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CN106634765A - Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof - Google Patents

Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof Download PDF

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Publication number
CN106634765A
CN106634765A CN201611169353.XA CN201611169353A CN106634765A CN 106634765 A CN106634765 A CN 106634765A CN 201611169353 A CN201611169353 A CN 201611169353A CN 106634765 A CN106634765 A CN 106634765A
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CN
China
Prior art keywords
black
lcd
sealing compound
allyl
prepolymer
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611169353.XA
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Chinese (zh)
Inventor
韦宏权
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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Application filed by Shenzhen China Star Optoelectronics Technology Co Ltd filed Critical Shenzhen China Star Optoelectronics Technology Co Ltd
Priority to CN201611169353.XA priority Critical patent/CN106634765A/en
Publication of CN106634765A publication Critical patent/CN106634765A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • C09J167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1339Gaskets; Spacers; Sealing of cells
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Nonlinear Science (AREA)
  • Organic Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention provides a black sealing compound and an LCD (liquid crystal display) special-shaped screen, and a manufacturing method thereof. The black sealing compound has high adhesive force and high OD (optical density) value, can be used for sealing the fracture notch of the LCD special-shaped screen, and has favorable shading effects. According to the manufacturing method of the LCD special-shaped screen, a cutting mode is adopted to manufacture the LCD special-shaped screen, and the black sealing compound is adopted to seal the LCD special-shaped screen. The prepared LCD special-shaped screen can not generate light leakage at the fracture notch, thereby avoiding the use of the black shading adhesive tape in the subsequent assembly process with the backlight module. Meanwhile, compared with the manufacturing method of the LCD special-shaped screen provided with a special photomask, the manufacturing method provided by the invention is lower in production cost. The LCD special-shaped screen is prepared by using a cutting mode and sealed by the black sealing compound, so that the fracture notch can not generate light leakage, and the LCD special-shaped screen has favorable display quality.

Description

Black sealing compound and LCD abnormity screens and preparation method thereof
Technical field
The present invention relates to display technology field, more particularly to a kind of black sealing compound and LCD abnormity screens and preparation method thereof.
Background technology
Fill as the planes such as the development of Display Technique, liquid crystal display (Liquid Crystal Display, LCD) show Put because having the advantages that high image quality, power saving, fuselage be thin and applied range, and be widely used in mobile phone, TV, individual number The various consumption electronic products such as word assistant, digital camera, notebook computer, desktop computer, become the master in display device Stream.
It is backlight liquid crystal display that liquid crystal indicator on existing market is most of, it include display panels and Backlight module (backlight module).The operation principle of display panels is put in the middle of the parallel glass substrate of two panels Liquid crystal molecule is put, there are many tiny electric wires vertically and horizontally in the middle of two panels glass substrate, by whether being powered liquid crystal is controlled Molecular changes direction, by the light of backlight module generation picture is reflected.
Generally display panels are by color film (CF, Color Filter) substrate, thin film transistor (TFT) (TFT, Thin Film Transistor) substrate, the liquid crystal (LC, Liquid Crystal) that is sandwiched between color membrane substrates and thin film transistor base plate and close Sealing frame (Sealant) is constituted, and its moulding process is generally comprised:Leading portion array (Array) processing procedure (film, gold-tinted, etching and stripping Film), stage casing (drive IC with printing electricity into box (Cell) processing procedure (TFT substrate and CF baseplate-laminatings) and back segment module group assembling processing procedure Road plate pressing).Wherein, leading portion Array processing procedures mainly form TFT substrate, in order to control the motion of liquid crystal molecule;Stage casing Cell processing procedures mainly add liquid crystal between TFT substrate and CF substrates;Back segment module group assembling processing procedure mainly drives IC pressings Rotate with the integration of printed circuit board (PCB), and then driving liquid crystal molecule, display image.
At present, the length-width ratio of most of liquid crystal display on the market is 4:3 or 16:9 rectangular display, both Ratio is applied by most occasions.But for the display field of some specific uses, it is often necessary to some special length and width Than or special shape electronic console, such as Medical Instruments, automobile instrument panel, subway train information display screen are this kind of aobvious Show that the display panels that device is adopted are commonly known as LCD abnormity screens.
