CN106614719A - Pesticide composition containing glyphosate dimethylamine salt and isononanoic acid dimethylamine salt, and preparation method and application thereof - Google Patents
Pesticide composition containing glyphosate dimethylamine salt and isononanoic acid dimethylamine salt, and preparation method and application thereof Download PDFInfo
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- CN106614719A CN106614719A CN201611227046.2A CN201611227046A CN106614719A CN 106614719 A CN106614719 A CN 106614719A CN 201611227046 A CN201611227046 A CN 201611227046A CN 106614719 A CN106614719 A CN 106614719A
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- Prior art keywords
- dimethylamine salt
- different
- nonanoic acid
- glyphosate
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000575 pesticide Substances 0.000 title claims abstract description 39
- VDCHTAFVUAPYGO-UHFFFAOYSA-N n-methylmethanamine;2-(phosphonomethylamino)acetic acid Chemical compound CNC.OC(=O)CNCP(O)(O)=O VDCHTAFVUAPYGO-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- JKODIXDBOAZPPI-UHFFFAOYSA-N dimethylazanium 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)[O-].C[NH2+]C JKODIXDBOAZPPI-UHFFFAOYSA-N 0.000 title abstract 5
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 5
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 54
- NCCHJUUQNUANKR-UHFFFAOYSA-N dimethylazanium;nonanoate Chemical compound C[NH2+]C.CCCCCCCCC([O-])=O NCCHJUUQNUANKR-UHFFFAOYSA-N 0.000 claims description 32
- 239000005562 Glyphosate Substances 0.000 claims description 29
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 29
- 229940097068 glyphosate Drugs 0.000 claims description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000000376 reactant Substances 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 235000019441 ethanol Nutrition 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 6
- -1 n-nonanoic acid diformazan ammonium salt Chemical compound 0.000 claims description 5
- 239000011833 salt mixture Substances 0.000 claims description 5
- 239000004550 soluble concentrate Substances 0.000 claims description 4
- 235000021016 apples Nutrition 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 235000019439 ethyl acetate Nutrition 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 241000220225 Malus Species 0.000 claims 2
- JBPBZQRUTGSRAC-UHFFFAOYSA-N 1-benzyl-4-(4-benzylphenyl)benzene Chemical group C=1C=C(C=2C=CC(CC=3C=CC=CC=3)=CC=2)C=CC=1CC1=CC=CC=C1 JBPBZQRUTGSRAC-UHFFFAOYSA-N 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 239000013543 active substance Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 17
- 230000002363 herbicidal effect Effects 0.000 description 11
- 239000004009 herbicide Substances 0.000 description 9
- 239000003814 drug Substances 0.000 description 7
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 244000025670 Eleusine indica Species 0.000 description 3
- 235000014716 Eleusine indica Nutrition 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 125000002147 dimethylamino group Chemical class [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 3
- 230000000857 drug effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 244000237956 Amaranthus retroflexus Species 0.000 description 1
- 235000013479 Amaranthus retroflexus Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 244000075634 Cyperus rotundus Species 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 241001325227 Eucrypta Species 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 241001582888 Lobus Species 0.000 description 1
- 244000070406 Malus silvestris Species 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- UUWDQKFQXYGVOG-UHFFFAOYSA-N N-methylmethanamine phosphane Chemical compound P.CNC UUWDQKFQXYGVOG-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 244000234609 Portulaca oleracea Species 0.000 description 1
- 235000001855 Portulaca oleracea Nutrition 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 1
- ABUGVBRDFWGJRD-CHOYNLESSA-N [9-[(2r,3r,4s,5r)-3,4-dihydroxy-5-methyloxolan-2-yl]-2-(2,4-dinitrophenyl)sulfanylpurin-6-yl] [hydroxy(phosphonooxy)phosphoryl] hydrogen phosphate Chemical compound O[C@@H]1[C@H](O)[C@@H](C)O[C@H]1N1C2=NC(SC=3C(=CC(=CC=3)[N+]([O-])=O)[N+]([O-])=O)=NC(OP(O)(=O)OP(O)(=O)OP(O)(O)=O)=C2N=C1 ABUGVBRDFWGJRD-CHOYNLESSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940000406 drug candidate Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000013401 experimental design Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 244000230342 green foxtail Species 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000005405 multipole Effects 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 230000005080 plant death Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing glyphosate dimethylamine salt and isononanoic acid dimethylamine salt, and a preparation method and application thereof, and belongs to the technical field of weedicide. The pesticide composition is prepared from the following raw materials in parts by weight: 1 to 40 parts of glyphosate dimethylamine salt, 1 to 40 parts of isononanoic acid dimethylamine salt and 2 to 20 parts of auxiliary agents. The synergistic effects of the glyphosate dimethylamine salt and the isononanoic acid dimethylamine salt are utilized; the glyphosate dimethylamine salt and the isononanoic acid dimethylamine salt are selected as the active substances of pesticide; the combination performance of major active groups and plant surfaces is improved; the liquid drop volume during the spraying is increased; the pesticide utilization rate is improved; the drift is reduced; the pesticide harm risk on non-target plants is reduced.
