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CN106665632A - Composition for preventing and removing herbicide-resistant weeds - Google Patents

Composition for preventing and removing herbicide-resistant weeds Download PDF

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Publication number
CN106665632A
CN106665632A CN201611140706.3A CN201611140706A CN106665632A CN 106665632 A CN106665632 A CN 106665632A CN 201611140706 A CN201611140706 A CN 201611140706A CN 106665632 A CN106665632 A CN 106665632A
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CN
China
Prior art keywords
cake fertilizer
preventing
orthosulfamuron
benthiocarb
compositionss
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611140706.3A
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Chinese (zh)
Inventor
邓大鹏
陈栋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Golden Dunfu Agricultural Technology Co Ltd
Original Assignee
Anhui Golden Dunfu Agricultural Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Golden Dunfu Agricultural Technology Co Ltd filed Critical Anhui Golden Dunfu Agricultural Technology Co Ltd
Priority to CN201611140706.3A priority Critical patent/CN106665632A/en
Publication of CN106665632A publication Critical patent/CN106665632A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a composition for preventing and removing herbicide-resistant weeds. The composition comprises 64-80% of thiobencarb, 5-15% of benzobicylon, 1-5% of orthosulfamuron and the balance of aid. The composition has favorable preventing and treating effects on herbicide-resistant weeds; the overall preventing effect is 94% or above and is apparently higher than the preventing effect of a single agent; and the composition has the advantages of lower application cost, obviously higher weed removal activity and obvious synergistic action, is especially suitable for preventing and removing barnyard grass, moleplant seed, monochoria, smallflower umbrellaplant and other unmanageable weeds, and has important popularization value for preventing and controlling herbicide-resistant weeds and postponing resistance generation of weeds.

