CN106645097A - Optical path system for laser probe component analyzer - Google Patents
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Abstract
本发明属于激光精密检测相关技术领域,其公开了一种用于激光探针成分分析仪的光路系统,所述光路系统包括光谱采集模块及成像模块。所述光路系统还包括激光控制模块、激光监测模块及照明模块,所述光谱采集模块、所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块是同轴设置的。所述激光控制模块用于控制激光能量及光斑;所述激光监测模块用于实时监测激光能量;所述光谱采集模块用于实时采集等离子光谱;所述照明模块用于对待测样品表面进行照明,以保证所述待测样品的表面清晰可见;所述成像模块用于对所述待测样品表面成像。所述光路系统同时实现稳定的光谱信息采集和清晰的表面成像。
The invention belongs to the related technical field of laser precision detection, and discloses an optical path system for a laser probe component analyzer. The optical path system includes a spectrum acquisition module and an imaging module. The optical path system further includes a laser control module, a laser monitoring module, and an illumination module, and the spectrum acquisition module, the laser control module, the laser monitoring module, the illumination module, and the imaging module are arranged coaxially. The laser control module is used to control laser energy and light spot; the laser monitoring module is used to monitor laser energy in real time; the spectrum acquisition module is used to collect plasma spectrum in real time; the lighting module is used to illuminate the surface of the sample to be tested, To ensure that the surface of the sample to be tested is clearly visible; the imaging module is used to image the surface of the sample to be tested. The optical path system simultaneously realizes stable spectral information collection and clear surface imaging.
Description
技术领域technical field
本发明属于激光精密检测相关技术领域,更具体地,涉及一种用于激光探针成分分析仪的光路系统。The invention belongs to the technical field related to laser precision detection, and more specifically relates to an optical path system for a laser probe component analyzer.
背景技术Background technique
激光探针,又称为激光诱导击穿光谱(Laser-induced breakdown spectroscopy,简称LIBS),是一种物质成分分析方法。激光探针利用激光在待测样品表面烧蚀产生等离子体,再通过分析等离子体发射光谱实现对物质元素成分的测量。从科研化走向工业化的过程中,激光探针需要一种成熟的光路系统,在保证稳定光谱采集的同时,获得样品表面成像信息,使用户能够对样品表面特定位置的原位信息进行采集,保证可见即所得。Laser probe, also known as laser-induced breakdown spectroscopy (LIBS for short), is a material composition analysis method. The laser probe uses a laser to ablate the surface of the sample to be tested to generate plasma, and then realizes the measurement of the material element composition by analyzing the plasma emission spectrum. In the process from scientific research to industrialization, laser probes need a mature optical path system, which can obtain sample surface imaging information while ensuring stable spectrum collection, so that users can collect in-situ information at specific positions on the sample surface, ensuring What you see is what you get.
目前,本领域相关技术人员已经做了一些研究,如公开号为CN103267746B的专利、公开号为CN101587074B的专利、授权公告号为CN101587074B的专利分别公开了不同的激光探针分析仪,以上所公开的激光探针分析仪均集成了激光探针光谱分析和同轴样品表面成像的功能,为激光探针光路系统的典型实例。但是上述实例皆存在以下几点不足:At present, those skilled in the art have done some research, such as the patent whose publication number is CN103267746B, the patent whose publication number is CN101587074B, and the patent whose authorization announcement number is CN101587074B respectively disclose different laser probe analyzers. Laser probe analyzers integrate the functions of laser probe spectral analysis and coaxial sample surface imaging, which are typical examples of laser probe optical system. But all there is following deficiency in above-mentioned example:
1.没有样品表面的同轴照明装置,对于表面光滑或者色彩较暗的样品,特别是在显微分析高倍成像时,难以保证样品表面清晰可见;1. There is no coaxial lighting device on the sample surface. For samples with smooth surface or dark color, especially in high-magnification imaging of microscopic analysis, it is difficult to ensure that the sample surface is clearly visible;
2.成像系统中,没有考虑对激光的滤除,同轴成像过程样品表面反射的激光很容易将成像相机损坏;2. In the imaging system, the filtering of the laser light is not considered, and the laser light reflected on the sample surface during the coaxial imaging process can easily damage the imaging camera;
3.没有激光能量实时调节和监控系统,既无法对激光光斑进行整形获得更适合激光探针使用的光束,也无法对激光能量波动和衰减效应进行实时校正、调节及监控;3. Without a real-time adjustment and monitoring system for laser energy, it is impossible to shape the laser spot to obtain a beam more suitable for the laser probe, and it is impossible to correct, adjust and monitor the laser energy fluctuation and attenuation effect in real time;
4.光谱采集器前面没有滤除激光,样品表面反射的激光容易将光纤采集头损坏。4. There is no laser filter in front of the spectrum collector, and the laser reflected from the sample surface is easy to damage the optical fiber collection head.
发明内容Contents of the invention
针对现有技术的以上缺陷或改进需求,本发明提供了一种用于激光探针成分分析仪的光路系统,其集成了激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块,可以同时实现激光能量和光斑控制、激光能量实时监测、等离子体光谱采集、样品表面照明、样品表面成像功能,实现稳定的光谱信息和样品图像信息的同时获取,满足现代工业应用需求;其中激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块在光路中是同轴的,结构紧凑,多个零件均可以实现多功能使用。此外,所述光路系统对各个零部件进行了激光防护,提高零部件的使用寿命。In view of the above defects or improvement needs of the prior art, the present invention provides an optical path system for a laser probe component analyzer, which integrates a laser control module, a laser monitoring module, a spectrum acquisition module, an illumination module and an imaging module5 One module can realize laser energy and spot control, laser energy real-time monitoring, plasma spectrum acquisition, sample surface illumination, sample surface imaging functions at the same time, realize simultaneous acquisition of stable spectral information and sample image information, and meet the needs of modern industrial applications; Among them, the five modules of laser control module, laser monitoring module, spectrum acquisition module, illumination module and imaging module are coaxial in the optical path, with compact structure, and multiple parts can realize multi-functional use. In addition, the optical path system provides laser protection for each component to improve the service life of the component.
