CN106630674B - One kind having self-cleaning function, anti-ultraviolet sound control glass and preparation method thereof - Google Patents
One kind having self-cleaning function, anti-ultraviolet sound control glass and preparation method thereof Download PDFInfo
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- CN106630674B CN106630674B CN201610880314.4A CN201610880314A CN106630674B CN 106630674 B CN106630674 B CN 106630674B CN 201610880314 A CN201610880314 A CN 201610880314A CN 106630674 B CN106630674 B CN 106630674B
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3417—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
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- Engineering & Computer Science (AREA)
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- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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Abstract
本发明提供了一种具有自洁功能、抗紫外线的隔音玻璃及其制备方法，该玻璃包括真空隔音层、透明基板以及分布在其上的抗紫外线薄膜层、具有自洁功能的薄膜层，所述的抗紫外线薄膜层位于玻璃与具有自洁功能薄膜层之间。本发明的具有自洁功能、抗紫外线的隔音玻璃，可以吸收波长为100‑350nm的光线，吸收率高达90％以上，从而有效防止紫外线对皮肤的伤害及致癌性，并达到净化空气的作用。同时，本发明玻璃表面的自洁功能层具有超亲水性的，减少了清洁玻璃表面的麻烦。隔音层可以对各类噪音起到一定的屏蔽作用，使室内的感觉变得柔和。
The invention provides a sound-insulating glass with self-cleaning function and anti-ultraviolet and a preparation method thereof. The glass comprises a vacuum sound-insulating layer, a transparent substrate, and an anti-ultraviolet film layer and a film layer with self-cleaning function distributed thereon. The anti-ultraviolet film layer is located between the glass and the film layer with self-cleaning function. The self-cleaning and anti-ultraviolet soundproof glass of the present invention can absorb light with a wavelength of 100-350 nm, and the absorption rate is as high as 90% or more, thereby effectively preventing ultraviolet rays from damaging the skin and carcinogenicity, and achieving the effect of purifying the air. Meanwhile, the self-cleaning functional layer on the glass surface of the present invention is super-hydrophilic, which reduces the trouble of cleaning the glass surface. The sound insulation layer can shield all kinds of noise to a certain extent, making the indoor feeling softer.
Description
[technical field]
The present invention relates to film application fields, and in particular to one kind have self-cleaning function, anti-ultraviolet sound control glass and
Preparation method.
[background technique]
If it is well known that people is exposed to the sun the sun for a long time, ultraviolet light can make it is accelerated skin ageing, to generate wrinkle, produce
Add lustre to spot, cause skin to become coarse or cause some skin diseases, such as dermatitis, cutaneum carcinoma etc..In addition, strong sunlight
It according to some ornaments agings also resulted in house and automobile, fades, shortens it and use the time.However current automobile mostly,
The simple glass general utility functions used on the window of material storage room, Sea View Room etc. are not less, good enough for ultraviolet radiation absorption, stain resistance
It is poor, not easy to clean.And soundproof effect is bad, indoor or interior vulnerable to ambient noise interference.In order to reduce ultraviolet light and make an uproar
Sound brings adverse effect to people's lives and body, and seeking makes glass of building and automobile window glass have strong absorption purple
Outside line and sound insulation function are essential.
Currently, there are many technologies has the glass for absorbing UV resistance to prepare, for example, Chinese publication
CN103613280A discloses the masking liquid and ultraviolet absorbing glass of a kind of ultraviolet absorbing coatings, the ultraviolet absorbing glass
Ultraviolet absorbing coatings include SiO2And ultraviolet absorbing agent, the ultraviolet absorbing coatings further include for storing and discharging purple
By the oxide M O of ultraviolet light excitation electronics in ultraviolet absorbersz, wherein M=V, Mn, Fe, Co, Ni, Zr, Nb, Mo, Ru, Ir,
Rh, Pd, W, Re, Bi, In, Ga, Os；1≤z≤4.Such glass can protect ultraviolet absorbing agent and SiO2Matrix prevents purple
The discoloration of outside line heat absorbing glass or devitrification.However the glass does not have sound insulation and self-cleaning function.
Chinese publication CN103097320A discloses a kind of laminated glass, i.e., adds one layer of PVB among two sheet glass
(polyvinyl butyral) film, the interlayer film have the function of absorbing ultraviolet light.However, this laminated glass preparation process is more multiple
It is miscellaneous, improve manufacturing cost.
