CN106637951A - Textile finishing agent added with sodium citrate and preparation method of textile finishing agent - Google Patents
Textile finishing agent added with sodium citrate and preparation method of textile finishing agent Download PDFInfo
- Publication number
- CN106637951A CN106637951A CN201611160500.7A CN201611160500A CN106637951A CN 106637951 A CN106637951 A CN 106637951A CN 201611160500 A CN201611160500 A CN 201611160500A CN 106637951 A CN106637951 A CN 106637951A
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- CN
- China
- Prior art keywords
- parts
- added
- sodium citrate
- textile
- finishing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000001509 sodium citrate Substances 0.000 title claims abstract description 43
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 title claims abstract description 43
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000009988 textile finishing Methods 0.000 title abstract description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 116
- 239000004753 textile Substances 0.000 claims abstract description 47
- -1 phthalic acid ester Chemical class 0.000 claims abstract description 44
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 19
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 19
- SJHCUXCOGGKFAI-UHFFFAOYSA-N tripropan-2-yl phosphite Chemical compound CC(C)OP(OC(C)C)OC(C)C SJHCUXCOGGKFAI-UHFFFAOYSA-N 0.000 claims abstract description 19
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims abstract description 18
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 17
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 17
- 229940057950 sodium laureth sulfate Drugs 0.000 claims abstract description 17
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims abstract description 17
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000000498 ball milling Methods 0.000 claims abstract description 11
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 238000013019 agitation Methods 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 229960000541 cetyl alcohol Drugs 0.000 claims description 18
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 claims description 18
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 235000002566 Capsicum Nutrition 0.000 claims description 16
- 239000006002 Pepper Substances 0.000 claims description 16
- 241000722363 Piper Species 0.000 claims description 16
- 235000016761 Piper aduncum Nutrition 0.000 claims description 16
- 235000017804 Piper guineense Nutrition 0.000 claims description 16
- 235000008184 Piper nigrum Nutrition 0.000 claims description 16
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 16
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 235000019394 potassium persulphate Nutrition 0.000 claims description 16
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 8
- 230000006641 stabilisation Effects 0.000 claims description 8
- 238000011105 stabilization Methods 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 8
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 241000206575 Chondrus crispus Species 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical group NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 235000009508 confectionery Nutrition 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000003756 stirring Methods 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- HEMYXNDMAAOTCK-UHFFFAOYSA-N methyl 2-(1,3-benzodioxol-5-yl)acetate Chemical compound COC(=O)CC1=CC=C2OCOC2=C1 HEMYXNDMAAOTCK-UHFFFAOYSA-N 0.000 abstract 1
- 239000012299 nitrogen atmosphere Substances 0.000 abstract 1
- 229940080236 sodium cetyl sulfate Drugs 0.000 abstract 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 13
- 238000011056 performance test Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000002604 ultrasonography Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 230000002285 radioactive effect Effects 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 241000588653 Neisseria Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 235000013847 iso-butane Nutrition 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920006277 melamine fiber Polymers 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000007918 pathogenicity Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000000554 physical therapy Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 206010040872 skin infection Diseases 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/232—Organic carbonates
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- D—TEXTILES; PAPER
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/415—Amides of aromatic carboxylic acids; Acylated aromatic amines
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a textile finishing agent added with sodium citrate and a preparation method of the textile finishing agent. The textile finishing agent takes phthalic acid ester, ethyl methacrylate, butyl acrylate and sodium citrate as the main ingredients, N,N-diethyl-m-toluamide, tri-isopropyl phosphite, ethylene carbonate, polyvinyl chloride, diethylene glycol, sodium cetyl sulfate, sodium laureth sulfate, potassium peroxodisulfate, methyl 1,3-benzodioxol-5-ylacetate, stannous octoate, a surfactant, a thickening agent and deionized water are added, the processes of heating, stirring, ultrasonic dispersing, ball-milling and reacting under the nitrogen atmosphere are adopted, the anti-ultraviolet performance of a textile is improved after the prepared finishing agent is used on the textile, the requirements of the industry are met, and the textile finishing agent has a better application prospect.