At present the preparation method of the LCD abnormity screens of industry mainly has two kinds:First method is by opening up with special The light shield of shape and size, according to normal production procedure the abnormity screens of the LCD with special requirement are produced.Second method is The display panels with certain size are first produced, the display panels of required form and size are then cut into, is applied Upper sealing compound is sealed, and is then connected after circuit part, completes the making of the LCD abnormity screens of required size.
LCD abnormity screen is not in leakage problem obtained in above-mentioned first method, but due to needing to newly open multiple tracks light Cover, therefore cost intensive, consider from economy, and manufacturer generally adopts second method, i.e., according to unified size and rule Lattice make display panels, then it are cut and is sealed, and refer to Fig. 1, the cutting processing procedure of the display panels Usually:The upper and lower polaroid 210,220 of display panels is cut first, and tears unwanted part, afterwards Upper and lower substrate 110,120 is cut, however, because the line of cut of the upper and lower polaroid 210,220 is usually located at institute The segment distance of inner side one of the line of cut of upper and lower substrate 110,120 is stated, do not go up during ensureing and cut upper and lower substrate 110,120, Down polaroid 210,220 is blocked, therefore the edge 300 of the upper and lower polaroid 210,220 obtained after cutting generally will not be with institute The otch 400 for stating upper and lower substrate 110,120 aligns, but positioned at one section of the inner side of otch 400 of the upper and lower substrate 110,120 Distance, so as to cause the fringe region 500 of obtained LCD abnormity screen 800 due to blocking without upper and lower polaroid 210,220 And light leak is produced, although sealing compound 600 can penetrate into one segment distance of the inside of liquid crystal layer 700 by siphonic effect, due to existing Some sealing compounds 600 are generally transparent or faint yellow, therefore can not play interception.To solve this problem, generally in institute State LCD abnormity screen 800 with backlight module be assembled into liquid crystal display when, stick a black shading glue in the bottom of backlight module Band carries out shading, but stickup required precision of the method to black shading rubber belt is higher, easily occurs that shaded effect is bad to lead The problem for causing liquid crystal display device light leakage to turn white.
The content of the invention
It is an object of the invention to provide a kind of black sealing compound, with high adhesion force and high OD values, can be used for different to LCD The section incision of shape screen is sealed, and shaded effect is preferable.
The present invention also aims to provide a kind of preparation method of LCD abnormity screen, obtained LCD abnormity screen is cut in section Light leak, and low manufacture cost will not be produced at mouthful.
The present invention also aims to provide a kind of LCD abnormity screen, section incision will not produce light leak, display quality compared with It is good.
A kind of for achieving the above object, black sealing compound of present invention offer, including modified pi-allyl unsaturated polyester resin, Olefines prepolymer, UV reactivity polyfunctional group acrylic resins, black dyes, ultraviolet initiator and auxiliary additive;Its In, the mass percent of the modified pi-allyl unsaturated polyester resin is 30%~80%, the matter of the olefines prepolymer Amount percentage is 10%~30%, and the mass percent of the UV reactivity polyfunctional group acrylic resin is 1%~11%, institute The mass percent for stating black dyes is 5%~25%, and the mass percent of the ultraviolet initiator is 1%~3%, described The mass percent of auxiliary additive is 0.5%~2%.
The modified pi-allyl unsaturated polyester resin includes that the polyorganosiloxane resin containing Allyl end groups, allyl ether change One or more in property unsaturated polyester (UP) and pi-allyl esters of unsaturated carboxylic acids;
The olefines prepolymer includes that butadiene prepolymer, isoprene prepolymer and styrene-butadiene are pre- One or more in polymer;
The black dyes includes organic black dyes, be shown as black the mixture of multiple color dyestuff, carbon black and One or more during titanium is black;
UV reactivity polyfunctional group acrylic resin include glycol diacrylate, 2- hydroxy acrylates, three One or more in hydroxymethyl-propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive include viscosity modifier, silane coupler, interfacial agent and plasticizer in one kind or It is various;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
The viscosity of the black sealing compound is 1000mPas~50000mPas.