Description

A kind of compositionss for preventing and kill off resistant weed
Technical field
The present invention relates to a kind of compositionss for preventing and kill off resistant weed, belong to technical field of pesticide preparations.
Background technology
Benthiocarb, CAS registration numbers are:28249-77-6, benthiocarb are the sulfo-aminos of Japanese combinatorial chemistry company exploitation Formate ester herbicide, the lipid synthetic inhibitor that non-acetyl-CoA carboxylase suppresses, Uptake and translocation, 1 ~ 1.5 leaf phase weeds are inhaled Receive and conductive activity shows as mesocotyl>Plumule>Root>First blade;It is poor to Weed-control effect after 2.5 leaf phases.Benthiocarb presses down Weeds cell mitogen processed, allows grass cutting blade to stop growing and gradually death.For prevent and kill off annual Semen Euphorbiae, the nit grass, Barnyard grass, Herba Eragrostidis ferrugineae of cracking rice, Herba Digitariae, Herba Eleusines Indicae, Herba Setariae Viridis, Leersia Sw, Weedy Rice, Herba Eleocharitis aciculariies, Herba Fimbristylis miliaceae, Herba Portulacae, water Folium Bambusae etc..Antagonism and difficult anti-barnyard grass, Semen Euphorbiae, nit grass, Herba Eragrostidis ferrugineae of cracking rice, Herba Digitariae, Weedy Rice etc. wait until excellent in having Preventive effect.
Benzobicylon, CAS registration numbers are:156963-66-5, benzobicylon are the double of Japanese history Di Shi companies exploitation Cyclooctane class herbicide, belongs to HPPD inhibitor, causes carotenoid close by suppressing p-hydroxybenzene pyruvic acid (HPP) ester Into albefaction after weeds poisoning is gradually withered.For preventing and kill off annual barnyard grass, Herba monochoriae vaginaliss, Lindernia procumbens (Krock.) Phillcox., firefly Lin, Herba Cyperi Glomerati, ox hair Felt, Herba Murdanniae Triquetrae, not plump shell grass, Leersia Sw, agrostis stolonifera, potamogeton grass etc., antagonism barnyard grass, Herba monochoriae vaginaliss, Herba Murdanniae Triquetrae, firefly Lin etc. have Efficiently.
Orthosulfamuron, CAS registration numbers are:213464-77-8, orthosulfamuron are Italian Yi Saige companies exploitations Sulfonylurea herbicide, belongs to ALS inhibitor, suppresses the synthesis of an aminoacid, so as to blocking protein synthesizes, allows weeds Stop growing and gradually death.For preventing and kill off annual barnyard grass, Herba monochoriae vaginaliss, short Rhizoma sagittariae sagittifoliae, mexicana, Lindernia procumbens (Krock.) Phillcox., Herba Cyperi Difformiss, firefly Lin, cyperus iria, Herba Eleocharitis aciculariies, Herba Spirodelae, moss etc. have efficiently.
The inventors discovered that, existing benthiocarb, benzobicylon, all kinds of single doses of orthosulfamuron are deposited if being used alone In the defect such as the prevention effect of single function, antagonism weeds is limited.
The content of the invention
The present invention is in view of the shortcomings of the prior art, there is provided a kind of compositionss for preventing and kill off resistant weed, particular technique Scheme is as follows:
A kind of compositionss for preventing and kill off resistant weed, constitute (percentage by weight) by following component:
Benthiocarb 64% ~ 80%;Benzobicylon 5% ~ 15%;Orthosulfamuron 1% ~ 5%;Remaining is auxiliary agent.
As the improvement of above-mentioned technical proposal, the gross mass of the benthiocarb, benzobicylon and orthosulfamuron with should Mass percent between the gross mass of compositionss is 80% ~ 90%.
Used as the improvement of above-mentioned technical proposal, the auxiliary agent includes vegetable oil, nonionic surfactant and cake fertilizer, described Vegetable oil is soybean oil, levant cotton oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestriss, Oleum Ricini, the one kind in Oleum helianthi;The non-ionic surface is lived Property agent be NPE, the one kind in spermol;The cake fertilizer is soybean cake fertilizer, colza cake fertilizer, pockmarks cake fertilizer, cotton seed One kind in cake fertilizer, peanut cake fertilizer, idesia cake fertilizer, Fructus Camelliae sinensis cake fertilizer, the water content of the cake fertilizer are less than 5%, the particle diameter of the cake fertilizer Less than 0.1mm.
Used as the improvement of above-mentioned technical proposal, said composition constitutes (percentage by weight) by following component:
Benthiocarb 80%;Benzobicylon 5%;Orthosulfamuron 5%;Vegetable oil 7%;Nonionic surfactant 1%;Cake fertilizer 2%.
Used as the improvement of above-mentioned technical proposal, said composition constitutes (percentage by weight) by following component:
Benthiocarb 72%;Benzobicylon 10%;Orthosulfamuron 3%;Vegetable oil 10.5%;Nonionic surfactant 1.5%;Cake Fertilizer 3%.
Used as the improvement of above-mentioned technical proposal, said composition constitutes (percentage by weight) by following component:
Benthiocarb 64%;Benzobicylon 15%;Orthosulfamuron 1%;Oleum Arachidis hypogaeae semen 13%;Nonionic surfactant 2%;Cake fertilizer 5%.
Beneficial effects of the present invention:The prevention effect of said composition antagonism weeds is excellent, its overall preventive effect 94% with On, and apparently higher than the preventive effect of each single dose, drug cost is reduced, and activity of weeding is significantly improved, and potentiation substantially, is especially fitted Weeds for the difficult preventing and treating such as barnyard grass, Semen Euphorbiae, Herba monochoriae vaginaliss, Herba Cyperi Difformiss are prevented and kill off, and to prevention and control resistant weed and delay miscellaneous Grass produces resistance and has important promotional value.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only to explain the present invention The present invention is limited, percentage ratio is weight percentage in the proportioning of all compositionss below.
1 90% benthiocarb benzobicylon orthosulfamuron oil-suspending agent of embodiment
Benthiocarb 80%;Benzobicylon 5%;Orthosulfamuron 5%;Soybean oil 7%;NPE 1%;Soybean cake fertilizer 2%; Wherein, the water content of soybean cake fertilizer is less than 5%, and the particle diameter of soybean cake fertilizer is less than 0.1mm.
