 parts, Fypro 4-8 parts, glass
Glass microballon 3-7 parts, the compound bombax cotton 20-30 parts of zeolite powder, Silane coupling agent KH550 4-8 parts, white carbon 6-10 parts, hydrogen-oxygen
Change magnesium 4-8 parts, foaming agent 3-7 parts, UV absorbent 1.5-2.5 part, age resistor 1-2 parts.
2. panel light weight high tenacity PVC foam frid according to claim 1, it is characterised in that polyvinyl chloride resin, polytetrafluoro
Ethylene, polypropylene, dibenzoyl peroxide, 2- mercapto benzimidazoles, the weight ratio of pyromellitic dianhydride are 55-65：5-7：
6-8：0.9-1.1：1.8-2.2：0.5-0.7.
3. panel according to claim 1 or claim 2 light weight high tenacity PVC foam frid, it is characterised in that ceramic microsphere, poly-
Nylon, glass microballoon, zeolite powder are combined bombax cotton, the weight ratio of Silane coupling agent KH550 is 5-7：5-7：4-6：22-
28：5-7.
4. the panel light weight high tenacity PVC foam frid according to any one of claim 1-3, it is characterised in that its raw material
Include by weight：Polyvinyl chloride resin 55-65 parts, politef 5-7 parts, polypropylene 6-8 parts, dibenzoyl peroxide 0.9-1.1
Part, 2- mercapto benzimidazole 1.8-2.2 parts, pyromellitic dianhydride 0.5-0.7 parts, coal tar 1.8-2.2 parts, phthalic acid
Dibutyl ester 0.6-0.8 parts, stearic acid 1.8-2.2 parts, triphenyl phosphate 1.2-1.8 parts, disproportionated rosin 0.6-0.8 parts, ceramics are micro-
Ball 5-7 parts, Fypro 5-7 parts, glass microballoon 4-6 parts, the compound bombax cotton 22-28 parts of zeolite powder, silane coupler
KH550 5-7 parts, white carbon 7-9 parts, magnesium hydroxide 5-7 parts, foaming agent 4-6 parts, UV absorbent 1.8-2.2 part prevents old
Agent 1.2-1.8 parts.
5. the panel light weight high tenacity PVC foam frid according to any one of claim 1-4, it is characterised in that zeolite powder
Compound bombax cotton is prepared using following technique：Bombax cotton, salpeter solution are heated up and is stirred, filtered, washed to neutrality, added
Soak in isopropanol, filter, wash to neutrality, add dehydrated alcohol, epoxychloropropane, heat up stirring, washing is dried to obtain pre-
Process bombax cotton；Dehydrated alcohol, γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, zeolite powder are heated up and is stirred, it is cold
But, solid-liquid separation, washs to neutrality, adds deionized water, lauroylamidopropyl betaine, supersound process, solid-liquid separation, washing
To neutral, pretreatment zeolite powder is dried to obtain；By pretreatment bombax cotton, pretreatment zeolite powder, deionized water mix homogeneously, nitrogen
Heat up under gas shielded, supersound process is separated, and solidss are washed to neutrality, dry, pulverize and obtain the compound bombax cotton of zeolite powder.
6. the panel light weight high tenacity PVC foam frid according to any one of claim 1-5, it is characterised in that zeolite powder
Compound bombax cotton is prepared using following technique：It is 2-2.4mol/ by weight by 20-30 part bombax cottons, 70-90 parts concentration
The salpeter solution of L heats up and stirs, and filters, and washs to neutrality, adds the immersion of 20-30 parts isopropanol, filters, and washs to neutrality, plus
Enter 35-55 part dehydrated alcohol, 25-45 part epoxychloropropane, heat up stirring, washing is dried to obtain pretreatment bombax cotton；By weight
Part is measured by 45-65 part dehydrated alcohol, 4-8 part γ-(oxygen of 2,3- epoxies third) propyl trimethoxy silicane, 14-22 part zeolite powder liters
Temperature stirring, cooling, solid-liquid separation is washed to neutrality, adds 55-85 part deionized waters, 2-6 part lauroylamidopropyl betaines,
Supersound process, solid-liquid separation is washed to neutrality, is dried to obtain pretreatment zeolite powder；By weight by 10-20 part pretreatment kapoks
Fiber, 15-35 part pretreatment zeolite powders, 100-140 part deionized water mix homogeneously, nitrogen protection is lower to heat up, supersound process, point
From solidss are washed to neutrality, be dry, pulverize and are obtained the compound bombax cotton of zeolite powder.
7. the panel light weight high tenacity PVC foam frid according to any one of claim 1-6, it is characterised in that zeolite powder
Compound bombax cotton is prepared using following technique：It is 2-2.4mol/ by weight by 20-30 part bombax cottons, 70-90 parts concentration
The salpeter solution of L is warming up to 62-70 DEG C of stirring 25-45min, filters, and washs to neutrality, adds 20-30 parts isopropanol immersion 4-
8h, filters, and washs to neutrality, adds 35-55 part dehydrated alcohol, 25-45 part epoxychloropropane, is warming up to 70-80 DEG C of stirring 25-
55min, washing, is dried to obtain pretreatment bombax cotton；By weight by 45-65 part dehydrated alcohol, 4-8 part γ-(2,3- epoxies
Third oxygen) propyl trimethoxy silicane, 14-22 part zeolite powders be warming up to 70-80 DEG C of stirring 15-25min, and cooling, solid-liquid separation is washed
Wash to neutrality, add 55-85 part deionized waters, 2-6 part lauroylamidopropyl betaines, supersound process 30-40min, at ultrasound
The frequency of reason is 20-25kHz, and solid-liquid separation is washed to neutrality, is dried to obtain pretreatment zeolite powder；By weight by 10-20 parts
Pretreatment bombax cotton, 15-35 part pretreatment zeolite powders, 100-140 part deionized water mix homogeneously, are warming up under nitrogen protection
65-75 DEG C, supersound process 10-16min, the frequency of supersound process is 25-35kHz, is separated, and solidss are washed to neutrality, are dried,
Crushing obtains the compound bombax cotton of zeolite powder.
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| CN201611132636.7A CN106674804A (en) | 2016-12-09 | 2016-12-09 | Light-weight high-toughness PVC foamed trough plate for display panel |
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| CN108797143A (en) * | 2018-07-27 | 2018-11-13 | 加通汽车内饰(常熟)有限公司 | A kind of automobile-used artificial leather of lightweight and preparation method thereof with wear-resisting epidermis |
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