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CN106671634B - A kind of production technology preparing cladding using laser marking machine - Google Patents

A kind of production technology preparing cladding using laser marking machine Download PDF

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Publication number
CN106671634B
CN106671634B CN201710022138.5A CN201710022138A CN106671634B CN 106671634 B CN106671634 B CN 106671634B CN 201710022138 A CN201710022138 A CN 201710022138A CN 106671634 B CN106671634 B CN 106671634B
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marking machine
leather
laser marking
laser
parts
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CN106671634A (en
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陈承涛
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Guangdong Tianyi New Material Technology Co ltd
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Dongguan City Tian Yi Paper Industry Science And Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M3/00Printing processes to produce particular kinds of printed work, e.g. patterns
    • B41M3/06Veined printings; Fluorescent printings; Stereoscopic images; Imitated patterns, e.g. tissues, textiles
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C09D123/30Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by oxidation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/24Homopolymers or copolymers of amides or imides
    • C09D133/26Homopolymers or copolymers of acrylamide or methacrylamide
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/44Mechanical treatment of leather surfaces
    • C14B1/56Ornamenting, producing designs, embossing
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/58Drying
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B2700/00Mechanical treatment or processing of skins, hides or leather in general; Pelt-shearing machines; Making driving belts; Machines for splitting intestines
    • C14B2700/07Leather tensioning or stretching frames; Stretching-machines; Setting-out boards; Pasting boards; Fastening devices; Drying of leather

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Vascular Medicine (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to leather processing technique fields, and in particular to a kind of production technology being prepared cladding using laser marking machine is included the following steps:(1)Selection:Sheepskin, pigskin or the ox-hide cladding scraped using inferior grade and surface spinosity are as scytoblastema;(2)It draws a design:It is drawn a design by the computer of laser marking machine, output pattern;(3)Laser engraving:The pattern of output concave-convex sense and relief lines have been provided into laser marking machine in cladding surface engraving.The production craft step of the present invention is simple, convenient operation and control, stable quality, and production efficiency is high, and raw material is cheap and easy to get, and cladding utilization rate is high, and production cost is low, can large-scale industrial production;The quality of finished product cladding obtained is close with first layer lether material, can be widely used in the fabric of the products such as footwear material, luggage, handbag, dress ornament and furniture, greatly improves the added value of the cladding.

Description

一种利用激光镭射打标机制备皮料的生产工艺A production process for preparing leather by using a laser laser marking machine

技术领域technical field

本发明涉及皮革加工技术领域,具体涉及一种利用激光镭射打标机制备皮料的生产工艺。The invention relates to the technical field of leather processing, in particular to a production process for preparing leather by using a laser marking machine.

背景技术Background technique

皮革大量应用于民生用品的表面,例如桌椅、沙发、鞋材、衣物等等,增添民生用品的质感、美感或耐用性。皮革可大致分为人造皮革与天然皮革。天然皮革指取动物毛皮并予以干燥、清洗、软化、染色、修边、裁切等制作工艺处理之后,形成表面平整且质地坚韧的皮料。Leather is widely used on the surface of daily necessities, such as tables and chairs, sofas, shoe materials, clothing, etc., to add texture, beauty or durability to daily necessities. Leather can be broadly classified into artificial leather and natural leather. Natural leather refers to taking animal fur and drying, cleaning, softening, dyeing, trimming, cutting and other production processes to form a smooth surface and tough texture.

现有的低等级且表面有刺刮的羊皮、猪皮或牛皮由于细度不够,光泽度差,只能用于制作皮料的内里,不能作为产品的面层材料来使用,应用范围受到限制,制得的皮料的经济效益不高。The existing low-grade sheepskin, pigskin or cowhide with thorns and scratches on the surface can only be used to make the inner lining of the leather because of its insufficient fineness and poor gloss. It cannot be used as the surface material of the product, and its application range is limited , the economic benefit of the leather material that makes is not high.