Description
Technical field
The present invention relates to textile dyeing and finishing technical field, is more particularly to added with the textile finish and its system of sodium citrate
Preparation Method.
Background technology
The finishing functions of textile are that to give yarn fabric to meet some Special use requirements of textile excellent
Using the Special Finishing processing method of the, performance such as safety, outward appearance.The functional finish of textile is then with chemistry, biological doctor
The development of the multidisciplinary technology such as, polymer composite, photochemistry, thermodynamics, electricity, ecology get up one
Class product.Due to textile finishing functions for textile some specific performances, thus purpose is strong, and effect is good,
Value-added content of product is also high.Textile is Jing after functional treatment, and its application target and scope are clearly, also very popular.
According to statistics, the demand of world's function textile is more than 50,000,000,000 meters, and the demand of China's function textile is nearly 5,000,000,000 meters.Weaving
The world demand amount of processing and arrangement chemicals increases every year 4.2%, and annual sales amount has reached tens billion of dollars.Feature is spun
The range of application of fabric is relatively broad, is such as used as biomedical tissue and organ；For the antibacterial diseases prevention of preventive medicine, health care
The physiotherapy body shaping of beauty；Fire-retardant, the antistatic of special trade, high/low temperature protection；Domestic environment improves, dust suction noise control, Fu Yousheng
Reason health, mite killing is antifouling, refuses oily water repellent, all kinds of radiation protections etc..Also, from the point of view of development, the arrangement of functional textile
Content and range of application are also during constantly expand, just gradually penetrating into the production of mill run and arranging.
Correspondingly, textile finish also mainly has following species：（1）Antistatic finishing agent：Textile band is quiet
Dust suction and the easy mutual adsorption phenomena for staiing phenomenon, clothes and clothes, clothes and human body after electricity, gently then produces picotement, electricity
Spark, it is heavy then using closing fire and explosion accident beyond fine fabric can cause.Anti-static fabric mainly has embedding knits conductive wire
Arrange with fabric face, the latter is that fabric Jing antistatic additive cover arrangement, can neutralize electrostatic load, reduces sheet resistance, is reduced
Static focus, strengthens fabric moisture so as to reach the effect for eliminating electrostatic.（2）Heat-resistant fireproof finishing agent：Using carbon fiber
High temperature resistant, radiation hardness, corrosion resistant feature performance, are largely used to air material, architectural engineering；Using high temperature resistant, fire-retardant and height
The aramid fiber of toughness makes protective garment, fire-entry suit and ballistic protective clothing.Phosphorous-containing polyester makees flame retardant textiles, for hospital, healthcare industry
And decoration industry；It is used as curtain, wall paper decoration added with the polypropylene fibre of fire retardant；Melamine fiber high temperature resistant, pliability very well, has
There is certain flame retardant efficiency, for fire-fighting domain.（3）Antibacterial finishing agent：Under ideal climate between fabric, bacterium can not
Interrupted ground amount reproduction, causes skin infection, causes sanitary condition deterioration and transmission of disease and spreads.Austrian Meng Daier
Cellulosic fabric is using capsule of nano antibacterial and deodouring technology to bacteriostasis rates such as staphylococcus aureus, gonococcus, Escherichia coli
Up to more than 99%, skin delay skin aging is protected.There is good antimicrobial effect using extensive organosilicone quaternary ammonium salt
With, can effectively suppress and killing cause infection or pathogenicity Gram-negative, positive bacteria, staphylococcus aureus, Candida albicans
The virus such as bacterium and Escherichia coli.It is used for the antibiotic finish of underwear, towel, sheet, shoes store, carpet and medical textile.（4）It is anti-
Moth finishing agent：Wool, silk, eider down, fur etc. are damaged by worms and invade food the rate of complaints up to 7.7%, are only second to change colour, are faded, stain, shrinking,
The 5th is arranged, mothproofing agent once used naphthalene, paracide and camphor, was typically now processed with pyrethroid.（5）Ultraviolet protection is whole
Reason agent：The ultraviolet radioactive for most having harm is at 300 ~ 310 UV-B peaks.The ultraviolet radioactive of fabric is penetrated by two kinds of wave components：One
Kind meeting is immovable through fabric, and another kind of dispersive wave can react with fabric.Ultraviolet protection is arranged ultraviolet radiation absorption
With the class of ultraviolet screener two.（6）PH adjusts finishing agent：There are 40 many kinds of substance in sweat:Sodium chloride, urea, lactic acid and amino acid,
Skin surface general pH=6, the initial stage pH that perspires drops to 4.4, and perspire in a large number pH=7, and time length, urea decomposites NH3, and pH reaches
To 8.0.The pH value of acid rain is less than 5.6.PH finishing agents are combined using nanoceramic particles with fiber, can adjust pH value, and simultaneous
There are sterilized smelly eliminating, ultraviolet screener effect.（7）Heat storing heat preserving finishing agent：Fabric heat-insulation conventional method has：Add carbon in spinning solution
Change zircon ceramic powder, absorb light and release heat, the far infrared of reflection human-body emitting so as to thermal isolation and heat storage；Doughnut is incubated
With automatic heat preserving arrange etc..It is to make iso-butane and propane mixture using catalyst to have studied successful automatic heat preserving cardinal principle
Flameless combustion, each heater block weighs about 495g.