Description
Technical field
A kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt of the present invention and preparation method thereof and
Using belonging to herbicide technology field.
Background technology
Farmland weed occurs generally, and main weeds have lady's-grass, barnyard grass, green bristlegrass, eleusine indica, Amaranthus retroflexus, purslane, iron amaranth
Dish, rhizome of nutgrass flatsedge etc..At present chemical herbicide have steriland herbicide and selective herbicide point, selective herbicide has soil again
Earth inorganic agent and cauline leaf process agent are not, and have contact-type and conduction type point.Different components, the herbicide of different cultivars, its
Weed control spectrum, adaptability and the sensitiveness to crop have herbicide in difference, but market multifarious, peasant often do not know as
What is selected, and many peasant households falsely drop, misuse herbicide, and to plant growth unnecessary harm is caused, and to soil permanent dirt is caused
Dye, has a strong impact on the yield of crop.
Glyphosate is a kind of non-selective, noresidue steriland herbicide, highly effective to prennical root weeds, is extensively used
In rubber, mulberry, tea, orchard and sugarcane field.The main enolpyruvyl shikimene phosphate synthase suppressed in plant body, so as to press down
Shikimene processed makes protein synthesis be interfered to the conversion of phenylalanine, tyrosine and tryptophan, causes Plant death.Grass
Sweet phosphine is to be transmitted to plant parts after cauline leaf absorbs, and can prevent and kill off unifacial leaf and dicotyledonous, annual and perennial, grass
The plant of the section more than 40 such as this and shrub.Glyphosate is combined quickly with the metal ion such as iron, aluminium after burying and lost activity, to soil
In hide seed and edaphon have no adverse effects.
Different n-nonanoic acid is the intermediate of paint and terebine, for production as lubricant and the ester of plasticizer, and
Produce the peroxide as polymerization catalyst.
Temporarily do not retrieve the report after both material mixings as Pesticide use.
The content of the invention
The present invention is intended to provide a kind of new composition pesticide, it includes glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine
Salt, both compositions have good synergistic function, and the control of weeds effect common to farmland is obvious.
In order to realize foregoing invention purpose, technical scheme is as follows：
A kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, it is characterised in that：Including following by weight
The raw material of amount part meter：1～40 part of glyphosate dimethylamine salt, 1～40 part of different n-nonanoic acid dimethylamine salt, 2～20 parts of auxiliary agent.
Further, the glyphosate dimethylamine salt, different n-nonanoic acid dimethylamine salt by glyphosate, different n-nonanoic acid respectively with dimethylamine
Reaction in a solvent is obtained；Or by reacting in a solvent with dimethylamine and obtain after glyphosate, the mixing of different n-nonanoic acid, the present invention preferably by
React in a solvent with dimethylamine after glyphosate, the mixing of different n-nonanoic acid and obtain.
Preferably, the composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt be microemulsion, can
Solution or aqua.
The soluble concentrate includes 1～10 part of 1～40 part of glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, dibenzyl connection
1～6 part of phenyl APEO, 1～44 part of absolute ethyl alcohol.
The second object of the present invention is to provide the pesticide combination containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt
The preparation method of thing, it is characterised in that：Comprise the following steps：
A. glyphosate, different n-nonanoic acid are weighed by formula, after mixing, by solid-liquid ratio 1:8～12g/ml adds solvent, by glyphosate and
The total amount of different n-nonanoic acid is 1 with the mol ratio of dimethylamine:1～1.2 is added dropwise dimethylamine, after dripping, in 55～95 DEG C of back flow reactions,
Filter, obtain reactant liquor；
B. the reactant liquor for step A being obtained carries out preparation.
Further, before the glyphosate, the mixing of different n-nonanoic acid, 60～100 mesh sieves are first crossed.