发明内容Contents of the invention

为了克服现有技术中存在的缺点和不足,本发明的目的在于提供一种利用激光镭射打标机制备皮料的生产工艺,该生产工艺步骤简单,操作控制方便,质量稳定,生产效率高,原料廉价易得,皮料利用率高,生产成本低,可大规模工业化生产;制得的成品皮料的品质与头层皮料相近,可大量应用于鞋材、箱包、手袋、服饰和家具等产品的面料,大大提升了该皮料的附加值。In order to overcome the shortcomings and deficiencies existing in the prior art, the object of the present invention is to provide a production process for preparing leather by using a laser laser marking machine. The production process has simple steps, convenient operation and control, stable quality, and high production efficiency. The raw materials are cheap and easy to obtain, the utilization rate of the leather is high, the production cost is low, and it can be industrialized on a large scale; the quality of the finished leather is similar to that of the top layer of leather, and it can be widely used in shoe materials, bags, handbags, clothing and furniture The fabrics of such products have greatly improved the added value of the leather.

本发明的目的通过下述技术方案实现:一种利用激光镭射打标机制备皮料的生产工艺,包括如下步骤:The purpose of the present invention is achieved through the following technical solutions: a production process for preparing leather by using a laser laser marking machine, comprising the following steps:

(1)选材:采用低等级且表面有刺刮的羊皮、猪皮或牛皮皮料作为皮胚;(1) Material selection: use low-grade sheepskin, pigskin or cowhide leather with thorns on the surface as the skin embryo;

(2)绘制图案:通过激光镭射打标机的电脑绘制图案,输出图案;(2) Draw patterns: draw patterns through the computer of the laser marking machine, and output the patterns;

(3)激光雕刻:将输出的图案用激光镭射打标机在皮料表面雕刻出具有凹凸感和立体感的纹路。(3) Laser engraving: Use a laser marking machine to engrave the output pattern on the surface of the leather with a concave-convex and three-dimensional texture.

优选的,所述步骤(2)中,输出的图案为分辨率在1000-2000L/cm的高分辨率图像。Preferably, in the step (2), the output pattern is a high-resolution image with a resolution of 1000-2000 L/cm.

本发明通过将输出的图案分辨率控制在1000-2000L/cm,雕刻出的图案清晰度高,立体美观。In the present invention, by controlling the output pattern resolution to 1000-2000L/cm, the engraved pattern has high definition and three-dimensional appearance.

优选的,所述步骤(3)中,激光雕刻的工艺参数为:电机功率为30-50W,焦距为20-24mm,切割宽度为10-100μm,雕刻深度为0.1-0.2mm,雕刻速度为400-500mm/s。Preferably, in the step (3), the process parameters of laser engraving are: the motor power is 30-50W, the focal length is 20-24mm, the cutting width is 10-100μm, the engraving depth is 0.1-0.2mm, and the engraving speed is 400 -500mm/s.

本发明通过采用上述工艺参数,激光雕刻效果好,制得的成品皮料的品质与头层皮料相近,大大提升了该皮料的附加值。By adopting the above process parameters, the present invention has good effect of laser engraving, and the quality of the finished leather material is similar to that of the top layer leather material, which greatly improves the added value of the leather material.

优选的,所述步骤(1)之后还包括步骤(11)刮补:用刮刀将补伤膏刮补填充在皮胚表面,将刮补后的皮胚放入烘箱中干燥定型,用辊光压板将皮胚压平整,干燥温度为60-100℃,干燥时间为5-10min。Preferably, after the step (1), the step (11) scraping and repairing is also included: use a scraper to scrape and fill the repairing ointment on the surface of the skin embryo, put the scraped skin embryo into an oven to dry and shape it, and use a roller to polish it. The pressing plate presses the leather embryo flat, the drying temperature is 60-100°C, and the drying time is 5-10min.

本发明通过在选材之后进行刮补,可以确保补伤膏的材料能充分嵌入皮胚,能很好得填平粗大的毛孔,制得的皮料的平整度高。In the present invention, by scraping and mending after material selection, it can ensure that the material of the repairing paste can be fully embedded in the skin embryo, and the coarse pores can be well filled up, and the prepared leather material has high smoothness.