为实现上述目的,本发明提供了一种用于激光探针成分分析仪的光路系统,其包括光谱采集模块及成像模块,其特征在于:In order to achieve the above object, the present invention provides a kind of optical path system for laser probe component analyzer, it comprises spectrum collection module and imaging module, it is characterized in that:
所述光路系统还包括激光控制模块、激光监测模块及照明模块,所述光谱采集模块、所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块是同轴设置的;The optical path system also includes a laser control module, a laser monitoring module, and an illumination module, and the spectrum acquisition module, the laser control module, the laser monitoring module, the illumination module, and the imaging module are arranged coaxially;
所述激光控制模块用于控制激光能量及光斑;所述激光监测模块用于实时监测激光能量,以便所述激光控制模块对激光能量波动及衰减效应进行实时校正;所述光谱采集模块用于实时采集等离子光谱;所述照明模块用于对待测样品表面进行照明,以保证所述待测样品的表面清晰可见;所述成像模块用于对所述待测样品表面成像。The laser control module is used to control the laser energy and the light spot; the laser monitoring module is used to monitor the laser energy in real time, so that the laser control module can correct the laser energy fluctuation and attenuation effect in real time; the spectrum acquisition module is used to real-time The plasma spectrum is collected; the illumination module is used to illuminate the surface of the sample to be tested to ensure that the surface of the sample to be tested is clearly visible; the imaging module is used to image the surface of the sample to be tested.
进一步的,所述激光控制模块、所述光谱采集模块、所述照明模块及所述成像模块共同具有物镜;所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块共同具有分束镜;所述激光控制模块及所述成像模块共同具有激光反射镜;所述照明模块及所述成像模块共同具有分光镜。Further, the laser control module, the spectrum acquisition module, the lighting module and the imaging module have an objective lens in common; the laser control module, the laser monitoring module, the lighting module and the imaging module have a common It has a beam splitter; the laser control module and the imaging module share a laser reflector; the illumination module and the imaging module share a beam splitter.
进一步的,所述激光控制模块还包括激光器、激光扩束镜、谐波分束镜、第一激光窗口、第一激光吸收体、半波片、偏振分束镜、第二激光窗口、第二激光吸收体、光闸及光阑;所述第一激光窗口位于所述谐波分束镜及所述第一激光吸收体之间;所述半波片位于所述谐波分束镜前方;所述第二激光窗口位于所述偏振分束镜及所述第二激光吸收体之间;所述激光反射镜位于所述光阑及所述分束镜之间;所述物镜位于所述分束镜及所述待测样品之间。Further, the laser control module also includes a laser, a laser beam expander, a harmonic beam splitter, a first laser window, a first laser absorber, a half-wave plate, a polarization beam splitter, a second laser window, a second A laser absorber, an optical gate, and an aperture; the first laser window is located between the harmonic beam splitter and the first laser absorber; the half-wave plate is located in front of the harmonic beam splitter; The second laser window is located between the polarizing beam splitter and the second laser absorber; the laser reflector is located between the aperture and the beam splitter; the objective lens is located between the splitter between the beam mirror and the sample to be tested.
进一步的,所述半波片是可旋转的。Further, the half-wave plate is rotatable.
进一步的,所述激光监测模块还包括第一线偏振片及激光能量计,所述第一线偏振片位于所述分束镜及所述激光能量计之间。Further, the laser monitoring module further includes a first linear polarizer and a laser energy meter, and the first linear polarizer is located between the beam splitter and the laser energy meter.
进一步的,所述光谱采集模块还包括第二线偏振片、光纤耦合镜、光纤接头、光纤及光谱仪,所述第二线偏振片位于所述分束镜及所述光纤耦合镜之间;所述光纤耦合镜连接于所述光纤接头;所述光纤连接所述光纤接头及所述光谱仪。Further, the spectrum acquisition module also includes a second linear polarizer, a fiber coupling mirror, a fiber connector, an optical fiber, and a spectrometer, and the second linear polarizer is located between the beam splitter and the fiber coupling mirror; the optical fiber The coupling mirror is connected to the optical fiber joint; the optical fiber is connected to the optical fiber joint and the spectrometer.
进一步的,所述照明模块还包括LED光源及照明准直镜,所述照明准直镜位于所述LED光源之前方。Further, the illumination module further includes an LED light source and an illumination collimation mirror, and the illumination collimation mirror is located in front of the LED light source.
进一步的,所述成像模块还包括目镜、第三线偏振片及相机,所述第三线偏振片位于所述相机之前方。Further, the imaging module further includes an eyepiece, a third linear polarizer and a camera, and the third linear polarizer is located in front of the camera.