In addition, the method for being usually used in manufacturing ultraviolet ray screening film-plating glass through retrieval discovery includes magnetron sputtering, chemical gaseous phase
Sedimentation and sol-gel process.
[summary of the invention]
In order to solve the problems existing in the prior art, the present invention provides a kind of with self-cleaning function, anti-ultraviolet sound insulation glass
Glass and preparation method thereof, the glass is not only strong to ultraviolet absorption ability, anti-ultraviolet function is realized, to effectively prevent ultraviolet
Injury and carcinogenicity of the line to skin, and have the function that purify air.In addition, the glass also has self-cleaning function and sound insulation effect
Fruit, self-cleaning function make glass easy to clean, mitigate the trouble of cleaning glass；Sound insulation value can play ambient noise centainly
Shielding action, to make indoor to feel to become soft.Preparation method of the invention is simple, and film doping ratio is easier to adjust
Section, the film even compact made, hardness are high.Preparation technology parameter is easy to control, and reproducibility is good.
To achieve the above object, the present invention uses following technological means:
One kind having self-cleaning function, anti-ultraviolet sound control glass, comprising: interior transparent substrate, outer transparent substrate and sets
Vacuum sound insulation layer between interior transparent substrate and outer transparent substrate, interior transparent substrate surface set gradually interior uvioresistant film
Layer and interior self-cleaning function layer, outer transparent substrate surface sets gradually outer uvioresistant film layer and outer self-cleaning function layer；
Inside and outside uvioresistant film layer is mixed with V2O5SiO2Film；
Inside and outside self-cleaning function layer is TiO2Film or nano silver film.
The light-absorbing wavelength of the sound control glass is 100-350nm, absorption of UV 90%-95%.
The inside and outside uvioresistant film layer is SiO2With V2O5Using same chamber, the mode of steaming is deposited and is made altogether；Wherein SiO2
It is deposited as material of main part by electron-beam evaporation mode；V2O5It is deposited as guest materials by vacuum evaporation mode.
The inside and outside self-cleaning function layer is TiO2It is deposited using electron beam mode obtained.
It is vacuum cavity inside the vacuum sound insulation layer, vacuum cavity is by small supporter or surface setting protrusion
Organic glass is made, and inside and outside transparent substrate is sealed by sealing material.
Inside and outside transparent substrate is water soda glass or plastics.
A kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass, comprising the following steps:
1) interior glass substrate is sequentially placed into dish washing liquid, acetone, alcohol, be cleaned by ultrasonic in deionized water respectively, after taking-up
It is dried with nitrogen；
2) the interior glass substrate dried is transferred to deposited chamber while uses vacuum evaporation V2O5And electron beam evaporation
SiO2, form SiO2And V2O5The interior uvioresistant film layer of composition, obtains the interior glass base that interior uvioresistant film layer is deposited
Plate；
3) the interior glass substrate of uvioresistant film layer is put into drying box drying in being deposited；
4) sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, prepare interior self-cleaning function
Layer；Obtain that there is self-cleaning function, anti-ultraviolet sheet glass；
5) by outer glass substrate successively according to it is above-mentioned 1), 2), 3) and 4) described in method other a piece of tool is prepared
There are self-cleaning function, anti-ultraviolet sheet glass；
6) organic glass for passing through small supporter or surface setting protrusion between two sheet glass is supported and between formation
Gap is sealed two panels semi-finished product using sealing material after being evacuated in gap, and being formed has self-cleaning function, uvioresistant
Sound control glass.
In step 2), V2O5With SiO2Doping concentration ratio be 3:4；Evaporating pressure is 2.5 × 10-4─5.0×10-4Pa。
In step 3), evaporation current 20-25mA, evaporation pressure is 1.2 × 10-4─2.6×10-4Pa。
Uvioresistant film layer with a thickness of 70-100nm；Self-cleaning function layer is with a thickness of 10-20nm；Vacuum sound insulation thickness degree
For 1-1.7mm.