优选的,所述补伤膏包括以下重量份的原料:Preferably, the repairing ointment includes the following raw materials in parts by weight:

本发明的补伤膏通过采用上述原料,并严格控制各原料的重量份,制得的补伤膏成膜性好,成膜非常紧实、弹性好,对皮胚的刮伤、划痕、空洞等瑕疵表面具有很好的遮蔽效果,且材料的附着力强能稳定地固定在皮胚上,材料的稳定性好,光泽度佳,赋予皮胚表面优异的平细度,恢复皮胚表面光滑平整,改善制得的皮料的质量,提升皮料附加值。The repairing plaster of the present invention adopts the above-mentioned raw materials and strictly controls the weight of each raw material, so that the prepared wound repairing plaster has good film-forming properties, very tight film formation and good elasticity, and is resistant to scratches, scratches, The surface with holes and other defects has a good masking effect, and the material has strong adhesion and can be stably fixed on the skin. The material has good stability and good gloss, which endows the surface of the skin with excellent flatness and restores the surface of the skin. It is smooth and smooth, improves the quality of the prepared leather material, and increases the added value of the leather material.

优选的,所述增稠剂是由羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮以重量比(1-2):(2-4):1组成的混合物。Preferably, the thickener is a mixture composed of sodium carboxymethylcellulose, organic bentonite and polyvinylpyrrolidone in a weight ratio of (1-2):(2-4):1.

本发明通过采用羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮作为增稠剂复配使用,并控制其重量比为(1-2):(2-4):1,其增稠效果好,制得的制得的补伤膏成膜性好,成膜非常紧实、弹性好。The present invention uses sodium carboxymethyl cellulose, organobentonite and polyvinylpyrrolidone as thickeners, and controls its weight ratio to be (1-2):(2-4):1, which has a good thickening effect , the prepared repair wound ointment has good film-forming property, very tight film-forming and good elasticity.

所述润湿剂是由壬基酚聚氧乙烯醚和十二烷基硫酸钠以重量比1-2:1组成的混合物。The wetting agent is a mixture of nonylphenol polyoxyethylene ether and sodium lauryl sulfate in a weight ratio of 1-2:1.

本发明通过采用壬基酚聚氧乙烯醚和十二烷基硫酸钠作为润湿剂复配使用,并控制其重量比为(1-2):1,去润湿效果好,制得的补伤膏成膜性好,对皮胚的刮伤、划痕、空洞等瑕疵表面具有很好的遮蔽效果。In the present invention, nonylphenol polyoxyethylene ether and sodium lauryl sulfate are compounded and used as a wetting agent, and the weight ratio thereof is controlled to be (1-2): 1, so that the dewetting effect is good, and the prepared supplement The wound ointment has good film-forming properties, and has a good masking effect on the scratches, scratches, cavities and other flawed surfaces of the skin embryo.

优选的,所述流平剂是由有机硅流平剂和丙烯酸酯流平剂以重量比0.8-1.2:1组成的混合物。Preferably, the leveling agent is a mixture of a silicone leveling agent and an acrylate leveling agent in a weight ratio of 0.8-1.2:1.

本发明通过采用有机硅流平剂和丙烯酸酯流平剂作为流平剂复配使用,并控制其重量比为(0.8-1.2):1,其流平效果好,制得的补伤膏稳定性好,光泽度佳,赋予皮胚表面优异的平细度,恢复皮胚表面光滑平整,改善制得的皮料的质量,提升皮料附加值。The present invention adopts silicone leveling agent and acrylate leveling agent as leveling agent compounded use, and controls its weight ratio to be (0.8-1.2): 1, and its leveling effect is good, and the repairing ointment prepared is stable Good resistance, good gloss, endows the surface of the skin with excellent flatness, restores the surface of the skin to be smooth and smooth, improves the quality of the produced leather, and increases the added value of the leather.

所述成膜助剂是由N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚以重量比1:(0.8-1.2):(1.5-2.5)组成的混合物。The film-forming aid is a mixture composed of N-methylpyrrolidone, methylphenyl ether and diethylene glycol butyl ether in a weight ratio of 1:(0.8-1.2):(1.5-2.5).

本发明通过采用N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚作为成膜助剂复配使用,并控制其重量比为1:(0.8-1.2):(1.5-2.5),制得的补伤膏成膜性好,成膜非常紧实、弹性好,对皮胚的刮伤、划痕、空洞等瑕疵表面具有很好的遮蔽效果。The present invention uses N-methylpyrrolidone, methylphenyl ether and diethylene glycol butyl ether as film-forming aids, and controls its weight ratio to be 1:(0.8-1.2):(1.5-2.5), The prepared repairing cream has good film-forming properties, very firm film-forming and good elasticity, and has a good masking effect on the scratches, scratches, cavities and other flawed surfaces of the leather embryo.