In step A, the solvent is the one kind in methyl alcohol, ethanol, ethyl acetate, acetone, chloroform or water.
In step A, the return time is 0.5～1 h.
The third object of the present invention is to provide application of the composition pesticide in preventing and treating crops apples rot.
The composition pesticide is diluted with water to when in use sweet phosphine dimethylamine salt and different n-nonanoic acid dimethylamine salt mixture
Concentration is 30～40%.
Beneficial effects of the present invention：
（1）The present invention selects glyphosate dimethylamine salt using glyphosate dimethylamine salt and the synergy of different n-nonanoic acid dimethylamine salt
With different n-nonanoic acid dimethylamine salt as the active material of agricultural chemicals, chief active group (glyphosate and different n-nonanoic acid are improve）With plant
The binding ability on surface, increases droplet size during sprinkling, improves the utilization rate of agricultural chemicals, and reduces drift, reduces
Poisoning risk to non-target plant.
（2）Composition pesticide in the present invention be microemulsion, soluble concentrate or aqua, to adapt to various insecticide-applying way, no
But a large amount of organic solvents are saved, and the pressure to environment is significantly reduced after pharmacy application, for safeguarding Agro-ecology ring
Border is significant, is conducive to the sustainable development of agricultural.
（3）In the present invention, solution includes 1～10 part of 1～40 part of glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt,
1～6 part of dibenzyl xenyl APEO, 1～44 part of absolute ethyl alcohol, significantly improves the quick-acting of product, has delayed to plant
Thing resistance is produced, and expands product herbicidal spectrum, reduces Pesticide use amount.
（4）The preparation method of the present invention is simple, high income, and three wastes are produced.
（5）In the present invention, before the glyphosate, the mixing of different n-nonanoic acid, 60～100 mesh sieves are first crossed, to control particle diameter, be easy to anti-
Answer thing to dissolve in a solvent, improve yield.
（6）In step A of the present invention, the solvent is the one kind in methyl alcohol, ethanol, ethyl acetate, acetone, chloroform or water,
With more preferable adaptability.
（7）In step A of the present invention, the return time is 0.5～1h, and overlong time can cause energy loss, composition point
Solution, the time is too short to cause reaction incomplete, and yield is low, and product drug effect is undesirable.
Specific embodiment
The present invention is described in further detail with reference to embodiment, but embodiments of the present invention not limited to this.
It should be noted that the different n-nonanoic acid of raw material, glyphosate in following examples is purchased from the sensible agricultural chemicals section of Sichuan Fu Hua
Skill Co., Ltd.
Embodiment 1
A kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, comprises the following steps：
A, glyphosate is weighed, different n-nonanoic acid mixes glyphosate and different n-nonanoic acid, add solvent, back flow reaction twice, to filter, merge
Filtrate, concentration makes reactant liquor weight be equal to 1.2 times of weight of raw material, obtains reactant liquor bq-01～bq-06；Wherein, each parameter is shown in
Table 1；
B, in reactant liquor bq-01～bq-06 add table 2 in auxiliary agent, stir, obtain containing glyphosate dimethylamine salt and different n-nonanoic acid
Composition pesticide BQ-01～the BQ-06 of dimethylamine salt mixture.
Table 1：
Table 2：
Embodiment 2
A kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, comprises the following steps：
It is prepared by A raw materials
A1：Glyphosate is weighed, adds solvent, back flow reaction twice, to filter, merging filtrate, concentration obtains glyphosate dimethylamine salt molten
Liquid, d1-01～d1-03, wherein, each parameter is shown in Table 3；
A2：Different n-nonanoic acid is weighed, adds solvent, back flow reaction twice, to filter, merging filtrate, concentration makes reactant liquor weight be equal to original
1.2 times of the weight of material, obtain different n-nonanoic acid dimethylamine salt solution d2-01～d2-03, wherein, each parameter is shown in Table 4；
B, glyphosate reactant liquor, different n-nonanoic acid reactant liquor and auxiliary agent are weighed, stirred and evenly mixed, obtained final product containing glyphosate dimethylamine salt and different nonyl
Composition pesticide BQ-07～the BQ-12 of sour dimethylamine salt mixture, wherein, each parameter is shown in Table 5.
Table 3：
Table 4：
Table 5：
Embodiment 3
Glyphosate and different n-nonanoic acid and auxiliary agent are weighed according to proportioning in table 6, is stirred and evenly mixed, obtained final product containing glyphosate dimethylamine salt and different nonyl
Composition pesticide BQ-13～the BQ-18 of sour dimethylamine salt.