Although having there is the finishing agent of above-mentioned different characteristics at present, specific to each class, what it had uses effect
Fruit need further raising.Therefore, corresponding textile finish is developed for the different qualities required for textile with
Phase greatly improves the performance of textile and just seems particularly necessary.
The content of the invention
To solve above-mentioned technical problem, the present invention provides the textile finish for being added with sodium citrate, by using special
Fixed raw material is combined, and coordinates specific production technology so that the finishing agent being prepared from is weaved after to textile use
The anti-ultraviolet property of product is improved, and the requirement of industry is disclosure satisfy that, with preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
The textile finish of sodium citrate is added with, is prepared by the raw materials in：Phthalic acid ester 40-50 parts,
Polyethyl methacrylate 30-40 parts, butyl acrylate 25-35 parts, sodium citrate 15-25 parts, Repudin-Special 10-16
Part, triisopropyl phosphite 8-12 parts, vinyl carbonate 6-10 parts, polyvinyl chloride 6-8 parts, diethylene glycol (DEG) 5-9 parts, cetanol sulfuric acid
Ester sodium salt 5-7 parts, sodium laureth sulfate 4-6 parts, potassium peroxydisulfate 4-6 parts, pepper methyl acetate 3-5 parts, stannous octoate 2-4
Part, surfactant 3-5 parts, thickener 3-5 parts, 300 parts of deionized water.
Preferably, the surfactant is in AEO, alhpa olefin sulfonate, isethionate
Any one.
Preferably, any one of the thickener in carboxymethylcellulose calcium, carragheen, aerosil.
The preparation method of the described textile finish for being added with sodium citrate, comprises the following steps：
（1）Each raw material is accurately weighed by the weight portion；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
90-110 DEG C, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate are added, in the power of 250-350W
Lower ultrasonic disperse 0.5-1.5 hours, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 1.5-2.5 hours make each component in mixed liquor complete
It is dispersed, diethylene glycol (DEG), cetanol sulfuric ester sodium salt are subsequently added, nitrogen is passed through, magnetic agitation reaction 3 is little at 90 DEG C of temperature
When；
（5）After reaction terminates, when being cooled to 60 DEG C, surfactant, thickener are added in reactant liquor, subsequently carry out magnetic
Power is stirred, until all of composition is well mixed, obtains finished product.
Preferably, the step（3）In, the power of ultrasonic disperse is 300W, and ultrasonic time is 1 hour.
Preferably, the step（4）In, the speed of magnetic agitation is 150-250 r/min.
Compared with prior art, its advantage is the present invention：
（1）The present invention be added with the textile finish of sodium citrate with phthalic acid ester, polyethyl methacrylate, third
Olefin(e) acid butyl ester, sodium citrate be main component, by add Repudin-Special, triisopropyl phosphite, vinyl carbonate,
Polyvinyl chloride, diethylene glycol (DEG), cetanol sulfuric ester sodium salt, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, octanoic acid are sub-
Tin, surfactant, thickener, deionized water, are aided with the work such as reaction under heating, stirring, ultrasonic disperse, ball milling, nitrogen environment
Skill so that after to textile use, the anti-ultraviolet property of textile is improved the finishing agent being prepared from, and disclosure satisfy that industry
Requirement, with preferable application prospect.