The present invention also provides a kind of preparation method of LCD abnormity screen, including:
Step 1, one display panels of offer, the display panels include the upper substrate being oppositely arranged and lower base Plate, the liquid crystal layer between the upper substrate and infrabasal plate, it is attached on the upper substrate away from the liquid crystal layer side Upper polaroid and down polaroid away from the liquid crystal layer side is attached on the infrabasal plate;
The display panels are cut according to required shape and size, is obtained one and be there is section otch LCD abnormity screens;
Step 2, offer black sealing compound, the black sealing compound includes modified pi-allyl unsaturated polyester resin, alkene Class prepolymer, UV reactivity polyfunctional group acrylic resins, black dyes, ultraviolet initiator and auxiliary additive;Wherein, The mass percent of the modified pi-allyl unsaturated polyester resin is 30%~80%, the quality hundred of the olefines prepolymer Divide than being 10%~30%, the mass percent of the UV reactivity polyfunctional group acrylic resin is 1%~11%, described black The mass percent of color dyestuff is 5%~25%, and the mass percent of the ultraviolet initiator is 1%~3%, the auxiliary The mass percent of additive is 0.5%~2%;
The black sealing compound is coated in into the section incision of the LCD abnormity screen, is stood, make the black sealing compound Penetrate into inside from the section incision to the liquid crystal layer;
Step 3, the LCD abnormity screens to having oozed glue carry out ultraviolet light, make the black sealing adhesive curing, complete to institute State the sealing of LCD abnormity screens.
The modified pi-allyl unsaturated polyester resin includes that the polyorganosiloxane resin containing Allyl end groups, allyl ether change One or more in property unsaturated polyester (UP) and pi-allyl esters of unsaturated carboxylic acids;
The olefines prepolymer includes that butadiene prepolymer, isoprene prepolymer and styrene-butadiene are pre- One or more in polymer;
The black dyes includes organic black dyes, be shown as black the mixture of multiple color dyestuff, carbon black and One or more during titanium is black;
UV reactivity polyfunctional group acrylic resin include glycol diacrylate, 2- hydroxy acrylates, three One or more in hydroxymethyl-propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive include viscosity modifier, silane coupler, interfacial agent and plasticizer in one kind or It is various;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
The viscosity of the black sealing compound is 1000mPas~50000mPas.
In the step 2, the mode that the black sealing compound is coated in the section incision of the LCD abnormity screen is: Using nozzle in section incision spray black sealing compound, Huo Zhewei:In the container for filling black sealing compound, by the LCD In the section incision immersion black sealing compound of abnormity screen, make the section incision fill black sealing compound, then take out;
The step 2 is carried out under 20 DEG C~60 DEG C of environment temperature, and time of repose is 5min~5h;
In the step 2, control the black sealing compound from the section incision to the liquid crystal layer inside penetrate into Depth is 1mm~5mm;
In the step 3, the wavelength of the ultraviolet light is 300nm~400nm, and the illumination of the ultraviolet light is 10mW/cm2 ~200mW/cm2, exposure is 1000mj/cm2~5000mj/cm2
The present invention also provides a kind of LCD abnormity screen, by entering to a display panels according to required shape and size Row cutting, is obtained in section incision coating black sealing compound and after carrying out UV solidifications, and the display panels include relatively The upper substrate and infrabasal plate of setting, the liquid crystal layer between the upper substrate and infrabasal plate, be attached on the upper substrate it is remote From the liquid crystal layer side upper polaroid and be attached on the infrabasal plate lower polarisation away from the liquid crystal layer side Piece;The black sealing compound penetrates into from the section incision to the inside of liquid crystal layer;
The black sealing compound includes modified pi-allyl unsaturated polyester resin, olefines prepolymer, many officials of UV reactivity Acrylic resin, black dyes, ultraviolet initiator and auxiliary additive can be rolled into a ball;Wherein, the modified pi-allyl is unsaturated poly- The mass percent of ester resin is 30%~80%, and the mass percent of the olefines prepolymer is 10%~30%, described The mass percent of UV reactivity polyfunctional group acrylic resins is 1%~11%, and the mass percent of the black dyes is 5%~25%, the mass percent of the ultraviolet initiator is 1%~3%, and the mass percent of the auxiliary additive is 0.5%~2%.