进一步的,所述激光控制模块、所述光谱采集模块、所述照明模块及所述成像模块共同具有物镜;所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块共同具有分束镜;所述激光控制模块及所述成像模块共同具有激光反射镜;所述照明模块及所述成像模块共同具有分光镜;所述激光控制模块、所述照明模块及所述成像模块共同具有宽带反射镜。Further, the laser control module, the spectrum acquisition module, the lighting module and the imaging module have an objective lens in common; the laser control module, the laser monitoring module, the lighting module and the imaging module have a common It has a beam splitter; the laser control module and the imaging module have a laser reflector; the lighting module and the imaging module have a beam splitter; the laser control module, the lighting module and the imaging module common with broadband mirrors.
进一步的,所述激光控制模块还包括激光器、激光扩束镜、谐波分束镜、第一激光窗口、第一激光吸收体、半波片、偏振分束镜、第二激光窗口、第二激光吸收体、光闸及光阑;所述第一激光窗口位于所述第一激光吸收体及所述谐波分束镜之间;所述半波片位于所述偏振分束镜前方;所述第二激光窗口位于所述偏振分束镜及所述第二激光吸收体之间;所述物镜位于所述分束镜及所述待测样品之间。Further, the laser control module also includes a laser, a laser beam expander, a harmonic beam splitter, a first laser window, a first laser absorber, a half-wave plate, a polarization beam splitter, a second laser window, a second A laser absorber, an optical gate, and an aperture; the first laser window is located between the first laser absorber and the harmonic beam splitter; the half-wave plate is located in front of the polarization beam splitter; the The second laser window is located between the polarization beam splitter and the second laser absorber; the objective lens is located between the beam splitter and the sample to be measured.
总体而言,通过本发明所构思的以上技术方案与现有技术相比,本发明提供的用于激光探针成分分析仪的光路系统,其集成了激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块,可以同时实现激光能量和光斑控制、激光能量实时监测、等离子体光谱采集、样品表面照明、样品表面成像功能,实现稳定的光谱信息和样品图像信息的同时获取,满足现代工业应用需求;其中激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块在光路中是同轴的,结构紧凑,多个零件均可以实现多功能使用。此外,所述光路系统对各个零部件进行了激光防护,提高零部件的使用寿命。Generally speaking, compared with the prior art, the above technical solutions conceived by the present invention provide an optical path system for a laser probe component analyzer, which integrates a laser control module, a laser monitoring module, and a spectrum acquisition module Five modules, namely, an illumination module and an imaging module, can realize laser energy and spot control, real-time monitoring of laser energy, plasma spectrum acquisition, sample surface illumination, and sample surface imaging functions at the same time, and achieve stable spectral information and sample image information at the same time. , to meet the needs of modern industrial applications; among them, the five modules of laser control module, laser monitoring module, spectrum acquisition module, illumination module and imaging module are coaxial in the optical path, compact in structure, and multiple parts can be used for multi-function. In addition, the optical path system provides laser protection for each component to improve the service life of the component.
附图说明Description of drawings
图1是本发明第一实施方式提供的用于激光探针成分分析仪的光路系统的使用状态示意图。Fig. 1 is a schematic view of the use state of the optical system for the laser probe component analyzer provided by the first embodiment of the present invention.
图2是本发明第二实施方式提供的用于激光成分分析仪的光路系统的使用状态示意图。Fig. 2 is a schematic view of the use state of the optical system for the laser component analyzer provided by the second embodiment of the present invention.
在所有附图中,相同的附图标记用来表示相同的元件或结构,其中:1.激光器;2.激光扩束镜;3.谐波分束镜;4.第一激光窗口;5.第一激光吸收体;6.半波片;7.偏振分束镜;8.第二激光窗口;9.第二激光吸收体;10.光闸;11.光阑;12.激光反射镜;13.分束镜;14.物镜;15.待测样品;16.第一线偏振片;17.激光能量计;18.第二线偏振片;19.光纤耦合镜;20.光纤接头;21.光纤;22.光谱仪;23.分光镜;24.照明准直镜;25.LED光源;26.全反镜;27.目镜;28.第三线偏振片;29.相机;30.宽带反射镜。In all drawings, the same reference numerals are used to denote the same elements or structures, wherein: 1. laser; 2. laser beam expander; 3. harmonic beam splitter; 4. first laser window; 5. 6. Half-wave plate; 7. Polarizing beam splitter; 8. Second laser window; 9. Second laser absorber; 10. Optical gate; 11. Aperture; 12. Laser mirror; 13. Beam splitter; 14. Objective lens; 15. Sample to be tested; 16. First linear polarizer; 17. Laser energy meter; 18. Second linear polarizer; 19. Fiber coupling mirror; 20. Fiber connector; 21. Optical fiber; 22. Spectrometer; 23. Beam splitter; 24. Illumination collimator; 25. LED light source; 26. Total reflection mirror; 27. Eyepiece; 28. Third linear polarizer; 29. Camera;
具体实施方式detailed description
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。此外,下面所描述的本发明各个实施方式中所涉及到的技术特征只要彼此之间未构成冲突就可以相互组合。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention. In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not constitute a conflict with each other.