优选的,所述步骤(11)之后还包括步骤(22)喷涂:在压平后的皮料表面喷涂遮盖涂料;遮盖涂料由以下重量份的原料组成:Preferably, after the step (11), the step (22) spraying is also included: the covering paint is sprayed on the flattened leather surface; the covering paint is composed of the following raw materials in parts by weight:

本发明的遮盖涂料通过采用上述原料,并严格控制各原料的重量份,制得的遮盖涂料的用成膜性好,压花定型效果好,材料的附着力强,且能对皮胚材料的瑕疵进行调整和遮盖,遮盖效果好。同时还具有防水性和防粘性。The hiding paint of the present invention adopts the above-mentioned raw materials and strictly controls the parts by weight of each raw material, so that the prepared covering paint has good film-forming properties, good embossing and setting effects, strong adhesion of the material, and can be used for the skin material. Blemishes are adjusted and covered with great coverage. It is also waterproof and anti-stick.

优选的,所述步骤(3)之后还包括步骤(4)甩软:将雕刻后的皮胚材料在10-30℃下放置10-24h,在10-30℃下通过甩软转鼓进行甩软1-2h。进甩软转鼓进行甩软加工,使皮身更加柔软,粒面更加细致,提升皮料的手感。Preferably, after the step (3), the step (4) is further included: placing the engraved leather embryo material at 10-30°C for 10-24h, and then passing through a soft-spinning drum at 10-30°C. Soft 1-2h. Enter the softening drum for softening processing, so that the leather body is softer, the grain surface is more delicate, and the hand feeling of the leather is improved.

优选的,所述步骤(4)之后还包括步骤(5)喷手感剂:在甩软加工后的皮料表面喷涂手感剂,所述手感剂由如下重量百分比的原料制成:Preferably, the step (4) also includes step (5) spraying a hand feeling agent after the step (4): spraying a hand feeling agent on the leather surface after softening processing, and the hand feeling agent is made of the following raw materials in weight percentage:

本发明的手感剂通过采用上述原料,并严格控制各原料的重量份,制得的手感剂稳定性好,能储存1年以上,可与多种树脂配伍使用,用作皮革手感剂,喷涂于皮革上快干、不浮油,使皮革柔软、高光泽;且不含有机溶剂,使用安全、符合环境保护的要求。The hand feel agent of the present invention adopts the above-mentioned raw materials and strictly controls the parts by weight of each raw material, so that the prepared hand feel agent has good stability, can be stored for more than one year, can be used in combination with various resins, and is used as a leather feel agent. The leather is quick-drying and does not slick oil, making the leather soft and high-gloss; and it does not contain organic solvents, which is safe to use and meets the requirements of environmental protection.

本发明的有益效果在于:本发明的生产工艺步骤简单,操作控制方便,质量稳定,生产效率高,原料廉价易得,皮料利用率高,生产成本低,可大规模工业化生产。The beneficial effects of the invention are: the production process of the invention has simple steps, convenient operation and control, stable quality, high production efficiency, cheap and easy-to-obtain raw materials, high utilization rate of leather materials, low production cost, and large-scale industrial production.

本发明制得的成品皮料的品质与头层皮料相近,可大量应用于鞋材、箱包、手袋、服饰和家具等产品的面料,大大提升了该皮料的附加值。The quality of the finished leather material prepared by the invention is similar to that of the top layer leather material, and can be widely used in the fabrics of shoe materials, bags, handbags, clothing and furniture, etc., greatly increasing the added value of the leather material.

具体实施方式Detailed ways

为了便于本领域技术人员的理解,下面结合实施例对本发明作进一步的说明,实施方式提及的内容并非对本发明的限定。In order to facilitate the understanding of those skilled in the art, the present invention will be further described below in conjunction with the examples, and the contents mentioned in the embodiments are not intended to limit the present invention.