The modified pi-allyl unsaturated polyester resin includes that the polyorganosiloxane resin containing Allyl end groups, allyl ether change One or more in property unsaturated polyester (UP) and pi-allyl esters of unsaturated carboxylic acids;
The olefines prepolymer includes that butadiene prepolymer, isoprene prepolymer and styrene-butadiene are pre- One or more in polymer;
The black dyes includes organic black dyes, be shown as black the mixture of multiple color dyestuff, carbon black and One or more during titanium is black;
UV reactivity polyfunctional group acrylic resin include glycol diacrylate, 2- hydroxy acrylates, three One or more in hydroxymethyl-propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive include viscosity modifier, silane coupler, interfacial agent and plasticizer in one kind or It is various;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
The viscosity of the black sealing compound is 1000mPas~50000mPas;The black sealing compound breaks from described The depth that face incision is penetrated into the inside of liquid crystal layer is 1mm~5mm.
Beneficial effects of the present invention:A kind of black sealing compound that the present invention is provided, with high adhesion force and high OD values, can use Seal in the section incision to LCD abnormity screens, and shaded effect is preferable.A kind of LCD abnormity screens that the present invention is provided Preparation method, makes LCD abnormity screens by the way of cutting, and LCD abnormity screens are sealed using above-mentioned black sealing compound, Obtained LCD abnormity screen will not produce light leak in section incision, so as to save in assembling process subsequently with backlight module The use of black removal shading rubber belt, while compared with the preparation method of LCD abnormity screens for opening up special light shield, the LCD of the present invention The preparation method production cost of abnormity screen is relatively low.A kind of LCD abnormity screens that the present invention is provided, are obtained by the way of cutting, and Sealed using above-mentioned black sealing compound, section incision will not produce light leak, display quality is preferable.
In order to be able to be further understood that the feature and technology contents of the present invention, refer to below in connection with the detailed of the present invention Illustrate and accompanying drawing, but accompanying drawing only provides with reference to and illustrates to use, not for being any limitation as to the present invention.
Description of the drawings
Below in conjunction with the accompanying drawings, described in detail by the specific embodiment to the present invention, technical scheme will be made And other beneficial effects are apparent.
In accompanying drawing,
Fig. 1 is the light leak schematic diagram of existing LCD abnormity screen;
Fig. 2 is the flow chart of the preparation method of the LCD abnormity screens of the present invention;
The structural representation of 1 display panels for providing of the step of Fig. 3 is the preparation method of the LCD abnormity screens of the present invention Figure;
Unsealed LCD abnormity screen obtained in the step of Fig. 4 A-4C are the preparation method of the LCD abnormity screens of the present invention 1 The structural representation of three kinds of embodiments;
The schematic diagram of the step of Fig. 5 is the preparation method of the LCD abnormity screens of the present invention 2;
The schematic diagram of the step of Fig. 6 is the preparation method of the LCD abnormity screens of the present invention 3 and the LCD abnormity screens of the present invention A kind of structural representation of embodiment.
Specific embodiment
Further to illustrate the technological means taken of the invention and its effect, below in conjunction with being preferable to carry out for the present invention Example and its accompanying drawing are described in detail.
Present invention firstly provides a kind of black sealing compound, including modified pi-allyl unsaturated polyester resin, olefines pre-polymerization Thing, UV reactivity polyfunctional group acrylic resins, black dyes, ultraviolet initiator and auxiliary additive;Wherein, it is described to change Property pi-allyl unsaturated polyester resin mass percent be 30%~80%, the mass percent of the olefines prepolymer is 10%~30%, the mass percent of the UV reactivity polyfunctional group acrylic resin is 1%~11%, the black dyes Mass percent be 5%~25%, the mass percent of the ultraviolet initiator is 1%~3%, the auxiliary additive Mass percent be 0.5%~2%.
Preferably, the mass percent of the olefines prepolymer is 10%~20%, the UV reactivity polyfunctional group The mass percent of acrylic resin is 1%~6%, and the mass percent of the black dyes is 5%~20%.
Specifically, the modified pi-allyl unsaturated polyester resin includes polyorganosiloxane resin, alkene containing Allyl end groups One or more in propyl ether modified unsaturated polyester and pi-allyl esters of unsaturated carboxylic acids.