Compared with prior art, the present invention having the advantage that
The present invention has self-cleaning function, anti-ultraviolet sound control glass piece, by transparent substrate, vacuum sound insulation layer, uvioresistant
Line film layer and self-cleaning function layer composition；The glass includes transparent substrate and distribution uvioresistant film layer on it, tool
There are the film layer and vacuum sound insulation layer of self-cleaning function, the uvioresistant film layer is located at glass and has self-cleaning function film
Between layer.The institute that simple glass may be implemented in transparent substrate is functional；First layer uvioresistant film layer is by mixed with V2O5Deng
SiO2Film or other film layer compositions with absorption ultraviolet light function, can largely absorb ultraviolet incident light, reduce harmful
The amount of incident of ultraviolet light, absorptivity reach 90 or more percent, effectively shielding harmful light, have stronger protection function to human body
Energy.In addition, the second layer film self-cleaning function layer is Superhydrophilic oxide TiO2Film and organic matter can be converted into dioxy
Change the films such as the nano silver of carbon and water, not only there is protective effect, but also there is anti-reflection effect, also there is certain self-cleaning function,
Antifouling effect is significant, reduces cleaning frequency.Automatically cleaning principle of the invention are as follows: for TiO2Film, TiO2In the effect of ultraviolet light
Under can generate good photocatalysis characteristic to have super hydrophilic characteristic so that the water droplet of very little is converged to large water droplet,
It falls off under gravity, so that the spot of contamination on it is easily washed away, makes glass that there is self-cleaning function.Middle layer is
Vacuum sound insulation layer, sound is propagated by medium, and vacuum layer can play effective shielding action to ambient noise, to make indoor
Feel to become soft.
Of the invention has self-cleaning function, anti-ultraviolet sound control glass, and the light that wavelength is 100-350nm can be absorbed
Line, absorptivity are up to 90% or more, to effectively prevent injury and carcinogenicity of the ultraviolet light to skin.Meanwhile glass of the present invention
The TiO on surface2Film layer has the self-cleaning function of Superhydrophilic, reduces the trouble of cleaning glass surface.
Preparation method of the invention is simple, and using same chamber, V is deposited in the mode of steaming altogether2O5Deng SiO2Film, then with electron beam side
Formula evaporation metal oxide TiO2.The method doping is convenient, ratio is more easily adjusted, the film even compact made, and hardness is high.
Preparation technology parameter is easy to control, and reproducibility is good.
[Detailed description of the invention]
Fig. 1 is the diagrammatic cross-section that the present invention has self-cleaning function, anti-ultraviolet sound control glass.
Wherein, A1 and A is respectively inside and outside glass substrate, and intermediate D is vacuum sound insulation layer, and B1 and B are respectively inside and outside uvioresistant
Line film layer, C1 and C are respectively inside and outside self-cleaning function layer.
Fig. 2 is various concentration doping of the invention on the analog simulation figure for absorbing ultraviolet light influence.
[specific embodiment]
The present invention is described in detail with reference to the accompanying drawing:
As shown in Figure 1, the present invention is a kind of to have a self-cleaning function, anti-ultraviolet sound control glass, including interior transparent substrate A1,
The outer transparent substrate A and vacuum sound insulation layer D between interior transparent substrate and outer transparent substrate, close to inside and outside transparent substrate
It include successively respectively from inside to outside uvioresistant film layer B1 and B and self-cleaning function layer C1 and C, sheet glass is to absorption of UV
Up to 90%-95%.
Transparent substrate A and A1 are simple glass or other transparent substrates with flexibility function；
Uvioresistant film layer B and B1 are mixed with V2O5Deng SiO2Film is other with the thin of absorption ultraviolet light function
Film layer.SiO2With V2O5Using same chamber, the mode of steaming is deposited altogether；V2O5It is deposited as guest materials by vacuum evaporation mode.SiO2Make
Based on material pass through electron-beam evaporation mode be deposited；
Self-cleaning function layer C and C1 are TiO2Film, and organic matter can be converted into the nano silver etc. of carbon dioxide and water
Film layer is deposited using electron beam mode.
The above-mentioned preparation method with self-cleaning function, anti-ultraviolet sound control glass, comprising the following steps:
1) transparent substrate A is sequentially placed into dish washing liquid, acetone, alcohol, is cleaned by ultrasonic 10-15min respectively in deionized water,
It is dried after taking-up with nitrogen；
2) cleaned transparent substrate is transferred to deposited chamber while uses vacuum evaporation V2O5Deng and electron beam evaporation
SiO2, uvioresistant film layer is formed, this film layer is by the oxide S iO2And V2O5Composition；The uvioresistant that vapor deposition generates altogether
Line film thickness is 70-100nm.
3) substrate being deposited is put into drying box drying；
4) substrate dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2Equal films, electron beam evaporation material
Expect TiO2Deng with a thickness of 10-20nm.Complete the film layer with self-cleaning function；So far, it is prepared with self-cleaning function, resists
The sheet glass of ultraviolet light.