请参阅图1,本发明第一实施方式提供的用于激光探针成分分析仪的光路系统,其包括激光器1、激光扩束镜2、谐波分束镜3、第一激光窗口4、第一激光吸收体5、半波片6、偏振分束镜7、第二激光窗口8、第二激光吸收体9、光闸10、光阑11、激光反射镜12、分束镜13、物镜14、待测样品15、第一线偏振片16、激光能量计17、第二线偏振片18、光纤耦合镜19、光纤接头20、光纤21、光谱仪22、分光镜23、照明准直镜24、LED光源25、全反镜26、目镜27、第三线偏振片28及相机29,以上所述的零部件分别组成了激光控制模块、激光监测模块、光谱采集模块、照明模块及成像模块。本实施方式中,所述激光控制模块、所述激光监测模块、所述光谱采集模块、所述照明模块及所述成像模块是同轴设置的;所述物镜14为所述激光控制模块、所述光谱采集模块、所述照明模块及所述成像模块共同具有;所述分束镜13为所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块共同具有;所述激光反射镜12为所述激光控制模块及所述成像模块共同具有;所述分光镜23为所述照明模块及所述成像模块共同具有。Please refer to Fig. 1, the optical path system for the laser probe component analyzer provided by the first embodiment of the present invention, which includes a laser 1, a laser beam expander 2, a harmonic beam splitter 3, a first laser window 4, a second A laser absorber 5, a half-wave plate 6, a polarizing beam splitter 7, a second laser window 8, a second laser absorber 9, an optical gate 10, a diaphragm 11, a laser reflector 12, a beam splitter 13, and an objective lens 14 , sample to be tested 15, first linear polarizer 16, laser energy meter 17, second linear polarizer 18, fiber coupling mirror 19, fiber optic connector 20, optical fiber 21, spectrometer 22, beam splitter 23, illumination collimator mirror 24, LED The light source 25, the total reflection mirror 26, the eyepiece 27, the third linear polarizer 28 and the camera 29, the components mentioned above constitute the laser control module, the laser monitoring module, the spectrum acquisition module, the lighting module and the imaging module respectively. In this embodiment, the laser control module, the laser monitoring module, the spectrum acquisition module, the lighting module and the imaging module are arranged coaxially; the objective lens 14 is the laser control module, the The spectrum collection module, the lighting module and the imaging module are shared; the beam splitter 13 is shared by the laser control module, the laser monitoring module, the lighting module and the imaging module; the The laser reflector 12 is shared by the laser control module and the imaging module; the beam splitter 23 is shared by the lighting module and the imaging module.
所述激光控制模块还包括所述激光器1、所述激光扩束镜2、所述谐波分束镜3、所述第一激光窗口4、所述第一激光吸收体5、所述半波片6、所述偏振分束镜7、所述第二激光窗口8、所述第二激光吸收体9、所述光闸10、及所述光阑11。所述激光扩束镜2位于所述激光器1及所述谐波分束镜3之间;所述第一激光窗口4位于所述谐波分束镜3及所述第一激光吸收体5之间;所述半波片6位于所述谐波分束镜3及所述偏振分束镜7之间;所述第二激光窗口8位于所述偏振分束镜7及所述第二激光吸收体9之间;所述光闸10位于所述偏振分束镜7及所述光阑11之间;所述激光反射镜12位于所述光阑11及所述分束镜13之间;所述物镜14位于所述分束镜13及待测样品15之间。本实施方式中,所述激光器1是Nd:YAG的2次谐波532nm波长的激光器。The laser control module also includes the laser 1, the laser beam expander 2, the harmonic beam splitter 3, the first laser window 4, the first laser absorber 5, the half-wave sheet 6, the polarizing beam splitter 7, the second laser window 8, the second laser absorber 9, the shutter 10, and the diaphragm 11. The laser beam expander 2 is located between the laser 1 and the harmonic beam splitter 3; the first laser window 4 is located between the harmonic beam splitter 3 and the first laser absorber 5 Between; the half-wave plate 6 is located between the harmonic beam splitter 3 and the polarization beam splitter 7; the second laser window 8 is located between the polarization beam splitter 7 and the second laser absorption between the body 9; the shutter 10 is located between the polarizing beam splitter 7 and the diaphragm 11; the laser reflector 12 is located between the diaphragm 11 and the beam splitter 13; the The objective lens 14 is located between the beam splitter 13 and the sample 15 to be tested. In this embodiment, the laser 1 is a laser with a wavelength of 532 nm of the second harmonic of Nd:YAG.
所述激光器1用于发射激光束。所述激光束从所述激光器1输出之后,所述激光扩束镜2用于对所述激光束进行扩束。所述谐波分束镜3用于使经所述激光扩束镜2扩束后的激光透过以进入光路系统中,同时,所述谐波分束镜3将波长为1064nm的激光反射后透过所述第一激光窗口4而被所述第一激光吸收体5吸收。透过所述谐波分束镜3的532nm激光束通过可旋转的所述半波片6调节偏振方向,即调节垂直偏振和水平偏振分量的比例。经所述半波片6调节偏振后的所述激光束的垂直偏振分量自所述偏振分束镜7通过,水平偏振分量反射并透过所述第二激光窗口8而被所述第二激光吸收体9吸收。所述光闸10设置于所述偏振分束镜7的后方,所述光闸10用于控制激光束的通断。所述光阑11设置在所述光闸10的后方,所述光阑11用于将所述激光束的光斑外围波动较大的部分滤除。经所述光阑11滤除处理后的激光束依次经所述激光反射镜12及所述分束镜13反射后,通过所述物镜14聚焦在所述待测样品15表面上,激发出等离子体。The laser 1 is used to emit laser beams. After the laser beam is output from the laser 1, the laser beam expander 2 is used to expand the laser beam. The harmonic beam splitter 3 is used to transmit the laser beam expanded by the laser beam expander 2 to enter the optical path system. At the same time, the harmonic beam splitter 3 reflects the laser light with a wavelength of 1064nm transmitted through the first laser window 4 and absorbed by the first laser absorber 5 . The 532nm laser beam passing through the harmonic beam splitter 3 passes through the rotatable half-wave plate 6 to adjust the polarization direction, that is, to adjust the ratio of vertical polarization and horizontal polarization components. The vertically polarized component of the laser beam after being polarized by the half-wave plate 6 passes through the polarizing beam splitter 7, and the horizontally polarized component is reflected and transmitted through the second laser window 8 to be received by the second laser beam Absorber 9 absorbs. The optical gate 10 is arranged behind the polarizing beam splitter 7, and the optical gate 10 is used to control the on-off of the laser beam. The aperture 11 is arranged behind the shutter 10, and the aperture 11 is used to filter out the portion of the laser beam with large fluctuations in the periphery of the light spot. After the laser beam filtered by the aperture 11 is reflected by the laser reflector 12 and the beam splitter 13 in turn, it is focused on the surface of the sample 15 by the objective lens 14 to excite plasma body.