Specifically, the olefines prepolymer include butadiene prepolymer, isoprene prepolymer and styrene- One or more in butadiene prepolymer.
Specifically, the black dyes include organic black dyes, be shown as black multiple color dyestuff mixture, One or more during carbon black and titanium are black.
Specifically, the UV reactivity polyfunctional groups acrylic resin includes glycol diacrylate, 2- hydroxies One or more in acid esters, trimethylolpropane trimethacrylate, dipentaerythritol acrylate.
Specifically, the photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
Specifically, the auxiliary additive is included in viscosity modifier, silane coupler, interfacial agent and plasticizer One or more.
Specifically, the viscosity of the black sealing compound is 1000mPas~50000mPas.
Above-mentioned black sealing compound, with high adhesion force and high OD values, can be used to carry out the section incision of LCD abnormity screens Sealing, and shaded effect is preferable.
Fig. 2 is referred to, based on above-mentioned black sealing compound, the present invention also provides a kind of preparation method of LCD abnormity screen, bag Include:
Step 1, as shown in Figure 3 a, there is provided display panels 100, the display panels 100 include being oppositely arranged Upper substrate 11 and infrabasal plate 12, the liquid crystal layer 30 between the upper substrate 11 and infrabasal plate 12, be attached at the upper base On plate 11 away from the side of the liquid crystal layer 30 upper polaroid 21 and be attached on the infrabasal plate 12 away from the liquid crystal layer The down polaroid 22 of 30 sides;
As shown in figs. 4 a-4 c, the display panels 100 are cut according to required shape and size, is obtained The one LCD abnormity screen 200 with section otch 40.
Specifically, the cutting processing procedure of the display panels 100 is:First to the upper and lower inclined of display panels 100 Mating plate 21,22 is cut, and tears unwanted part, and upper and lower substrate 11,12 is cut afterwards, described upper and lower inclined The line of cut of mating plate 21,22 is usually located at the segment distance of inner side one of the line of cut of the upper and lower substrate 11,12, to ensure cutting There is no blocking for upper and lower polaroid 21,22 during upper and lower substrate 11,12, therefore the upper and lower polaroid 21,22 obtained after cutting Edge generally will not align with the otch of the upper and lower substrate 11,12, but in the otch of the upper and lower substrate 11,12 The segment distance of side one, so as to cause the fringe region of obtained LCD abnormity screen 200 due to blocking without upper and lower polaroid 21,22 And produce light leak.After the follow-up section otch 40 of black sealing compound 50 pairs using the present invention is coated, using siphon Effect, makes black sealing compound 50 penetrate into inside liquid crystal layer 30, and using the black sealing compound 50 for penetrating into 200 sides of LCD abnormity screens are blocked The light-leaking area of edge, so as to play a part of to block light leak.
Specifically, between the line of cut of the line of cut of the upper and lower polaroid 21,22 and the upper and lower substrate 11,12 Distance is 1mm~5mm.
Specifically, the section otch 40 can be upper and lower substrate 11,12 alignment smooth otch (as shown in Figure 4 A), Step-like otch (as shown in Figure 4 B) that upper and lower substrate 11,12 is not lined up or be to panel itself depression U-shaped breach (such as Shown in Fig. 4 C).
Specifically, the platform that the smooth otch of the alignment of the upper and lower substrate 11,12 is not lined up with the upper and lower substrate 11,12 Scalariform otch is generally obtained by way of cutter cutting, the U-shaped breach to panel itself depression generally by liquid or The mode of laser ablation is obtained.
Step 2, as shown in Figure 5, there is provided black sealing compound 50, the black sealing compound 50 is that previously described black is sealed Glue, its concrete component and characteristic are as it was noted above, here is omitted.
The black sealing compound 50 is coated at the section otch 40 of the LCD abnormity screen 200, is stood, made described black Color sealing compound 50 penetrates into from the section otch 40 to the inside of the liquid crystal layer 30.
Specifically, in the step 2, the black sealing compound 50 is coated in into the section otch of the LCD abnormity screen 200 Mode at 40 is:Using nozzle (Nozzle) at section otch 40 spray black sealing compound 50, Huo Zhewei:Filling black In the container of sealing compound 50, will immerse in black sealing compound 50 at the section otch 40 of LCD abnormity screen 200, make described disconnected Black sealing compound 50 is filled at face otch 40, is then taken out.