5) by transparent substrate A1 successively according to it is above-mentioned 1), 2), 3) and 4) described in method another tool is prepared
There are self-cleaning function, anti-ultraviolet glass.
6) by what two panels was prepared there is self-cleaning function, anti-ultraviolet glass to be sealed using sealing material, centre is logical
It crosses supporter to isolate with a thickness of the gap 1-1.7mm, this space is evacuated.
Wherein, transparent substrate is as thin-film carrier, and the selection of material is water soda glass or other has transparent base flexible
Plate.The uvioresistant film layer is by mixed with V2O5Deng SiO2Film composition.The self-cleaning function layer is located at uvioresistant film
The upper surface of layer, mainly by the oxide TiO containing super hydrophilic characteristic2Organic matter can be converted into carbon dioxide and water by film
Other films composition.
TiO2Good photocatalysis characteristic can be generated under the action of ultraviolet light to have super hydrophilic characteristic, so that very
Small water droplet is converged to large water droplet, falls off under the effect of gravity, so that the spot of contamination on it is easily washed away, makes
Glass has self-cleaning function.
A kind of specific preparation process with self-cleaning function, anti-ultraviolet sound control glass of the present invention is as follows, now with part
It is illustrated for material, is certainly not limited to following material.
Glass substrate A is the water soda glass of high-flatness.Uvioresistant film layer is that deposited chamber is steamed using vacuum simultaneously
Plate V2O5And electron beam evaporation SiO2, the film layer V of completion2O5:SiO2.Self-cleaning function layer is Superhydrophilic oxide TiO2It is thin
Film not only has protective effect, but also has anti-reflection effect.It is organic glass among vacuum sound insulation layer, is then with concentration
1%-60% acetone soak organic glass, then this layer of organic glass is made by silk-screen printing by convex-concave profile, form supporter.
Embodiment 1
It is described to have self-cleaning function, anti-ultraviolet glass preparation process as follows:
1, soda-lime glass is sequentially placed into dish washing liquid, acetone, alcohol, be cleaned by ultrasonic respectively ten minutes in deionized water, taken
It is dried after out with nitrogen.
2, cleaned glass substrate is transferred to deposited chamber while uses vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet light film layer is formed, this film layer is by the oxide S iO2And V2O5Composition, film thickness monitoring 70-100nm, V2O5Doping
The SiO that concentration is 10%2, doping concentration V2O5:SiO2=3:4, evaporation pressure are 5.0 × 10-4Pa；.
3, the sheet glass being deposited is put into drying box drying；
4, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete that there is self-cleaning function
Film layer, film thickness 10-20nm, evaporation current 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, it is prepared with self-cleaning function, anti-ultraviolet sheet glass.
5, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method be prepared in addition
One kind having self-cleaning function, anti-ultraviolet glass.
6, by what two panels was prepared there is self-cleaning function, anti-ultraviolet glass to be sealed using sealing material, centre is logical
It crosses supporter to isolate with a thickness of the gap 1.0mm, this space is evacuated.
Embodiment 2
It is described to have self-cleaning function, anti-ultraviolet glass preparation process as follows:
1, soda-lime glass is sequentially placed into dish washing liquid, acetone, alcohol, be cleaned by ultrasonic respectively 15 minutes in deionized water, taken
It is dried after out with nitrogen.
2, cleaned glass substrate is transferred to deposited chamber while uses vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet light film layer is formed, this film layer is by the oxide S iO2And V2O5Composition, film thickness monitoring 80-100nm, V2O5Doping
The SiO that concentration is 37.5%2, doping concentration V2O5:SiO2=3:4, evaporation pressure are 5.0 × 10-4Pa；.
3, the sheet glass being deposited is put into drying box drying；
4, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete that there is self-cleaning function
Film layer, film thickness 15-20nm, evaporation current 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, it is prepared with self-cleaning function, anti-ultraviolet sheet glass.
5, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method be prepared in addition
One kind having self-cleaning function, anti-ultraviolet glass.
6, by what two panels was prepared there is self-cleaning function, anti-ultraviolet glass to be sealed using sealing material, centre is logical
It crosses supporter to isolate with a thickness of the gap 1.5mm, this space is evacuated.
