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CN106630698A - Carbide slag-based cement co-production process - Google Patents

Carbide slag-based cement co-production process Download PDF

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Publication number
CN106630698A
CN106630698A CN201611212509.8A CN201611212509A CN106630698A CN 106630698 A CN106630698 A CN 106630698A CN 201611212509 A CN201611212509 A CN 201611212509A CN 106630698 A CN106630698 A CN 106630698A
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CN
China
Prior art keywords
carbide slag
cement
waste gas
joint production
production technique
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611212509.8A
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Chinese (zh)
Inventor
曾秀芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Zhiben Information Technology Co Ltd
Original Assignee
Hubei Zhiben Information Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Zhiben Information Technology Co Ltd filed Critical Hubei Zhiben Information Technology Co Ltd
Priority to CN201611212509.8A priority Critical patent/CN106630698A/en
Publication of CN106630698A publication Critical patent/CN106630698A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/24Cements from oil shales, residues or waste other than slag
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a carbide slag-based cement co-production process which comprises the steps of carrying out electromagnetic deironing on carbide slag, carrying out circulating capture of CO2 after drying by using residual heat of the exhaust gas of a cement plant to obtain high-purity CO2, and carrying out storage; discharging the carbide slag which circulates for certain times through a discharge pump, and feeding the carbide slag to a raw meal homogenizing silo of a cement process for mixing with other raw materials to obtain cement raw meal; and carrying out high-temperature preheating, pre-decomposition, rotary kiln calcination, grate cooler cooling and grinding on the cement raw meal to prepare cement, wherein the moisture content of the carbide slag is not higher than 12%, and SiO2 in the exhaust gas is removed through a desulfurizing tower before the carbide slag is dried. According to the carbide slag-based cement co-production process, the problems of occupation of carbide slag stacking on soil resource and environmental pollution are solved; and meanwhile, the carbon emission of the cement plant is reduced.