Specifically, in the step 2, due to existing between the air pressure inside and external atmosphere pressure of LCD abnormity screen 200 , there is siphonic effect in pressure reduction, therefore the black sealing compound 50 can be made to penetrate into inside liquid crystal layer 30 from the section otch 40.
Preferably, the step 2 is carried out under 20 DEG C~60 DEG C of environment temperature, and time of repose is 5min~5h.
Specifically, in the step 2, by control environment temperature (20 DEG C~60 DEG C), time of repose (5min~5h) and The factors such as the viscosity (1000mPas~50000mPas) of black sealing compound 50 are controlling the infiltration depth of black sealing compound 50 Degree, under backlight, by rotating the LCD abnormity screen 200 strike-through depth is observed.
Specifically, in the step 2, the black sealing compound 50 is generally controlled from the section otch 40 to the liquid The depth that the inside of crystal layer 30 is penetrated into is 1mm~5mm.
Step 3, as shown in fig. 6, the LCD abnormity screen 200 to having oozed glue carries out ultraviolet light (UV) irradiation, seal the black Chewing-gum 50 solidifies, and completes the sealing to LCD abnormity screen 200.
Specifically, in the step 3, the wavelength of the ultraviolet light is 300nm~400nm, and the illumination of the ultraviolet light is 10mW/cm2~200mW/cm2, exposure is 1000mj/cm2~5000mj/cm2
The preparation method of above-mentioned LCD abnormity screen, makes LCD abnormity screen 200 by the way of cutting, and using above-mentioned black The LCD abnormity screen 200 of sealing compound 50 pairs is sealed, and obtained LCD abnormity screen 200 will not be produced Lou at section otch 40 Light, so as to the use that can save black removal shading rubber belt in assembling process subsequently with backlight module, while with open up special light The preparation method of the LCD abnormity screens of cover is compared, and the preparation method production cost of the LCD abnormity screens of the present invention is relatively low.
Fig. 3 and Fig. 6 is referred to, based on the preparation method of above-mentioned LCD abnormity screens, the present invention also provides a kind of LCD abnormity screen 200, it is coated by cutting to a display panels 100 according to required shape and size at section otch 40 Black sealing compound 50 simultaneously carries out being obtained after UV solidifications;The display panels 100 include the upper substrate 11 being oppositely arranged with Substrate 12, the liquid crystal layer 30 between the upper substrate 11 and infrabasal plate 12, it is attached on the upper substrate 11 away from described The upper polaroid 21 of the side of liquid crystal layer 30 and lower polarisation away from the side of the liquid crystal layer 30 is attached on the infrabasal plate 12 Piece 22;The black sealing compound 50 penetrates into from the section otch 40 to the inside of liquid crystal layer 30.
Specifically, the black sealing compound 50 is previously described black sealing compound, and its concrete component and characteristic are as above Described, here is omitted.
Specifically, to the inside of liquid crystal layer 30, the depth of infiltration is the black sealing compound 50 from the section otch 40 1mm~5mm, so as to block the light-leaking area at 200 edges of the LCD abnormity screen, plays a part of to block light leak.
Above-mentioned LCD abnormity screen, is obtained by the way of cutting, and is sealed using above-mentioned black sealing compound 50, section Light leak will not be produced at otch 200, display quality is preferable.
In sum, the present invention provides a kind of black sealing compound and LCD abnormity screens and preparation method thereof.The black of the present invention Sealing compound, with high adhesion force and high OD values, can be used to seal the section incision of LCD abnormity screens, and shaded effect Preferably.The preparation method of the LCD abnormity screens of the present invention, makes LCD abnormity screens by the way of cutting, and is sealed using above-mentioned black Chewing-gum is sealed to LCD abnormity screens, and obtained LCD abnormity screen will not produce light leak in section incision, so as to subsequently with The use of black removal shading rubber belt can be saved in the assembling process of backlight module, at the same with open up special light shield LCD abnormity screen Preparation method is compared, and the preparation method production cost of the LCD abnormity screens of the present invention is relatively low.The LCD abnormity screens of the present invention, adopt and cut The mode cut is obtained, and is sealed using above-mentioned black sealing compound, and section incision will not produce light leak, display quality compared with It is good.