实施例1Example 1

一种利用激光镭射打标机制备皮料的生产工艺,包括如下步骤:A production process for preparing leather by using a laser laser marking machine, comprising the following steps:

(1)选材:采用低等级且表面有刺刮的羊皮、猪皮或牛皮皮料作为皮胚;(1) Material selection: use low-grade sheepskin, pigskin or cowhide leather with thorns on the surface as the skin embryo;

(2)绘制图案:通过激光镭射打标机的电脑绘制图案,输出图案;(2) Draw patterns: draw patterns through the computer of the laser marking machine, and output the patterns;

(3)激光雕刻:将输出的图案用激光镭射打标机在皮料表面雕刻出具有凹凸感和立体感的纹路。(3) Laser engraving: Use a laser marking machine to engrave the output pattern on the surface of the leather with a concave-convex and three-dimensional texture.

所述步骤(2)中,输出的图案为分辨率在1000L/cm的高分辨率图像。In the step (2), the output pattern is a high-resolution image with a resolution of 1000 L/cm.

所述步骤(3)中,激光雕刻的工艺参数为:电机功率为30W,焦距为20mm,切割宽度为10μm,雕刻深度为0.1mm,雕刻速度为400mm/s。In the step (3), the process parameters of the laser engraving are as follows: the motor power is 30W, the focal length is 20mm, the cutting width is 10μm, the engraving depth is 0.1mm, and the engraving speed is 400mm/s.

所述步骤(1)之后还包括步骤(11)刮补:用刮刀将补伤膏刮补填充在皮胚表面,将刮补后的皮胚放入烘箱中干燥定型,用辊光压板将皮胚压平整,干燥温度为60℃,干燥时间为5min。After the step (1), step (11) scraping and mending is also included: use a scraper to scrape and fill the repairing ointment on the surface of the skin embryo, put the scraped skin embryo into an oven to dry and shape, and use a roller to smooth the skin The embryo is pressed flat, the drying temperature is 60°C, and the drying time is 5 minutes.

所述补伤膏包括以下重量份的原料:Described repairing ointment comprises the raw material of following weight portion:

所述步骤(11)之后还包括步骤(22)喷涂:在压平后的皮料表面喷涂遮盖涂料;遮盖涂料由以下重量份的原料组成:Step (22) spraying is also included after the step (11): spraying a covering paint on the flattened leather surface; the covering paint is composed of the following raw materials in parts by weight:

所述步骤(3)之后还包括步骤(4)甩软:将雕刻后的皮胚材料在10℃下放置10h,在10℃下通过甩软转鼓进行甩软1h。After the step (3), step (4) softening is also included: place the engraved leather embryo material at 10° C. for 10 hours, and then spin it through a softening drum at 10° C. for 1 hour.

所述步骤(4)之后还包括步骤(5)喷手感剂:在甩软加工后的皮料表面喷涂手感剂,所述手感剂由如下重量百分比的原料制成:After the step (4), also include the step (5) of spraying a hand feeling agent: spraying a hand feeling agent on the leather surface after softening processing, and the hand feeling agent is made of the raw materials in the following weight percentages:

实施例2Example 2

本实施例与上述实施例1的区别在于:The difference between this embodiment and above-mentioned embodiment 1 is:

所述步骤(2)中,输出的图案为分辨率在1500L/cm的高分辨率图像。In the step (2), the output pattern is a high-resolution image with a resolution of 1500 L/cm.

所述步骤(3)中,激光雕刻的工艺参数为:电机功率为40W,焦距为22mm,切割宽度为50μm,雕刻深度为0.15mm,雕刻速度为450mm/s。In the step (3), the process parameters of the laser engraving are as follows: the motor power is 40W, the focal length is 22mm, the cutting width is 50μm, the engraving depth is 0.15mm, and the engraving speed is 450mm/s.

所述步骤(1)之后还包括步骤(11)刮补:用刮刀将补伤膏刮补填充在皮胚表面,将刮补后的皮胚放入烘箱中干燥定型,用辊光压板将皮胚压平整,干燥温度为80℃,干燥时间为8min。After the step (1), step (11) scraping and mending is also included: use a scraper to scrape and fill the repairing ointment on the surface of the skin embryo, put the scraped skin embryo into an oven to dry and shape, and use a roller to smooth the skin The embryo is pressed flat, the drying temperature is 80°C, and the drying time is 8 minutes.