Table 6
Embodiment 4
The test of pesticide effectiveness.
1 test material
1.1 for examination object：
Eleusine indica
1.2 medicament
Test medicine：BQ-01～BQ-12；
Glyphosate dimethylamine salt single dose（D1）；Glyphosate single dose（D2）；Different n-nonanoic acid dimethylamine salt single dose（D3）；Different n-nonanoic acid single dose
（D4）；Clear water is compareed（CK）.
Wherein, the preparation method of glyphosate dimethylamine salt single dose is：The d1-03 of 50g is taken, 6g dibenzyl xenyl polyoxy second is added
Alkene ether, 44g ethanol, stirs and evenly mixs, and obtains final product.
Different n-nonanoic acid dimethylamine salt single dose preparation method is：The d2-03 of 50g is taken, 6g dibenzyl xenyl polyoxyethylene is added
Ether, 44g ethanol, stirs and evenly mixs, and obtains final product.
The preparation method of glyphosate single dose is：The glyphosate of 50g is taken, 6g dibenzyl xenyl APEOs, 44g is added
Ethanol, stirs and evenly mixs, and obtains final product.
Different n-nonanoic acid single dose preparation method is：The different n-nonanoic acid of 50g is taken, 6g dibenzyl xenyl APEOs, 44g second is added
Alcohol, stirs and evenly mixs, and obtains final product.
2nd, experimental design and method
2.1 dosings numbering see the table below 7
Table 7：
3.2 pilot regions are divided
Trial zone is divided into into 69 experimental plots according to following table, the area of each experimental plot is 30-50m2, each test
Cell is applied respectively the medicament described in above-mentioned table 7 by mark group, and trial zone situation is shown in Table 8, it should be noted that form
In 1-1,1-2,1-3, apply the medicine that medicament numbering is 1, other Testing Team's coding rules are the same.
Table 8：
3.3 dispenser same day weather conditions
The dispenser same day is partly cloudy, 26.4 DEG C of temperature on average, relative humidity 68%, without Precipitation Process, 2-15 days after dispenser, with fine day and
Based on cloudy weather, wherein have within 3 days Precipitation Process, total rainfall 41.9mm, 22.8-31.1 DEG C of temperature, relative humidity 61-75%.
It is experimental field red soil, PH6.2 or so.
3.4 application method
Weeds foliar spray method dispenser, using the manual backpack sprayer of Singapore's JactoHD400 types, per hectare converts liquid 675
Rise.
3.5 drug effect computational methods
Strain number investigation is carried out after investigational agent after 30 days, each treatment region survival weeds strain number, statistic record is investigated.Drug effect computing formula
It is as follows：
And analyze the significance of difference with poor (DMRT) method of the new multipoles of Deng Kenshi.
4 result of the tests
Daily fixed point observation is carried out to the weeds in trial zone, the weeds lobus cardiacus having for 3-7 days after medicine starts chlorosis, stopped within 7-10 days
Growth, starts to wilt afterwards, withered and yellow until dead, causes weeds withered death to be 7-20 days after dispenser.Weed control in 30 days after medicine
Situation see the table below 9.
Table 9：
Note：Data are and value are repeated several times in table.
As shown in Table 9, composition pesticide pair of the present invention containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt mixture
Eleusine indica has preferable preventive effect.
Using composition pesticide made by common reaction method（BQ-01～BQ-06）Preventive effect apparently higher than individually reaction
The composition pesticide being mixed to get afterwards（BQ-07～BQ-012）, it is seen that common reaction is favorably improved adhesive force and permeability, carries
High herbicidal efficiency；And the different nonyl that glyphosate dimethylamine single dose D1 that is prepared from than single glyphosate and different n-nonanoic acid are prepared from
The prevention effect of sour dimethylamine single dose D3 is good, it is seen then that have synergistic function between the product compositions of the present invention.
Meanwhile, the composition pesticide obtained using glyphosate and different n-nonanoic acid compounding（BQ-13～BQ-18）Preventive effect it is also obvious
Higher than glyphosate single dose D2 and different n-nonanoic acid single dose D4, it is seen then that glyphosate and different n-nonanoic acid compounding have synergistic function.
Additionally, having no substantially drift during dispenser.