Embodiment 3
It is described to have self-cleaning function, anti-ultraviolet glass preparation process as follows:
1, soda-lime glass is sequentially placed into dish washing liquid, acetone, alcohol, be cleaned by ultrasonic respectively 20 minutes in deionized water, taken
It is dried after out with nitrogen.
2, cleaned glass substrate is transferred to deposited chamber while uses vacuum evaporation V2O5And electron beam evaporation SiO2,
Ultraviolet light film layer is formed, this film layer is by the oxide S iO2And V2O5Composition, film thickness 70-80nm, V2O5Doping concentration
For 50% SiO2, doping concentration V2O5:SiO2=3:4, evaporation pressure are 5.0 × 10-4Pa；.
3, the sheet glass being deposited is put into drying box drying；
4, the sheet glass dried is placed into vacuum chamber and TiO is evaporated using electron beam mode2, complete that there is self-cleaning function
Film layer, film thickness 10-18nm, evaporation current 20mA, evaporation pressure be 2.6 × 10-4Pa。
So far, it is prepared with self-cleaning function, anti-ultraviolet sheet glass.
5, by other one block of soda-lime glass successively according to it is above-mentioned 1), 2), 3) and 4) described in method be prepared in addition
One kind having self-cleaning function, anti-ultraviolet glass.
6, by what two panels was prepared there is self-cleaning function, anti-ultraviolet glass to be sealed using sealing material, centre is logical
It crosses supporter to isolate with a thickness of the gap 1.7mm, this space is evacuated.
As shown in Fig. 2, different levels of doping of the invention influences to absorb the analog simulation figure of ultraviolet light:
Uvioresistant film layer is by mixed with V2O5SiO2Film composition, we are by changing V2O5Doping concentration simulation draw
Made membrane layer is clear that different proportion concentration film by absorption spectra to the absorption spectra of ultraviolet light (100-350nm)
Absorbing state.As seen from the figure, V on the whole2O5Adulterate SiO2Film has stronger absorbability to ultraviolet light.And for can
Light-exposed (390-780nm) does not then absorb or absorbs substantially less.It can guarantee of the invention there is self-cleaning function, anti-purple in this way
The glass of outside line does not influence the transmission of visible light to the assimilation effect of ultraviolet light, does not influence indoor or interior light.
Compare each curve in Fig. 2, it has been found that pure SiO2Although there is peak-peak to the absorption of ultraviolet light at 50nm in film.But
Its range for absorbing light wave is very narrow, is limited only to the shortwave of 10-100nm range.As doping V2O5Afterwards, SiO2The suction of film layer
It receives optical wavelength range to significantly increase, especially works as V2O5When doping concentration is 37.5% and 50%, to the light wave of 40-320nm range
There is preferable absorption.It is well known that the medium wave carcinogenicity of wavelength 290-320nm is most strong, sunburn and sunburn effect are other frequencies
1000 times of Duan Guangbo.And V2O5The SiO that doping concentration is 37.5% and 50%2Film layer has preferable assimilation effect to it,
Phenomena such as caning effectively protect human skin, preventing wrinkle of skin caused by ultraviolet light, aging, even carcinogenic blackspot generation.
Of the invention has self-cleaning function, anti-ultraviolet sound control glass, can make the transmitance of required wavelength light
Up to 90% or more, to effectively prevent injury and carcinogenicity of the ultraviolet light to skin, and have the function that purify air.Together
When, the TiO of glass surface of the present invention2Film layer has the self-cleaning function of Superhydrophilic, reduces the trouble of cleaning glass surface.
Puigging can play certain shielding action to all kinds of noises, make indoor to feel to become soft.
The foregoing is merely one embodiment of the present invention, it is not all of or unique embodiment, this field is common
Any equivalent transformation that technical staff takes technical solution of the present invention by reading description of the invention, is the present invention
Claim covered.
Claims (8)
1. one kind has self-cleaning function, anti-ultraviolet sound control glass characterized by comprising interior transparent substrate (A1), outer
Bright substrate (A) and the vacuum sound insulation layer (D) between interior transparent substrate and outer transparent substrate, interior transparent substrate (A1) surface
Interior uvioresistant film layer (B1) and interior self-cleaning function layer (C1) are set gradually, outer transparent substrate (A) surface sets gradually outer anti-
Ultraviolet light film layer (B) and outer self-cleaning function layer (C)；
Inside and outside uvioresistant film layer (B1, B) is mixed with V2O5SiO2Film；V2O5With SiO2Doping concentration ratio be 3:4, institute
The inside and outside uvioresistant film layer (B1, B) stated is SiO2With V2O5Using same chamber, the mode of steaming is deposited and is made altogether；Wherein SiO2As
Material of main part is deposited by electron-beam evaporation mode；V2O5It is deposited as guest materials by vacuum evaporation mode；
Inside and outside self-cleaning function layer (C1, C) is nano silver film.