所述补伤膏包括以下重量份的原料:Described repairing ointment comprises the raw material of following weight portion:

所述步骤(11)之后还包括步骤(22)喷涂:在压平后的皮料表面喷涂遮盖涂料;遮盖涂料由以下重量份的原料组成:Step (22) spraying is also included after the step (11): spraying a covering paint on the flattened leather surface; the covering paint is composed of the following raw materials in parts by weight:

所述步骤(3)之后还包括步骤(4)甩软:将雕刻后的皮胚材料在20℃下放置16h,在20℃下通过甩软转鼓进行甩软1.5h。After the step (3), step (4) softening is also included: place the engraved leather embryo material at 20° C. for 16 hours, and carry out softening by a spinning drum at 20° C. for 1.5 hours.

所述步骤(4)之后还包括步骤(5)喷手感剂:在甩软加工后的皮料表面喷涂手感剂,所述手感剂由如下重量百分比的原料制成:After the step (4), also include the step (5) of spraying a hand feeling agent: spraying a hand feeling agent on the leather surface after softening processing, and the hand feeling agent is made of the raw materials in the following weight percentages:

实施例3Example 3

本实施例与上述实施例1的区别在于:The difference between this embodiment and above-mentioned embodiment 1 is:

所述步骤(2)中,输出的图案为分辨率在2000L/cm的高分辨率图像。In the step (2), the output pattern is a high-resolution image with a resolution of 2000 L/cm.

所述步骤(3)中,激光雕刻的工艺参数为:电机功率为50W,焦距为24mm,切割宽度为100μm,雕刻深度为0.2mm,雕刻速度为500mm/s。In the step (3), the process parameters of the laser engraving are as follows: the motor power is 50W, the focal length is 24mm, the cutting width is 100μm, the engraving depth is 0.2mm, and the engraving speed is 500mm/s.

所述步骤(1)之后还包括步骤(11)刮补:用刮刀将补伤膏刮补填充在皮胚表面,将刮补后的皮胚放入烘箱中干燥定型,用辊光压板将皮胚压平整,干燥温度为100℃,干燥时间为10min。After the step (1), step (11) scraping and mending is also included: use a scraper to scrape and fill the repairing ointment on the surface of the skin embryo, put the scraped skin embryo into an oven to dry and shape, and use a roller to smooth the skin The embryo is pressed flat, the drying temperature is 100°C, and the drying time is 10 minutes.

所述补伤膏包括以下重量份的原料:Described repairing ointment comprises the raw material of following weight portion:

所述步骤(11)之后还包括步骤(22)喷涂:在压平后的皮料表面喷涂遮盖涂料;遮盖涂料由以下重量份的原料组成:Step (22) spraying is also included after the step (11): spraying a covering paint on the flattened leather surface; the covering paint is composed of the following raw materials in parts by weight:

所述步骤(3)之后还包括步骤(4)甩软:将雕刻后的皮胚材料在30℃下放置24h,在30℃下通过甩软转鼓进行甩软2h。After the step (3), step (4) softening is also included: place the engraved leather embryo material at 30° C. for 24 hours, and then spin it through a softening drum at 30° C. for 2 hours.

所述步骤(4)之后还包括步骤(5)喷手感剂:在甩软加工后的皮料表面喷涂手感剂,所述手感剂由如下重量百分比的原料制成:After the step (4), also include the step (5) of spraying a hand feeling agent: spraying a hand feeling agent on the leather surface after softening processing, and the hand feeling agent is made of the raw materials in the following weight percentages:

实施例4Example 4

本实施例与上述实施例1的区别在于:The difference between this embodiment and above-mentioned embodiment 1 is:

所述增稠剂是由羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮以重量比1:2:1组成的混合物;所述润湿剂是由壬基酚聚氧乙烯醚和十二烷基硫酸钠以重量比1:1组成的混合物。The thickener is a mixture of sodium carboxymethylcellulose, organic bentonite and polyvinylpyrrolidone in a weight ratio of 1:2:1; the wetting agent is made of nonylphenol polyoxyethylene ether and dodecane A mixture of sodium base sulfate in a weight ratio of 1:1.

所述流平剂是由有机硅流平剂和丙烯酸酯流平剂以重量比0.8:1组成的混合物;所述成膜助剂是由N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚以重量比1:0.8:2.5组成的混合物。The leveling agent is a mixture of silicone leveling agent and acrylate leveling agent with a weight ratio of 0.8:1; A mixture of alcohol butyl ether in a weight ratio of 1:0.8:2.5.