Description

A kind of cement joint production technique based on carbide slag
Technical field
The invention belongs to cement joint production technology field, and in particular to a kind of cement joint production technique based on carbide slag.
Background technology
At present, the whole world is discharged into every year the CO in air2There are more than 300 hundred million tons, wherein there are about 22% from cement plant, steel Ironworks and oil plant etc..To reduce CO2Discharge capacity, at present generally adopt CO2The mode of trapping is processed.
With regard to CO2Trapping, presently, there are the modes such as pre-combustion capture, post-combustion capture and oxygen-enriched combusting.Wherein, before burning Trapping technique is mainly integrated gasification combined cycle plants (IGCC) technology;Post-combustion capture mainly has monoethanolamine (MEA) absorption method (CLP) absorption method is circulated with calcium, monoethanolamine absorption method is only suitable for low temperature (65 DEG C) decarburization circulation, and efficiency is not high, calcium circulation absorption Method, as adsorbent, is adapted to high temperature circulation absorption generally using natural limestone;Oxygen-enriched combustion technology application also than wide, but Oxygen-enriched combusting need to adopt air separation unit, and its energy consumption is especially big, and the cost of carbon trapping is very high.
The content of the invention
For the disadvantages described above or Improvement requirement of prior art, the invention provides a kind of cement joint production based on carbide slag Technique, it passes through the PROCESS FOR TREATMENT means innovated, using dry carbide slag CO is carried out2Trapping and manufacture of cement, not only greatly carry High dry carbide slag utilization rate and greatly reduce CO2Discharge.
For achieving the above object, the technical scheme that the present invention is provided is specific as follows:
A kind of cement joint production technique based on carbide slag, comprises the steps:
The carbide slag that dry acetylene generation process is obtained, carries out electromagnetism except iron, is then dried using the remaining temperature of cement plant waste gas Sending into CCS systems afterwards carries out CO2Circularly trapping, to obtain high-purity CO2And sealed up for safekeeping
Carbide slag is circulated after certain number of times, wherein the CaO that activity is reduced is discharged by discharge pump, delivers to the life of cement industry Material homogenizing storehouse obtains cement slurry with other raw material proportionings
High temperature preheating, predecomposition, calcined by rotary kiln, grate-cooler cooling and grinding are carried out to cement slurry, that is, water is obtained Mud.
Used as present invention further optimization, the carbide slag moisture that the dry acetylene generation process is obtained is not higher than 12%.
Used as present invention further optimization, the waste gas first passed through desulfurizing tower before being dried to dry carbide slag and removes Remove SO therein2, the wherein raw material of desulfurization except the dry carbide slag after iron by being obtained.
In this programme, the CO in cement plant waste gas2Before trapping, first desulfurization process are carried out to waste gas, because SO2With CO2 Competitive reaction, SO are there is to calcium oxide2Reactivity it is stronger, remove waste gas in SO2Enable to CCS systems and keep higher CO2Arresting efficiency.
Used as present invention further optimization, the waste material after desulfurization can be used to prepare cement retarder after being dried.
Used as present invention further optimization, the baking temperature is less than 135 °.
It is described to require to exceed with other raw material proportionings acquisition cement slurry grain diameters as present invention further optimization 75um。
Used as present invention further optimization, adsorption tower, desorption column adopt circulating fluid bed reactor in CCS systems, its The reaction temperature of middle adsorption tower is 650 DEG C, and the temperature of desorption column is 900 DEG C, and adsorbent is given up using the cement plant after desulfurization The carbide slag that temperature is dried more than gas.
In the joint production process of this programme, raw material use the calcium carbide waste slag of dry method acetylene technique acquisition, Jing Guo electricity After magnetic is dried except iron and cement plant waste gas residual heat, CO in CCS systems is used as2The adsorbent of trapping, this measure solves calcium carbide slag muck The occupancy of land resource of being rivals in a contest and the pollution problem to environment, while reducing the carbon emission amount in cement plant.In addition, dry carbide slag Before sending into desorption column calcining, first it is dried via the remaining temperature of cement plant waste gas, on the one hand can traps the part CO in waste gas2, separately On the one hand the remaining temperature of waste gas is used, further reduces the moisture in dry carbide slag, to obtain higher economic benefit.
The present invention, using the CO in discarded dry carbide slag trapping cement plant discharge waste gas2, on the one hand solve calcium carbide and give up A pollution difficult problem for slag, at the same it is consistent with the low-carbon (LC) policy that country advocates, substantially reduce the carbon emission amount in cement plant.And inactivate CaO be used for preparing cement, it is to avoid the waste of resource, can be with the stacking pollution problem of effectively solving carbide slag, and and cement CO in factory's waste gas2Trapping combines, and process costs are relatively low, high financial profit.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only to explain the present invention Limit the present invention.
It is related to following system in the joint production process of embodiment:The storage of carbide slag, except iron drying system, CCS systems, cement Production system.
In the present embodiment, dry carbide slag is preferred from dry acetylene generation process, and preferably its moisture is not higher than 12%.Carbide slag is deposited Storage is in carbide slag storehouse.
Via electromagnetism iron removal step, major part delivers to dry carbide slag drying system to dry carbide slag, partly delivers to desulfurizing tower work For desulfurization raw material.
Desulfurizing tower is first passed around by electric cleaner cement plant waste gas out and removes SO therein2, it is subsequently into being dried The carbide slag united after being dried except iron using remaining temperature;
Send into adsorption tower from drying system waste gas out, and dried carbide slag into feed proportioning system with come to coal dust The fine breeze of preparation system carries out rational proportion and sends into desorption column;
Air isolates N via air separation unit2With O2, O2Oxygen-enriched combusting is carried out into desorption column and coal dust so that absorption CO2CaCO3Decompose and generate CaO and CO2,
Cyclone separator is sent into from desorption column gas-solid mixture out, the CaO for separating sends into adsorption tower and carries out CO2 Circulation absorption reacts, and removes CO2Waste gas send into smoke stack emission;Adsorption tower gas-solid mixture out via cyclone separator, The CaCO for separating3Send into desorption column calcining, the high-purity CO for separating2(preferably approximately 97%) is sealed in ground through compression Under.
After certain circulation, the adsorption activity of CaO is reduced, then discharged by discharge pump, delivers to cement preparation system Raw material homogenizing silo, with uniformly mix come the raw material to raw mill granularity less than 75um after feeding five-stage cyclone preheater it is fully pre- Heat, then via predecomposition furnace, deliver to dry type calcined by rotary kiln.
Cyclone preheater, predecomposition furnace, the thermal source of rotary kiln carry out the burning of the fine breeze provided to coal dust preparation system.
It is divided into two-way from kiln tail preheater high-temp waste gas out, all the way into raw mill as drying medium, all the way Jing Enter remittance air compartment and mix come the waste gas to raw mill after the cooling of multitube cooling device, mixed waste gas is through kiln tail bag dedusting Device, is re-fed into the further dedusting of electrostatic precipitator.
The material accepted from kiln tail bag dust collector is sent into raw material homogenizing silo and is mixed with raw meal powder;Material is passed through in rotary kiln The chemical reaction of series of complex, ultimately forms high temperature chamotte, after sending into grate-cooler cooling, into cement grinding system, with it The dispensing mixing that his grinding needs, grinds qualified finished cement.
Hot-air part after grate-cooler cooling high-temperature clinker enters rotary kiln and sends into as tertiary air pre- as Secondary Air Dore furnace, partly as the medium of drying raw coal, unnecessary waste gas Jing kiln hoods bag dust collector with come to coal dust preparation system to pass through The waste gas of bag dust collector sends into together electrostatic precipitator, and the waste gas for going out electrostatic precipitator sends into desulfurizing tower, so whole technique stream Journey is combined.
In order to realize to the CO in the waste gas of cement plant2Trapping comprehensively, can be determined so that the CCS systems in this technique are connected to Cement producing line, to reduce the carbon emission amount of cement industry.In a word, according to actual situation, neatly using this technique, Reach the CO in the process and cement plant waste gas to the carbide slag that gives up2The purpose of the Joint Production of trapping.
As it will be easily appreciated by one skilled in the art that the foregoing is only presently preferred embodiments of the present invention, not to The present invention, all any modification, equivalent and improvement made within the spirit and principles in the present invention etc. are limited, all should be included Within protection scope of the present invention.