The above, for the person of ordinary skill of the art, can be with technology according to the present invention scheme and technology Other various corresponding changes and deformation are made in design, and all these changes and deformation should all belong to the claims in the present invention Protection domain.

Claims (10)

1. a kind of black sealing compound, it is characterised in that including modified pi-allyl unsaturated polyester resin, olefines prepolymer, UV Reactive polyfunctional group acrylic resin, black dyes, ultraviolet initiator and auxiliary additive;Wherein, the modified allyl The mass percent of base unsaturated polyester resin is 30%~80%, the mass percent of the olefines prepolymer is 10%~ 30%, the mass percent of the UV reactivity polyfunctional group acrylic resin is 1%~11%, the quality of the black dyes Percentage is 5%~25%, and the mass percent of the ultraviolet initiator is 1%~3%, the quality of the auxiliary additive Percentage is 0.5%~2%.
2. black sealing compound as claimed in claim 1, it is characterised in that the modified pi-allyl unsaturated polyester resin includes In polyorganosiloxane resin containing Allyl end groups, allyl ether modified unsaturated polyester and pi-allyl esters of unsaturated carboxylic acids one Plant or various;
The olefines prepolymer includes butadiene prepolymer, isoprene prepolymer and styrene-butadiene prepolymerization One or more in thing;
The black dyes is black including organic black dyes, the mixture of the multiple color dyestuff for being shown as black, carbon black and titanium In one or more;
The UV reactivity polyfunctional groups acrylic resin includes glycol diacrylate, 2- hydroxy acrylates, three hydroxyl first One or more in base propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive includes the one kind or many in viscosity modifier, silane coupler, interfacial agent and plasticizer Kind;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
3. black sealing compound as claimed in claim 1, it is characterised in that the viscosity of the black sealing compound is 1000mPas ~50000mPas.
4. the preparation method that a kind of LCD abnormity shields, it is characterised in that include:
Step 1, one display panels of offer (100), the display panels (100) are including the upper substrate being oppositely arranged (11) and infrabasal plate (12), the liquid crystal layer (30) between the upper substrate (11) and infrabasal plate (12), it is attached on described On substrate (11) away from the liquid crystal layer (30) side upper polaroid (21) and be attached on the infrabasal plate (12) away from The down polaroid (22) of liquid crystal layer (30) side;
The display panels (100) are cut according to required shape and size, is obtained one and be there is section otch (40) LCD abnormity screen (200);
Step 2, provide black sealing compound (50), the black sealing compound (50) including modified pi-allyl unsaturated polyester resin, Olefines prepolymer, UV reactivity polyfunctional group acrylic resins, black dyes, ultraviolet initiator and auxiliary additive;Its In, the mass percent of the modified pi-allyl unsaturated polyester resin is 30%~80%, the matter of the olefines prepolymer Amount percentage is 10%~30%, and the mass percent of the UV reactivity polyfunctional group acrylic resin is 1%~11%, institute The mass percent for stating black dyes is 5%~25%, and the mass percent of the ultraviolet initiator is 1%~3%, described The mass percent of auxiliary additive is 0.5%~2%;
The black sealing compound (50) is coated in into section otch (40) place of LCD abnormity screen (200), is stood, made described Black sealing compound (50) penetrates into from from the section otch (40) to the inside of the liquid crystal layer (30);
Step 3, LCD abnormity screen (200) to having oozed glue carry out ultraviolet light, solidify the black sealing compound (50), complete The sealing of LCD abnormity screen (200) in pairs.
5. the preparation method that LCD abnormity as claimed in claim 4 shields, it is characterised in that the modified pi-allyl is unsaturated poly- Ester resin includes the polyorganosiloxane resin containing Allyl end groups, allyl ether modified unsaturated polyester and pi-allyl unsaturation carboxylic One or more in acid esters;
The olefines prepolymer includes butadiene prepolymer, isoprene prepolymer and styrene-butadiene prepolymerization One or more in thing;
The black dyes is black including organic black dyes, the mixture of the multiple color dyestuff for being shown as black, carbon black and titanium In one or more;
The UV reactivity polyfunctional groups acrylic resin includes glycol diacrylate, 2- hydroxy acrylates, three hydroxyl first One or more in base propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive includes the one kind or many in viscosity modifier, silane coupler, interfacial agent and plasticizer Kind;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
6. the preparation method of LCD as claimed in claim 4 abnormity screen, it is characterised in that the black sealing compound (50) it is viscous Spend for 1000mPas~50000mPas.