所述激光监测模块还包括第一线偏振片16及激光能量计17,所述第一线偏振片16位于所述分束镜13及所述激光能量计17之间。经所述分束镜13透过的激光光束部分通过所述第一线偏振片16控制而到达所述激光能量计17的激光能量范围。通过实时监控激光能量,可以得到每一次光谱信号所对应的激光能量信息,通过计算机光谱分析软件做光谱信号波动修正,以及通过调节所述半波片6实现能量调节以消除激光能量衰减效应。The laser monitoring module further includes a first linear polarizer 16 and a laser energy meter 17 , the first linear polarizer 16 is located between the beam splitter 13 and the laser energy meter 17 . The part of the laser beam passing through the beam splitter 13 is controlled by the first linear polarizer 16 to reach the laser energy range of the laser energy meter 17 . By monitoring the laser energy in real time, the laser energy information corresponding to each spectral signal can be obtained, and the spectral signal fluctuation correction is performed through computer spectral analysis software, and the energy adjustment is realized by adjusting the half-wave plate 6 to eliminate the laser energy attenuation effect.
所述光谱采集模块还包括第二线偏振片18、光纤耦合镜19、光纤接头20、光纤21及光谱仪22。所述待测样品15表面等离子体发射的光通过所述物镜14的准直后透过所述分束镜13而到达到所述第二线偏振片18,所述待测样品15表面反射的激光在所述第二线偏振片18处滤除;等离子体光信号可以透过所述第二线偏振片18,并通过所述光纤耦合镜19耦合进所述光纤接头20处;耦合到所述光纤接头20的等离子体光信号通过所述光纤21传导以进入所述光谱仪22。The spectrum acquisition module also includes a second linear polarizer 18 , a fiber coupling mirror 19 , an optical fiber connector 20 , an optical fiber 21 and a spectrometer 22 . The light emitted by the surface plasmon of the sample to be measured 15 is collimated by the objective lens 14 and passes through the beam splitter 13 to reach the second linear polarizer 18, and the laser light reflected by the surface of the sample to be measured 15 Filter out at the second linear polarizer 18; the plasma optical signal can pass through the second linear polarizer 18, and be coupled into the optical fiber connector 20 through the fiber coupling mirror 19; coupled to the optical fiber connector The plasma light signal of 20 is transmitted through the optical fiber 21 to enter the spectrometer 22 .
所述照明模块还包括所述LED光源25及所述照明准直镜24,所述照明准直镜24位于所述LED光源25及所述分光镜23之间。所述LED光源25发出的光依次通过所述照明准直镜24准直及所述分光镜23反射后进入同轴光路中,再依次通过所述分束镜13反射及所述物镜14聚焦后照明在所述待测样品15表面的待测区域上。The lighting module further includes the LED light source 25 and the lighting collimation mirror 24 , and the lighting collimation mirror 24 is located between the LED light source 25 and the beam splitter 23 . The light emitted by the LED light source 25 enters the coaxial optical path after being collimated by the illumination collimator 24 and reflected by the beam splitter 23 in turn, and then reflected by the beam splitter 13 and focused by the objective lens 14 in turn. The illumination is on the area to be measured on the surface of the sample 15 to be tested.
所述成像模块还包括所述全反镜26、所述目镜27、所述第三线偏振片28及所述相机29,所述全反镜26位于所述目镜27及所述分光镜23之间,所述第三线偏振片28位于所述目镜27及所述相机29之间。所述待测样品15表面反射的光依次通过所述物镜14准直及所述分束镜13反射后,经所述激光反射镜12滤除大部分波长为532nm的激光。经所述激光反射镜12滤除处理后的光透过所述分光镜23后被所述全反镜26反射到达所述目镜27,所述目镜27将光信号在所述相机29处成像。所述第三线偏振片28位于所述目镜27及所述相机29之间,以用于将剩余的激光滤除。The imaging module also includes the total reflection mirror 26, the eyepiece 27, the third linear polarizer 28 and the camera 29, the total reflection mirror 26 is located between the eyepiece 27 and the beam splitter 23 , the third linear polarizer 28 is located between the eyepiece 27 and the camera 29 . The light reflected from the surface of the sample 15 to be tested is collimated by the objective lens 14 and reflected by the beam splitter 13 in turn, and then filtered by the laser reflector 12 to filter out most of the laser light with a wavelength of 532 nm. The light filtered by the laser reflector 12 passes through the beam splitter 23 and is reflected by the total reflection mirror 26 to reach the eyepiece 27 , and the eyepiece 27 images the light signal at the camera 29 . The third linear polarizer 28 is located between the eyepiece 27 and the camera 29 for filtering the remaining laser light.