The above, is only presently preferred embodiments of the present invention, not does any pro forma restriction to the present invention, it is every according to
According to any simple modification, equivalent variations that the technical spirit of the present invention is made to above example, the protection of the present invention is each fallen within
Within the scope of.
Claims (10)
1. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, it is characterised in that：Press including following
The raw material of weight portion meter：1～40 part of glyphosate diformazan ammonium salt, different 1～40 part of n-nonanoic acid diformazan ammonium salt, 2～20 parts of auxiliary agent.
2. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt as claimed in claim 1, it is special
Levy and be：Obtained by reacting in a solvent with dimethylamine after glyphosate, the mixing of different n-nonanoic acid.
3. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt as claimed in claim 1, it is special
Levy and be：The composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt is microemulsion, soluble concentrate or water
Agent.
4. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt as claimed in claim 1, it is special
Levy and be：The soluble concentrate is by 1～10 part of 1～40 part of glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt, dibenzyl biphenyl
1～6 part of base APEO, 1～44 part of absolute ethyl alcohol.
5. a kind of preparation containing glyphosate dimethylamine salt and the composition pesticide of different n-nonanoic acid dimethylamine salt as claimed in claim 1
Method, it is characterised in that：Comprise the following steps：
A. glyphosate, different n-nonanoic acid are weighed by formula, after mixing, by solid-liquid ratio 1:8～12g/ml adds solvent, by glyphosate and
The total amount of different n-nonanoic acid is 1 with the mol ratio of dimethylamine:1～1.2 is added dropwise dimethylamine, after dripping, in 55～95 DEG C of back flow reactions,
Filter, obtain reactant liquor；
B. the reactant liquor for step A being obtained carries out preparation.
6. a kind of preparation containing glyphosate dimethylamine salt and the composition pesticide of different n-nonanoic acid dimethylamine salt as claimed in claim 5
Method, it is characterised in that：In step A, before the glyphosate, the mixing of different n-nonanoic acid, 60～100 mesh sieves are first crossed.
7. a kind of preparation containing glyphosate dimethylamine salt and the composition pesticide of different n-nonanoic acid dimethylamine salt as claimed in claim 5
Method, it is characterised in that：In step A, the solvent is the one kind in methyl alcohol, ethanol, ethyl acetate, acetone, chloroform or water.
8. a kind of preparation containing glyphosate dimethylamine salt and the composition pesticide of different n-nonanoic acid dimethylamine salt as claimed in claim 5
Method, it is characterised in that：In step A, the return time is 0.5～1 h.
9. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt is in preventing and treating crops apples rot
Application.
10. a kind of composition pesticide containing glyphosate dimethylamine salt and different n-nonanoic acid dimethylamine salt as claimed in claim 5 is anti-
Control the application in crops apples rot, it is characterised in that：The composition pesticide is diluted with water to when in use sweet phosphine diformazan
The concentration of amine salt and different n-nonanoic acid dimethylamine salt mixture is 30～40%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611227046.2A CN106614719A (en) | 2016-12-27 | 2016-12-27 | Pesticide composition containing glyphosate dimethylamine salt and isononanoic acid dimethylamine salt, and preparation method and application thereof |
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| CN201611227046.2A CN106614719A (en) | 2016-12-27 | 2016-12-27 | Pesticide composition containing glyphosate dimethylamine salt and isononanoic acid dimethylamine salt, and preparation method and application thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0494386A1 (en) * | 1991-01-08 | 1992-07-15 | Mycogen Corporation | Novel process and composition for controlling weeds |
| CN101723973A (en) * | 2009-12-09 | 2010-06-09 | 浙江新安化工集团股份有限公司 | Method for preparing glyphosate dimethylamine salt solid |
| WO2016156075A1 (en) * | 2015-03-31 | 2016-10-06 | Basf Se | Composition comprising a pesticide and isononanoic acid n,n-dimethyl amide |
-
2016
- 2016-12-27 CN CN201611227046.2A patent/CN106614719A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0494386A1 (en) * | 1991-01-08 | 1992-07-15 | Mycogen Corporation | Novel process and composition for controlling weeds |
| CN101723973A (en) * | 2009-12-09 | 2010-06-09 | 浙江新安化工集团股份有限公司 | Method for preparing glyphosate dimethylamine salt solid |
| WO2016156075A1 (en) * | 2015-03-31 | 2016-10-06 | Basf Se | Composition comprising a pesticide and isononanoic acid n,n-dimethyl amide |
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