A kind of there is self-cleaning function, anti-ultraviolet sound control glass 2. according to claim 1, it is characterised in that: should be every
The light-absorbing wavelength of sound glass is 100-350nm, absorption of UV 90%-95%.
3. according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, which is characterized in that described
Vacuum sound insulation layer (D) inside be vacuum cavity, vacuum cavity be by small supporter or surface setting protrusion organic glass
It is made, inside and outside transparent substrate (A1, A) is sealed by sealing material.
4. according to claim 1 a kind of with self-cleaning function, anti-ultraviolet sound control glass, which is characterized in that inside and outside
Transparent substrate (A1, A) is water soda glass or plastics.
5. a kind of preparation with self-cleaning function, anti-ultraviolet sound control glass according to any one of claims 1 to 4
Method, which comprises the following steps:
1) interior glass substrate (A1) is sequentially placed into dish washing liquid, acetone, alcohol, be cleaned by ultrasonic in deionized water respectively, after taking-up
It is dried with nitrogen；
2) the interior glass substrate (A1) dried is transferred to deposited chamber while uses vacuum evaporation V2O5And electron beam evaporation
SiO2, formed by SiO2And V2O5The interior uvioresistant film layer (B1) of composition, obtains that interior uvioresistant film layer (B1) is deposited
Interior glass substrate (A1)；
3) the interior glass substrate (A1) of uvioresistant film layer (B1) is put into drying box drying in being deposited；
4) sheet glass dried is placed into vacuum chamber and nano silver film is evaporated using electron beam mode, prepare interior self-cleaning function
Layer (C1)；Obtain that there is self-cleaning function, anti-ultraviolet sheet glass；
5) by outer glass substrate (A) successively according to above-mentioned 1), 2), 3) and 4) described in method be prepared and in addition a piece of have
Self-cleaning function, anti-ultraviolet sheet glass；
6) organic glass for passing through small supporter or surface setting protrusion between two sheet glass is supported and is formed gap, it will
After being evacuated in gap, two panels semi-finished product are sealed using sealing material, being formed has self-cleaning function, anti-ultraviolet sound insulation
Glass.
6. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 5, feature
It is, in step 2), V2O5The SiO that doping concentration is 10~50%2, V2O5With SiO2Doping concentration ratio be 3:4；Evaporate pressure
It is 2.5 × 10-4─5.0×10-4Pa。
7. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 5, feature
It is, in step 2), evaporation current 20-25mA, evaporation pressure is 1.2 × 10-4─2.6×10-4Pa。
8. a kind of preparation method with self-cleaning function, anti-ultraviolet sound control glass according to claim 5, feature
Be, interior uvioresistant film layer (B1) with a thickness of 70-100nm；Interior self-cleaning function layer (C1) with a thickness of 10-20nm；Very
Empty puigging (D) with a thickness of 1-1.7mm.
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| CN201610880314.4A CN106630674B (en) | 2016-10-09 | 2016-10-09 | One kind having self-cleaning function, anti-ultraviolet sound control glass and preparation method thereof |
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| CN106630674B true CN106630674B (en) | 2019-05-24 |
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| CN205615110U (en) * | 2016-03-25 | 2016-10-05 | 江苏耀兴安全玻璃有限公司 | Laminated glass |
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| JPS62223703A (en) * | 1986-03-26 | 1987-10-01 | Toshiba Corp | Optical film forming method |
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| CN1705766A (en) * | 2002-10-22 | 2005-12-07 | 旭硝子株式会社 | Substrate with multilayer film and method for producing same |
| CN1951850A (en) * | 2006-11-15 | 2007-04-25 | 福耀集团双辽有限公司 | Ultraviolet ray screening film-plating glass and producing method thereof |
| CN203640561U (en) * | 2013-10-14 | 2014-06-11 | 上海耀江实业有限公司 | Energy-saving and heat-insulating ultraviolet-resisting hollow glass |
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| CN105882069A (en) * | 2015-01-26 | 2016-08-24 | 南昌欧菲光学技术有限公司 | Coated glass and preparation method thereof |
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