Claims (5)

1. a kind of cement joint production technique based on carbide slag, comprises the steps:
The carbide slag that dry acetylene generation process is obtained, carries out electromagnetism except iron, send after being then dried using the remaining temperature of cement plant waste gas Entering CCS systems carries out CO2Circularly trapping, to obtain high-purity CO2And sealed up for safekeeping;
Carbide slag is circulated after certain number of times, wherein the CaO that activity is reduced is discharged by discharge pump, the raw material for delivering to cement industry are equal Change storehouse and obtain cement slurry with other raw material proportionings;
High temperature preheating, predecomposition, calcined by rotary kiln, grate-cooler cooling and grinding are carried out to cement slurry, that is, cement is obtained;
Wherein, the carbide slag moisture that the dry acetylene generation process is obtained is not higher than 12%;The waste gas is being carried out to dry carbide slag Desulfurizing tower is first passed through before drying and removes SO therein2, the wherein raw material of desulfurization except the dry carbide slag after iron by being obtained.
2. a kind of cement joint production technique based on carbide slag according to claim 1, wherein, after the waste material after desulfurization is dried Can be used to prepare cement retarder.
3. a kind of cement joint production technique based on carbide slag according to claim 2, wherein, the baking temperature is less than 135°。
4. a kind of cement joint production technique based on carbide slag according to any one of claim 1 to 3, wherein, it is described with Other raw material proportionings obtain cement slurry grain diameter and are less than 75um.
5. a kind of cement joint production technique based on carbide slag according to any one of claim 1 to 4, wherein, CCS systems Middle adsorption tower, desorption column adopt circulating fluid bed reactor, and the wherein reaction temperature of adsorption tower is 650 DEG C, the temperature of desorption column For 900 DEG C, adsorbent adopts the warm carbide slag being dried more than the cement plant waste gas after desulfurization.
CN201611212509.8A 2016-12-25 2016-12-25 Carbide slag-based cement co-production process Pending CN106630698A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107563545A (en) * 2017-08-17 2018-01-09 上海大学 Fine chemistry industry ecological Industrial Area industrial chain construction method using natural gas as raw material
CN112390551A (en) * 2019-08-12 2021-02-23 天津水泥工业设计研究院有限公司 Adjustable CO reformed from off-line decomposer2Enrichment cement kiln system and method
CN113950365A (en) * 2019-06-12 2022-01-18 海德堡水泥公司 Scrubbing the exhaust gas to remove CO2And/or SOxMethod (2)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560067A (en) * 2008-04-15 2009-10-21 新疆天业(集团)有限公司 Technology for preparing cement by dry carbide slag method
CN102527225A (en) * 2010-12-17 2012-07-04 中国科学院过程工程研究所 Method for trapping carbon dioxide from smoke by renewable carbide slag

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560067A (en) * 2008-04-15 2009-10-21 新疆天业(集团)有限公司 Technology for preparing cement by dry carbide slag method
CN102527225A (en) * 2010-12-17 2012-07-04 中国科学院过程工程研究所 Method for trapping carbon dioxide from smoke by renewable carbide slag

Non-Patent Citations (2)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107563545A (en) * 2017-08-17 2018-01-09 上海大学 Fine chemistry industry ecological Industrial Area industrial chain construction method using natural gas as raw material
CN113950365A (en) * 2019-06-12 2022-01-18 海德堡水泥公司 Scrubbing the exhaust gas to remove CO2And/or SOxMethod (2)
CN112390551A (en) * 2019-08-12 2021-02-23 天津水泥工业设计研究院有限公司 Adjustable CO reformed from off-line decomposer2Enrichment cement kiln system and method
CN112390551B (en) * 2019-08-12 2023-07-25 天津水泥工业设计研究院有限公司 Adjustable CO retrofitted from off-line decomposing furnace 2 Enriched cement kiln system and method

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