（2）The textile finish raw material for being added with sodium citrate of the invention is cheap, process is simple, is suitable to extensive work
Industryization is used, practical.
Specific embodiment
The technical scheme invented is described in detail with reference to specific embodiment.
Embodiment 1
（1）40 parts of phthalic acid ester, 30 parts of polyethyl methacrylate, butyl acrylate 25 are accurately weighed by the weight portion
Part, 15 parts of sodium citrate, 10 parts of Repudin-Special, 8 parts of triisopropyl phosphite, 6 parts of vinyl carbonate, polyvinyl chloride 6
Part, 5 parts of diethylene glycol (DEG), 5 parts of cetanol sulfuric ester sodium salt, 4 parts of sodium laureth sulfate, 4 parts of potassium peroxydisulfate, pepper methyl acetate 3
Part, 2 parts of stannous octoate, 3 parts of AEO, 3 parts of carboxymethylcellulose calcium, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to 90
DEG C, add sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate, the ultrasonic disperse 1 under the power of 300W
Hour, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 1.5 hours makes each component substantially uniformity in mixed liquor
Dispersion, is subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, is passed through nitrogen, with speed as 150 r/min magnetic at 90 DEG C of temperature
Power stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, AEO, carboxymethyl cellulose are added in reactant liquor
Element, subsequently carries out magnetic agitation, until all of composition is well mixed, obtains finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
Embodiment 2
（1）45 parts of phthalic acid ester, 35 parts of polyethyl methacrylate, butyl acrylate 30 are accurately weighed by the weight portion
Part, 20 parts of sodium citrate, 13 parts of Repudin-Special, 10 parts of triisopropyl phosphite, 8 parts of vinyl carbonate, polyvinyl chloride 7
Part, 7 parts of diethylene glycol (DEG), 6 parts of cetanol sulfuric ester sodium salt, 5 parts of sodium laureth sulfate, 5 parts of potassium peroxydisulfate, pepper methyl acetate 4
Part, 3 parts of stannous octoate, 4 parts of alhpa olefin sulfonate, 4 parts of carragheen, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
100 DEG C, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate are added, the ultrasound point under the power of 300W
Dissipate 1 hour, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 2 hours makes each component substantially uniformity point in mixed liquor
Dissipate, be subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, be passed through nitrogen, with speed as 200 r/min magnetic force at 90 DEG C of temperature
Stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, alhpa olefin sulfonate, carragheen are added in reactant liquor, subsequently carried out
Magnetic agitation, until all of composition is well mixed, obtains finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
Embodiment 3
（1）50 parts of phthalic acid ester, 40 parts of polyethyl methacrylate, butyl acrylate 35 are accurately weighed by the weight portion
Part, 25 parts of sodium citrate, 16 parts of Repudin-Special, 12 parts of triisopropyl phosphite, 10 parts of vinyl carbonate, polyvinyl chloride
8 parts, 9 parts of diethylene glycol (DEG), 7 parts of cetanol sulfuric ester sodium salt, 6 parts of sodium laureth sulfate, 6 parts of potassium peroxydisulfate, pepper methyl acetate 5
Part, 4 parts of stannous octoate, 5 parts of isethionate, 5 parts of aerosil, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
110 DEG C, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate are added, the ultrasound point under the power of 300W
Dissipate 1 hour, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 2.5 hours makes each component substantially uniformity in mixed liquor
Dispersion, is subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, is passed through nitrogen, with speed as 250 r/min magnetic at 90 DEG C of temperature
Power stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, isethionate, aerosil are added in reactant liquor, with
After carry out magnetic agitation, until all of composition is well mixed, obtain finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
Embodiment 4