请参阅图2,本发明第二实施方式提供的用于激光探针成分分析仪的光路系统,其包括激光器1、激光扩束镜2、谐波分束镜3、第一激光窗口4、第一激光吸收体5、半波片6、偏振分束镜7、第二激光窗口8、第二激光吸收体9、光闸10、光阑11、激光反射镜12、分束镜13、物镜14、待测样品15、第一线偏振片16、激光能量计17、第二线偏振片18、光纤耦合镜19、光纤接头20、光纤21、光谱仪22、分光镜23、照明准直镜24、LED光源25、全反镜26、目镜27、第三线偏振片28、相机29及宽带反射镜30。以上所述的零部件分别组成了激光控制模块、激光监测模块、光谱采集模块、照明模块及成像模块。Please refer to Fig. 2, the optical path system for the laser probe component analyzer provided by the second embodiment of the present invention, which includes a laser 1, a laser beam expander 2, a harmonic beam splitter 3, a first laser window 4, a second A laser absorber 5, a half-wave plate 6, a polarizing beam splitter 7, a second laser window 8, a second laser absorber 9, an optical gate 10, a diaphragm 11, a laser reflector 12, a beam splitter 13, and an objective lens 14 , sample to be tested 15, first linear polarizer 16, laser energy meter 17, second linear polarizer 18, fiber coupling mirror 19, fiber optic connector 20, optical fiber 21, spectrometer 22, beam splitter 23, illumination collimator mirror 24, LED A light source 25 , a total reflection mirror 26 , an eyepiece 27 , a third linear polarizer 28 , a camera 29 and a broadband reflection mirror 30 . The components mentioned above constitute a laser control module, a laser monitoring module, a spectrum acquisition module, an illumination module and an imaging module respectively.
本实施方式中,所述激光控制模块、所述激光监测模块、所述光谱采集模块、所述照明模块及所述成像模块是同轴设置的;所述物镜14为所述激光控制模块、所述光谱采集模块、所述照明模块及所述成像模块共同具有;所述分束镜13为所述激光控制模块、所述激光监测模块、所述照明模块及所述成像模块共同具有;所述激光反射镜12为所述激光控制模块及所述成像模块共同具有;所述分光镜23为所述照明模块及所述成像模块共同具有;所述宽带反射镜30为所述激光控制模块、所述照明模块及所述成像模块共同具有。In this embodiment, the laser control module, the laser monitoring module, the spectrum acquisition module, the lighting module and the imaging module are arranged coaxially; the objective lens 14 is the laser control module, the The spectrum acquisition module, the lighting module and the imaging module are shared; the beam splitter 13 is shared by the laser control module, the laser monitoring module, the lighting module and the imaging module; the The laser reflector 12 is shared by the laser control module and the imaging module; the beam splitter 23 is shared by the illumination module and the imaging module; the broadband reflector 30 is shared by the laser control module and the imaging module. The lighting module and the imaging module are shared.
所述激光控制模块还包括所述激光器1、所述激光扩束镜2、所述谐波分束镜3、所述第一激光窗口4、所述第一激光吸收体5、所述半波片6、所述偏振分束镜7、所述第二激光窗口8、所述第二激光吸收体9、所述光闸10及所述光阑11。本实施方式中,所述激光器1是Nd:YAG的3次谐波355nm波长的激光器。The laser control module also includes the laser 1, the laser beam expander 2, the harmonic beam splitter 3, the first laser window 4, the first laser absorber 5, the half-wave sheet 6 , the polarizing beam splitter 7 , the second laser window 8 , the second laser absorber 9 , the shutter 10 and the diaphragm 11 . In this embodiment, the laser 1 is a laser with a wavelength of 355 nm of the third harmonic of Nd:YAG.
所述激光扩束镜2位于所述激光器1及所述光阑11之间,所述光闸10位于所述光阑11及所述谐波分束镜3之间。所述第一激光窗口4位于所述第一激光吸收体5及所述谐波分束镜3之间。所述半波片6位于所述谐波分束镜3及所述偏振分束镜7之间。所述第二激光窗口8位于所述偏振分束镜7及所述第二激光吸收体9之间。所述激光反射镜12位于所述偏振分束镜7及所述宽带反射镜30之间。所述分束镜13位于所述宽带反射镜30及所述物镜14之间。所述物镜14位于所述分束镜13及待测样品15之间。The laser beam expander 2 is located between the laser 1 and the aperture 11 , and the shutter 10 is located between the aperture 11 and the harmonic beam splitter 3 . The first laser window 4 is located between the first laser absorber 5 and the harmonic beam splitter 3 . The half-wave plate 6 is located between the harmonic beam splitter 3 and the polarization beam splitter 7 . The second laser window 8 is located between the polarizing beam splitter 7 and the second laser absorber 9 . The laser reflector 12 is located between the polarization beam splitter 7 and the broadband reflector 30 . The beam splitter 13 is located between the broadband mirror 30 and the objective lens 14 . The objective lens 14 is located between the beam splitter 13 and the sample 15 to be tested.