Preparation method is:After above-mentioned raw materials are weighed up according to weight portion, mixing disperses 50min using high-speed shearing machine, then uses Both obtain after ball mill ball milling.
2 85% benthiocarb benzobicylon orthosulfamuron oil-suspending agent of embodiment
Benthiocarb 72%;Benzobicylon 10%;Orthosulfamuron 3%;Oleum Brassicae campestriss 10.5%;Spermol 1.5%;Colza cake fertilizer 3%;Its In, the water content of colza cake fertilizer is less than 5%, and the particle diameter of colza cake fertilizer is less than 0.1mm.Preparation method is with embodiment 1.
3 80% benthiocarb benzobicylon orthosulfamuron oil-suspending agent of embodiment
Benthiocarb 64%;Benzobicylon 15%;Orthosulfamuron 1%;Oleum Arachidis hypogaeae semen 13%;Spermol 2%;Peanut cake fertilizer 5%;Wherein, The water content of peanut cake fertilizer is less than 5%, and the particle diameter of peanut cake fertilizer is less than 0.1mm.Preparation method is with embodiment 1.
Field control effectiveness test
Reagent agent:In 90% benthiocarb benzobicylon orthosulfamuron oil-suspending agent, embodiment 2 in embodiment 1 80% benthiocarb benzobicylon in 85% benthiocarb benzobicylon orthosulfamuron oil-suspending agent and embodiment 3 Orthosulfamuron oil-suspending agent.
Comparison medicament:90% benthiocarb cream(Comparison medicament 1);25% benzobicylon suspending agent(Comparison medicament 2);50% Orthosulfamuron water dispersible granules(Comparison medicament 3).
Prevent and kill off object:Resistance barnyard grass(Anti- ALS inhibitor), resistance Semen Euphorbiae(Anti- ACC inhibitor), resistance Herba monochoriae vaginaliss(It is anti- ALS inhibitor), resistance Herba Cyperi Difformiss(Anti- ALS inhibitor).
Test method:Testing is carried out in Jing direct sowing of rices field, and each group is processed and is repeated 3 times, processing area 20m2, according to Hillslope processes area, the good various medicaments of precise, in 1.5 leaf phase of rice seedling spraying treatment.30d weeds death feelings after statistics medicine Condition, the activity of weeding of the various medicaments of comparison.The results are shown in Table 1.
30d herbicidal effects after the compositionss medicine of 1 different formulations of table
Result of the test shows that the prevention effect of the herbicidal composition antagonism weeds of the present invention is good, to key resistance weeds Preventive effect be superior to single dose.The compositionss of the present invention also have good preventive effect to other resistances and difficult anti-weeds simultaneously, to prevention and control Resistant weed and delay weeds produce resistance there is important promotional value.
In the above-described embodiments, by multiple optimization design formula and through multiple field control effectiveness test, spend a large amount of Manpower and materials, design the optimum proportioning between benthiocarb, benzobicylon, orthosulfamuron, then aid in by vegetable oil, non- The auxiliary agent of ionic surface active agent and cake fertilizer composition, activity of weeding significantly improves, potentiation substantially, in particular for barnyard grass, Semen Euphorbiae, Herba monochoriae vaginaliss, the preventive effect of Herba Cyperi Difformiss have exceeded 94%, and preventive effect is significantly higher than single dose, also a saving drug cost.Its In, by the use of vegetable oil as carrier oil, the optional conventional soybean oil of the vegetable oil, levant cotton oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestriss, Semen Ricini One kind in oil, Oleum helianthi.The nonionic surfactant it is special in NPE, spermol one Kind;Spermol can increase the water absorption of compositionss, beneficial to compositionss moistening, be attached to target blade face;Spermol also have help breast Change, thickening, the effect of hardening so that said composition drug effect under drought condition is more prominent, and which is extremely strong in plant leaf surface cohesiveness. NPE has good infiltration, emulsifying, dispersion, antiacid, alkali resistant, hard water resistance, anti-reduction, oxidation resistance, Therefore so that each composition of said composition can keep uniform, be affected relatively low by external force, even if on the more serious ground of acid rain, water pollution Area does not interfere with said composition yet and uneven components occurs, and keeps the drug effect of said composition.Cake fertilizer is the solid in said composition Carrier, the cake fertilizer is soybean cake fertilizer, in colza cake fertilizer, pockmarks cake fertilizer, cotton seed cake fertilizer, peanut cake fertilizer, idesia cake fertilizer, Fructus Camelliae sinensis cake fertilizer One kind, and strictly control cake fertilizer water content and particle diameter, relative to kieselguhr, Magnesiumaluminumsilicate, active hargil, Kaolin, Clay, Gypsum Fibrosum, bentonite, White Carbon black, precipitated calcium carbonate, limestone, silicon dioxide, hexamethylene diamine, cumarone resin, benzene For the solid carrier such as ethene polymerss and copolymer, corn starch and soluble starch, cake fertilizer source is wide, and price is low, cake fertilizer Itself contains trace plant oils and fatss so that the affinity between cake fertilizer and carrier oil is high, i.e., cake fertilizer is easily dispersed in carrier oil, can Avoid oarse-grained reunion, cake fertilizer granule to be sent as an envoy to as the Vegetable oil lipoprotein of itself is squeezed and there is multiple micropores, hole inside which Road structure, which easily adsorbs a large amount of vegetable oil, and cake fertilizer coordinates with vegetable oil so that compositionss are easier to be attached on plant leaf surface And each component is difficult dispersion, it is ensured that the drug effect of compositionss can perform to maximization;Also, killed weeds are together with cake fertilizer In placing into the soil, cake fertilizer easily attracts a large amount of microorganisms, can promote weeds corruption, decompose, be conducive to increasing soil fertility.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (6)