（1）50 parts of phthalic acid ester, 30 parts of polyethyl methacrylate, butyl acrylate 35 are accurately weighed by the weight portion
Part, 15 parts of sodium citrate, 16 parts of Repudin-Special, 8 parts of triisopropyl phosphite, 10 parts of vinyl carbonate, polyvinyl chloride 6
Part, 9 parts of diethylene glycol (DEG), 5 parts of cetanol sulfuric ester sodium salt, 6 parts of sodium laureth sulfate, 4 parts of potassium peroxydisulfate, pepper methyl acetate 5
Part, 2 parts of stannous octoate, 5 parts of alhpa olefin sulfonate, 3 parts of carboxymethylcellulose calcium, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
110 DEG C, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate are added, the ultrasound point under the power of 300W
Dissipate 1 hour, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 1.5 hours makes each component substantially uniformity in mixed liquor
Dispersion, is subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, is passed through nitrogen, with speed as 250 r/min magnetic at 90 DEG C of temperature
Power stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, alhpa olefin sulfonate, carboxymethylcellulose calcium are added in reactant liquor, with
After carry out magnetic agitation, until all of composition is well mixed, obtain finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
Comparative example 1
（1）45 parts of phthalic acid ester, 35 parts of polyethyl methacrylate, butyl acrylate 30 are accurately weighed by the weight portion
Part, 20 parts of sodium citrate, 13 parts of Repudin-Special, 10 parts of triisopropyl phosphite, 8 parts of vinyl carbonate, polyvinyl chloride 7
Part, 7 parts of diethylene glycol (DEG), 6 parts of cetanol sulfuric ester sodium salt, 5 parts of potassium peroxydisulfate, 4 parts of pepper methyl acetate, 4 parts of alhpa olefin sulfonate,
4 parts of carragheen, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
100 DEG C, potassium peroxydisulfate, pepper methyl acetate are added, ultrasonic disperse 1 hour, obtains mixed liquid B under the power of 300W；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 2 hours makes each component substantially uniformity point in mixed liquor
Dissipate, be subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, be passed through nitrogen, with speed as 200 r/min magnetic force at 90 DEG C of temperature
Stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, alhpa olefin sulfonate, carragheen are added in reactant liquor, subsequently carried out
Magnetic agitation, until all of composition is well mixed, obtains finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
Comparative example 2
（1）50 parts of phthalic acid ester, 30 parts of polyethyl methacrylate, butyl acrylate 35 are accurately weighed by the weight portion
Part, 15 parts of sodium citrate, 16 parts of Repudin-Special, 8 parts of triisopropyl phosphite, 10 parts of vinyl carbonate, polyvinyl chloride 6
Part, 9 parts of diethylene glycol (DEG), 5 parts of cetanol sulfuric ester sodium salt, 6 parts of sodium laureth sulfate, 2 parts of stannous octoate, alhpa olefin sulfonate 5
Part, 3 parts of carboxymethylcellulose calcium, 300 parts of deionized water；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
110 DEG C, sodium laureth sulfate, stannous octoate are added, ultrasonic disperse 1 hour, obtains mixed liquid B under the power of 300W；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 1.5 hours makes each component substantially uniformity in mixed liquor
Dispersion, is subsequently added diethylene glycol (DEG), cetanol sulfuric ester sodium salt, is passed through nitrogen, with speed as 250 r/min magnetic at 90 DEG C of temperature
Power stirring reaction 3 hours；
（5）After reaction terminates, when being cooled to 60 DEG C, alhpa olefin sulfonate, carboxymethylcellulose calcium are added in reactant liquor, with
After carry out magnetic agitation, until all of composition is well mixed, obtain finished product.
The performance test results of the obtained textile finish for being added with sodium citrate are as shown in table 1.
By embodiment 1-4 and comparative example 1-2 be added with the textile finish of sodium citrate to textile administration after, it is right
Respectively UVA transmitances, UVB transmitances, UPF values are measured textile.