所述激光器1用于发射激光束。所述激光束从所述激光器1输出之后,所述激光扩束镜2用于对所述激光束进行扩束。所述光阑11用于将经所述激光扩束镜2扩束后的激光束光斑外围波动较大的部分滤除。所述光闸10用于控制通过所述激光扩束镜2的激光束的通断。所述谐波分束镜3用于使经过所述光闸10的激光束中波长为355nm的激光透过以进入光路系统中,同时,所述谐波分束镜3将波长为1064nm及532nm的激光反射后透过所述第一激光窗口4而被所述第一激光吸收体5吸收。透过所述谐波分束镜3的355nm激光束通过可旋转的所述半波片6调节偏振方向,即调节垂直偏振和水平偏振分量的比例。经所述半波片6调节偏振后的所述激光束的垂直偏振分量自所述偏振分束镜7通过,水平偏振分量反射并透过所述第二激光窗口8而被所述第二激光吸收体9吸收。透过所述偏振分束镜7的激光光束依次经所述激光反射镜12、所述宽带反射镜30及所述分束镜13反射后,通过所述物镜14聚焦在所述待测样品15的表面上以激发出等离子体。The laser 1 is used to emit laser beams. After the laser beam is output from the laser 1, the laser beam expander 2 is used to expand the laser beam. The aperture 11 is used to filter out the part with larger fluctuations in the periphery of the laser spot after the laser beam expander 2 expands the beam. The shutter 10 is used to control the on-off of the laser beam passing through the laser beam expander 2 . The harmonic beam splitter 3 is used to transmit the laser beam with a wavelength of 355nm in the laser beam passing through the optical gate 10 to enter the optical path system. The reflected laser light passes through the first laser window 4 and is absorbed by the first laser absorber 5 . The 355nm laser beam passing through the harmonic beam splitter 3 passes through the rotatable half-wave plate 6 to adjust the polarization direction, that is, to adjust the ratio of vertical polarization and horizontal polarization components. The vertically polarized component of the laser beam after being polarized by the half-wave plate 6 passes through the polarizing beam splitter 7, and the horizontally polarized component is reflected and transmitted through the second laser window 8 to be received by the second laser beam. Absorber 9 absorbs. The laser beam passing through the polarizing beam splitter 7 is sequentially reflected by the laser mirror 12, the broadband mirror 30 and the beam splitter 13, and then focused on the sample 15 by the objective lens 14 on the surface to generate plasma.
所述激光监测模块还包括第一线偏振片16及激光能量计17,所述第一线偏振片16位于所述分束镜13及所述激光能量计17之间。经所述分束镜13透过的激光光束部分通过所述第一线偏振片16控制而到达所述激光能量计17的激光能量范围。通过实时监控激光能量,可以得到每一次光谱信号所对应的激光能量信息,通过计算机光谱分析软件做光谱信号波动修正,以及通过调节所述半波片6实现能量调节以消除激光能量衰减效应。The laser monitoring module further includes a first linear polarizer 16 and a laser energy meter 17 , the first linear polarizer 16 is located between the beam splitter 13 and the laser energy meter 17 . The part of the laser beam passing through the beam splitter 13 is controlled by the first linear polarizer 16 to reach the laser energy range of the laser energy meter 17 . By monitoring the laser energy in real time, the laser energy information corresponding to each spectral signal can be obtained, and the spectral signal fluctuation correction is performed through computer spectral analysis software, and the energy adjustment is realized by adjusting the half-wave plate 6 to eliminate the laser energy attenuation effect.
所述光谱采集模块还包括第二线偏振片18、光纤耦合镜19、光纤接头20、光纤21及光谱仪22。所述第二线偏振片18位于所述分束镜13及所述光纤耦合镜19之间,所述光纤接头20位于所述光纤耦合镜19及所述光纤21之间,所述光纤21连接所述光谱仪22及所述光纤接头20。所述待测样品15表面等离子体发射的光通过所述物镜14的准直后透过所述分束镜13而到达到所述第二线偏振片18,所述待测样品15表面反射的激光在所述第二线偏振片18处滤除;等离子体光信号可以透过所述第二线偏振片18,并通过所述光纤耦合镜19耦合进所述光纤接头20处;耦合到所述光纤接头20的等离子体光信号通过所述光纤21传导以进入所述光谱仪22。The spectrum acquisition module also includes a second linear polarizer 18 , a fiber coupling mirror 19 , an optical fiber connector 20 , an optical fiber 21 and a spectrometer 22 . The second linear polarizer 18 is located between the beam splitter 13 and the fiber coupling mirror 19, the fiber connector 20 is located between the fiber coupling mirror 19 and the optical fiber 21, and the optical fiber 21 is connected to the The spectrometer 22 and the optical fiber connector 20. The light emitted by the surface plasmon of the sample to be measured 15 is collimated by the objective lens 14 and passes through the beam splitter 13 to reach the second linear polarizer 18, and the laser light reflected by the surface of the sample to be measured 15 Filter out at the second linear polarizer 18; the plasma optical signal can pass through the second linear polarizer 18, and be coupled into the optical fiber connector 20 through the fiber coupling mirror 19; coupled to the optical fiber connector The plasma light signal of 20 is transmitted through the optical fiber 21 to enter the spectrometer 22 .
所述照明模块还包括所述照明准直镜24、所述LED光源25及所述全反镜26。所述照明准直镜24位于所述LED光源25及所述全反镜26之间,所述全反镜26位于所述分光镜23及所述照明准直镜24之间。所述LED光源25发出的光依次经所述照明准直镜24准直、所述全反镜26反射及所述分光镜23透射后进入同轴光路中,然后再依次通过所述宽带反射镜30及所述分束镜13反射、所述物镜14聚焦后照明在所述待测样品15表面的待测区域上。The lighting module also includes the lighting collimating mirror 24 , the LED light source 25 and the total reflection mirror 26 . The illumination collimating mirror 24 is located between the LED light source 25 and the total reflection mirror 26 , and the total reflection mirror 26 is located between the beam splitter 23 and the illumination collimation mirror 24 . The light emitted by the LED light source 25 enters the coaxial optical path after being collimated by the illumination collimating mirror 24, reflected by the total reflection mirror 26 and transmitted by the beam splitter 23, and then passes through the broadband reflector in turn. 30 and the beam splitter 13 reflect, the objective lens 14 focuses and then illuminates the area to be measured on the surface of the sample 15 to be measured.