7. the preparation method that LCD abnormity as claimed in claim 4 shields, it is characterised in that in the step 2, by the black Sealing compound (50) is coated in the mode at section otch (40) place of LCD abnormity screen (200):Using nozzle in section otch (40) place's spray black sealing compound (50), Huo Zhewei:In the container for filling black sealing compound (50), LCD abnormity is shielded (200) in section otch (40) place immersion black sealing compound (50), section otch (40) place is made to fill black sealing compound (50), then take out;
The step 2 is carried out under 20 DEG C~60 DEG C of environment temperature, and time of repose is 5min~5h;
In the step 2, the black sealing compound (50) is controlled interior to the liquid crystal layer (30) from from the section otch (40) The depth that portion is penetrated into is 1mm~5mm;
In the step 3, the wavelength of the ultraviolet light is 300nm~400nm, and the illumination of the ultraviolet light is 10mW/cm2~ 200mW/cm2, exposure is 1000mj/cm2~5000mj/cm2
8. a kind of LCD abnormity screen, it is characterised in that by according to required shape and size to a display panels (100) Cut, be obtained at section otch (40) place coating black sealing compound (50) and after carrying out UV solidifications, the LCD Plate (100) including the upper substrate (11) that is oppositely arranged and infrabasal plate (12), located at the upper substrate (11) and infrabasal plate (12) it Between liquid crystal layer (30), be attached on the upper substrate (11) upper polaroid (21) away from the liquid crystal layer (30) side, with And the down polaroid (22) away from the liquid crystal layer (30) side is attached on the infrabasal plate (12);The black sealing compound (50) penetrate into the inside of liquid crystal layer (30) from from the section otch (40);
The black sealing compound (50) includes modified pi-allyl unsaturated polyester resin, olefines prepolymer, many officials of UV reactivity Acrylic resin, black dyes, ultraviolet initiator and auxiliary additive can be rolled into a ball;Wherein, the modified pi-allyl is unsaturated poly- The mass percent of ester resin is 30%~80%, and the mass percent of the olefines prepolymer is 10%~30%, described The mass percent of UV reactivity polyfunctional group acrylic resins is 1%~11%, and the mass percent of the black dyes is 5%~25%, the mass percent of the ultraviolet initiator is 1%~3%, and the mass percent of the auxiliary additive is 0.5%~2%.
9. LCD abnormity as claimed in claim 8 shields, it is characterised in that the modified pi-allyl unsaturated polyester resin includes In polyorganosiloxane resin containing Allyl end groups, allyl ether modified unsaturated polyester and pi-allyl esters of unsaturated carboxylic acids one Plant or various;
The olefines prepolymer includes butadiene prepolymer, isoprene prepolymer and styrene-butadiene prepolymerization One or more in thing;
The black dyes is black including organic black dyes, the mixture of the multiple color dyestuff for being shown as black, carbon black and titanium In one or more;
The UV reactivity polyfunctional groups acrylic resin includes glycol diacrylate, 2- hydroxy acrylates, three hydroxyl first One or more in base propane triacrylate and dipentaerythritol acrylate;
The auxiliary additive includes the one kind or many in viscosity modifier, silane coupler, interfacial agent and plasticizer Kind;
The photosensitive wave band of the ultraviolet initiator is 300nm~400nm.
10. LCD as claimed in claim 8 abnormity screen, it is characterised in that the viscosity of the black sealing compound (50) is 1000mPas~50000mPas;The black sealing compound (50) is from from the section otch (40) into liquid crystal layer (30) The depth that portion is penetrated into is 1mm~5mm.
CN201611169353.XA 2016-12-16 2016-12-16 Black sealing compound and LCD (liquid crystal display) special-shaped screen, and manufacturing method thereof Pending CN106634765A (en)

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