Table 1
| UVA transmitances（%） | UVB transmitances（%） | UPF values | |
| Embodiment 1 | 3.9 | 1.2 | 62.7 |
| Embodiment 2 | 3.5 | 0.8 | 71.8 |
| Embodiment 3 | 3.8 | 1.1 | 65.6 |
| Embodiment 4 | 3.6 | 0.9 | 70.4 |
| Comparative example 1 | 5.2 | 1.6 | 59.5 |
| Comparative example 2 | 5.7 | 1.9 | 57.3 |
The present invention's is added with the textile finish of sodium citrate with phthalic acid ester, polyethyl methacrylate, propylene
Acid butyl ester, sodium citrate are main component, by adding Repudin-Special, triisopropyl phosphite, vinyl carbonate, poly-
Vinyl chloride, diethylene glycol (DEG), cetanol sulfuric ester sodium salt, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate,
Surfactant, thickener, deionized water, are aided with the technique such as reaction under heating, stirring, ultrasonic disperse, ball milling, nitrogen environment,
So that the finishing agent being prepared from is after to textile use, the anti-ultraviolet property of textile is improved, and disclosure satisfy that industry
Require, with preferable application prospect.The textile finish raw material for being added with sodium citrate of the invention is cheap, technique is simple
It is single, heavy industrialization utilization is suitable to, it is practical.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (6)
1. a kind of textile finish for being added with sodium citrate, it is characterised in that：It is prepared by the raw materials in：Adjacent benzene
Dicarboxylic acid esters 40-50 parts, polyethyl methacrylate 30-40 parts, butyl acrylate 25-35 parts, sodium citrate 15-25 parts, two
It is formamide 10-16 parts between ethyl, triisopropyl phosphite 8-12 parts, vinyl carbonate 6-10 parts, polyvinyl chloride 6-8 parts, two sweet
Alcohol 5-9 parts, cetanol sulfuric ester sodium salt 5-7 parts, sodium laureth sulfate 4-6 parts, potassium peroxydisulfate 4-6 parts, pepper methyl acetate
3-5 parts, stannous octoate 2-4 parts, surfactant 3-5 parts, thickener 3-5 parts, 300 parts of deionized water.
2. the textile finish for being added with sodium citrate according to claim 1, it is characterised in that：The surface-active
Any one of agent in AEO, alhpa olefin sulfonate, isethionate.
3. the textile finish for being added with sodium citrate according to claim 1, it is characterised in that：The thickener choosing
Any one from carboxymethylcellulose calcium, carragheen, aerosil.
4. according to the preparation method of the arbitrary described textile finish for being added with sodium citrate of claim 1-3, its feature
It is to comprise the following steps：
（1）Each raw material is accurately weighed by the weight portion；
（2）100 parts of ionized water is removed, sodium citrate, Repudin-Special, triisopropyl phosphite, ethene is added thereto to
Carbonic ester, polyvinyl chloride, are heated to 55 DEG C, and magnetic agitation is carried out after temperature stabilization, and magnetic agitation rotating speed is 200 rpm, is stirred
To uniform, mixed liquor A is obtained；
（3）By deionized water, 200 parts mix with phthalic acid ester, polyethyl methacrylate, butyl acrylate, are warming up to
90-110 DEG C, sodium laureth sulfate, potassium peroxydisulfate, pepper methyl acetate, stannous octoate are added, in the power of 250-350W
Lower ultrasonic disperse 0.5-1.5 hours, obtain mixed liquid B；
（4）Mixed liquor A and mixed liquid B are merged, ball mill is sent into, ball milling 1.5-2.5 hours make each component in mixed liquor complete
It is dispersed, diethylene glycol (DEG), cetanol sulfuric ester sodium salt are subsequently added, nitrogen is passed through, magnetic agitation reaction 3 is little at 90 DEG C of temperature
When；
（5）After reaction terminates, when being cooled to 60 DEG C, surfactant, thickener are added in reactant liquor, subsequently carry out magnetic
Power is stirred, until all of composition is well mixed, obtains finished product.
5. the preparation method of the textile finish for being added with sodium citrate according to claim 4, it is characterised in that institute
State step（3）In, the power of ultrasonic disperse is 300W, and ultrasonic time is 1 hour.
6. the preparation method of the textile finish for being added with sodium citrate according to claim 4, it is characterised in that institute
State step（4）In, the speed of magnetic agitation is 150-250 r/min.
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