所述成像模块还包括所述目镜27、所述第三线偏振片28及所述相机29,所述第三线偏振片28位于所述目镜27及所述分光镜23之间,所述目镜27位于所述第三线偏振片28及所述相机29之间。所述待测样品15表面反射的光依次通过所述物镜14准直、所述分束镜13反射及所述宽带反射镜30反射后,经所述激光反射镜12滤除大部分波长为355nm的激光。经所述激光反射镜12滤除处理后的光经所述分光镜23反射后,所述光经所述第三线偏振片28滤除剩余激光后到达所述目镜27,所述目镜27将光信号在所述相机29处成像。The imaging module also includes the eyepiece 27, the third linear polarizer 28 and the camera 29, the third linear polarizer 28 is located between the eyepiece 27 and the beam splitter 23, and the eyepiece 27 is located between the third linear polarizer 28 and the camera 29 . The light reflected from the surface of the sample 15 to be tested is collimated by the objective lens 14, reflected by the beam splitter 13 and reflected by the broadband reflector 30 in sequence, and then filtered by the laser reflector 12 with a wavelength of 355nm laser. After the light filtered by the laser reflector 12 is reflected by the beam splitter 23, the light reaches the eyepiece 27 after the remaining laser light is filtered by the third linear polarizer 28, and the eyepiece 27 converts the light The signal is imaged at said camera 29 .
本实施方式中,多个零件可以实现多功能使用,如:①所述物镜14在激光控制模块中的作用是将激光光斑聚焦,在光谱采集模块中的作用是将等离子体的发光平行化,在照明模块中的作用是将照明光聚焦在待测样品所需区域,在成像模块中作用是承担了显微镜中物镜的功能;②所述激光反射镜12在激光控制模块中的作用是将激光光束高效率地反射,在成像模块中的作用是将样品表面反射的激光滤除防止损害相机;③所述分束镜13在激光控制模块中的作用是反射激光光束,在激光测量模块中的作用是获取部分激光光束用于测量,在照明模块中的作用是反射照明光至样品表面,在成像模块中的作用是反射样品表面光至相机。In this embodiment, multiple parts can be used for multiple functions, such as: ① the function of the objective lens 14 in the laser control module is to focus the laser spot, and the function in the spectrum acquisition module is to parallelize the light emission of the plasma, The function of the illumination module is to focus the illumination light on the required area of the sample to be measured, and the function of the objective lens in the microscope in the imaging module; ② the function of the laser reflector 12 in the laser control module is to focus the laser The light beam is reflected with high efficiency, and the effect in the imaging module is to filter out the laser light reflected by the sample surface to prevent damage to the camera; ③ the effect of the beam splitter 13 in the laser control module is to reflect the laser beam, and in the laser measurement module The function is to obtain part of the laser beam for measurement, the function in the illumination module is to reflect the illumination light to the sample surface, and the function in the imaging module is to reflect the sample surface light to the camera.
本实施方式中,所述光路系统对各个零部件进行了激光防护,如①激光控制模块中,2个激光吸收体前面均设置有激光窗口,以防止激光在吸收体表面烧蚀出颗粒飘散附着在反射镜上;②光谱采集模块中,光纤耦合镜前面设置有线偏振片,防止从样品表面反射的激光通过光纤耦合镜聚焦损害光纤接头;③成像模块中,待测样品表面的光先通过激光反射镜滤除绝大部分激光,再通过线偏振片滤除剩余激光,以保护相机。In this embodiment, the optical path system provides laser protection for each component. For example, in the laser control module, laser windows are set in front of the two laser absorbers to prevent particles from being ablated by the laser on the surface of the absorber from floating and adhering. On the mirror; ②In the spectrum acquisition module, a linear polarizer is set in front of the fiber coupling mirror to prevent the laser reflected from the sample surface from being focused by the fiber coupling mirror and damage the fiber joint; ③In the imaging module, the light on the surface of the sample to be measured first passes through the laser The mirror filters out most of the laser light, and the remaining laser light is filtered out by a linear polarizer to protect the camera.
本发明提供的用于激光探针成分分析仪的光路系统,其集成了激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块,可以同时实现激光能量和光斑控制、激光能量实时监测、等离子体光谱采集、样品表面照明、样品表面成像功能,实现稳定的光谱信息和样品图像信息的同时获取,满足现代工业应用需求;其中激光控制模块、激光监测模块、光谱采集模块、照明模块和成像模块五个模块在光路中是同轴的,结构紧凑,多个零件均可以实现多功能使用。此外,所述光路系统对各个零部件进行了激光防护,提高零部件的使用寿命。The optical path system for a laser probe component analyzer provided by the present invention integrates five modules of a laser control module, a laser monitoring module, a spectrum acquisition module, an illumination module and an imaging module, and can simultaneously realize laser energy and spot control, laser Energy real-time monitoring, plasma spectrum acquisition, sample surface illumination, sample surface imaging functions, to achieve simultaneous acquisition of stable spectral information and sample image information, to meet the needs of modern industrial applications; including laser control module, laser monitoring module, spectrum acquisition module, The five modules of the illumination module and the imaging module are coaxial in the optical path, and the structure is compact, and multiple parts can be used for multiple functions. In addition, the optical path system provides laser protection for each component to improve the service life of the component.
本领域的技术人员容易理解,以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。It is easy for those skilled in the art to understand that the above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention, All should be included within the protection scope of the present invention.
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