实施例5Example 5

本实施例与上述实施例2的区别在于:The difference between this embodiment and the above-mentioned embodiment 2 is:

所述增稠剂是由羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮以重量比1.5:3:1组成的混合物;所述润湿剂是由壬基酚聚氧乙烯醚和十二烷基硫酸钠以重量比1.5:1组成的混合物。The thickener is a mixture of sodium carboxymethylcellulose, organic bentonite and polyvinylpyrrolidone in a weight ratio of 1.5:3:1; the wetting agent is made of nonylphenol polyoxyethylene ether and dodecane A mixture of sodium base sulfate in a weight ratio of 1.5:1.

所述流平剂是由有机硅流平剂和丙烯酸酯流平剂以重量比1.0:1组成的混合物;所述成膜助剂是由N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚以重量比1:1:2组成的混合物。The leveling agent is a mixture of silicone leveling agent and acrylate leveling agent with a weight ratio of 1.0:1; A mixture of alcohol butyl ether in a weight ratio of 1:1:2.

实施例6Example 6

本实施例与上述实施例3的区别在于:The difference between this embodiment and the above-mentioned embodiment 3 is:

所述增稠剂是由羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮以重量比2:4:1组成的混合物;所述润湿剂是由壬基酚聚氧乙烯醚和十二烷基硫酸钠以重量比2:1组成的混合物。The thickener is a mixture of sodium carboxymethylcellulose, organic bentonite and polyvinylpyrrolidone in a weight ratio of 2:4:1; the wetting agent is made of nonylphenol polyoxyethylene ether and dodecane A mixture of sodium base sulfate in a weight ratio of 2:1.

所述流平剂是由有机硅流平剂和丙烯酸酯流平剂以重量比1.2:1组成的混合物;所述成膜助剂是由N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚以重量比1:1.2:1.5组成的混合物。The leveling agent is a mixture of silicone leveling agent and acrylate leveling agent with a weight ratio of 1.2:1; A mixture of alcohol butyl ether in a weight ratio of 1:1.2:1.5.

上述实施例为本发明较佳的实现方案,除此之外,本发明还可以其它方式实现,在不脱离本发明构思的前提下任何显而易见的替换均在本发明的保护范围之内。The above-mentioned embodiments are preferred implementation solutions of the present invention. In addition, the present invention can also be realized in other ways, and any obvious replacements are within the protection scope of the present invention without departing from the concept of the present invention.

Claims (7)