1. a kind of compositionss for preventing and kill off resistant weed, it is characterised in that (percentage by weight) is constituted by following component:
Benthiocarb 64% ~ 80%;Benzobicylon 5% ~ 15%;Orthosulfamuron 1% ~ 5%;Remaining is auxiliary agent.
2. a kind of compositionss for preventing and kill off resistant weed according to claim 1, it is characterised in that the benthiocarb, bicyclic Mass percent between the gross mass of the gross mass and said composition of sulphur oxadiazon and orthosulfamuron is 80% ~ 90%.
3. a kind of compositionss for preventing and kill off resistant weed according to claim 2, it is characterised in that the auxiliary agent includes plant Oil, nonionic surfactant and cake fertilizer, the vegetable oil are soybean oil, levant cotton oil, Oleum Arachidis hypogaeae semen, Oleum Brassicae campestriss, Oleum Ricini, Xiang One kind in certain herbaceous plants with big flowers oil;The nonionic surfactant is NPE, the one kind in spermol;The cake fertilizer is One kind in soybean cake fertilizer, colza cake fertilizer, pockmarks cake fertilizer, cotton seed cake fertilizer, peanut cake fertilizer, idesia cake fertilizer, Fructus Camelliae sinensis cake fertilizer, the cake fertilizer Water content be less than 5%, the particle diameter of the cake fertilizer is less than 0.1mm.
4. a kind of compositionss for preventing and kill off resistant weed according to claim 3, it is characterised in that be made up of following component (percentage by weight):
Benthiocarb 80%;Benzobicylon 5%;Orthosulfamuron 5%;Vegetable oil 7%;Nonionic surfactant 1%;Cake fertilizer 2%.
5. a kind of compositionss for preventing and kill off resistant weed according to claim 3, it is characterised in that be made up of following component (percentage by weight):
Benthiocarb 72%;Benzobicylon 10%;Orthosulfamuron 3%;Vegetable oil 10.5%;Nonionic surfactant 1.5%;Cake Fertilizer 3%.
6. a kind of compositionss for preventing and kill off resistant weed according to claim 3, it is characterised in that be made up of following component (percentage by weight):
Benthiocarb 64%;Benzobicylon 15%;Orthosulfamuron 1%;Vegetable oil 13%;Nonionic surfactant 2%;Cake fertilizer 5%.
CN201611140706.3A 2016-12-12 2016-12-12 Composition for preventing and removing herbicide-resistant weeds Pending CN106665632A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611140706.3A CN106665632A (en) 2016-12-12 2016-12-12 Composition for preventing and removing herbicide-resistant weeds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611140706.3A CN106665632A (en) 2016-12-12 2016-12-12 Composition for preventing and removing herbicide-resistant weeds

Publications (1)

Publication Number Publication Date
CN106665632A true CN106665632A (en) 2017-05-17

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CN201611140706.3A Pending CN106665632A (en) 2016-12-12 2016-12-12 Composition for preventing and removing herbicide-resistant weeds

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101578046A (en) * 2006-12-11 2009-11-11 伊萨格罗股份公司 Herbicidal compositions
CN105724390A (en) * 2016-04-28 2016-07-06 青岛清原抗性杂草防治有限公司 Rice field herbicide composition and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101578046A (en) * 2006-12-11 2009-11-11 伊萨格罗股份公司 Herbicidal compositions
CN105724390A (en) * 2016-04-28 2016-07-06 青岛清原抗性杂草防治有限公司 Rice field herbicide composition and application thereof

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