1.一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:包括如下步骤:1. A production technique utilizing a laser laser marking machine to prepare leather, is characterized in that: comprises the steps: (1)选材:采用低等级且表面有刺刮的羊皮、猪皮或牛皮皮料作为皮胚;(1) Material selection: use low-grade sheepskin, pigskin or cowhide leather with thorns on the surface as the skin embryo; (11)刮补:用刮刀将补伤膏刮补填充在皮胚表面,将刮补后的皮胚放入烘箱中干燥定型,用辊光压板将皮胚压平整,干燥温度为60-100℃,干燥时间为5-10min;(11) Scraping and mending: Use a scraper to scrape and fill the repairing ointment on the surface of the skin embryo, put the scraped skin embryo in an oven to dry and shape, and use a roller light plate to flatten the skin embryo. The drying temperature is 60-100 ℃, the drying time is 5-10min; (22)喷涂:在压平后的皮料表面喷涂遮盖涂料;遮盖涂料由以下重量份的原料组成:(22) Spraying: Spray covering paint on the leather surface after flattening; Covering paint is made up of the following raw materials of weight part: 聚丙烯酰胺20-40份、聚丁二烯树脂10-20份、甘油三酸酯5-15份、水性光油6-10份、木质纤维素6-10份、硅酸钠4-8份、二氧化硅2-6份、二氧化钛1-5份、热膨胀性中空微球1-5份、干酪素4-8份、水60-100份;20-40 parts of polyacrylamide, 10-20 parts of polybutadiene resin, 5-15 parts of triglyceride, 6-10 parts of water-based varnish, 6-10 parts of lignocellulose, 4-8 parts of sodium silicate , 2-6 parts of silicon dioxide, 1-5 parts of titanium dioxide, 1-5 parts of heat-expandable hollow microspheres, 4-8 parts of casein, 60-100 parts of water; (2)绘制图案:通过激光镭射打标机的电脑绘制图案,输出图案;(2) Draw patterns: draw patterns through the computer of the laser marking machine, and output the patterns; (3)激光雕刻:将输出的图案用激光镭射打标机在皮料表面雕刻出具有凹凸感和立体感的纹路;(3) Laser engraving: use a laser laser marking machine to carve the output pattern on the surface of the leather with concave-convex and three-dimensional textures; (4)甩软:将雕刻后的皮胚材料在10-30℃下放置10-24h,在10-30℃下通过甩软转鼓进行甩软1-2h。(4) Spinning and softening: place the engraved leather material at 10-30°C for 10-24h, and at 10-30°C for 1-2h through a spinning drum. 2.根据权利要求1所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述步骤(2)中,输出的图案为分辨率在1000-2000L/cm的高分辨率图像。2. A kind of production technology that utilizes laser laser marking machine to prepare leather according to claim 1, it is characterized in that: in described step (2), the output pattern is the height of resolution 1000-2000L/cm resolution image. 3.根据权利要求1所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述步骤(3)中,激光雕刻的工艺参数为:电机功率为30-50W,焦距为20-24mm,切割宽度为10-100μm,雕刻深度为0.1-0.2mm,雕刻速度为400-500mm/s。3. A kind of production technology that utilizes laser laser marking machine to prepare leather according to claim 1, is characterized in that: in described step (3), the process parameter of laser engraving is: motor power is 30-50W, The focal length is 20-24mm, the cutting width is 10-100μm, the engraving depth is 0.1-0.2mm, and the engraving speed is 400-500mm/s. 4.根据权利要求1所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述补伤膏包括以下重量份的原料:4. A kind of production technology that utilizes laser laser marking machine to prepare leather according to claim 1, is characterized in that: described repairing ointment comprises the raw material of following weight portion: 5.根据权利要求4所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述增稠剂是由羧甲基纤维素钠、有机膨润土和聚乙烯吡咯烷酮以重量比(1-2):(2-4):1组成的混合物;所述润湿剂是由壬基酚聚氧乙烯醚和十二烷基硫酸钠以重量比(1-2):1组成的混合物。5. a kind of production technology that utilizes laser laser marking machine to prepare leather according to claim 4 is characterized in that: described thickener is made of sodium carboxymethylcellulose, organobentonite and polyvinylpyrrolidone by weight Ratio (1-2): (2-4): 1 mixture; the wetting agent is composed of nonylphenol polyoxyethylene ether and sodium lauryl sulfate in a weight ratio of (1-2): 1 mixture. 6.根据权利要求4所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述流平剂是由有机硅流平剂和丙烯酸酯流平剂以重量比(0.8-1.2):1组成的混合物;所述成膜助剂是由N-甲基吡咯烷酮、甲基苯醚和二乙二醇丁醚以重量比1:(0.8-1.2):(1.5-2.5)组成的混合物。6. a kind of production technique that utilizes laser laser marking machine to prepare leather according to claim 4 is characterized in that: described leveling agent is to be by weight ratio ( 0.8-1.2): the mixture of 1 composition; Described film-forming auxiliary agent is by weight ratio 1:(0.8-1.2):(1.5-2.5 ) mixture. 7.根据权利要求1所述的一种利用激光镭射打标机制备皮料的生产工艺,其特征在于:所述步骤(4)之后还包括步骤(5)喷手感剂:在甩软加工后的皮料表面喷涂手感剂,所述手感剂由如下重量百分比的原料制成:7. A kind of production technology that utilizes laser laser marking machine to prepare leather according to claim 1, it is characterized in that: after described step (4), also comprise step (5) spraying hand feeling agent: after throwing soft processing The surface of the leather material is sprayed with a feel agent, and the feel agent is made of the following raw materials in weight percentage: 氧化聚乙烯蜡 10-30%Oxidized polyethylene wax 10-30% 脂肪醇聚氧乙烯醚 1-5%Fatty alcohol polyoxyethylene ether 1-5% 山梨糖醇酐油酸酯 2-4%Sorbitan Oleate 2-4% 聚氧乙烯山梨糖醇酐单硬脂酸酯 1-3%Polyoxyethylene sorbitan monostearate 1-3% 改性聚硅氧烷 0.5-1.5%Modified polysiloxane 0.5-1.5% 60-80℃软化水 余量。60-80 ℃ demineralized water balance.
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